KCET-2014-Set-A-1 Questions - Chemistry: © Acadecraft PVT LTD

KCET-2014-Set-A-1
Questions – Chemistry
1. 25 cm3 of oxalic acid completely neutralised 0.064 g of sodium

hydroxide. Molarity of the oxalic acid solution is
(1) 0.045
(2) 0.032
(3) 0.064
(4) 0.015
2. The statement that is NOT correct is

(1) Energies of stationary states in hydrogen like atoms is
inversely proportional to the square of the principal quantum
number
(2) The radius of the first orbit of He is half that of the first
orbit of hydrogen atom.
(3) Angular quantum number signifies the shape of the orbital.
(4) Total number of nodes for 3s orbital is three.
3. For the equilibrium:
© Acadecraft Pvt Ltd.

CaCO3s  CaOs   CO2 g  ; K p  1.64atm at 1000 K
50 g of CaCO3 in a 10 litre closed vessel is heated to 1000 K.

Percentage of CaCO3 that remains unreacted at equilibrium is
 Given R  0.0821 L atm K 1

mol1 
(1) 50
(2) 20
(3) 40
(4) 60
4. Conversion of oxygen into ozone is non-spontaneous at

(1) high temperature
(2) low temperature
(3) all temperatures
(4) room temperature
5. Density of carbon monoxide is maximum at

(1) 0.5 atm and 273 K
(2) 4 atm and 500 K
(3) 2 atm and 600 K
(4) 6 atm and 1092 K

6. The acid strength of active methylene group in
(a) CH3COCH2COOC2 H5
(b) CH3COCH2COCH3
(c) C2H5OOCCH2COOC2H5 decreases as
(1) a  b  c
(2) c  a  b
(3) a  c  b
(4) b  a  c
7. A metallic oxide reacts with water to from its hydroxide,

hydrogen peroxide and also liberates oxygen. The metallic oxide
could be
(1) KO2
(2) Na 2O2
(3) CaO
(4) Li 2O
8. X 
 Reductive   Y  Z
Ozonolysis
Y can be obtained by Etard‟s reaction, Z undergoes

disproportionation reaction with concentrated alkali. X could be

(1)
(2)
(3)
(4)
9. Gold Sol is not

(1) a lyophobic colloid
(2) negatively charged colloid
(3) a macro molecular colloid
(4) a multimolecualr colloid
10. Carbocation as an intermediate is likely to be formed in the

reaction:
 OH
(1) Acetone  HCN   acetonecyanohydrin
(2) Hexane 
Anhy.AlCl3 /HCl
 2-methyl pentane
(3) Propene  Cl2 

hν
 2-chloropropane

(4) Ethylbromide  Aq KOH   ethyl alcohol
11. For an ideal binary liquid mixture
(1) H mix   0; S mix   0
(2) S mix   0; G  mix   0
(3) S mix   0; G  mix   0
(4) V mix   0; G  mix   0
12. For hydrogen–oxygen fuel cell at one atm and 298 K

1
H 2 g  O2 g  H 2O l ; G ο  240 kJ
2
E ο for the cell is approximately,
 Given F  96,500 C
(1) 1.24 V
(2) 1.26 V
(3) 2.48 V
(4) 2.5 V
13. Which one of these is not known ?

(1) CuI2
(2) CuBr2
(3) CuCl2
(4) CuF2
14. The correct statement is

(1) The extent of actinoid contraction is almost the same as
lanthanoid contraction.
(2) Ce4 in aqueous solution is not known.
(3) The earlier members of lanthanoid series resemble calcium
in their chemical properties.
(4) In general, lanthanoid and actinoids do not show variable
oxidation states.
15. P 
1. CH3MgBr
2. H O +  R 
1. dil. NaOH
2. 
 4-methylpent-3-en-2-one
3
P is
(1) ethanamine
(2) ethanal
(3) propanone
(4) ethanenitrile

16. When CH2  CH  O  CH2  CH3 reacts with one mole of HI,
one of the products formed is
(1) ethanol
(2) ethanal
(3) ethane
(4) iodoethene
17. 0.44 g of a monohydric alcohol when added to

methylmagnesium iodide in ether liberates at S.T.P., 112 cm3 of
methane. With PCC the same alcohol forms a carbonyl
compound that answers silver mirror test. The monohydric
alcohol is
(1)  CH3 3 C  CH 2OH
(2)  CH3 2 CH  CH2OH
(3)
(4)
18.

