Chem 16 2nd LE Review

I. Modified T/F
1. For the reaction to be truly spontaneous at all temperatures, ∆G, ∆S and ∆H must be negative, negative,
and positive, respectively.
2. The amount of heat required to raise the temperature of 7.35g of water from 21 to 98℃ is 2.36 x 10 J. 3

(specific heat of water = 4.18 J g °C ). -1 -1

3. The standard enthalpy of formation of a pure element in its reference form is 1.

4. There are 3.11 x1023 atoms of P in 0.50 moles of P4O10.
5. A 0.7745 g solid of (Ba)3(PO4)2 contains 0.136 moles of PO43-

II. Multiple Choice

For numbers 1-4, refer to the following scenario:
A 5.000 M Copper (II) sulfate solution was prepared by dissolving the appropriate amount of Copper (II) sulfate
solid (MW: 159.6 g/mol) in 250.0 mL of water. The resulting solution was then treated with excess barium nitrate ,
forming barium sulfate (MW: 233.4 g/mol) as a solid precipitate. The precipitate was filtered, dried and weighed.

1.) What is the balanced chemical equation for the reaction?

a.) Cu SO 4(aq) + Ba NO 3(aq) →Cu(NO 3)2(aq)+ ¿ ¿
b.)Cu( SO¿ ¿ 4)2(aq) + Ba NO 3(aq ) → Cu(NO3 )2(aq) + Ba SO 4(s) ¿
c.)Cu SO 4(aq) + Ba( NO¿¿ 3)2(aq) →Cu(NO 3)2(aq) +Ba SO 4(s ) ¿
d.)Cu SO 4(aq) + Ba NO 3(aq) →Cu( NO 3)(aq) +Ba SO4(s)

2.) How much of the CuSO4 solid was used to prepare the 250.0 mL 5.000 M CuSO4 solution?
a.) 199.5 g b.) 798.0 g c.) 3.192 g d.) 31.92 g

3.) Identify the kind of reaction between barium nitrate and copper (II) sulfate.
a.) Single displacement c.) Double displacement
b.) Synthesis d.) Decomposition

4.) What is the weight of the collected BaSO4 precipitate?

a.) 116.7 g b.) 291.8 g c.) 466.8 g d.) 46.68 g

For numbers 5-7, refer to the following unbalanced redox reaction:

−¿ ¿
2−¿ +I ¿

2−¿+ I 3−¿→ S O
4 6 ¿
¿
S2 O 3
5.) What is the reducing agent in this reaction?
a.) S2O32- b.) I3- c.) S4O62- d.) I-

6.) Which is the balanced chemical equation?

−¿ ¿
2−¿ +I ¿
−¿→2 S4 O6
a.) S2 O 32−¿+3 I
¿
3
¿
−¿ ¿
2−¿ +3I ¿
−¿→2 S 4 O
b.)3 S 2 O 32−¿+2 I
¿
3
6
¿
−¿ ¿
2−¿+3 I ¿
−¿→S 4 O6
c.)2 S 2 O 32−¿+I
¿
3
¿
−¿ ¿
2−¿ +3I ¿
−¿ →S4 O6
d.)2 S 2 O 32−¿+2 I
¿
¿ 3

7.) 12.5 mL of a solution of 0.05 M Na2S2O3 was reacted with a unknown solution of I3-. What is the molarity of I3- in
the solution if its volume was 25 mL?

a.) 0.05M b.) 0.025M c.) 0.0125M d.) 0.00625M

Prepared by UP ACME and UP ChemSoc .

 Chem 16 2nd LE Review

Prepared by UP ACME and UP ChemSoc .