|

| |
|||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||| |
|
*6
  

    
O| What is the effect of increase of temperature on equilibrium condition?|

| Gow is chemical equilibrium established?|
| Why concentration of components is constant at the time of equilibrium? |
| What is protic solution?|
| Why isn͛t LowryʹBronsted principle concerned universal?|
| Dn the basis of what can the quantitative tendencies for loosing or accepting protons be
described?|
 | What is self ionization of water? State the effect of temperature on it.|
 | State pG value during 50% and 99.9 neutralization|
 | Îive definition of I.P. and state its relation with Ksp|
O | efine oxidising agent and reducing agent according to modern concept.|
OO | ention step-wise, the redox reaction occurring by Al in silver nitrate solution.|
O
| Gow is the oxidation number of an element in a Gydrogen compound or Gydrogen
compound ion calculated?|
O | What is meant by Stock Notation? When is this method used?|
O | What is used in fulfilling the requirement of oxygen and hydrogen in redox reaction
occurring in acidic medium?|
O | What is meant by electrode?|

  




 (2 arks)

1.| Îive the following information for the reaction showed in above question.
i.| Which reactant undergoes oxidation? In what?
ii.| Which reactant is oxidizing agent?
iii.| Which reactant undergoes reduction? In what?
M | Which reactant is reducing agent?|
2.| Write a short note on hydrogen electrode.(Figure is necessary)
3.| Explain the principle of Lewis acid base.
4.| erive the equation for the ionization constant Kw of water.
5.| Explain hydrolysis of slat made from weak acid and weak base
6.| Îiving examples, explain how a Lewis base is also a LowryʹBronsted base, but all Lewis
acids are not Lowry ʹ Bronsted acids.
7.| Chemical equilibrium is not static but dynamic. Explain
8.| Effect of changes of pressure on equilibrium. iscuss.
9.| Ice melts on applying pressure even below 0º C. EXPLAIN
10.| Equilibrium cannot be reached between water and its vapour in an open vessel

*  




 (3 arks)

1.| iscuss the relation between KC and KP.

| Explain the law of active mass and give formula for constant equilibrium.|
3.| 3.65 x 10ʹ2 gram GCl has been dissolved in 500 ml of solution. Find out its Ph

|
 |

| |
|||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||| |
|
4.| 2 litres of an aqueous solution contain 4.0 g of NaDG. Calculate pG of the solution.
5.| If the value of ionization constant Ka = 1.28 x 10ʹ10 for an aqueous solution of 0.05 
C6G5DG, calculate the concentration of [G ^' D .
6.| Find out pG of a solution of 0.025  CG3CDDNa. Ionization constant of CG3CDDG is 1.75 x
10ʹ5.
7.| Balance the following redox reaction:

|||||||||||||||||||||||||||
 U '  U
 0 ' ' 0 | M
M |
M|

|||||||||||||||||||||||||| 0 '   '  ^ ' 0 ||M |
M|