The IUPAC name of „B‟ is
(1) 2-methylbutan-3-ol
(2) Pentan-2-ol
x
19. For Freundilich isotherm a graph of log is plotted against log
m
P. The slope of the line and its y-axis intercept, respectively
corresponds to
1
(1) log , k
n
1
(2) log ,log k
n
1
(3) ,k
n
1
,log k
(4) n

1
20. A plot of Vs. k for a reaction gives the slope 1104 K The
T
energy of activation for the reaction is
 Given R  8.314 J K 1
mol1 
(1) 1.202 kJ mol1

(2) 83.14 kJ mol1
(3) 8314 J mol1
(4) 12.02 J mol1
21. The IUPAC name of the complex ion formed when gold
dissolves in aquaregia is
(1) tetrachloridoaurate (I)
(2) dichloridoaurate (III)
(3) tetrachloridoaurate (III)
(4) tetrachloridoaurate (II)
22. The correct sequence of reactions to be performed to convert

benzene into m-bromoaniline is
(1) bromination, nitration, reduction
(2) reduction, nitration, bromination
(3) nitration, reduction, bromination
(4) nitration, bromination, reduction
23.
Y is
(1)
(2)
(3)
(4)

24. A g    P g   Q g   R  g  , follows first order kinetics with a
half life of 69.3 s at 500 C . Starting from the gas „A‟ enclosed
in a container at 500 C and at a pressure of 0.4 atm, the total
pressure of the system after 230 s will be
(1) 1.32 atm
(2) 1.12 atm
(3) 1.15 atm
(4) 1.22 atm

MnO 2  HCl   Ag 
25. A g   F2 excess  
573 K
 B g 
B l   U s  
 C g   D  g 
The gases A, B, C and D are respectively

(1) Cl2 ,ClF3 , UF6 ,ClF
(2) O2 ,O2F2 , U2O3 ,OF2
(3) Cl2 ,ClF, UF6 ,ClF3
(4) O2 ,OF2 , U2O3 ,O2F2
26. Acetophenone cannot be prepared easily starting from

(1) C6 H5CH3
(2) C6 H6
(3) C6H5CH  OH  CH3
(4) C6H5C  CH
27. One mole of ammonia was completely absorbed in one litre

solution each of
(a) 1 M HCl , (b) 1 M CH3COOH and (c) 1 M H2SO4 at 298 K.
The decreasing order for the pH of the resulting solutions is
 Given K  NH   4.74
b 3
(1) a  b  c
(2) c  b  a
(3) b  c  a
(4) b  a  c
28. 5.5 mg of nitrogen gas dissolves in 180 g of water at 273 K and

one atm pressure due to nitrogen gas. The mole fraction of
nitrogen in 180 g of water at 5 atm nitrogen pressure is
approximately
(1) 1105
(2) 1104
(3) 1106
(4) 1103
29. 50 cm3 of 0.04 M K 2Cr2O7 in acidic medium oxidizes a sample

of H 2S gas to sulphur. Volume of 0.03 M KMnO4 required to
oxidize the same amount of H 2S gas to sulphur, in acidic
medium is
(1) 80 cm3

(2) 120 cm3
(3) 60 cm3
(4) 90 cm3
30. The compound that reacts the fastest with sodium methoxide is
(1)
(2)
(3)
(4)
31. The pair of compounds having identical shapes for their

molecules is
(1) BCl2 ,ClF3
(2) SO2 ,CO2
(3) CH 4 ,SF4
(4) XeF2 , ZnCl2
32. Conductivity of a saturated solution of a sparingly soluble salt

AB at 298 K is 1.85 105 S m1 . Solubility product of the salt
AB at 298 K is
Given οm  AB  140 104 S m2 mol-1
(1) 1.32 1012

(2) 1.74 1012
(3) 5.7 1012
(4) 7.5 1012
33. An incorrect statement with respect to SN1 and SN 2 mechanisms

for alkyl halide is
(1) Competing reaction for an SN 2 reaction is rearrangement.
(2) A weak nucleophile and a protic solvent increases the rate or
favours SN1 reaction.

