TECHNOLOGICAL INSTITUTE OF THE PHILIPPINES

QUEZON CITY
FINAL EXAMINATION
SET A
NAME______________________________________________________ DATE OF EXAM________________________
SUBJECT/SECTION_______CHE 324L2_________________________INSTRUCTOR: ENGR. LORRAINE A. CARRILLO
Directions: Shade the circle that corresponds to the correct answer.
1. It was first used as an anesthetic in 1824. It produces unconsciousness and insensitivity to pain by inhibiting activity of the
central nervous system.
a) chloroform b) diethyl ether c) benzaldehyde d) thiopental sodium
2. They are a class of cyclic ethers in which the ether oxygen is included in a three-membered ring.
a) furan b) esters c) epoxides d) ethers
3The acidic ingredient in vinegar and the pure acid is a useful solvent and manufacturing intermediate.
a) Benzoic acid b) Nitric acid c) acetic acid d) oxalic acid
4. These are different compounds that have the same molecular formula but different structural formula
a. isomers b. enantiomers c. isobars d. polar
5. This geometric isomer indicate that a particular group are on the same side of the molecules.
a. cis-isomer b. diastereomers c. trans-isomer d. enantiomer
6. This principle states that the addition of an acid to the carbon-carbon double bond of an alkene, the hydrogen of the acid
attachés itself to the carbon that already holds the greater number of hydrogens.
a. Markovnikov’s Rule b. Anti- Markovnikov’s Rule c. Saytzeff’s Rule d. Hund’s Rule of maximum Multiplicity
7. The name use to indicate that the alcohol has two OH group
a. diene b. diol c. triol d. triene
8. The angle separating hybrid orbitals in an alkane HC such as methane .
a. 110º b. 120º c. 180º d. 90º
9. The most stable structure for a carbocation
a. tertiary b. secondary c. primary d. quaternary
10. The IUPAC name for the substance HOCH2C=CCH2OH is
a. 2-butyne-1,3-diol b. 2-butyne-1,4 diol c. 2-ene-1,3-diol d. 2-ene-1,4-butanediol
11. This substituent is an example of a good leaving group.
a. Halogens b. Hydride ion c. Proton ion d. Alkyl group
12. The most acidic hydrogen in an alpha carbon occurs in
a. alkane b. alkene c. alkyne d. alcohol
13. A carbonyl group occurs in all of the following groups EXCEPT
a. aldehydes b. ketones c. ether d. carboxylic acid
14. The reason why some alcohols are soluble in water
a. hydrophobic interactions b. hydrogen bondings c. electrostatic interactions d. van der vaal’s forces
15. Which of the following alcohols will undergo a 1,2-methyl shift when it is heated with acid?
a. 1-methylcyclohexanol b. 2,3-dimethyl-3-hexanol c. 3-methyl-2-butanol d. 1,1-
dimethylcyclohexanol
16. The interconversion between the keto and enol forms is a special kind of isomerism.
a. geoisomerism b. tautomerism c. enantiomerism d. epimers
17. The reaction of carboxylic acids in their conversion into esters by reaction with an alcohol ( the substitution of
an -OH group with an -OR)
a. Fischer esterification b. saponification c. Wolf Kishner Reaction d. Aldol Condensation
18. Ethers can also exist as cyclic molecules.
a. ethylene glycol b. furans c. epoxides d. dioxane
19. This reagent oxidizes aldehydes while reducing cupric ion to red cuprous oxide precipitates indicating the
presence of aldehydes
a. Benedict’s reagent b. Tollens reagent c. Lucas Reagent d. Beilstein Reagent
20. The oxidation of aldehyde using chromic acid gives this product.
a. hemiacetals b. hemiketals c. ketones d. carboxylic acid
21. The addition of alcohols (in excess) to aldehydes yields this product.
a. acetals b. ketals c. hemiacetals d. hemiketals
22. It is the reaction when an enolate ion is prepared from an aldehyde, remaining un-ionized aldehyde is attacked
by the formed enolate ion.
