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(1001CJA103118012) )1001CJA103118012)
CLASSROOM CONTACT PROGRAMME
(Academic Session : 2018 - 2019)
JEE (Main + Advanced)

LEADER & ENTHUSIAST COURSE SCORE(ADVANCED)
Test Type : FULL SYLLABUS Test Pattern : JEE-Advanced
TEST DATE : 14 - 04 - 2019
Time : 3 Hours PAPER – 2 Maximum Marks : 186
READ THE INSTRUCTIONS CAREFULLY
GENERAL :
1. This sealed booklet is your Question Paper. Do not break the seal till you are told
to do so.
2. Use the Optical Response sheet (ORS) provided separately for answering the questions.
DO NOT BREAK THE SEALS WITHOUT BEING INSTRUCTED TO DO SO BY THE INVIGILATOR

3. Blank spaces are provided within this booklet for rough work.
4. Write your name, form number and sign in the space provided on the back cover of this
booklet.
5. After breaking the seal of the booklet, verify that the booklet contains 32 pages and
that all the 18 questions in each subject and along with the options are legible. If not,
contact the invigilator for replacement of the booklet.
6. You are allowed to take away the Question Paper at the end of the examination.
OPTICAL RESPONSE SHEET :
7. The ORS will be collected by the invigilator at the end of the examination.
8. Do not tamper with or mutilate the ORS. Do not use the ORS for rough work.
9. Write your name, form number and sign with pen in the space provided for this purpose
on the ORS. Do not write any of these details anywhere else on the ORS. Darken
the appropriate bubble under each digit of your form number.
DARKENING THE BUBBLES ON THE ORS :

10. Use a BLACK BALL POINT PEN to darken the bubbles on the ORS.
11. Darken the bubble COMPLETELY.
12. The correct way of darkening a bubble is as :

13. The ORS is machine-gradable. Ensure that the bubbles are darkened in the correct
way.
14. Darken the bubbles ONLY IF you are sure of the answer. There is NO WAY to erase
or "un-darken" a darkened bubble.
15. Take g = 10 m/s2 unless otherwise stated.
Please see the last page of this booklet for rest of the instructions
Target : JEE (Main + Advanced) 2019/14-04-2019/Paper-2
SOME USEFUL CONSTANTS

Atomic No. : H = 1, B = 5, C = 6, N = 7, O = 8, F = 9, Al = 13, P = 15, S = 16,
Cl = 17, Br = 35, Xe = 54, Ce = 58
Atomic masses : H = 1, Li = 7, B = 11, C = 12, N = 14, O = 16, F = 19, Na = 23, Mg = 24,
Al = 27, P = 31, S = 32, Cl = 35.5, Ca=40, Fe = 56, Br = 80, I = 127,
Xe = 131, Ba=137, Ce = 140,
· Boltzmann constant k = 1.38 × 10–23 JK–1

1
· Coulomb's law constant = 9 ×10 9
4 pe0
· Universal gravitational constant G = 6.67259 × 10–11 N–m 2 kg–2
· Speed of light in vacuum c = 3 × 108 ms–1
· Stefan–Boltzmann constant s = 5.67 × 10–8 Wm–2 –K–4
· Wien's displacement law constant b = 2.89 × 10–3 m–K
· Permeability of vacuum µ0 = 4p × 10–7 NA–2
1
· Permittivity of vacuum Î0 =
m0 c2
· Planck constant h = 6.63 × 10–34 J–s
Space for Rough Work
E-2/32 1001CJA103118012
Leader & Enthusiast Course/Score(Advanced)/14-04-2019/Paper-2
HAVE CONTROL ¾® HAVE PATIENCE ¾® HAVE CONFIDENCE Þ 100% SUCCESS
BEWARE OF NEGATIVE MARKING
PART-1 : PHYSICS
SECTION–I(i) : (Maximum Marks : 18)
This section contains SIX questions.
Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four options
is correct.
For each question, darken the bubble corresponding to the correct option in the ORS.
For each question, marks will be awarded in one of the following categories :
Full Marks : +3 If only the bubble corresponding to the correct option is darkened.
Zero Marks : 0 If none of the bubbles is darkened.
Negative Marks : –1 In all other cases
1. A block of wood is floating in water such that 1/2 of it is submerged in water. When the same
block is floated in alcohol, 1/3rd of it's volume is submerged. Now a mixture of water and
alcohol is made taking equal volume of both and block is floated in it. What is the % of it's
volume that is now submerged?
(A) 30 (B) 40 (C) 50 (D) 60
1001CJA103118012 E-3/32
2. A long coaxial cable (figure) carries a uniform volume charge density r on the inner cylinder
(radius a), and a uniform surface charge density of the outer cylindrical shell (radius b). This
surface charge is negative and is of just the right magnitude that the cable as a whole is electrically
neutral. Graph between |E| and s (distance from the axis) is best represented by:
b
a
a
b
|E| |E|
(A) (B)
a b s a b s
|E| |E|
(C) (D)
a b s a b s
E-4/32 1001CJA103118012
3. A flat metal spiral (with a constant distance h between coils) and a total number of coils N is
placed in a uniform magnetic field B = B0 cos wt perpendicular to the plane of the spiral
(see figure). The total electromotive force induced in the spiral (between points A and C) is
approximately. (Assume N >> 1)
A
C
2pB0wh 2N 3 sin wt pB0 wh 2N 2 sin wt pB0 wh2N 3 sin wt pB0 wh2N 3 sin wt
(A) (B) (C) (D)
3 3 1 3
4. A tank of cross-sectional area A0 is filled with a non-viscous liquid. A small orifice of area
A (<< A0) is present at the bottom of tank. At a moment the height of liquid in the tank is H,
what is the acceleration of top layer of liquid at this moment ?
2
A æ A ö
(A) g (B) A g (C) ç ÷ g (D) Depends on H
0 è A0 ø
1001CJA103118012 E-5/32
5. Two rods of same length and areas of cross-section A1 and A2 have their ends maintained at
same temperature. If K1 and K2 are their thermal conductivities, C1 and C2 are the specific
heats of their material and r1 & r2 their densities, then for the rate of flow by conduction
through them to be equal,
A1 K1 C2r2 A1 K1 A1 K1C1r1 A1 K 2
(A) A = C r K (B) A = K (C) A = K C r (D) A = K
2 1 1 2 2 2 2 2 2 2 2 1
6. In a long cylinder of liquid of density r, 2 balls of density r1 and r2 are hung by an ideal pulley.
String is taut. Both balls have same volume V. Assume r1 > r > r2. The condition under which
the string remains taut is :
2r1r2 2r1r2 2r1r2 3r1r2

(A) >r (B) <r (C) >r (D) =r
2r1 + r2 r1 + r2 r1 + r2 r1 + r2
E-6/32 1001CJA103118012
SECTION-I(ii) : (Maximum Marks: 32)
This section contains EIGHT questions.
Each question has FOUR options for correct answer(s). ONE OR MORE THAN ONE of
these four option(s) is (are) correct option(s).
For each question, choose the correct option(s) to answer the question.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +4 If only (all) the correct option(s) is (are) chosen.
Partial Marks : +3 If all the four options are correct but ONLY three options are chosen.
Partial Marks : +2 If three or more options are correct but ONLY two options are chosen,
both of which are correct options.
Partial Marks : +1 If two or more options are correct but ONLY one option is chosen
and it is a correct option.
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered).
Negative Marks : –2 In all other cases.
For Example : If first, third and fourth are the ONLY three correct options for a question with
second option being an incorrect option; selecting only all the three correct options will result
in +4 marks. Selecting only two of the three correct options (e.g. the first and fourth options),
without selecting any incorrect option (second option in this case), will result in +2 marks.
Selecting only one of the three correct options (either first or third or fourth option), without
selecting any incorrect option (second option in this case), will result in +1 marks. Selecting
any incorrect option(s) (second option in this case), with or without selection of any correct
option(s) will result in –2 marks.
7. Consider an equilateral prism of refractive index µ. It is found that when light is incident at
an angle 60°, angle of emergence is 'e', while when light is incident at an angle 50°, it undergoes
TIR on the 2nd refracting surface. Choose the CORRECT options :-
(A) A ray incident at an angle 65° will surely emerge from other surface.
(B) A ray incident at an angle of 40° will surely suffer TIR on other surface.
(C) A ray incident at an angle of 50.7°, will surely suffers TIR on other surface.
(D) A ray incident at an angle 59°, may suffer TIR on the other surface.
1001CJA103118012 E-7/32
8. Consider the situation shown in diagram :-
VC VB
A VA
CAR OBSERVER Reflecting wall
Observer hears sound from car directly and also after reflection from the wall. Choose the
CORRECT statement(s) :-
(A) If VB = VC = 0, then beat frequency heard by observer is zero irrespective of VA.
(B) If VA = 0, beat frequency heard by observer is zero irrespective of VB & VC.
(C) If VB ¹ 0, observer will surely hear beat for any value of VA & VC.
(D) For VA = VB = VC, beat frequency heard by observer may be zero.
9. A rod of length l, has linear coefficient of thermal expansion a which is given as

a = a0 + a1x + a2T. The rod is heated from temperature T0 to T1. Then choose the INCORRECT
statement(s) :-
x
x=0 x=l
(A) Dimensional formulae of a0, a1 & a2 are different.

(B) Change in length of small element of length 'dx' is different for different portion of rod.
(C) Total elongation in the rod varies linearly with length 'l' of the rod.
l
(D) Net elongation in the rod is given by Dl = a0l (T1 – T0) + a1 (T1 – T0) + a2l(T12 – T02)
2
E-8/32 1001CJA103118012
10. A medium is separated from other medium of refractive index µ0 by x-z plane. Refractive
index of the medium varies as µ = µ0 – µ1y + µ2y2, choose the CORRECT statement(s). A ray
is incident from the other medium to this medium (µ0, µ1 & µ2 are positive) :-
µ0 + µ2y2 – µ1y
x-z plane
q
µ0
(A) Ray will definitely return in the medium of refractive index µ0.
(B) Ray will never return in the medium of refractive index µ0 for any value of q, µ1 & µ2
(C) If ray crosses a particular y, then it will never return to medium having refractive index µ0.
(D) For ray to not return in medium of refractive index µ0, q < sin -1 éê1 - m1 ùú
2
ë 4m 0 m 2 û
1001CJA103118012 E-9/32
11. An alternating current I(t) = I0cos(wt) (amplitude 0.5 A, frequency 60 Hz) flows down a straight
wire, which runs along the axis of a toroidal coil with rectangular cross section (inner radius
1 cm, outer radius 2 cm, height 1 cm, 1000 turns) as shown in figure. The coil is connected to
a 500 W resistor.
I(t)
(A) emf is induced in the toroid is 2.61 × 10–4 sin (wt) where w = 2p × 60.
2.61 ´ 10-4 sin ( wt )
(B) current in the resistor is where w = 2p × 60.
500
(C) back emf in the coil, due to the current in resistor is –2.74 × 10 –7 cos(wt) where w = 2p × 60.
(D) ratio of the amplitudes of this back emf and the "direct" emf is 1.05 × 10–3.
E-10/32 1001CJA103118012
12. Diagram shows a wedge kept on a rough surface. A ball of mass 'm' is dropped on the slant
face of the wedge. If the collision is perfectly elastic, choose the CORRECT statement(s) :
M=2m
q µ
(A) The ball of mass 'm' may jump to the same maximum height from the point of impact for
some values of q except 0°.
(B) Friction acting between wedge and ground is impulsive in nature.
(C) Momentum of the system (M + m) can be conserved in horizontal direction.
(D) We can choose some axis such that momentum of system (M + m) is conserved along that
axis.
1001CJA103118012 E-11/32
13. Consider two conductors of some shape. Use them in two alternative ways, as a capacitor and
as a resistor as shown in (a) and (b) of figure respectively. In case (a), the space between the
conductors is filled with a homogeneous material of permittivity e while in case (b), it is
filled with a homogeneous material of finite conductivity s.
e s
–Q
a b
e
(A) Value of RC is given by (where R is resistance in case (b) and C is capacitance in
s
case (a)) when conductors are square in shape.
2e
(B) Value of RC is given by (where R is resistance in case (b) and C is capacitance in
s
case (a)) when conductors are square in shape.
(C) Time constant of the system is independent of shape of the conductors when a medium
having permittivity e and conductivity s is inserted between the conductors.
(D) Time constant of the system depends on shape of the conductors when a medium having
permittivity e and conductivity s is inserted between the conductors.
E-12/32 1001CJA103118012
14. A parallel plate capacitor with square plates of side L and plate separation d is charged to a
potential V and disconnected from the battery. It is then vertically inserted into a large
reservoir of dielectric liquid with relative dielectric constant e and density r until the liquid
fills half the space between the capacitor plates as shown in figure :-
L/2
L2e0
(A) The capacitance of the system is (1 + e )
2d
2 V
(B) The electric field strength, between the capacitor plates is .
1+e d
2ee0 V
(C) Charge density over the plates where fluid is present is 4 p (1 + e ) d .
2e0 V
(D) Charge density over the plates where fluid is absent is 4 p (1 + e ) d .
1001CJA103118012 E-13/32
SECTION–I(iii) : (Maximum Marks : 12)
This section contains TWO paragraphs.
Based on each paragraph, there are TWO questions.
Each question has FOUR options (A), (B), (C) and (D) ONLY ONE of these four options
is correct.
Full Marks : +3 If only the bubble corresponding to the correct answer is darkened.
Zero Marks : 0 In all other cases.
Paragraph for Questions 15 and 16
The Fermi-Dirac distribution function, also called Fermi function, provides the probability
of occupancy of energy levels by Fermions. Fermions are half-integer spin particles, which
obey the Pauli exclusion principle. The Fermi-function is given by
1
f ( E) = ( E- EF ) ,
1+e kT
Where k is Boltmann constant, T is temperature in kelvin, f(E) is the probability that an