(3) A strong nucleophile in an aprotic solvent increases the rate
or favours SN 2 reaction.
(4) SN1 reactions can be catalysed by some Lewis acids.
34. Butylated hydroxyl toluene as a food additive acts as

(1) flavouring agent
(2) emulsifier
(3) antioxidant
(4) colouring agent
35. Terylene is NOT a

(1) polyester fiber
(2) step growth polymer
(3) copolymer
(4) chain growth polymer
36. The correct statement is

(1) One mole each of benzene and hydrogen when reacted gives
1/3 mole of cyclohexane and 2/3 mole unreacted hydrogen.
(2) It is easier to hydrogenate benzene when compared to
cyclohexene.
(3) Cyclohexadiene and cyclohexene cannot be isolated with
ease during controlled hydrogenation of benzene.
(4) Hydrogenation of benzene to cyclohexane is an endothermic
process.
37. Among the elements from atomic number 1 to 36, the number of
elements which have an unpaired electron in their s subshell is
(1) 7
(2) 9
(3) 4
(4) 6

(1) Van der Waals constant „a‟ measures extent of
intermolecular attractive forces for real gases.
(2) Boyle point depends on the nature of real gas.
(3) Compressibility factor measures the deviation of real gas
from ideal behaviour.
(4) Critical temperature is the lowest temperature at which
liquefaction of a gas first occurs.

39. The correct arrangement for the ions in the increasing order of
their radii is
(1) Ca 2 ,K  ,S2
(2) Cl ,F ,S2
(3) Na  ,Cl ,Ca 2
(4) Na  ,Al3 ,Be2
40. The correct arrangement of the species in the decreasing order of

the bond length between carbon and oxygen in them is
(1) CO2 ,HCO2 ,CO,CO32
(2) CO,CO32 ,CO2 ,HCO2
(3) CO,CO2 ,HCO2 ,CO32
(4) CO32 ,HCO2 ,CO2 ,CO
41. The species that is not hydrolysed in water is

(1) BaO2
(2) CaC2
(3) P4O10
(4) Mg3 N 2

42. For the properties mentioned, the correct trend for the different
species is in
(1) inert pair effect Al  Ga  In
(2) first ionization enthalpy B  Al  Tl
(3) strength as Lewis acid BCl3  AlCl3  GaCl3
(4) oxidising property Al3  In 3  Tl 3
43. A correct statement is

(1)  MnBr4  is tetrahedral.
2
2
(2)  Ni  NH3 6  is an inner orbital complex.
2
(3) CO  NH3 6  is paramagnetic.

(4) COBr2  en 2  exhibits linkage isomerism.
44. Iodoform reaction is answered by all, except

(1) CH3CHO
(2) CH3  CH2  CH2OH
(3) CH3  CH  CH 2  COOH
|
OH

(4) CH3  CH2  OH
45. A crystalline solid XY3 has ccp arrangement for its element Y.
X occupies
(1) 33% of tetrahedral voids
(4) 66% of octahedral voids
46. C6H5COOH 

1. NH3
2. 
 P 
NaOBr
 Q 
1. Conc. H2SO4
2. heat to460 K
 'R '
„R‟ is
(1) sulphanilamide
(2) p-bromo sulphanilamide
(3) o-bromo sulphanilic acid
(4) sulphanilic acid

(1) Carbohydrates are optically active.
(2) Lactose has glycosidic linkage between C 4 of glucose and
C1 of galactose unit.

(3) Aldose or ketose sugars in alkaline medium do not
isomerise.
(4) Penta acetate of glucose does not react with hydroxylamine.
48. Match the reactant in Column-I with the reaction in Column-II.

I II
(i) Acetic Acid Stephen
(ii) Sodium phenate Friedel-Crafts
(iii) Methyl cyanide HVZ
(iv) Toluene Kolbe‟s
(1) i  d, ii  b, iii  c, iv  a
(2) i  c, ii  d, iii  a, iv  b
(3) i  c, ii  a, iii  d, iv  b
(4) i  b, ii  c, iii  a, iv  d

(1) In solid state PCl5 exists as  PCl4   PCl6 
 
(2) Phosphorous acid on heating disproportionates to give

metaphosphoric acid and phosphine.
(3) Hypophosphorous acid reduces silver nitrate to silver.
(4) Pure phosphine is non-inflammable.
50. In which one of the pairs of ion given, there is an ion that forms
a co-ordination compound with both aqueous sodium hydroxide
and ammonia and another ion that forms a co-ordination
compound only with aqueous sodium hydroxide?
(1) Zn 2 , Al3
(2) Al3 , Cu 2
(3) Pb2 , Cu 2
(4) Cu 2 , Zn 2
51. A crystalline solid X reacts with dil. HCl to liberate a gas Y. Y

decolorizes acidified KMnO4 . When a gas „Z‟ is slowly passed
into an aqueous solution of Y, colloidal Sulphur is obtained X
and Z could be, respectively?
(1) Na 2SO4 , H2S
(2) Na 2SO4 , SO2
(3) Na 2S, SO3
(4) Na 2SO3 , H2S