a. Fischer esterification b. saponification c. Wolf Kishner Reaction d. Aldol Condensation
23. It is the reaction of sodium alkoxides with alkyl halides producing an ether.
a. Williamson synthesis b. saponification c. Wolf kischner reaction d. Fischer esterification
24. Which of the following compounds is 5-bromo-4-chloro-1-heptene
a. CH3CH2CHClCHBrCH2CH=CH2 b. CH3CH2CHBrCHClCH2CH=CH2
c. CH3CH2CBr=CClCH2CH2CH3 d. CH3CH2CHBrCHClCH2CH2CH3
25. How many carbons does the smallest asymmetrical internal alkyne have?
a. 5 b. 3 c. 4 d. 6
26. The molecular formula of a cyclic alkyne with 10 carbon atoms?
a. C10H14 b. C10H18 c. C10H16 d. C10H20
28. The molecular formula of benzene was established by Faraday but the structure was proposed by_________
a. Kekule’ b. Fischer c. Pauling d. Watson and Cricks
29. This rule determines whether a compound is aromatic or not.
a. 4+2 rule b. Huckel’s rule c. Resonance Hybridization d. Hund’s rule
30. Methyl groups, although it does not possess a pair of non-boned p electrons are ortho- and para- directing
because they undergo a special type of resonance.
a. hybridisation b. hyperconjugation c. resonance hybrid d. conjugation
31. This test determines a primary, secondary, and tertiary alcohols by observing the differences in the reaction
rates.
a. Benedict’s test b. Tollens test c. Lucas test d. Beilstein test
32. It is the reaction of esters with excess alcohol in the presence of a strong acid catalyst to give a new ester.
a. saponification b. alcoholysis c. ammonolysis d. hydrolysis of esters
33. It is the most abundant naturally occurring polysaccharide in nature.
a.glycogen b. amylose c. cellulose d. starch
34. They are derivatives of carboxylic acids in which the hydroxyl of the carboxyl group has been replaced by an
alkoxy group.
a. ethers b. esters c. waxes d. oils
35. The product of the reaction CH3CH=CH2 + H2 is
a. CH3CHOHCH3 b. CH3CH2CH3 c. CH3CH2CH2OH d. CH4 + C2H6
36. The hybridization of carbon 3 in 2-hexene.
sp b. sp2 c. sp3 d. sp4
37. Aromatic hydrocarbons such as benzene undergo what type of reactions.
a. nucleophilic aromatic substitution reactions b. electrophilic addition reactions
c. electrophilic aromatic substitution reactions d. electophilic aliphatic substitution reactions
38. What is the major product formed from the reaction of benzene with isobutyl chloride and AlCl 3?
a. 2-methyl-2-phenylpropane b. 2-phenylpropane c. isobutylbenzene d. 2-methyl-1-phenylpropane
39. The name of the electrophile that is used to nitrate benzene.
a. nitrate ion b. nitronium ion c. nitrite ion d. nitrosonium ion
40. Which series of reactions would give 1-phenylbutane as the major product?
a. ) butanoyl chloride + benzene + AlCl3 2) N2H4 + HCl
b) butanoyl chloride + benzene 2) Zn + HCl
c) butanoyl chloride + benzene + AlCl3
d) 1-chlorobutane + benzene + AlCl3
41. In what positions are the two carbonyl carbons in hexanedial?
a. 1 and 4 b. 1 and 5 c. 1 and 6 d. 3 and 4
42. Which of the following compounds is the most reactive?
a. 3-methyl-2-pentanone b. 3-pentanone c. 2-pentanone d. 3-methyl-2-butanone
43. The reagent needed to convert a ketone or an aldehyde into an oxime.
a. amine b. hydroxylamine c. hydrazine d. semicarbazide
44. Common table sugar, sucrose, is a disaccharide made up of one molecule of glucose and one molecule of
_______________.
a. mannose b. galactose c. fructose d. glucose
45. Test for hydrocarbons using KMnO4 solution.
a. Baeyer’s test b. Tollen’s test c. Fehling’s test d. Benedict’s test
46. The following are ortho-, para- directors except
a. –NO2 b. –CH3 c. -CN d. -Cl
47. A substance that donates a hydrogen ion (H+)
a. Bronsted-Lowry acid b. Bronsted-Lowry base c. Lewis acid d. Lewis base
48. A substance that has a vacant valence orbital and can thus accept an electron pair.
a. Bronsted-Lowry acid b. Bronsted-Lowry base c. Lewis acid d. Lewis base
49. An alkyl group is attached to an aromatic ring on reaction with an alkyl chloride, RCl, in the presence of AlCl3
catalyst, a process called _______.