energy level at energy 'E' in thermal equilibrium with a large system is occupied by a Fermion
and EF is Fermi energy given by
2
h 2 æ 3p 2 N f ö 3
EF = ç ÷ ,
2m0 è V ø
Where Nf is number of fermions, m0 the rest mass of each fermion, V is volume of system and
æ h ö
h is reduced Planck constant ç ÷ .
è 2p ø
Towards the end of a star, depending on the mass of star, it can undergo a red giant phase or
a supernova explosion. The first results in the formation of white dwarf star where helium
fuses to form heavier element while the later results in the formation of neutron star (if mass
of star > 1.5 times mass of sun)
3
In case of white dwarf, the average electron energy is EF , and therefore the total electron
5
3
energy is N f EF . The total energy of the white dwarf, which we assume to be spherical, of
5
uniform density and at a constant temperature, is
2
3 h2 æ 3p2N f ö 3 3 GM2 3
E = Nf ç ÷ - + N a kT + Erad
5 2me è V ø 5 R 2
The second term is the gravitational potential energy, the third term takes into account the
thermal motions of the atoms (Na = number of atoms), and the fourth term gives the energy
radiated by the star. At equilibrium energy of the star must be minimum with respect to
radius.
E-14/32 1001CJA103118012
15. The surface temperature of a white dwarf is approximately 104K, the approx radiant energy,
per unit time is (Assume radius of white dwarf is 7.1 × 103 km)
(A) 2.3 × 1018 MeV/s (B) 2.3 × 1030 MeV/s
(C) 2.3 × 1027 MeV/s (D) 2.3 × 1036 MeV/s
16. Neglecting third and fourth term with respect to first and second and assuming star to be
1
composed of N nucleons and approximately N electrons, the radius of white dwarf is
2
given by :
34 /3 p2/ 3 h2 34 /3 p2/ 3 h2
(A) R = 2
N -1/ 3 (B) R = 2
N -2 /3
4 Gme mn 4 Gme mn
34 /3 p2/ 3 h2 34 /3 p2/ 3 h2
(C) R = N -1/ 3 (D) R = N -2 /3
8 Gme mn2 8 Gme mn2
1001CJA103118012 E-15/32
Magnetic Resonance Imaging (MRI) is a widely used diagnostic technique. It shows internal
organs in minute detail. This technique is based on Nuclear Magnetic Resonance (NMR). Our
tissues mostly contain water and about two thirds of the atoms in human body are 'hydrogen'.
Nucleus of a hydrogen atom is a proton. Proton, like electron, has a spin angular momentum
and also a magnetic moment. Thus proton can be regarded as a tiny magnet. Its spin magnetic
eh
moment is nearly 2.79 µn, where m n = = 5.05 ´ 10 -27 J / T is called a nuclear magneton;
4 pmP
r
here mP is the mass of proton. Let us apply an external magnetic field B and discuss how
proton behaves. Obviously, proton will behave in a manner similar to a magnet placed in an
r
external magnetic field. We know that potential energy of a magnet of magnetic moment m
r
when placed in an external magnetic field B can be expressed as U = µB(1 – cosq), where q is
r r
the angle between m and B . Due to the interaction of external magnetic field and the spin
magnetic moment of proton, energy of the proton becomes quantised resulting in two allowed
state-(1) spin of the proton aligned with the magnetic field-(2) spin of the proton antialigned
i.e., opposite to field. These states will have different energy. In fact, the energy difference
between the two states is very small and photons whose energy matches the energy gap can
cause transitions of protons between the two energy states. These transitions are called
spin-flip transitions. A set-up for conducting such experiment is shown in figure. A coil is
wrapped around the sample and alternating current of variable frequency is made to pass in
the coil. Protons in the sample absorb power from the coil when frequency of current in the
coil is the same as required to induce transitions between the two energy states of
protons. This is called Resonance absorption of energy and the technique called
'Nuclear Magnetic Resonance'. With B = 1.5 T and, as mentioned above, spin magnetic moment
of proton = 2.79 µn, (µn = 5.05 × 10–27 J/T), answer the following questions.
Absorption
NMR signal
N S
Frequency
E-16/32 1001CJA103118012
17. Which state lies lower in energy?
(A) The state where proton spin component is parallel to external magnetic field.
(B) The state where proton spin component is antiparallel to external magnetic field.
(C) The state where proton spin component is perpendicular to external magnetic field.
(D) The state where proton spin component is inclined 60° to the external magnetic field.
18. As mentioned earlier, the widely used diagnostic technique 'Magnetic Resonance Imaging'
(MRI) employs NMR (spin-flip transitions). Compared to techniques that use X-rays and
g-rays which have energies in the range 104 – 106 eV,
(A) MRI causes a greater cellular damage since the photons associated with transitions used
in MRI are of greater energy and, in fact, much greater than 10 6 eV
(B) MRI causes equal cellular damage since the photons associated with transitions used in
MRI are of comparable energy
(C) MRI causes a greater cellular damage since the photons associated with transitions used
in MRI though these are comparable energy, but their flux is quite large
(D) MRI causes quite an insignificant cellular damage since the photons associated with
transitions used in MRI are of a much smaller energy which is generally of the order of
10 –7 eV
1001CJA103118012 E-17/32
PART-2 : CHEMISTRY
is correct.
1. For following conductomeric titration :
NaOH
HCl
+
CH3COOH
Correct plot is :
(A) Conductance (B) Conductance
Volume of titrate Volume of titrate
Conductance Conductance
(C) (D)
Volume of titrate Volume of titrate
E-18/32 1001CJA103118012
2. 5 litres of a freshly prepared aqueous solution has 0.03 M CaCl2 and 0.05 M Na2SO4. If Ksp
for CaSO4 is 2.4 × 10–5. Find number of moles of precipitate obtained finally :
(A) 4.08 g (B) 6.8 g (C) 20.4 g (D) 34 g
3. For a second order reaction value of rate constant is 1.5 × 107 M–1S–1 and 4.5 × 107 M–1 S–1 at
227°C and 727°C respectively. Value of activation energy for the reaction is : [ln3 = 1.1]
(A) 1.1 Kcal mol–1 (B) 2.2 Kcal mol–1 (C) 2.8 Kcal mol–1 (D) 3.3 Kcal mol–1
4. Which of the following complex is paramagnetic and high spin ?
(A) [Cr(H2O)6]3Å (B) [Fe(H2O)6]3Å (C) [Ni(H2O)6]2Å (D) [Ti(H2O)6]3Å
5. Identify disacelaride with a-L-Glucossidic linkage ?
CH2OH OH OH OH
O O O
H CH2 O CH2OH
(A) OH (B) OH HO
H
H HO
O H HO O OH
HO
H OH OH OH
OH H
HO O O O H O
O HO OH OH
OH HO
OH OH
(C) (D) O OH
OH
HO OH HO OH OH OH
O
CºCH
D
¾¾¾¾ ® ¾¾¾¾
dil. H SO
6. ¾® ¾¾® X , X is :
2 4 (i) I2 / NaOH
HgSO4 +
(ii) H
COOH
(A) (B) (C) (D)
1001CJA103118012 E-19/32
7. A solution of volatile components A and B has total vapour pressure of 200 torr. If this solution
contains 1 mol A and 2 mol B.
Given : PAo = 150 torr
PBo = 240 torr
Identify incorrect option(s) :
(A) The plot between boiling point of solution and composition of mixture will show a minima.
(B) At a particular compostion vapour pressure of solution will minimize.
(C) Interactions of type [A–B] are stronger than pure [A–A] and [B–B] interactions.
(D) At a particular composition minimum boiling azetrope is formed by mixing A and B.
E-20/32 1001CJA103118012
8. Identify correct statement(s) regarding colloidal mixtures :
(A) Colloids made of proteins (dispersed phase) may be positively or negatively charged
depending on pH of solution.
(B) Blue colour of sky is an example of Tyndall effect.
(C) Egg albumin in water is an example of multi-molecular colloid.
(D) Purification of water by addition of alum is an example of coagulation.
9. Let r = radius of atom packed in different possible arrangements. Identify correct option(s) :
(A) If these atoms are packed in ccp or hcp arrangements nearest inter-planar distance in
é 2ù
both would be ê 2r 3 ú
ëê ûú
(B) If these atoms are packed in HCP arrangement nearest octa-void and tetra-void distance
é 3ù
would be ê r 2 ú .
ëê úû
(C) If packed in HCP arrangement volume of unit cell is éë24 3r ùû
3
(D) Both HCP and CCP arrangements have same void fraction.
10. Which of the following complex show optical isomerism but don't show geometrical isomerism?
(A) [Ni(en)3]2+ (B) [Ni(en)2Cl2] (C) [Ni(DMG) 2] (D) [Cr(acac)2]!
11. Which of the following order is correct
(A) B.P. PH3 < AsH3 < SbH3 < NH3
(B) M.P. PH3 < AsH3 < SbH3 < NH3
(C) B.P. HCl < HBr < HI < HF
(D) M.P. HCl < HBr < HI < HF
12. Which of the following ore/s is/are concentrated by Froth floatation method?
(A) Galena (B) Sphelerite (C) Cinnabar (D) Zincite
1001CJA103118012 E-21/32
13. Identify correct statement/s for following reaction sequence?
Br D
F NaCN NaOEt
(P) NC
DMSO EtOD / D
[O] [Q]
(A) ‘P’ product formation occur through ‘SN2’ mechanism

(B) P ¾® Q conversion is 2nd order reaction
(C) P ¾® Q step is E1 CB reaction
(D) ‘O’ compound on dehalogenation and polymerisation give polystyrene.
14. Identify reaction’s or sequence of reactions give hexamethyl benzene as one of the product?
COOH
Conc. NaOH
(A) H2SO4 (B) CaO /D
O HOOC COOH
CHO N – NH2
O
Zn – Hg / HCl EtO / HO OH
excess D
(C) (D)
CHO N – NH2
E-22/32 1001CJA103118012
is correct.
According to molecular orbital theory when a pair of atomic orbitals combine they give rise
to a pair of molecular orbitals. The number of molecular orbitals produced must always be
equal to the number of atomic orbitals involved.
15. Which of the following is correct?
(A) HOMO of O 2 molecule is gerade
(B) LUMO of O2 molecule is gerade
(C) HOMO of N2 molecule is ungerade
(D) LUMO of N2 molecule is ungerade
16. Which of the following have shortest N–N bond length?
(A) N 22Å (B) N 22! (C) N Å2 (D) N 2-
1001CJA103118012 E-23/32
Pd / BaSO4 / H2 Br2 + H2O Conc. HBr
Me – C º C – Me ¾¾¾¾¾¾ ¾
® (Q) ¾¾¾¾¾ ® (S) ¾¾¾¾¾ ® (T)
(P) ( ±) ( ±)
17. In above reaction sequence identify ‘T’ product?
Me Me Me Me
(A) H OH (B) H Br (C) H Br (D) H Br
H OH HO H Br H H Br
Me Me Me Me
(±) (±)
18. Identify ‘X’ product in above sequence?