52. An aromatic compound „A‟  C7 H 9 N  on reacting with
NaNO2 /HCl at 0 C forms benzylalcohol and nitrogen gas. The

number of isomers possible for the compound „A‟ is
(1) 7
(2) 6
(3) 5
(4) 3

(1) Collectors enhance the wettability of mineral particles
during froth flotation.
(2) Copper from its low grade ores is extracted by
hydrometallurgy.
(3) A furnace lined with Haematitie is used to convert cast iron
to wrought iron.
(4) In vapour phase refining, metal should form a volatile
compound.
54. A solution of 1.25 g of „P‟ in 50 g of water lowers freezing point

by 0.3 C . Molar mass of „P‟ is 94. K f  water   1.86 K kg mol-1 .
The degree of association of „P‟ in water is

(1) 60%
(2) 75%
(3) 80%
(4) 65%
55. Volume occupied by single CsCl ion pair in a crystal is

7.014 1023 cm3 . The smallest Cs  Cs internuclear distance is
equal to length of the side of the cube corresponding to volume
of one CsCl ion pair. The smallest Cs to Cs internuclear distance
is nearly
ο
(1) 4.3 A
ο
(2) 4.5 A
ο
(3) 4.4 A
ο
(4) 4 A
56. For Cr2O72  14 H  6e  2Cr 3  7H 2O; E ο  1.33 V At
Cr2O72   4.5 milimole, Cr 3   15 milimole, E is 1.067 V.
The pH of the solution is nearly equal to

(1) 3

(2) 4
(3) 2
(4) 5
57. 1.78 g of an optically active L-amino acid (A) is treated with

NaNO2 /HCl at 0 C . 448 cm3 of nitrogen was at STP is evolved.
A sample of protein has 0.25% of this amino acid by mass. The
molar mass of the protein is
(1) 34,500 g mol1
(2) 35,600 g mol1
(3) 36,500 g mol1
(4) 35,400 g mol1
58. 10 g of a mixture of BaO and CaO requires 100 cm3 of 2.5 M

HCl to react completely. The percentage of calcium oxide in the
mixture is approximately
 Given : molar mass of BaO  153
(1) 55.1
(2) 47.4
(3) 52.6

(4) 44.9
59. The ratio of heats liberated at 298 K from the combustion of one
kg of coke and by burning water gas obtained from kg of coke is
(Assume coke to be 100% carbon).
(Given enthalpies of combustion of CO2 , CO and H 2 as 393.5
kJ, 285 kJ, 285 kJ respectively all at 298 K).
(1) 0.69 :1
(2) 0.96 :1
(3) 0.79 :1
(4) 0.86 :1
60. Impure copper containing Fe, Au, Ag as impurities is

electrolytically refined. A current of 140 A for 482.5 s decreased
the mass of the anode by 22.26 g and increased the mass of
cathode by 22.011 g. Percentage of iron in impure copper is
(Given molar mass Fe  55.5 g mol1 , molar mass
Cu  63.54 g mol1 )
(1) 0.85
(2) 0.90
(3) 0.95
(4) 0.97

KCET-2014-Set-A-1
Answer keys
1 2 16 2 31 4 46 4
2 4 17 1 32 2 47 3
3 4 18 3 33 1 48 2
4 1 19 4 34 3 49 4
5 2 20 2 35 4 50 1
6 4 21 3 36 3 51 4
7 1 22 4 37 4 52 3
8 1 23 3 38 4 53 1
9 3 24 2 39 1 54 3
10 2 25 1 40 4 55 4
11 2 26 1 41 1 56 3
12 1 27 4 42 2 57 2
13 1 28 2 43 3 58 3
14 3 29 1 44 2 59 1
15 4 30 4 45 2 60 2

KCET-2014-Set-A-1
Solutions – Chemistry
1. The molarity of oxalic acid can be calculated as:

Moles of oxalic acid  Moles of NaOH
w
V N 
M
25 0.064
N 
1000 M
0.064  1000
N
40  25
Simplify the above equation,
N  0.064
The relation between molarity and normality is shown below.
N
M
2
0.064

2
 0.032
2. The total number of nodes for 3s orbital is 2 as calculated below.
For 3s, the value of n will be equal to 3.
Therefore,

Total nodes  n  1
 3 1
2
3. The reaction is shown below.

