repeatability between lab

repeatability within lab Horwitz %RSD

Analyte, % Analyte ratio Unit =0.5*Cvhorwitz =0.67*Cvhorwitz = 2 * C ^(-0.1505)
100 1 100% 1.0 1.3 2.0
10 0.1 10% 1.4 1.9 2.8
1 0.01 1% 2.0 2.7 4.0
0.1 0.001 0.1% 2.8 3.8 5.7
0.01 0.0001 100 ppm 4.0 5.4 8.0
0.001 1E-05 10 ppm 5.7 7.6 11.3
0.0001 1E-06 1 ppm 8.0 10.7 16.0
1E-05 1E-07 100 ppb 11.3 15.2 22.6
1E-06 1E-08 10 ppb 16.0 21.4 32.0
1E-07 1E-09 1 ppb 22.6 30.3 45.2
Unknown 0.1813 1.3 1.7 2.59
0.1813
18.13
100

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9.7E-06
9.7
1000000

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0.1085
10.85
100
epeatability between lab
Horwitz %RSD
= 2 ^(1-0.5*LogC)
2.0 2.0
2.8 2.8
4.0 4.0
5.7 5.7
8.0 8.0
11.3 11.3
16.0 16.0
22.6 22.6
32.0 32.0
45.3 45.3
2.59

11.4

2.79
 Lab Fat Content (%) Mean SD RSD (%)
10.7
01 11.08 10.92 0.196 1.791
10.97
11.59
02 11.71 11.73 0.146 1.243
11.88
10.62
03 10.68 10.65 0.031 0.287
10.66
10.79
04 10.98 11.04 0.290 2.628
11.36
9.71
05 9.69 0.035 0.365
9.66
11.2
06 11.28 11.21 0.061 0.545
11.16
10.92
07 10.89 10.87 0.062 0.575
10.8
10.14
08 10.34 10.28 0.118 1.153
10.35
average 10.84652173913 10.80 0.117 1.073
Grand mean 10.85 N= 23 0.471588
Sr 0.150 0.563 0.615 0.090 0.117
RSDr 1.38
SR 0.59
RSDR 5.4395318 5.42
PRSDR 2.79
HORRAT 1.94