O
(1) N Na
(1) Red P + X 2 C
1% HgSO4 (1) NaOH (2) EtOH / H+ O
'P' (A) B + yellow ppt (C) 'X'
dil. H2 SO4 (2) H + +
(2) H3O
(A) Glycine (B) Phenyl alanine (C) Alanine (D) Valine

E-24/32 1001CJA103118012
PART-3 : MATHEMATICS
is correct.
1. A bag initially contains 1 red and 3 blue balls. An experiment consisting of selecting a ball at
random, noting down its colour and replacing it with an additional ball of same colour. (Balls
of both colours are in abundance). If three such trials are made, then
3
(A) Probability that exactly one blue ball is drawn is
20
7
(B) Probability that exactly one blue ball is drawn is
20
9
(C) Probability that atleast one blue ball is drawn is
20
7
(D) Probability that atleast one blue ball is drawn is
20
2. Locus of curve represented by equation |Z – (1 + i) cosq| + |Z – (1 – i) sinq|= 2 (where q is
constant, i = -1 and Z Î £) is
(A) circle (B) parabola (C) ellipse (D) hyperbola

3. Let ƒ(x) is an even function such that ƒ(x) + ƒ(x – l) = x(x – l) + l2, l > 0, then value of
12 æl ƒ (x ) ö
å çç ò 2
l= 1 è 0 x - l x + l
2
dx ÷÷ is-
ø
(A) 144 (B) 12 (C) 6 (D) 39

1001CJA103118012 E-25/32
æ 2018 2019 ö
4. The value of lim ç 2018
- ÷ is
x ®1 è 1 - x 1 - x 2019 ø
1 1
(A) 0 (B) - (C) (D) does not exist
2 2
5. For x Î (0, 5p), the equation tan–1(2sinx) = cot–1(cosx) has
(A) infinite many solutions
(B) three solutions
(C) five solutions
(D) no solution
6. The locus of foot of perpendicular drawn from origin upon any tangent of parabola
y2 = 8(x–1) is
(A) x3 + xy2 + 2y2 + x2 = 0 (B) x3 – xy2 + 2y2 – x2 = 0
(C) x3 – xy2 + 2y2 + x2 = 0 (D) x3 + xy2 + 2y2 – x2 = 0
E-26/32 1001CJA103118012
7. If the polynomial P(x) = 24x4 + l1x3 + l2x2 + l3x + 1, where l1,l2,l3 Î R has four positive real
roots a,b,g,d such that a + 2b + 3g + 4d = 4, then
(A) l1 + l2 + l3 = –25 (B) l1 = –50 (C) l3 = –10 (D) l2 = 25
8. Consider differential equation y1y3 = 3(y2)2 (where yi is the ith derivative of y and y = ƒ(x) is
thrice differentiable function), then-
d 2 y dy
(A) = (B) y = ax2 + bx + c, where a,b,c Î ¡
dx 2 dx
d2x dy
(C) = (D) x = ay2 + by + c, where a,b,c Î ¡
dy2 dx
1001CJA103118012 E-27/32
9. Consider two function ƒ(x) = x3 and g(x) = 2x, then
æ 1 ö
(A) lim g ( x ) sin ç
x ®0 ç ƒ ( x ) ÷÷ does not exist
è ø
(B) y = ƒ(x) |g(x)| is differentiable everywhere
32
(C) area bounded by curve y2 = ƒ(x) and |y|= g(x) is square units
5
(D) y = |ƒ(x)| + |g(x)| is differentiable everywhere
2020
Let ƒ be a real valued function defined on ¡ such that ƒ ' ( x ) = Õ (x - r)

r
10. and g is a function
r =1
ò (e )
- g ( x - t ) dt = 2019x + 2020 , then
ƒ (t )
defined on ¡ such that
0
(A) ƒ has 505 points of local maximum (B) ƒ has 505 points of local minimum
(C) g has 505 points of local maximum (D) g has 505 points of local minimum
é x 2018 x 2019 + 2018 x 2020 - 2019 ù

ê ú
11. Consider matrix A = êx 2020 - 2018 x 2019 x 2018 + 2020 ú ,x Î ¡ and ƒ(x) = det(A), then-
ê x 2019 + 2019 x 2018 - 2020 x 2020 ú
ë û
(A) curve y = ƒ(x) passes through origin (B) x-axis is tangent to curve at origin
(C) y-axis is tangent to curve at origin (D) matrix A can never be an identity matrix
12. From a point P on curve S1 : + x2 y2
= 8, a pair of tangents are drawn to curve S2 : x2 + y2 = 4
touching S2 at points A and B then
(A) length of chord AB is 2 2 units (B) length of chord AB is 4 units

(C) area of triangle PAB is 2 sq. units (D) area of triangle PAB is 4 sq. units
2
x y2
13. The equations of tangent to hyperbola - = 1 which are parallel to line y = 2x – 1, are
9 4
(A) y = 2x - 4 2 (B) y = 2x - 2 10 (C) y = 2x + 4 2 (D) y = 2x + 2 10
14.
r r r
If a,b,c are three non zero non coplanar vectors then
r r r r r r r r r r r r r r r
(A) ëéa - b b - c c - a ûù = 0 (B) éëa + b b + c c + a ùû = 2 éëa b c ùû
r r r r r r r r r r r r r r r 2
(C) éëa ´ b b ´ c c ´ a ùû = 0 (D) éë a ´ b b ´ c c ´ a ùû = éëa b c ùû
E-28/32 1001CJA103118012
is correct.
Let P(Z), Z Î £ is a point in complex plane which satisfies relation Z + Z + 4 Z - Z = 34 and
A1 is area of region bounded by locus of P(Z).

A2 is area bounded by the polygon formed by joining those points of locus of P(Z) for which
|Z| is minimum
15. Value of A1 is -
289 289
(A) 289 (B) (C) (D) 34
2 4
16. Value of A2 is -
(A) 16 (B) 8 (C) 4 (D) 289
1001CJA103118012 E-29/32
Consider a plane P whose equation is x – y = 0 and two points A(3,2,4) and B(7,0,–10)
17. Coordinates of point P, which lies on plane P such that |PA + PB| is minimum, are-
æ 21 21 9 ö æ 21 21 9 ö æ 21 21 9 ö
(A) (21,21,9) (B) ç , , ÷ (C) ç , , ÷ (D) ç , , ÷
è 4 4 4ø è 8 8 4ø è 16 16 16 ø
uuur
18. Angle between AB and vector perpendicular to plane P is-
-1 æ 1 ö p -1 æ 1 ö -1 æ 1 ö
(A) cos ç ÷ (B) (C) cos ç ÷ (D) cos ç ÷
è2 3ø 4 è6ø è 12 ø
E-30/32 1001CJA103118012
ADMISSION ANNOUNCEMENT
CLASSROOM CONTACT PROGRAMMES (Session : 2019-20)
KOTA CENTER
IIT-JEE : JEE(Main+Advanced) JEE (Main)
Courses Medium Course Classes Admission Courses Medium Course Classes Admission
Code Mode Code Mode
NURTURE PH-I English 1001 03/04/2019 ASAT/TALLENTEX NURTURE PH-I Eng/Hindi 2001 01/04/2019 Direct
NURTURE PH-II Eng/Hindi 1002 15/04/2019 ASAT/TALLENTEX NURTURE PH-II Eng/Hindi 2002 15/04/2019 Direct
NURTURE PH-III English 1003 29/04/2019 ASAT/TALLENTEX NURTURE PH-III Eng/Hindi 2003 15/05/2019 Direct
NURTURE PH-IV Eng/Hindi 1004 13/05/2019 ASAT/TALLENTEX ENTHUSIAST PH-I Eng/Hindi 2021 01/04/2019 Direct
ENTHUSIAST PH-II Eng/Hindi 1022 01/04/2019 Direct ENTHUSIAST PH-II Eng/Hindi 2022 06/05/2019 Direct
ENTHUSIAST PH-III Eng/Hindi 1023 08/05/2019 Direct ENTHUSIAST PH-III Eng/Hindi 2023 27/05/2019 Direct
LEADER PH-I Eng/Hindi 1031 24/04/2019 Through ASAT LEADER PH-I Eng/Hindi 2031 24/04/2019 Direct
LEADER PH-II Eng/Hindi 1032 08/05/2019 Through ASAT LEADER PH-II Eng/Hindi 2032 06/05/2019 Direct
LEADER PH-III Eng/Hindi 1033 29/05/2019 Through ASAT LEADER PH-III Eng/Hindi 2033 27/05/2019 Direct
PRE-MEDICAL (NEET-UG & AIIMS)

Courses Medium Course Code Classes Admission Mode
NURTURE PH-I English 3001 07/04/2019 Direct
NURTURE PH-II English/Hindi 3002 21/04/2019 Direct
NURTURE PH-III English 3003 19/05/2019 Direct
NURTURE PH-III(B) English 3261 20/05/2019 Direct
ENTHUSIAST PH-I English/Hindi 3021 01/04/2019 Direct
ENTHUSIAST PH-II English/Hindi 3022 15/05/2019 Direct
LEADER PH-I English/Hindi 3031 08/04/2019 Direct
LEADER PH-II English/Hindi 3032 29/04/2019 Direct
LEADER PH-III English/Hindi 3033 20/05/2019 Direct
ACHIEVER PH-I English/Hindi 3051 15/05/2019 Direct
ACHIEVER PH-II English/Hindi 3052 03/06/2019 Direct
For JEE (Adv.) | JEE (Main) | NEET | AIIMS

NTSE | OLYMPIADS | PNCF | Class 6th to 12th
To Apply online Log on to www.allen.ac.in or walk-in to nearest ALLEN Center for Application Form
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1001CJA103118012 E-31/32
QUESTION PAPER FORMAT AND MARKING SCHEME :
16. The question paper has three parts : Physics, Chemistry and Mathematics.
17. Each part has one section as detailed in the following table.
Que. No. Category-wise Marks for Each Question Maximum

Section Type of Full Partial Zero Negative Marks of the
Que. Marks Marks Marks Marks section
+3 0 –1
I(i) Single If only the bubble If none In all
correct option 6 corresponding to — of the other 18
the correct option bubbles is cases
is darkened darkened
+4 +1 0 –2
One or more If only the bubble(s) For darkening a bubble If none In all
I(ii) correct corresponding corresponding to each of the other
option(s) 8 to all the correct correct option, provided bubbles is cases 32
option(s) is(are) NO incorrect option darkened
darkened darkened
Paragraph +3 0
Based If only the bubble In all
I(iii) (Single 4 corresponding to — other — 12
correct the correct option cases
option) is darkened
NAME OF THE CANDIDATE ................................................................................................
FORM NO. .............................................
I have read all the instructions I have verified the identity, name and Form
and shall abide by them. number of the candidate, and that question
paper and ORS codes are the same.
____________________________ ____________________________
Signature of the Candidate Signature of the Invigilator
Corporate Office : ALLEN CAREER INSTITUTE, “SANKALP”, CP-6, Indra Vihar, Kota (Rajasthan) INDIA 324005
+91-744-2757575 info@allen.ac.in www.allen.ac.in
E-32/32 Your Target is to secure Good Rank in JEE 2019 1001CJA103118012
Paper Code
(1001CJA103118012) )1001CJA103118012)
CLASSROOM CONTACT PROGRAMME
HINDI
(Academic Session : 2018 - 2019)
JEE (Main + Advanced)