CaCO3 CaO  CO2
PV
Moles of CO 2  n  
RT
1.64  10

0.082  1000
 0.2
50 g CaCO3  0.5 mol CaCO3
Therefore,
0.5 mol CaCO3 produces 0.2 mol CO2
The percentage of CaCO3 that remains unreacted is calculated
as:
0.3
Percentage of unreacted CaCO3  100
0.5
 60%
4. At high temperature, ozone remains unstable. Thedecomposition

reaction is shown below.
2O3  O2
Hence, the conversion of oxygen into ozone is non-spontaneous
at high temperature.
PM
5. Density depends upon the ratio of
RT
In the above expression, M and R remains constant for a specific
gas.
P
Therefore, density is directly proportional to
T
0.5
(1) d   0.0183
273
4
(2) d   0.0080
500
2
(3) d   0.0033
600
6
(4) d   0.00549
1092
Therefore, the density of CO2 is maximum at a condition of 4
atm and 500 K

6. The acid strength of active methylene group depends upon the
presence of electron withdrawing groups. The electron
withdrawing ability of is higher than

Therefore, the correct order is
7. When potassium superoxide reacts with water to give a mixture

of potassium hydroxide, hydrogen peroxide and liberates
oxygen. The reaction is shown below.
2KO2  2H2O  2KOH  H2O2  O2
8. It is given that Y is obtained from Etard‟srecation. This means it

is:
It is given that Z shows disproportionation reaction with a base.

This means it undergoes Cannizzaro‟s reaction. Thus, Z is
HCHO.
Therefore, X is:

9. Gold sol possesses particles of different sizes. Therefore, it
cannot be a macromolecular colloid.
10. The carbocation is likely to be formed in the following reaction.
The above reaction forms highly stable carbocation as it

involves methyl shift.
11. For an ideal binary liquid mixture, the value of H mix and Vmix
remains zero.
Therefore,
Gmix  0
Smix  0
12. The cell potential is calculated by applying Nernst equation as

shown below.

G ο  nFE ο
240 kJ  2  96500  E ο
240 kJ
Eο 
2  96500
 1.24 V
13. The substance CuI2 remains unstable; therefore, it converts into

cuprous iodide and iodine. The reaction is as follows:
2CuI2  Cu 2I2  I2
14. The chemical properties of earlier members of lanthanoid series

are identical to that of calcium.
15. P is ethanenitrile.
16. CH2CH  CH  O  CH2  CH3 is an allyl ethyl ether which

undergoes nucleophilic substitution reaction with one mole of
HI and form ethanal. The reaction mechanism is shown below.

17. .At STP, the molar mass of alcohol is calculated as:
0.44  22400 cm3
Molar mass of alcohol 
112 cm3
 88
Therefore, the correct option is (a) which is having molecular
mass of 88.
18. When methylmagensium bromide reacts with carbonyl

compound, it gives addition product and then undergoes
hydrolysis to form 3-methylbutan-2-ol.
x
19. A graph of log versus P is shown below.
m

1
20. In the graph of ln K vs , the slope is equal to:
T
Ea
Slope  
R
Ea
1 104  
8.314
E a  8.314  104 J
The conversion of E a into kJ is done as:

1 kJ
E a  8.314  104 J 
1000 J
 83.14 kJ mol1
21. Aquaregia is a solution of HCl and concentrated HNO3 which

are present in the ratio of 3:1.

The reaction is shown below.
AuCl3  HCl  4AuCl4
Therefore, the IUPAC name of the complex ion is
Tetrachloridoaurljate (III)
22. In the first step, nitration of benzene forms nitrobenzene. In the

second step, the bromination forms 1-bromo-3-nitrobenzene and
in third step, the reduction of nitro compound takes place and
forms m-bromoaniline.
The reaction is as follows.
23. Phenol undergoes nucleophilic substitution reaction when it

reacts with benzoyl chloride and gives phenylbenzoate. The
nitration of phenylbenzoate gives a desired product as shown
below.