a. Friedel-Crafts alkylation reaction b. Clemmensen Reaction c. Wolf-Kishner Reaction d. Wittig Synthesis
50. C6H5OH
a. phenyl alcohol b. Phenone c. phenol d. 1-benzene alcohol
51. Enantiomers are different molecules that are mirror images of each other.
a. structural isomers b. diastereoisomers c. stereoisomers d. none of the given
52. Enantiomers are different molecules that are mirror images of each other.
a. structural isomers b. diastereoisomers c. stereoisomers d. none of the given
53. The dehydration of 2-propanol produces
a. 2- propene b. propyne c. propene d. NOTG
54. What is the molecular formula of the molecule shown to the right:
a) C8H10 b) C6H6 b) C6H8 d) C8H12
55. The correct IUPAC name for the molecule below is:
a) 5-methyl-5-propylheptane
b) 4-ethyl-4-methyloctane
c) 3-methyl-3-propyloctane
d) 3-methyl-3-propylheptane
56. Which of the following is not a disubstituted benzene
a. O-xylene b. 2,4-dinitrotoluene c. 1,3-diamino benzene d. p-dichlorobenzene
57. Which of the following molecules does not contain C=O?
a. methanol b. methanal c. pentanone d. glucose
58. Another name for methoxybenzene
a. aniline b. xylene c. anisole d. cresol
59. Another name for aminobenzene
a. aniline b. xylene c. anisole d. cresol
60. Which of the following is not a polyhydric alcohol
a. 2,2.Dimethyl propanol b. glycerol c. propylene glycol d. 1,6- hexanedicol
61. The alkane containing a total of 20 hydrogen atoms must be an isomers of
a. cyclononane b. decane c. eicosane d. nonane
62. A liquid hydrocarbon is converted into a mixture of gaseous hydrocarbons by
a. Cracking b. Hydrolysis c. oxidation d. reduction
63. An Sp3hybrid orbital possesses
a. ¼ of S character b. ½ of s character c. 2/3 S character d. ¾ s character
64. The following reaction: RadC2H4∙ + C2H4 = RadC2H4 C2H4∙
a. addition b. elimination c. substitution d. rearrangement
65. Which of the following characteristics of chirality is not true?
a) The carbon atom is single bonded to four different atoms or groups of atoms.
b) The chiral carbon atom is said to be unsaturated.
c) Chiral molecules have optically active isomers.
d) Chiral molecules have two enantiomers.
66. A compound whose molecular structure rotates polarized light counterclockwise:
a) is designated as being dextrorotatory.
b) always has two chiral carbon centers.
c) is designated as being levoratatory.
d) belongs to the most abundant or naturally occurring group of carbohydrate enantiomers.
67. The product between benzene and ethyl chloride in the presence of aluminum chloride is
a. phenyl ethane b. chlorobenzene c. phenyl chloride d. NOTG
68. The reaction between benzene and 2-chloro-3-methylbutane in the presence of aluminum chloride produces _______
a. 2-methyl-2-phenylbutane b. 2-methyl-3-phenylbutane c. 2-phenyl-3-methylbutane d. NOTG
69.All of these are ortho, para directors and activator except one which is deactivating.
a. OH b. CH3 c. F d. NH2
70. the product between nitrobenzene and chlorine in the presence of FeCl3 is _____
a. 3-chloronitrobenzene b. 2-chloronitrobenzene c. 4-chloronitrobenzene d. NOTG
71.Friedal-crafts Alkylation only works with benzne, halobenzene and _________________.
a. deactivated compounds b. activated compounds c. NOTG
72.They make benzene ring less reactive than benzene.
a. activating group b. deactivating group c. substituent d. NOTG
73. The reaction between butanoic acid and sodium hydroxide produces
a. butanol b. butanone c. butanal d. sodium butanoate
74.Ethanoic acid reacts with ethanol to give
a. Diethanoic acid b. ethyl ethanoate c. hydroxyethanoic acid d. NOTG
75. Give the reagents and/or catalyst necessary to carry out the conversion of benzene to 3-nitrobenznesulfonic acid.