LEADER & ENTHUSIAST COURSE SCORE(ADVANCED)
Test Type : FULL SYLLABUS Test Pattern : JEE-Advanced
TEST DATE : 14 - 04 - 2019
Time : 3 Hours PAPER – 2 Maximum Marks : 186
Ïi;k bu funsZ'kksa dks /;ku ls i<+sa

lkekU; %
1. ;g eksgjcU/k iqfLrdk vkidk iz'ui= gAS bldh eqgj rc rd u rksM+s tc rd bldk funsZ'k u fn;k tk;sA
2. iz'uksa dk mÙkj nsus ds fy, vyx ls nh x;h vkWfIVdy fjLikal 'khV (vks- vkj- ,l-) (ORS) dk mi;ksx djsaA
3. dPps dk;Z ds fy, bl iqfLrdk esa [kkyh LFkku fn;s x;s gaAS
4. bl iqfLrdk ds fiNys i`"B ij fn, x, LFkku esa viuk uke o QkWeZ uEcj fyf[k, ,oa gLrk{kj cukb;sA
5. bl iqfLrdk dh eqgj rksM+us ds ckn Ïi;k tk¡p ysa fd blesa 32 i`"B gaS vkjS izR;sd fo"k; ds lHkh 18 iz'u vkjS muds mÙkj
fodYi Bhd ls i<+s tk ldrs gaSA ;fn ugha] rks iz'ui= dks cnyus ds fy, fujh{kd ls lEidZ djsaA
fujh{kd ds vuqns'kksa ds fcuk eq gjs a u rks M + s

6. ijh{kkFkhZ iz'ui= dks ijh{kk dh lekIrh ij ys tk ldrs gaAS
vkW f IVdy fjLika l 'khV (vks - vkj-,l-) %
7. vks- vkj- ,l- dks ijh{kk ds lekiu ij fujh{kd ds }kjk ,d= dj fy;k tk,xkA
8. vks- vkj- ,l- esa gsj&Qsj@foÏfr u djsaA vks - vkj-,l- dk dPps dke ds fy, iz ;ks x u djs a A
9. viuk uke vkSj QkWeZ uEcj vks-vkj-,l- esa fn, x, [kkuksa esa dye ls fy[ksa vkSj vius gLrk{kj djsaA buesa ls dksbZ Hkh fooj.k
vks - vkj-,l- es a dgha vkSj u fy[ks a A QkWeZ uEcj ds gj vad ds uhps vuq:i cqycqys dks dkyk djsaA
vks - vkj-,l- ij cq ycq yks a dks dkyk djus dh fof/k :
10. vks-vkj-,l- ds cqycqyksa dks dkys ckWy ikWbUV dye ls dkyk djsaA
11. cqycqys dks iw .k± :i ls dkyk djsaA
12. cqycqys dks dkyk djus dk mi;qDr rjhdk gS :
13. vks-vkj-,l- e'khu tk¡P; gAS lqfuf'pr djsa dh cqycqys lgh fof/k ls dkys fd, x;sa gaSA
14. cqycqys dks rHkh dkyk djsa tc vki mÙkj ds ckjs esa fuf'pr gksA dkys fd, gq, cqycqys dks feVkus vFkok lkQ djus dk dksbZ
rjhdk ugha gAS
15. g = 10 m/s2 iz;qDr djsa] tc rd fd vU; dksbZ eku ugha fn;k x;k gksA
Ïi;k 'ks "k funs Z' kks a ds fy, bl iqfLrdk ds vfUre i`"B dks i<+s aA
SOME USEFUL CONSTANTS

Atomic No. : H = 1, B = 5, C = 6, N = 7, O = 8, F = 9, Al = 13, P = 15, S = 16,
Cl = 17, Br = 35, Xe = 54, Ce = 58
Atomic masses : H = 1, Li = 7, B = 11, C = 12, N = 14, O = 16, F = 19, Na = 23, Mg = 24,
Al = 27, P = 31, S = 32, Cl = 35.5, Ca=40, Fe = 56, Br = 80, I = 127,
Xe = 131, Ba=137, Ce = 140,
· Boltzmann constant k = 1.38 × 10–23 JK–1
1
· Coulomb's law constant = 9 ×10 9
4 pe0
· Universal gravitational constant G = 6.67259 × 10–11 N–m 2 kg–2
· Speed of light in vacuum c = 3 × 108 ms–1
· Stefan–Boltzmann constant s = 5.67 × 10–8 Wm–2 –K–4
· Wien's displacement law constant b = 2.89 × 10–3 m–K
· Permeability of vacuum µ0 = 4p × 10–7 NA–2
1
· Permittivity of vacuum Î0 =
m0 c2
· Planck constant h = 6.63 × 10–34 J–s
dPps dk;Z ds fy, LFkku
H-2/32 1001CJA103118012
HAVE CONTROL ¾® HAVE PATIENCE ¾® HAVE CONFIDENCE Þ 100% SUCCESS
BEWARE OF NEGATIVE MARKING
Hkkx-1 : Hkk Sfrd foKku
[k.M –I(i) : (vf/kdre vad : 18)
bl [k.M esa N% iz 'u gSa
izR;sd iz'u esa pkj mÙkj fodYi (A), (B), (C) vkjS (D) gSaA ftuesa dso y ,d gh lgh gaSA
izR;sd iz'u ds fy , vks-vkj-,l ij lgh mÙkj fodYi ds vuq:i cqycqys dks dkyk djsaA
izR;sd iz'u ds fy , vad fuEufyf[kr ifjfLFkfr;ksa esa ls fdlh ,d ds vuq l kj fn;s tk,ax s %
iw.kZ vad : +3 ;fn flQZ lgh fodYi ds vuq:i cqycqys dks dkyk fd;k gSA
'kwU; vad : 0 ;fn fdlh Hkh cqycqys dks dkyk ugha fd;k gSA
½.k vad : –1 vU; lHkh ifjfLFkfr;ksa esaA
1. ydM+h dk ,d CykWd ty esa bl izdkj rjS jgk gS fd bldk 1/2 Hkkx ty esa Mwck jgrk gSA tc blh CykWd dks ,Ydksgy
esa rjS k;k tkrk gS rks bldk 1/3 xquk vk;ru Mwc tkrk gAS vc ty rFkk ,Ydksgy nksuksa ds leku vk;ru dks ysdj ,d
feJ.k cuk;k tkrk gS rFkk blesa CykWd dks rjS k;k tkrk gAS vc bl feJ.k esa blds vk;ru dk fdruk izfr'kr Hkkx Mwc
tk;sxk\
(A) 30 (B) 40 (C) 50 (D) 60
1001CJA103118012 H-3/32
2. ,d yEch lek{kh; dscy ds vkarfjd csyu (f=T;k a) ij ,dleku vk;ru vkos'k ?kuRo r fo|eku gS rFkk ckg~;
csyukdkj dks' k (f=T;k b) ij ,dleku i`"Bh; vkos'k ?kuRo fo|eku gSA ;g i`"Bh; vkos'k ½.kkRed gS rFkk Bhd
dscy ds leku ifjek.k okyk gS ftlds QyLo:i ;g fo|q r :i ls mnklhu gks tkrk gSA |E| o s (v{k ls nw jh) ds
eè; lokZf/kd lgh vkjs[k gS %&
b
a
a
b
|E| |E|
(A) (B)
a b s a b s
|E| |E|
(C) (D)
a b s a b s
H-4/32 1001CJA103118012
3. ,d lery /kkfRod Likbjy dh dq.Mfy;ksa ds e/; fu;r nwjh h gS rFkk dq.Mfy;ksa dh dqy la[;k N gAS bls fp=kuqlkj
Likbjy ds ry ds yEcor~ le:i pqEcdh; {ks= B = B0 cos wt esa j[kk tkrk gSA Likbjy esa fcUnqvksa A o C ds e/;
izsfjr dqy fo|qr okgd cy dk yxHkx eku gksxk%&(ekuk N >> 1 g)S
A
C
2pB0wh 2N 3 sin wt pB0 wh 2N 2 sin wt pB0 wh2N 3 sin wt pB0 wh2N 3 sin wt
(A) (B) (C) (D)
3 3 1 3
4. vuqizLFkdkV {ks=Qy A0 okys ,d VaSd dks v';ku æo ls Hkjk tkrk gAS {ks=Qy A (<< A0) okyk ,d NksVk fNæ bl VaSd
ds iaSns ij fLFkr gAS fdlh {k.k tc Vad
S eas æo dh Å¡pkbZ H gksrh g]S ml {k.k æo dh Åijh ijr dk Roj.k D;k gksxk\
2
A æ A ö
(A) g (B) g (C) ç ÷ g (D) H ij fuHkZj djrk gAS
A0 è A0 ø
1001CJA103118012 H-5/32
5. leku yEckbZ rFkk vuqizLFkdkV {ks=Qy A1 o A2 okyh nks NM+kas ds fljs leku rkieku ij vuqjf{kr gAS ;fn K1 o K2
budh rkih; pkydrk;sa] C1 o C2 buds inkFkZ dh fof'k"V Å"ek;sa rFkk r1 o r2 buds ?kuRo gS rc buls pkyu }kjk izokg
dh nj leku gksus ds fy;s %&
A1 K1 C2r2 A1 K1 A1 K1C1r1 A1 K 2
(A) A = C r K (B) A = K (C) A = K C r (D) A = K
2 1 1 2 2 2 2 2 2 2 2 1
6. ?kuRo r okys æo ls Hkjs ,d yEcs csyu esa ?kuRo r1 o r2 okyh nks xsanks dks ,d vkn'kZ f?kjuh }kjk yVdk;k x;k gAS jLlh
ruh gqbZ gAS nksuksa xasnks dk leku vk;ru V gAS ekuk r1 > r > r2 gAS fdl fLFkfr esa jLlh ruh gqbZ jgrh g\
S
2r1r2 2r1r2 2r1r2 3r1r2

(A) >r (B) <r (C) >r (D) =r
2r1 + r2 r1 + r2 r1 + r2 r1 + r2
H-6/32 1001CJA103118012
[kaM -I(ii) : (vf/kdre vad : 32)
bl [kaM esa vkB iz'u gSaA
izR;sd iz'u ds lgh mÙkj (mÙkjksa) ds fy, pkj fodYi fn, x, gAaS bl pkj fodYiksa esa ls ,d ;k ,d ls vfèkd
fodYi lgh gS(gSa)A
izR;sd iz'u ds fy,] iz'u dk (ds) mÙkj nsus gsrq lgh fodYi (fodYiksa) dks pqusA
izR;sd iz'u ds mÙkj dk ewY;kadu fuEu vadu ;kstuk ds vuqlkj gksxk %
iw.kZ vad : +4 ;fn dsoy (lkjs) lgh fodYi (fodYiksa) dks pquk x;k gSA
vkaf'kd vad : +3 ;fn pkjksa fodYi lgh gSa ijUrq dsoy rhu fodYiksa dks pquk x;k gSA
vkaf'kd vad : +2 ;fn rhu ;k rhu ls vf/kd fodYi lgh gaS ijUrq dsoy nks fodYiksa dks pquk x;k gS vkjS
pqus gq, nksuksa fodYi lgh fodYi gSaA
vkaf'kd vad : +1 ;fn nks ;k nks ls vf/kd fodYi lgh gSa ijUrq dsoy ,d fodYi dks pquk x;k gS vkSj
pquk gqvk fodYi lgh fodYi gSaA
'kwU; vad : 0 ;fn fdlh Hkh fodYi dks ugha pquk x;k gS (vFkkZr~ iz'u vuqÙkfjr g)S A
mnkgj.k Lo:i % ;fn fdlh iz'u ds fy , dsoy igyk] rhljk ,oa pkSFkk lgh fodYi gaS vkjS nwljk fodYi xyr
gS_ rks ds oy lHkh rhu lgh fodYiks a dk p;u djus ij gh +4 va d feys axs aA fcuk dks bZ xyr fodYi pq us
(bl mnkgj.k esa nwljk fodYi) rhu lgh fodYiksa esa ls flQZ nks dks pquus ij (mnkgj.kr% igyk rFkk pkFS kk fodYi)
+2 vad feysaxsA fcuk dksbZ xyr fodYi pqus (bl mnkgj.k esa nwljk fodYi)] rhu lgh fodYiksa esas ls flQZ ,d
dks pquus ij (igyk ;k rhljk ;k pkFS kk fodYi) +1 vad feysaxsA dksbZ Hkh xyr fodYi pquus ij (bl mnkgj.k
esa nwljk fodYi), –2 vad feysaxs] pkgs lgh fodYi (fodYiksa) dks pquk x;k gks ;k u pquk x;k gksA
7. viorZukad µ okys ,d leckgq fizTe ij fopkj dhft;sA ;g ns[kk x;k gS fd tc bl ij izdk'k 60° dks.k ij vkifrr
gksrk gS rks fuxZeu dks.k 'e' gksrk gS tcfd tc izdk'k 50° dks.k ij vkifrr gksrk gS rks ;g f}rh; viorZd lrg ij iw.kZ
vkarfjd ijkorZu ls xqtjrh gAS lgh fodYi@fodYiksa dks pqfu;sA
(A) 65° dks.k ij vkifrr fdj.k fuf'pr :i ls nwljh lrg ls fuxZfer gks tk;sxhA
(B) 40° dks.k ij vkifrr fdj.k fuf'pr :i ls vU; lrg ij iw.kZ vkarfjd ijkorZu n'kkZ;sxhA
(C) 50.7° dks.k ij vkifrr fdj.k fuf'pr :i ls vU; lrg ij iw.kZ vkarfjd ijkorZu n'kkZ;sxhA
(D) 59° dks.k ij vkifrr fdj.k vU; lrg ij iw.kZ vkarfjd ijkorZu n'kkZ ldrh gAS
1001CJA103118012 H-7/32
8. iznf'kZr fLFkfr ij fopkj dhft;sA
VC VB
A VA
CAR OBSERVER Reflecting wall
izs{kd lh/ks dkj ls vkus okyh /ofu rFkk nhokj ls ijkorZu ds i'pkr~ vkus okyh /ofu nksuksa dks lqurk gSA lgh
dFku@dFkuksa dks pqfu;s%&
(A) ;fn VB = VC = 0 gks rks iz{s kd }kjk lquh x;h foLiUn vko`fÙk 'kwU; gksxh pkgs VA dqN Hkh gksA
(B) ;fn VA = 0 gks rks iz{s kd }kjk lquh x;h foLiUn vko`fÙk 'kwU; gksxh pkgs VB o VC dqN Hkh gksA
(C) ;fn VB ¹ 0 gks rks izs{kd dks VA o VC ds fdlh Hkh eku ds fy;s fuf'pr :i ls foLiUn lqukbZ nsxkA
(D) VA = VB = VC ds fy;s izs{kd }kjk lquh x;h foLiUn vko`fÙk 'kwU; gks ldrh gAS
9. yEckbZ l okyh ,d NM+ ds fy;s js[kh; rkih; izlkj xq.kkad a = a0 + a1x + a2T }kjk fn;k tkrk gSA NM+ dks rkieku T0
ls T1 rd xeZ fd;k tkrk gAS xyr dFku@dFkuksa dks pqfu;s%&
x
x=0 x=l
(A) a0, a1 o a2 ds foeh; lw= fHkUu&fHkUu gAS