24. For first order reaction,
0.693
k
t1/2
0.693

69.3
 0.01 s 1
Now, the final pressure is calculated as:
2.303 a
k log
t ax
2.303 0.4
0.01  log
230 s 0.4  x
0.4
0.01  0.01 log
0.4  x
0.4
10 
0.4  x
x  0.36

A g    P g  Q g  R g 
Initial 0.4 0 0 0
Final 0.4  0.36 0.36 0.36 0.36
Therefore, total pressure is calculated as:

Total pressure   0.4  0.36    3  0.36 
 1.12 atm
25. When MnO2 reacts with HCl, chlorine gas is liberated.


MnO2  4HCl   Cl2  A   MnCl2  2H 2O
When chlorine reacts in the presence of excess fluorine, chlorine
trifluoride gas is formed.

Cl2  F2 excess    ClF3  B
When ClF3 reacts with uranium, uranium hexafluoride and

chlorine monofluoride are formed.
3ClF3  U5  UF6  C   3ClF  D 
26. The synthesis of acetophenone from toluene cannot be done

easily as this involves multistep reactions. Acetophenone can be
easily synthesized from other organic compounds as shown
below.
(2)
(3)

(4)
27. The correct order of acidic strength is shown below,

H2SO4  HCl  CH3COOH
As we know, the pH is inversely proportional to acidic strength.
Therefore, the correct order is:
CH3COOH  HCl  H2SO4
28. The quantity of nitrogen at 5 atm can be calculated as:

Mass of N 2  5  5.5
 27.5 mg
The mole fraction of nitrogen is calculated as:
nN2
N2 
nH2O
2.7  103  18

28  180
 1 104
29. The normality is calculated by using the expression shown

below.

Normality Molar mass

Molarity Equivalent mass
Therefore,
0.04 M K 2Cr2O7  0.24 N
0.04 M KMnO4  0.15 N
The volume of KMnO4 required is calculated as:
N1V1  N 2 V2
N1V1
V2 
N2
0.24  50

0.15
 80 mL
30. Lesser the number ofelectron withdrawing groups present in a
ring, the higher is the rate of reaction.In , no withdrawing

group is present, therefore, this compound reacts the fastest with
sodium methoxide.
31. Both XeF2 and ZnCl2 have linear shape.

32. The solubility is calculated as:
K  1000
S
 οm
1.85  105

1000  140  104
 1.3  106
K sp   A    B 
 SS
 S2
Therefore,
K sp  1.3  106 
2
 1.69  1012
 1.74  1012
33. SN 2 reaction does not undergo rearrangement reaction as it

involves the inversion of configuration.
34. Butylated hydroxyl toluene is also known as BHT which is used

in the preservation of food items as they slow down the effect of
oxygen on them.

35. Terylene is referred to as step growth polymer. It is formed from
terephthalic acid and ethylene glycol.
36. Cyclohexadiene and cylcohexene cannot be isolated on

controlled hydrogenation of benzene. This is due to the
availability of reducing agent which further reduces hexadiene
to hexene. The reaction is shown below.
37. Among the elements from 1 to 36 atomic number, the elements

which have an unpaired electron in their s-subshell are shown
below.
1 H, 3Li, 11Na, 19K, 24Cr and 29Cu
38. The maximum temperature below which a particular gas

undergoes liquefication by pressure but above that temperature,
the gas cannot be liquefied.
39. Ca 2+ , K + and S2- are isoelectronic species as they have identical

number of electrons ,i.e., 18.
As we know that the atomic radius depends upon the size of
protons. The atomic radius decreases as the number of protons
increases.
Ca 2+ K+ S2-
Number of protons 20 19 16
Therefore, the correct order of ionic radii is:

Ca 2  K   S2
40. The bond length is related to the type of bond present in a

compound.
Single bond: longest bond length
Double bond: Intermediate bond length
Triple bond: shortest bond length.
Therefore, the correct order of bond length is as follows:
CO32  HCO2  CO2 > CO
41. The species that is not hydrolysed in water is BaO2 . All other
species undergo hydrolysis in water.

42. As we move down a group in the periodic table, the ionization
enthalpy goes on decreasing. Therefore, the correct order of first
ionization enthalpy is shown below.
B  Al  Tl
2
43. In the complex ion CO  NH3 6  , the oxidation state of Co is
2 . Its electronic configuration is 3d 7 which is equal to  18 Ar  .
All the electrons are paired; hence, the complex ion is

2
CO  NH3 6  isparamagnetic.
44. Iodoform reaction is answered by those compounds in which

carbonyl groups  CH3CO   are present.
When CH3CH2CH2OH undergoes iodoform reaction, it gives

CH3CH2CHO which is a member of carbonyl group. The
reaction is shown below.
 
CH3CH2CH2OH   CH3CH2CHO
O

45. A unit cell has four particles of Y in ccp arrangement.
Therefore,
4
Number of X particles 
3
 1.33
There are total four octahedral voids in a ccp arrangement.
Therefore,
1.33
Percentage of X particles containing octhaderal voids   100
4
 33%
46. In first step, when C6H5COOH is heated with ammonia,

ammonium benzoate is formed. On further heating, benzamide
(P) is formed.
In second step, when benzamide reacts with NaOBr, it gives
aniline (Q).
In third step, aniline reacts with concentrated H 2SO4 to form
aniline hydrogen sulphate. By rearrangement reaction, the final
product formed is sulphanilic acid (R).
The reaction is as follows:

47. Aldose or ketose sugar undergoes isomerization in basic
medium in the presence of alkaline earth aluminate catalyst.
48. Acetic acid which has an hydrogen undergoes Hell-Volhard-

Zelinsky reaction (HVZ) to form an  halocarboxylic acid.
In Kolbe‟s reaction, phenol reacts with NaOHand form sodium

phenate which undergoes hydrolysis reaction to form salicylic
acid.

In Stephen reaction, cyanide undergoes reduction to form an
imide which on subsequent hydrolysis gives an aldehyde.
In Friedel-Craft‟s reaction, the heating of benzene in the

presence of AlCl3 catalyst forms toluene.
Therefore, the correct order is

i  c, ii  d, iii  a, iv  b
49. Pure phosphine is inflammable at high temperature. It catches

fire easily when temperature is above 460 K.

50. Zn 2+ forms co-ordination complexes of Na 2  Zn  OH 4  and
2
 Zn  NH3 4  with NaOH and ammonia respectively.
Al3+ forms co-ordination complex of Na  Al  OH 4  when it
reacts with NaOH.
51. When Na 2SO3 (X) react with dil HCl, sulphur dioxide gas (Y) is
liberated. The reaction is as follows:
Na 2SO3  X   2HCl  2NaCl  H 2O  SO2  Y 
Sulphur is obtained when hydrogen sulphide (Z) is passed into
aqueous solution of SO2 ,i.e., H 2SO3
H 2O  SO2  Y   H 2SO3
H 2SO3  2H 2S  Z   2S  3H 2O
52. The aromatic compound is benzyl imine  C6H5CH 2 NH 2  . There

are five possible isomers of benzyl amine as shown below.

53. In froth floatation process, pine oil, fatty acids and xanthates act
as collectors. They enhance the non-wettability of mineral
particles.
54. The Van‟t Hoff factor is calculated by using the expression

shown below.
Tf  iK f m
25
0.3  i  1.86 
94
0.3  94
i
1.86  25
 0.6064
The degree of association of “P” is calculated as:
i 1

1
1
n
0.6064  1

1
1
2
 0.7872
 78.8%
Therefore, the approximated degree of dissociation of P is
 80 % .

55. The internuclear distance is calculated as:
V  a3
7.014  1023  a 3
a  3 7.014  1023
 4.124  108 cm
ο
The conversion of edge length into A is done as:
ο
1A
a  4.124  108 cm 
108 cm
ο
 4.12 A
ο
 4A
56. Apply Nernst equation;
Cr 3+   H 2O
2 7
0.0591
Ecell  Ecell 
ο
log 14
n Cr2O72   H  
The number of transferred electrons is 6. Therefore, the value of

n is 6.
Substitute all the values in the above expression to calculate
concentration of H 

1.5 103  1
2 7
0.0591
1.067  1.33  log
6  4.5  10 3
  
 H  14
0.0591 2.25  106

0.263   log
6  4.5  10 3
  
 H  14
0.263 
 log50  log  H   
14
0.0098  
  14 
26.83  log 50  log  H 
 
26.83  1.6990  14 pH
25.131  14 pH
25.131
pH  2
14
57. At STP, the molar mass of L-amino acidis calculated as:

1.78  22400 cm3
Molar mass of L-amino acid 
448 cm3
 89
It is given that protein contains 0.25% of amino acid
Therefore, the molar mass of protein is calculated as:

100  89
Molar mass of protein 
0.25
 35600 g/mol
58. Let‟s assume that mass of CaO is x and BaOis 10  x .