(B) NM+ ds fofHkUu Hkkxksa ds fy;s yEckbZ ds y?kq vYika'k dh yEckbZ esa ifjorZu 'dx' fHkUu&fHkUu gksxkA
(C) NM+ esa dqy foLrkj NM+ dh yEckbZ 'l' ds lkFk jfS [kd :i ls ifjofrZr gksrk gAS
l
(D) NM+ esa dqy foLrkj Dl = a0l (T1 – T0) + a1 (T – T0) + a2l(T12 – T02) }kjk fn;k tkrk gAS
2 1
H-8/32 1001CJA103118012
10. ,d ek/;e x-z ry }kjk µ0 viorZukad okys ,d vU; ek/;e ls i`Fkd gAS ek/;e dk viorZukad µ = µ0 – µ1y + µ2y2
ds vuqlkj ifjofrZr gksrk gAS lgh dFku@dFkuksa dks pqfu;sA ,d fdj.k vU; ek/;e ls bl ek/;e ij vkifrr gksrh gAS
(µ0, µ1 o µ2 /kukRed g)S :-
µ0 + µ2y2 – µ1y
x-z plane
q
µ0
(A) fdj.k fuf'pr :i ls viorZukad µ0 okys ek/;e esa ykVS tk;sxhA

(B) fdj.k q, µ1 o µ2 ds fdlh Hkh eku ds fy;s µ0 viorZukad ds ek/;e esa dHkh ugha ykVS xs hA
(C) ;fn fdj.k y ds ,d fo'ks"k eku ls xqtjrh gS rks ;g dHkh Hkh µ0 viorZukad ds ek/;e esa ugha ykVS xs hA
é m12 ù
(D) fdj.k µ0 viorZukad ds ek/;e esa ugha ykVS s blds fy;s q < sin -1 ê1 - ú gksxkA
ë 4m 0 m 2 û
1001CJA103118012 H-9/32
11. ,d izR;korhZ /kkjk I(t) = I0cos(wt) (vk;ke 0.5 A, vko`fÙk 60 Hz) ,d lh/ks rkj esa cgrh gAS ;g rkj vk;rkdkj
vuqizLFk dkV okyh ,d VksjkWbM dq.Myh (vkarfjd f=T;k 1 cm, ckg~; f=T;k 2 cm, Å¡pkbZ 1 cm, 1000 ?ksjs) dh v{k
ds vuqfn'k fLFkr gAS dq.Myh dks 500 W izfrjks/kd ls tksM+k tkrk gAS
I(t)
(A) VksjkWbM esa izfs jr fo|qr okgd cy 2.61 × 10–4 sin (wt) gksxk tgk¡ w = 2p × 60 gAS
2.61 ´ 10-4 sin ( wt )
(B) izfrjks/kd esa /kkjk gS tgk¡ w = 2p × 60 gAS
500
(C) izfrjks/kd esa /kkjk ds dkj.k dq.Myh esa fojks/kh fo|qr okgd cy –2.74 × 10–7 cos(wt) gksxk tgk¡ w = 2p × 60 gAS
(D) bl fojks/kh fo|qr okgd cy rFkk lh/ks fo|qr okgd cy ds vk;keksa dk vuqikr 1.05 × 10–3 gAS
H-10/32 1001CJA103118012
12. fp= esa [kqjnjh lrg ij ,d ost j[kk gqvk gAS æO;eku m okyh xsan dks ost dh <kyw lrg ij fxjk;k tkrk gAS ;fn VDdj
iw.kZr;k çR;kLFk gks rks lgh dFku@dFkuksa dks pqfu;sA
m
M=2m
q µ
(A) æO;eku 'm' okyh xsan 0° ds vfrfjDr q ds dqN ekuksa ds fy;s la?kV~V fcUnq ls leku vf/kdre Å¡pkbZ rd mNy
ldrh gAS
(B) ost o /kjkry ds e/; dk;Zjr ?k"kZ.k vkosxh; çd`fr dk gAS
(C) fudk; (M + m) dk laoxs {kSfrt fn'kk esa lajf{kr gks ldrk gAS
(D) ;gk¡ ,slh v{k pquh tk ldrh g]S ftlds vuqfn'k fudk; (M + m) dk laoxs lajf{kr jgrk gAS
1001CJA103118012 H-11/32
13. fdlh vkd`fr okys nks pkydksa ij fopkj dhft;sA bUgsa nks od
S fYid rjhdks ls ,d la/kkfj= (fp= a) rFkk ,d çfrjks/kd
(fp= b) ds :i esa ç;qDr dhft;sA çdj.k (a) esa pkydksa ds e/; LFkku dks fo|qr'khyrk e okys lekaxh inkFkZ ls Hkjk
tkrk gS tcfd çdj.k (b) esa bls ifjfer pkydrk s okys lekaxh inkFkZ ls Hkjk tkrk gAS
e s
–Q
a b
e
(A) tc pkyd oxkZdkj vkd`fr ds gksa rks RC dk eku }kjk fn;k tkrk gAS (tgk¡ R çdj.k (b) eas çfrjks/k rFkk C
s
çdj.k (a) esa /kkfjrk gAS )
2e
(B) tc pkyd oxkZdkj vkd`fr ds gksa rks RC dk eku }kjk fn;k tkrk gAS (tgk¡ R çdj.k (b) eas çfrjks/k rFkk C
s
çdj.k (a) esa /kkfjrk gAS )
(C) tc pkydksa ds e/; fo|qr'khyrk e rFkk pkydrk s okyk ,d ek/;e Hkj fn;k tkrk gS rks fudk; dk le; fu;rkad
pkydksa dh vkd`fr ij fuHkZj ugha djrk gAS
(D) tc pkydksa ds e/; fo|qr'khyrk e rFkk pkydrk s okyk ,d ek/;e Hkj fn;k tkrk gS rks fudk; dk le; fu;rkad
pkydksa dh vkd`fr ij fuHkZj djrk gAS
H-12/32 1001CJA103118012
14. ,d lekUrj iV~V la/kkfj= dh Hkqtk L okyh oxkZdkj IysVas ,d nwljs ls d nwjh ij gS rFkk bls V foHko rd vkosf'kr fd;k
tkrk gAS vc bls cVS jh ls gVk fn;k tkrk gAS vc bls lkisf{kd ijko| S qrkad e o ?kuRo r okys ,d ijko| S qr æo ls Hkjs cM+s
ik= eas Å/okZ/kj :i ls bruk Mqcks;k tkrk gS fd æo la/kkfj= dh IysVksa ds e/; ds LFkku esa vk/ks rd Hkj tkrk g]S fp= ns[ksaA
L/2
L2e0
(A) fudk; dh /kkfjrk (1 + e ) gAS
2d
2 V
(B) la/kkfj= dh IysVksa ds e/; fo|qr {ks= lkeF;Z dk eku gAS
1+e d
2ee0 V
(C) IysVkas ij tgk¡ æo fo|eku gS] vkos'k ?kuRo dk dk eku 4 p (1 + e ) d gAS
2e0 V
(D) IysVkas ij tgk¡ æo fo|eku ugha g]S vkos'k ?kuRo dk eku 4 p (1 + e ) d gAS
1001CJA103118012 H-13/32
[k.M –I(iii) : (vf/kdre vad : 12)
bl [k.M esa nks vuqPNsn gSa
izR;sd vuqPNsn ij nks iz'u fn, x;sa gSaA
izR;sd iz'u esa pkj mÙkj fodYi (A), (B), (C) vkSj (D) gSa ftuesa ds o y ,d lgh gaSA
izR;sd iz'u ds fy, vks-vkj-,l- ij lgh mÙkj fodYi ds vuq:i cqycqys dks dkyk djsaA
iw.kZ vad : +3 ;fn flQZ lgh fodYi ds vuq : i cq y cq ys dks dkyk fd;k gSA
'kwU; vad : 0 vU; lHkh ifjfLFkfr;ksa esaA
iz ' u 15 ,oa 16 ds fy;s vuq P Ns n
QehZ&fMjkd forj.k Qyu] ftls QehZ Qyu Hkh dgk tkrk g]S QfeZvkWUl }kjk ÅtkZ Lrj ds vf/kHkksx (Occupancy) dh
çkf;drk dks n'kkZrk gAS QfeZvkWUl v/kZ&iw.kk±d pØ.k d.k gksrs gS tks ikmyh ds viotZu fu;e dh ikyuk djrs gAS
QehZ&Qyu fuEu izdkj fy[kk tkrk gS
1
f ( E) = ( E- EF ) ,
1+e kT
tgk¡ k cksYV~teku fu;rkad, T dsfYou esa rkieku] f(E) QfeZvkWu }kjk ,d cMs+ fudk; ds lkFk rkih; lkE;koLFkk eas ÅtkZ
'E' ij ÅtkZ Lrj }kjk izkIr çkf;drk gS rFkk EF QehZ ÅtkZ gS ftls fuEu izdkj fy[kk tkrk gS
2
h 2 æ 3p 2 N f ö 3
EF = ç ÷ ,
2m0 è V ø
tgk¡ Nf QfeZvkWUl dh la[;k] m0 çR;sd QfeZvkWu dk fojke æO;eku] V fudk; dk vk;ru rFkk h lekfur Iykad
æ h ö
fu;rkad ç 2p ÷ gAS
è ø
,d rkjs ds var dh vksj] rkjs ds æO;eku ds vk/kkj ij ;g ,d yky fo'kky dyk (red giant phase) ;k lqij uksok
foLQksVu ls xqtj ldrk gAS çFke ?kVuk ds dkj.k 'osr ckSuk rkjk (white dwarf star) fufeZr gksrk gS tgk¡ ghfy;e
layf;r gksdj Hkkjh rRo dk fuekZ.k djrh gS tcfd nwljh ?kVuk ds dkj.k U;wVªkWu rkjs dk fuekZ.k gksrk gAS (;fn rkjs dk
æO;eku > lw;Z dk 1.5 xquk æO;eku gksA)
3 3
'osr ckSus rkjs ds çdj.k esa vkl
S r bysDVªkWu ÅtkZ EF gksrh gS rFkk blfy;s dqy bysDVªkWu ÅtkZ N f EF gksrh gAS 'osr
5 5
ckSus rkjs ftls fu;r rkieku ij ,dleku ?kuRo okyk rFkk xksykdkj ekuk x;k g]S dh dqy ÅtkZ fuEu çdkj nh tkrh g%S
2
3 h2 æ 3p2N f ö 3 3 GM2 3
E = Nf ç ÷ - + N a kT + Erad
5 2me è V ø 5 R 2
;gk¡ f}rh; in xq:Roh; fLFkfrt ÅtkZ dks n'kkZrk g]S r`rh; in ijek.kqvksa dh rkih; xfr dks (Na = ijek.kqvksa dh la[;k)
rFkk prqFkZ in rkjs }kjk fofdjhr ÅtkZ dks n'kkZrk gAS lkE;koLFkk ij rkjs dh ÅtkZ fuf'pr :i ls f=T;k ds lkis{k U;wure
gksuh pkfg;sA
H-14/32 1001CJA103118012
15. 'osr ckSus rkjs dk i`"Bh; rkieku yxHkx 104K gAS çfr bdkbZ le; esa yxHkx fofdjhr ÅtkZ gksxh (ekuk 'osr ckuS s rkjs
dh f=T;k 7.1 × 103 km gAS )
(A) 2.3 × 1018 MeV/s (B) 2.3 × 1030 MeV/s
(C) 2.3 × 1027 MeV/s (D) 2.3 × 1036 MeV/s
1
16. çFke o f}rh; in ds lkis{k r`rh; o prqFkZ in dks ux.; ekusa rFkk rkjs dks N U;wfDy;kuksa o yxHkx N bysDVªkWuksa ls cuk
2
gqvk ekuus ij 'osr ckuS s rkjs dh f=T;k gksxh :
34 /3 p2/ 3 h2 34 /3 p2/ 3 h2
(A) R = N -1/ 3 (B) R = N -2 /3
4 Gme mn2 4 Gme mn2
34 /3 p2/ 3 h2 34 /3 p2/ 3 h2
(C) R = N -1/ 3 (D) R = N -2 /3
8 Gme mn2 8 Gme mn2
1001CJA103118012 H-15/32
iz ' u ,oa 18 ds fy;s vuq P Ns n