The equivalent mass of CaO is 28 and BaO is 76.5
Therefore,
10  x x 100  2.5
 
76.5 28 1000
10  x x
  0.25
76.5 28
76.5 x  28 10  x   0.25  28  76.5
x  5.26
The percentage of CaO is calculated as:
5.26
% of CaO   100
10
 52.6%
59. The number of moles of 1kg coke is calculated as:

1000
Moles 
12
 83.33 mol
For 1 mol of coke, the heat liberated is 393.6 kJ.
For 83.33 mol of coke, the heat liberated is calculated as:
Heat liberated  83.33  393.5 kJ
For the reaction,
CO  H2  O2  CO2  H2O; H  285  285  570 kJ
Therefore, the ratio is equal; to
393.5 : 570
0.69 :1
60. The equivalent of weight of Cu 2 and Fe2 are 31.77 and 27.55
respectively.
22.011
Number of gram equivalents of Cu deposited 
31.77
 0.698
Apply Faraday‟s Law;
Q  It
 140  482.5 s
 67550 C
At 96500 C, 31.77 g of Cu deposited.
Therefore, at 67550 C, the mass of Cu deposited is calculated
as:
31.77
Mass of Cu deposited   67550
96500
 22.239 g
Hence,
22.239 g  22.011g  0.228 g
Now, the mass of Fe deposited is calculated as:
0.228
Mass of Fe deposited   27.75
31.77
 0.199 g
Mass of Fe
%of Fe   100
Amount of impurity
0.199
  100
22.26
 0.90

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KCET-2014-Set-A-1

1. 25 cm3 of oxalic acid completely neutralised 0.064 g of sodium

2. The statement that is NOT correct is

3. For the equilibrium:

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50 g of CaCO3 in a 10 litre closed vessel is heated to 1000 K.

 Given R  0.0821 L atm K 1

4. Conversion of oxygen into ozone is non-spontaneous at

5. Density of carbon monoxide is maximum at

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7. A metallic oxide reacts with water to from its hydroxide,

Y can be obtained by Etard‟s reaction, Z undergoes

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9. Gold Sol is not

10. Carbocation as an intermediate is likely to be formed in the

(3) Propene  Cl2 

(2) S mix   0; G  mix   0

(3) S mix   0; G  mix   0

(4) V mix   0; G  mix   0

12. For hydrogen–oxygen fuel cell at one atm and 298 K

13. Which one of these is not known ?

14. The correct statement is

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17. 0.44 g of a monohydric alcohol when added to

(2)  CH3 2 CH  CH2OH

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(1) 1.202 kJ mol1

22. The correct sequence of reactions to be performed to convert

The gases A, B, C and D are respectively

26. Acetophenone cannot be prepared easily starting from

27. One mole of ammonia was completely absorbed in one litre

28. 5.5 mg of nitrogen gas dissolves in 180 g of water at 273 K and

29. 50 cm3 of 0.04 M K 2Cr2O7 in acidic medium oxidizes a sample

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31. The pair of compounds having identical shapes for their

32. Conductivity of a saturated solution of a sparingly soluble salt

(1) 1.32 1012

33. An incorrect statement with respect to SN1 and SN 2 mechanisms

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34. Butylated hydroxyl toluene as a food additive acts as

35. Terylene is NOT a

36. The correct statement is

38. The statement that is NOT correct is

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40. The correct arrangement of the species in the decreasing order of

41. The species that is not hydrolysed in water is

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43. A correct statement is

44. Iodoform reaction is answered by all, except

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46. C6H5COOH 

47. The statement that is NOT correct is

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48. Match the reactant in Column-I with the reaction in Column-II.

49. The statement that is NOT correct is

(2) Phosphorous acid on heating disproportionates to give

51. A crystalline solid X reacts with dil. HCl to liberate a gas Y. Y

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NaNO2 /HCl at 0 C forms benzylalcohol and nitrogen gas. The

53. The statement that is NOT correct is

54. A solution of 1.25 g of „P‟ in 50 g of water lowers freezing point

The degree of association of „P‟ in water is