17
Magnetic Resonance Imaging (MRI) cgq/kk ç;qDr gksus okyh fpfdRlh; unS kfud rduhd gAS ;g fefuVksa esa
vkarfjd vaxksa dks çnf'kZr djrh gAS ;g rduhd ukfHkdh; pqEcdh; vuqukn (NMR) ij vk/kkfjr gksrh gAS gekjs Ård
eq[;r;k ty ls cus gksrs gS rFkk ekuo 'kjhj eas ijek.kqvksa dk yxHkx nks frgkbZ Hkkx ^gkbMªkt
s u* gAS ,d gkbMªkt
s u ijek.kq
dk ukfHkd çksVksu gksrk gAS bysDVªkWu ds leku çksVksu dk pØ.k dks.kh; laosx o pqEcdh; vk?kw.kZ Hkh gksrk gAS bl çdkj
çksVksu dks ,d NksVh pqEcd ekuk tk ldrk gSA bldk pØ.k pqEcdh; vk?kw.kZ yxHkx 2.79 µn gksrk gS] tgk¡
eh
mn = = 5.05 ´ 10 -27 J / T ukfHkdh; eXS usVkWu (nuclear magneton) dgykrk g;S ;gk¡ mP çksVksu dk æO;eku
4 pmP
r
gAS vc ;gk¡ ,d cká pqEcdh; {ks= B yxkrs gS rFkk çksVksu ds O;ogkj dh foospuk djrs gAS Li"Vr% ;g çksVkWu Bhd mlh
r
rjg O;ogkj djrk gS tl S k fd ckg~; pqEcdh; {ks= esa j[kh ,d pqEcd djrh gAS ge tkurs gS fd cká pqEcdh; {ks= B
esa j[kh pqEcdh; vk?kw.kZ mr okyh pqEcd dh fLFkfrt ÅtkZ dks U = µB(1 – cosq) }kjk O;Dr fd;k tk ldrk g]S tgk¡
r r
q, m o B ds eè; dks.k gAS cká pqEcdh; {ks= o çksVksu ds pØ.k pqEcdh; vk?kw.kZ ds e/; vU;ksU; fØ;k ds dkj.k
çksVksu dh ÅtkZ DokUVhd`r gks tkrh g]S ftlds QyLo:i nks vuqer voLFkk;sa çkIr gksrh gS % (1) pqEcdh; {ks= ds lajfs [kr
çksVksu dk pØ.k rFkk (2) pqEcdh; {ks= ds foijhr çksVksu dk pØ.kA bu voLFkkvksa dh vyx&vyx ÅtkZ gksrh gAS
okLro esa nksuksa voLFkkvksa ds e/; ÅtkZ vUrj cgqr vYi gksrk gS rFkk os QksVksu ftudh ÅtkZ] bl ÅtkZ vUrjky ls feyrh
g]S os bu nksuksa ÅtkZ Lrjksa ds e/; çksVksuksa ds laØe.k dk dkj.k curs gAS ;s laØe.k pØ.k&O;ofLFkr laØe.k (spin-flip
transitions) dgykrs gAS ,sls ç;ksx dh ,d O;oLFkk fp= eas n'kkZ;h x;h gAS ,d dq.Myh dks çfrn'kZ ij pkjksa vksj
yisVk tkrk gS rFkk ifjorhZ vko`fr okyh çR;korhZ /kkjk dks dq.Myh esa ls çokfgr fd;k tkrk gSA tc dq.Myh esa /kkjk dh
vko`fr] çksVksuksa dh nks ÅtkZ voLFkkvksa ds e/; laØe.k çsfjr djus ds fy;s vko';d vko`fr ds leku gks tkrh gS rks
çfrn'kZ esa fo|eku çksVksu dq.Myh ls 'kfDr dk vko'kks"k.k djrs gAS bls ÅtkZ dk vuquknh vo'kks"k.k dgk tkrk gS rFkk ;g
rduhd ^ukfHkdh; pqEcdh; vuqukn* dgykrh gS tgk¡ B = 1.5 T rFkk mijksDr o.kZu ds vuqlkj çksVksu dk pØ.k
pqEcdh; vk?kw.kZ = 2.79 µn, (µn = 5.05 × 10–27 J/T) gksrk gSA
Absorption
NMR signal
N S
Frequency
H-16/32 1001CJA103118012
17. fdl voLFkk dh ÅtkZ de gksrh g\ S

(A) og voLFkk tgk¡ çksVksu pØ.k ?kVd] cká pqEcdh; {ks= ds lekUrj gksrk gSA
(B) og voLFkk tgk¡ çksVksu pØ.k ?kVd] cká pqEcdh; {ks= ds çfrlekUrj gksrk gAS
(C) og voLFkk tgk¡ çksVksu pØ.k ?kVd] cká pqEcdh; {ks= ds yEcor~ gksrk gAS
(D) og voLFkk tgk¡ çksVksu pØ.k ?kVd] cká pqEcdh; {ks= ls 60° ij >qdk gksrk gSA
18. tSlk fd mijksDr x|ka'k esa fooj.k fn;k tk pqdk gS fd cgq/kk ç;qDr uSnkfud rduhd 'Magnetic Resonance
Imaging' (MRI) esa NMR (pØ.k&O;ofLFkr laØe.k) rduhd ç;qDr dh tkrh gAS X-fdj.kksa rFkk g-fdj.kksa ds lkFk
ç;qDr dh tkus okyh rduhdsa ftudh ÅtkZ;as 104 – 106 eV ijkl esa gksrh g]S dh rqyuk esa
(A) MRI esa ç;qDr laØe.kksa ls lacaf/kr QksVksu mPp ÅtkZ okLro esa 106 eV ls vf/kd ÅtkZ okys gksus ds dkj.k bl
rduhd esa vf/kd dks'kh; {kfr gksrh gAS
(B) MRI esa ç;qDr laØe.kksa ls lacaf/kr QksVksu rqyukRed ÅtkZ okys gksus ds dkj.k bl rduhd esa leku dks'kh; {kfr
gksrh gSA
(C) MRI esa ç;qDr laØe.kksa ls lacaf/kr QksVksu rqyukRed ÅtkZ okys gksrs gS] ijUrq mudk ¶yDl vR;f/kd gksrk g]S vr%
bl rduhd esa vf/kd dks'kh; {kfr gksrh gAS
(D) MRI esa ç;qDr laØe.kksa ls lacaf/kr QksVksu cgqr vYi ÅtkZ okys gksrs g]S tks yxHkx 10 –7 eV ds Øe dh gksrh gS ;
vr% bl rduhd esa ux.; dks'kh; {kfr gksrh gAS
1001CJA103118012 H-17/32
Hkkx-2 : jlk;u foKku

[k.M–I(i) : (vf/kdre vad : 18)
1. fuEu pkydrkferh; vuqekiu ds fy;s :
NaOH
HCl
+
CH3COOH
lgh oØ gS :
(A) pkydRo (B) pkydRo
NaOH dk vk;ru NaOH dk vk;ru
pkydRo
(C) pkydRo (D)
NaOH dk vk;ru
NaOH dk vk;ru
H-18/32 1001CJA103118012
2. rktk cus 5 yhVj ds tyh; foy;u esa 0.03 M CaCl2 rFkk 0.05 M Na2SO4 mifLFkr gS ;fn CaSO4 dh Ksp
2.4 × 10–5 gS rks vUr esa izkIr gksus okys vo{ksi ds eksyksa dh la [;k gS
(A) 4.08 g (B) 6.8 g (C) 20.4 g (D) 34 g
3. ,d f}rh;d dksfV vfHkfØ;k ds fy;s 227°C rFkk 727°C ij nj fu;rkad ds eku Øe'k% 1.5 × 107 M–1S–1 rFkk
4.5 × 107 M–1 S–1 gS rks vfHkfØ;k ds fy;s lfØ;.k ÅtkZ dk eku gS [ln3 = 1.1]
(A) 1.1 Kcal mol–1 (B) 2.2 Kcal mol–1 (C) 2.8 Kcal mol–1 (D) 3.3 Kcal mol–1
4. fuEu esa ls dkSu lk ladqy vuqpqEcdh; rFkk mPp pØ.k gS?
(A) [Cr(H2O)6]3Å (B) [Fe(H2O)6]3Å (C) [Ni(H2O)6]2Å (D) [Ti(H2O)6]3Å
5. ,slk Mkbld
S js kbM crkb;s ftlesa a-L-XywdksflfMd ca/ku mifLFkr gS ?
CH2OH OH OH OH
O O O
H CH2 O CH2OH
(A) OH (B) OH HO
H
H HO
O H HO O OH
HO
H OH OH OH
OH H
HO O O O H O
O HO OH OH
OH HO
OH OH
(C) (D) O OH
OH
HO OH HO OH OH OH
O
CºCH
D
¾¾¾¾ ® ¾¾¾¾
dil. H SO
6. ¾® ¾¾® X , X gS :
2 4 (i) I2 / NaOH
HgSO4 +
(ii) H
COOH
(A) (B) (C) (D)
1001CJA103118012 H-19/32

fodYi lgh gS(gSa)A
mnkgj.k Lo:i % ;fn fdlh iz'u ds fy , dsoy igyk] rhljk ,oa pkSFkk lgh fodYi gaS vkjS nwljk fodYi xyr
7. ok"i'khy ?kVd A rFkk B ds foy;u dk dqy ok"i nkc 200 torr g]S ;fn bl foy;u es 1 eksy A rFkk 2 eksy B
mifLFkr gAS
fn;k gS : PAo = 150 torr
PBo = 240 torr
xyr fodYiksa dk p;u dhft;s (s) :

(A) foy;u ds DoFkukad rFkk feJ.k ds la?kVu ds e/; vkjs[k esa ,d fufEu"B fcUnq (minima) iznf'kZr gksrk gS
(B) ,d fo'ks"k Lka?kVu ij foy;u dk ok"i nkc U;wure gksxk
(C) 'kq¼ [A–A] rFkk [B–B] vkd"kZ.k cyksa dh rqyuk esa [A–B] izdkj ds vkd"kZ.k cy vf/kd izcy gksrs gS
(D) ,d fo'ks"k la?kVu ij A rFkk B fefaJr fd;s tkus ls U;wure DoFkukadh fLFkj DokFkh feJ.k curk gSA
H-20/32 1001CJA103118012
8. dksyksbMh feJ.kksa ds lanHkZ esa lgh dFkuksa dk p;u dhft;s

(A) dksyksbM izkfs Vu (ifjf{kIr izkoLFkk) ds cus gksrs gS tks foy;u dh pH ij fuHkZj djrs gq, /kukosf'kr ;k ½.kkosf'kr gks
ldrs gS
(B) vkdk'k dk uhyk jax fV.My izHkko dk mnkgj.k gS
(C) ty esa v.Ms dk ,sYcqfeu cgqvkf.od dksyksbM dk mnkgj.k gS
(D) ,sye dks feykdj ty dk 'kqf¼dj.k fd;k tkuk Ldanu dk mnkgj.k gS
9. ekusa r = fofHkUu laHkkfor O;oLFkkvksa esa ladqfyr ijek.kq dh f=T;kA lgh fodYiksa dk p;u dhft;sA
é 2ù
(A) ;fn ;s ijek.kq ccp ;k hcp O;oLFkk esa ladqfyr gksrs gS rks nksuksa esa fudVre vUrjryh; nwjh ê 2r ú gksxh
êë 3 úû
(B) ;fn ;s ijek.kq HCP O;oLFkk esa ladqfyr gksrs g]S rks fudVre v"VQydh; fjfDr ,oa prq"Qydh; fjfDr ds e/;
é 3ù
nwjh êr ú gksxhA
ëê 2 úû
(C) ;fn HCP O;oLFkk esa ladqfyr gksrs g]S rks bdkbZ lSy dk vk;ru é24 3r 3 ù gS
ë û
(D) HCP rFkk CCP nksuksa O;oLFkkvksa dk fjfDRk izHkkt leku gksrk gSA
10. fuEu esa ls dkuS lk ladqy izdkf'kd leko;ork iznf'kZr djrk gS ysfdu T;kfefr ; leko;ork iznf'kZr ugha djrk gS ?
(A) [N i (en)3]2+ (B) [Ni(en)2Cl2] (C) [Ni(DMG) 2] (D) [Cr(acac)2]!
1001CJA103118012 H-21/32
11. fuEu esa ls dkSu lk Øe lgh gS
(A) B.P. PH3 < AsH3 < SbH3 < NH3
(B) M.P. PH3 < AsH3 < SbH3 < NH3
(C) B.P. HCl < HBr < HI < HF
(D) M.P. HCl < HBr < HI < HF
12. fuEu eas ls dkuS lk v;Ld >kx Iyou fof/k }kjk lkfUær fd;k tkrk gS ?
(A) xsysuk (B) LQsysjkbV (C) flusckj (D) ftadkbV
13. fuEu vfHkfØ;k Øe ds fy;s lgh dFkuksa dk p;u dhft;s \
Br D
F NaCN NaOEt
(P) NC
DMSO EtOD / D
[O] [Q]
(A) ‘P’ mRikn dk fuekZ.k ‘SN2’ fØ;kfof/k }kjk gksrk gS

(B) P ¾® Q :ikUrj.k 2nd dksfV vfHkfØ;k gS
(C) P ¾® Q in E1 CB fØ;kfof/k gS
(D) ‘O’ ;kfS xd fogy
S kstuhdj.k rFkk cgqyhdj.k ij ikWyhLVk;fju nsrk gS
14. ,slh vfHkfØ;k,sa ;k vfHkfØ;kvksa dk Øe crkb;s tks ,d mRikn ds :i esa gsDlkesfFky casthu nsrh g?S
COOH
Conc. NaOH
(A) H2SO4 (B) CaO /D
O HOOC COOH
CHO N – NH2
O
Zn – Hg / HCl EtO / HO OH
excess D
(C) (D)
CHO N – NH2
H-22/32 1001CJA103118012
vkf.od d{kd fl¼kUr ds vuqlkj tc ijekf.o; d{kdksa dk ,d ;qX e la; ksx djrk gS rks os vkf.od d{kdksa dk
,d ;qXe cukrs gAS cuus okys vkf.od d{kdksa dh la[;k] lfEefyr ijekf.o; d{kdksa dh la[;k ds leku gh gksuk
pkfg,
15. fuEu esa ls dkSulk fodYi lgh gS\
(A) O2 v.kq dk HOMO, ftjsM gS
(B) O2 v.kq dk LUMO, ftjsM gS
(C) N2 v.kq dk HOMO, vuftjsM gS
(D) N2 v.kq dk LUMO, vuftjsM gS
16. fuEu esa ls fdlesa U;wure N–N ca/k yEckbZ mifLFkr gksrh gS?
(A) N 22Å (B) N 22! (C) N Å2 (D) N 2-
1001CJA103118012 H-23/32

Pd / BaSO4 / H2 Br2 + H2O Conc. HBr
Me – C º C – Me ¾¾¾¾¾¾ ¾
® (Q) ¾¾¾¾¾ ® (S) ¾¾¾¾¾ ® (T)
(P) ( ±) ( ±)
17. mijksDr vfHkfØ;k Øe esa ‘T’ mRikn crkb;sa ?
Me Me Me Me
(A) H OH (B) H Br (C) H Br (D) H Br
H OH HO H Br H H Br
Me Me Me Me
(±) (±)
18. mijksDr Øe esa ‘X’ mRikn crkb;s ?

O
(1) N Na
(1) Red P + X 2 C
1% HgSO4 (1) NaOH (2) EtOH / H+ O
'P' (A) B + yellow ppt (C) 'X'
dil. H2 SO4 (2) H + +
(2) H3O
(A) Xykbflu (B) Qsfuy ,sykfuu (C) ,sykfuu (D) osfyu

H-24/32 1001CJA103118012
Hkkx-3 : xf.kr
[k.M –I(i) : (vf/kdre vad : 18)
1. ,d FkyS s esa 1 yky rFkk 3 uhyh xsanas gAS ,d ijh{k.k esa ;kn`fPNd :i ls ,d xsan dk p;u fd;k tkrk gS rFkk blds jax dks
uksV dj fy;k tkrk gS rFkk bls mlh jax dh ,d vfrfjDr xsan ds lkFk izfrLFkkfir dj fn;k tkrk gAS (nksuksa jaxksa dh xsans
i;kZIr ek=k esa g)S ;fn bl rjg ds rhu ijh{k.k fad;s tkrs g]S rks
3
(A) Bhd ,d uhyh xsan fudkyus dh izkf;drk gksxh
20
7
(B) Bhd ,d uhyh xsan fudkyus dh izkf;drk gksxh
20
9
(C) de ls de ,d uhyh xsan fudkyus dh izkf;drk gksxh
20
7
(D) de ls de ,d uhyh xsan fudkyus dh izkf;drk gksxh
20
2. lehdj.k |Z – (1 + i) cosq| + |Z – (1 – i) sinq|= 2 (tgk¡ q vpj g]S i = -1 rFkk Z Î £) }kjk iznf'kZr oØ dk
fcUnqiFk gksxk
(A) o`Ùk (B) ijoy; (C) nh?kZo`Ùk (D) vfrijoy;
ekuk ,d leQyu ƒ(x) bl izdkj gS fd ƒ(x) + ƒ(x – l) = x(x – l) + l2, l > 0 gks] rks å çç ò 2 ( ) 2 dx ÷÷
12 æl ƒ x ö
3.
x - lx + l
l=1 è0 ø
dk eku gksxk -
(A) 144 (B) 12 (C) 6 (D) 39
1001CJA103118012 H-25/32
æ 2018 2019 ö
4. lim ç
x ®1 è 1 - x 2018
- ÷ dk eku gksxk
1 - x 2019 ø
1 1
(A) 0 (B) - (C) (D) fo|eku ugha gksxk
2 2
5. x Î (0, 5p) ds fy;s] lehdj.k tan–1(2sinx) = cot–1(cosx) dk@ds
(A) vuUr gy gksaxs
(B) rhu gy gksaxs
(C) ikap gy gksaxs
(D) dksbZ gy ugha gksxk
6. ijoy; y2 = 8(x–1) dh fdlh Hkh Li'kZ js[kk ij ewyfcUnq ls [khaps x;s yEc ds ikn dk fcUnqiFk gksxk
(A) x3 + xy2 + 2y2 + x2 = 0 (B) x3 – xy2 + 2y2 – x2 = 0
(C) x3 – xy2 + 2y2 + x2 = 0 (D) x3 + xy2 + 2y2 – x2 = 0
H-26/32 1001CJA103118012
fodYi lgh gS(gSa)A
mnkgj.k Lo:i % ;fn fdlh iz'u ds fy, dsoy igyk] rhljk ,oa pkSFkk lgh fodYi gaS vkjS nwljk fodYi xyr
7. ;fn cgqin P(x) = 24x4 + l1x3 + l2x2 + l3x + 1, (tgk¡ l1,l2,l3 Î R) ds pkj /kukRed okLrfod ewy a,b,g,d bl
izdkj gS fd a + 2b + 3g + 4d = 4 gks] rks
(A) l1 + l2 + l3 = –25 (B) l1 = –50 (C) l3 = –10 (D) l2 = 25
8. ekuk vody lehdj.k y1y3 = 3(y2)2 (tgk¡ yi, y dk iok¡ vodyt gS rFkk y = ƒ(x) rhu ckj vodyuh; Qyu g)S g]S
rks -
d 2 y dy
(A) = (B) y = ax2 + bx + c, tgk¡ a,b,c Î ¡
dx 2 dx
d 2x dy
(C) = (D) x = ay2 + by + c, tgk¡ a,b,c Î ¡
dy2 dx
1001CJA103118012 H-27/32
9. ekuk nks Qyu ƒ(x) = x3 rFkk g(x) = 2x gks] rks

æ 1 ö
(A) lim g ( x ) sin ç
x ®0 ç ƒ ( x ) ÷÷ fo|eku ugha gksxk
è ø
(B) y = ƒ(x) |g(x)| loZ= vodyuh; gksxk
32
(C) oØ y2 = ƒ(x) rFkk |y|= g(x) }kjk ifjc¼ {ks=Qy oxZ bdkbZ gksxk
5
(D) y = |ƒ(x)| + |g(x)| loZ= vodyuh; gksxk
2020
esa bl izdkj ifjHkkf"kr gS fd ƒ ' ( x ) = Õ ( x - r ) rFkk

r
10. ekuk ƒ ,d okLrfod eku Qyu gS tks ¡ g, ¡ esa bl izdkj
r =1
x
ifjHkkf"kr gS fd ò ( eƒ (t ) - g ( x - t ) ) dt = 2019x + 2020 gks] rks
0
(A) ƒ ds LFkkuh; mfPp"B ds 505 fcUnq gkasxs (B) ƒ ds LFkkuh; fufEu"B ds 505 fcUnq gksaxs
(C) g ds LFkkuh; mfPp"B ds 505 fcUnq gksaxs (D) g ds LFkkuh; fufEu"B ds 505 fcUnq gksaxs
é x 2018 x 2019 + 2018 x 2020 - 2019 ù

ê 2020 ú
11. ekuk vkO;wg A = êx - 2018 x 2019 x 2018 + 2020 ú ,x Î ¡ rFkk ƒ(x) = det(A) gks] rks -
ê x 2019 + 2019 x 2018 - 2020 x 2020 ú
ë û
(A) oØ y = ƒ(x) ewy fcUnq ls xqtjrk gS (B) x-v{k oØ dh ewy fcUnq ij Li'kZ js[kk gS
(C) y-v{k oØ ds ewy fcUnq ij Li'kZ js[kk gS (D) vkO;wg A dHkh Hkh rRled vkO;wg ugha gks ldrk gS
12. oØ S1 : x2 + y2 = 8 ij fLFkr fcUnq P ls] oØ S2 : x2 + y2 = 4 ij [khaph xbZ Li'kZ js[kkvksa dk ;qXe oØ S2 dks fcUnq
A rFkk B ij Li'kZ djrk g]S rks
(A) thok AB dh yEckbZ 2 2 bdkbZ gksxh (B) thok AB dh yEckbZ 4 bdkbZ gksxh
(C) f=Hkqt PAB dk {ks=Qy 2 oxZ bdkbZ gksxk (D) f=Hkqt PAB dk {ks=Qy 4 oxZ bdkbZ gksxk
2 2
x y
13. vfrijoy; - =1 dh Li'kZ js[kkvksa dk lehdj.k] tks js[kk y = 2x – 1 ds lekUrj g]S gksxk@gksxh
9 4
(A) y = 2x - 4 2 (B) y = 2x - 2 10 (C) y = 2x + 4 2 (D) y = 2x + 2 10
r r r
14. ;fn a,b,c rhu v'kwU; leryh; lfn'k gks] rks
r r r r r r r r r r r r r r r
(A) éëa - b b - c c - a ùû = 0 (B) éëa + b b + c c + a ùû = 2 éëa b c ùû
r r r r r r r r r r r r r r r 2
(C) éëa ´ b b ´ c c ´ a ùû = 0 (D) éë a ´ b b ´ c c ´ a ùû = éëa b c ùû
H-28/32 1001CJA103118012
ekuk P(Z), Z Î £ lfEeJ lery esa ,d fcUnq gS tks laca/k Z + Z + 4 Z - Z = 34 dks larq"V djrk gS rFkk P(z)
ds fcUnqiFk }kjk ifjc¼ {ks= dk {ks=Qy A1 gSA

P(Z) ds fcUnqiFk ds fcUnqvksa dks feykus ls cuus okys cgqH kq t }kjk ifjc¼ {ks=Qy A2 gS ftlds fy;s |Z|
U;wure gksA
15. A1 dk eku gksxk -
289 289
(A) 289 (B) (C) (D) 34
2 4
16. A2 dk eku gksxk -
(A) 16 (B) 8 (C) 4 (D) 289
1001CJA103118012 H-29/32

ekuk ,d lery P gS ftldk lehdj.k x– y= 0 rFkk nks fcUnq A(3,2,4) rFkk B(7,0,–10) gSA
17. fcUnq P ds funsZ'kkad] tks lery P esa bl izdkj gS fd |PA + PB| U;wure gks] gksaxs -
æ 21 21 9 ö æ 21 21 9 ö æ 21 21 9 ö
(A) (21,21,9) (B) ç , , ÷ (C) ç , , ÷ (D) ç , , ÷
è 4 4 4ø è 8 8 4ø è 16 16 16 ø
uuur
18. AB rFkk lery P ds yEcor~ lfn'k ds e/; dks.k gksxk -
-1 æ 1 ö p -1 æ 1 ö -1 æ 1 ö
(A) cos ç ÷ (B) (C) cos ç ÷ (D) cos ç ÷
è2 3ø 4 è6ø è 12 ø
H-30/32 1001CJA103118012
ADMISSION ANNOUNCEMENT
CLASSROOM CONTACT PROGRAMMES (Session : 2019-20)
KOTA CENTER
IIT-JEE : JEE(Main+Advanced) JEE (Main)
Courses Medium Course Classes Admission Courses Medium Course Classes Admission
Code Mode Code Mode
NURTURE PH-I English 1001 03/04/2019 ASAT/TALLENTEX NURTURE PH-I Eng/Hindi 2001 01/04/2019 Direct
NURTURE PH-II Eng/Hindi 1002 15/04/2019 ASAT/TALLENTEX NURTURE PH-II Eng/Hindi 2002 15/04/2019 Direct
NURTURE PH-III English 1003 29/04/2019 ASAT/TALLENTEX NURTURE PH-III Eng/Hindi 2003 15/05/2019 Direct
NURTURE PH-IV Eng/Hindi 1004 13/05/2019 ASAT/TALLENTEX ENTHUSIAST PH-I Eng/Hindi 2021 01/04/2019 Direct
ENTHUSIAST PH-II Eng/Hindi 1022 01/04/2019 Direct ENTHUSIAST PH-II Eng/Hindi 2022 06/05/2019 Direct
ENTHUSIAST PH-III Eng/Hindi 1023 08/05/2019 Direct ENTHUSIAST PH-III Eng/Hindi 2023 27/05/2019 Direct
LEADER PH-I Eng/Hindi 1031 24/04/2019 Through ASAT LEADER PH-I Eng/Hindi 2031 24/04/2019 Direct
LEADER PH-II Eng/Hindi 1032 08/05/2019 Through ASAT LEADER PH-II Eng/Hindi 2032 06/05/2019 Direct
LEADER PH-III Eng/Hindi 1033 29/05/2019 Through ASAT LEADER PH-III Eng/Hindi 2033 27/05/2019 Direct
PRE-MEDICAL (NEET-UG & AIIMS)

Courses Medium Course Code Classes Admission Mode
NURTURE PH-I English 3001 07/04/2019 Direct
NURTURE PH-II English/Hindi 3002 21/04/2019 Direct
NURTURE PH-III English 3003 19/05/2019 Direct
NURTURE PH-III(B) English 3261 20/05/2019 Direct
ENTHUSIAST PH-I English/Hindi 3021 01/04/2019 Direct
ENTHUSIAST PH-II English/Hindi 3022 15/05/2019 Direct
LEADER PH-I English/Hindi 3031 08/04/2019 Direct
LEADER PH-II English/Hindi 3032 29/04/2019 Direct
LEADER PH-III English/Hindi 3033 20/05/2019 Direct
ACHIEVER PH-I English/Hindi 3051 15/05/2019 Direct
ACHIEVER PH-II English/Hindi 3052 03/06/2019 Direct
For JEE (Adv.) | JEE (Main) | NEET | AIIMS

NTSE | OLYMPIADS | PNCF | Class 6th to 12th
To Apply online Log on to www.allen.ac.in or walk-in to nearest ALLEN Center for Application Form
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u SIKAR (Tel.: 7425808333) u SURAT (Tel.: 8511143785) u UJJAIN (Tel.: 0734-2980122) u VADODARA (Tel.: 7490055248)
1001CJA103118012 H-31/32
iz'ui= dk izk:i vkSj vadu ;kst uk %
16. bl iz'ui= esa rhu Hkkx gaS % HkkfS rd foKku] jlk;u foKku ,oa xf.krA
17. izR;sd Hkkx esa ,d [k.M gaS ftudk fooj.k fuEufyf[kr rkfydk esa fn;k x;k gAS
[k.M iz'u dk iz'uksa oxkZ uq lkj iz R ;s d iz ' u ds va d [k.M es a
izdkj dh iw. kZ vad vka f 'kd va d 'kw U ; va d ½.k va d vf/kdÙke
la[ ;k va d
I(i) ,dy lgh +3 0 –1
fodYi 6
;fn flQZ lgh fodYi ds —
;fn fdlh Hkh vU; lHkh 18
vuq:Ik cqycqys dks cqycqys dks dkyk ifjfLFkfr;ksa
dkyk fd;k gS ugha fd;k gS esa
,dy ;k ,d ls +4 +1 0 –2
I(ii) vf/kd lgh ;fn flQZ lkjs lgh fodYi izR;sd lgh fodYi ds vuq:i ;fn fdlh Hkh vU; lHkh
fodYi 8 (fodYiksa) ds vuq:Ik cqycqys dks dkyk djus ij] cqycqys dks ifjfLFkfr;ksa 32
cqycqys (cqycqyksa) dks ;fn dksbZ xyr fodYi dkyk dkyk ugha esa
dkyk fd;k x;k gS ugha fd;k gS fd;k gS
vuqPNsn ij +3 0
I(iii) vk/kkfjr ;fn flQZ lgh fodYi ds vU; lHkh
4 — — 12
(,dy lgh vuq:Ik cqycqys dks ifjfLFkfr;ksa
fodYi) dkyk fd;k gS esa
ijh{kkFkhZ dk uke ................................................................................................
QkWeZ uEcj .............................................
eSa u s lHkh funsZ ' kks a dks i<+ fy;k gS vkSj eS mudk eSa us ijh{kkFkhZ dk ifjp;] uke vkjS QkWeZ uEcj dks iwjh rjg
vo'; ikyu d:¡ xk@d:¡ xhA tk¡p fy;k gS ,oa iz' u i= vkSj vks- vkj- ,l- dks M nks uks a
leku gSaA
____________________________ ____________________________
ijh{kkFkhZ ds gLrk{kj fujh{kd ds gLrk{kj
Corporate Office : ALLEN CAREER INSTITUTE, “SANKALP”, CP-6, Indra Vihar, Kota (Rajasthan) INDIA 324005
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H-32/32 Your Target is to secure Good Rank in JEE 2019 1001CJA103118012

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JEE (Main + Advanced)

DO NOT BREAK THE SEALS WITHOUT BEING INSTRUCTED TO DO SO BY THE INVIGILATOR

OPTICAL RESPONSE SHEET :

DARKENING THE BUBBLES ON THE ORS :

11. Darken the bubble COMPLETELY.

12. The correct way of darkening a bubble is as :

SOME USEFUL CONSTANTS

· Boltzmann constant k = 1.38 × 10–23 JK–1

Space for Rough Work

Space for Rough Work

2r1r2 2r1r2 2r1r2 3r1r2

Space for Rough Work

Space for Rough Work

CAR OBSERVER Reflecting wall

9. A rod of length l, has linear coefficient of thermal expansion a which is given as

(A) Dimensional formulae of a0, a1 & a2 are different.

Space for Rough Work

Space for Rough Work

Space for Rough Work

Where k is Boltmann constant, T is temperature in kelvin, f(E) is the probability that an

Space for Rough Work

(A) Conductance (B) Conductance

Volume of titrate Volume of titrate

Volume of titrate Volume of titrate

Space for Rough Work

(A) 4.08 g (B) 6.8 g (C) 20.4 g (D) 34 g

4. Which of the following complex is paramagnetic and high spin ?

(A) [Cr(H2O)6]3Å (B) [Fe(H2O)6]3Å (C) [Ni(H2O)6]2Å (D) [Ti(H2O)6]3Å

5. Identify disacelaride with a-L-Glucossidic linkage ?

Space for Rough Work

(A) ‘P’ product formation occur through ‘SN2’ mechanism

Space for Rough Work

Space for Rough Work

17. In above reaction sequence identify ‘T’ product?

18. Identify ‘X’ product in above sequence?

(A) Glycine (B) Phenyl alanine (C) Alanine (D) Valine

(A) circle (B) parabola (C) ellipse (D) hyperbola

(A) 144 (B) 12 (C) 6 (D) 39

Space for Rough Work

(A) l1 + l2 + l3 = –25 (B) l1 = –50 (C) l3 = –10 (D) l2 = 25

Space for Rough Work

Let ƒ be a real valued function defined on ¡ such that ƒ ' ( x ) = Õ (x - r)

é x 2018 x 2019 + 2018 x 2020 - 2019 ù

(A) length of chord AB is 2 2 units (B) length of chord AB is 4 units

Space for Rough Work

Let P(Z), Z Î £ is a point in complex plane which satisfies relation Z + Z + 4 Z - Z = 34 and

A1 is area of region bounded by locus of P(Z).

Space for Rough Work

PRE-MEDICAL (NEET-UG & AIIMS)

For JEE (Adv.) | JEE (Main) | NEET | AIIMS

Que. No. Category-wise Marks for Each Question Maximum

NAME OF THE CANDIDATE ................................................................................................

FORM NO. .............................................

(Academic Session : 2018 - 2019)

JEE (Main + Advanced)

Ïi;k bu funsZ'kksa dks /;ku ls i<+sa

fujh{kd ds vuqns'kksa ds fcuk eq gjs a u rks M + s

SOME USEFUL CONSTANTS

dPps dk;Z ds fy, LFkku

dPps dk;Z ds fy, LFkku

dPps dk;Z ds fy, LFkku

2r1r2 2r1r2 2r1r2 3r1r2