CM(1921) TEST # 1-1

FIITJEE MONTHLY ASSESSMENT TEST

MONTHLY
ASSESSMENT PHYSICS, CHEMISTRY & MATHEMATICS

CM - TEST CODE:

Time Allotted: 3 Hours Maximum Marks: 186

▪ Please read the instructions carefully. You are allotted 5 minutes specifically for
this purpose.
▪ You are not allowed to leave the Examinat ion Hall before the end of the test.

INSTRUCTIONS
Caution: Question Paper CODE as given above MUST be correctly marked in the answer OMR
sheet before attempting the paper. Wrong CODE or no CODE will give wrong results.

A. General Instructions
BATCH – 1921

1. Attempt ALL the questions. Answers have to be marked on the OMR sheets.
2. This question paper contains Three Section.
3. Section-I is Physics, Section-II is Chemistry and Section-III is Mathematics.
4. Each section is further divided into two parts: Part-A & Part-C
5. Rough spaces are provided for rough work inside the question paper. No additional sheets will be provided
for rough work.
6. Blank Papers, clip boards, log tables, slide rule, calculator, cellular phones, pagers and electronic devices, in
any form, are not allowed.

B. Filling of OMR Sheet

1. Ensure matching of OMR sheet with the Question paper before you start marking your answers on OMR
sheet.
2. On the OMR sheet, darken the appropriate bubble with HB pencil for each character of your Enrolment No.
and write in ink your Name, Test Centre and other details at the designated places.
3. OMR sheet contains alphabets, numerals & special characters for marking answers.

C. Marking Scheme For All Three Parts.

(i) Part-A (01 – 05) contains 5 multiple choice questions which have only one correct answer. Each question
carries +3 marks for correct answer and – 1 mark for wrong answer.

(06 – 13) contains 8 multiple choice questions which have one or more than one correct
answer. Each question carries +4 marks for all correct answer and – 2 mark for wrong answer.

(iii) Part-C (01 – 05) contains 5 Numerical based questions with single digit integer as answer, ranging from 0
to 9 and each question carries +3 marks for correct answer. There is no negative marking..

Name of the Candidate :__________________________________________

Batch :___________________ Date of Examination :___________________

Enrolment Number :______________________________________________

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CM(1921) TEST # 1-2

P
PAAR
RTT –– II:: P
PHHY
YSSIIC
CSS
SECTION – A
(Single Correct Choice Type)
This section contains 5 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out
of which ONLY ONE is correct.

1. A particle is projected with speed u at an angle  (< 60°) with the horizontal. The time taken
by it, so that its velocity makes an angle 60° with the initial velocity.
3 u 1 3 u 1
(A) (B)
2 g sin( + 60 ) o
2 g sin( + 30o )
3 u 1 3 u 1
(C) (D)
2 g sin( − 30o ) 2 g sin( − 60o )

2. The magnitude of a vector 'a' is constant, but its direction is not constant then
da da
(A) and a are in same direction. (B) is opposite to a
dt dt
da
(C) is perpendicular to a (D) none of these
dt

3. The graph which represents the variation of slope m of the trajectory of a projectile with
horizontal displacement s is

(A) (B)
m m
s
s

(C) (D)
m m
s
s

4. A particle starts from rest and travels a distance s with uniform acceleration, then it travels a
distance 2s with uniform speed finally it travels a distance 3s with uniform retardation and
comes to rest. if the complete motion of the particle is a straight line then the ratio of its
average velocity to maximum velocity is
(A) 6/7 (B) 4/5
(C) 3/5 (D) 2/5
Space for rough work

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CM(1921) TEST # 1-3

5. A particle starts moving in straight line with constant acceleration. After time t0 acceleration
changes its sign (just opposite to the initial direction) remaining the same in magnitude.
Determine the time from the beginning of motion in which the particle returns to the initial
position.
(A) 2 t0 (
(B) 2 + 2 t0 )
(C) 3 t0 (D) ( 2 − 2 ) t 0

(Multi Correct Choice Type)

This section contains 8 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out
of which ONE OR MORE may be correct.

6. If r1 = 2iˆ + Jˆ & r2 = ˆi − 2jˆ + 3kˆ and angle between r1 & r2 is , then which of the following is
correct?
(A)  = 0° (B)  = 90°
(C) r1  r2 = 0 (D) r1  r2 = 70

7. A man who can swim at a speed v relative to the water wants to cross a river of width d,
flowing with a speed u. The point opposite him across the river is P.
d
(A) The minimum time in which he can cross the river is .
v
d
(B) He can reach the point P in time .
v
d
(C) He can reach the point P in time
v − u2
2

(D) He cannot reach P if u > v.

8. A body is projected with velocity u at an angle of projection  with the horizontal. The body
makes 30° with the horizontal at t = 2 second and then after 1 second it reaches the
maximum height. Then
(A) u = 20 3 m/s (B)  = 60°
(C)  = 45° (D) u = 20 / 3 m/s

9. Two particles projected from the same point with same speed u at angles of projection  and
 strike the horizontal ground at the same point. If h1 and h2 are the maximum heights
attained by the projectiles, R is the range for both and t1 and t2 are their time of flights,
respectively, then:

(A)  +  = (B) R = 4 h1h2
2
t
(C) 1 = tan  (D) tan  = 4 h1 / h2
t2
Space for rough work

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CM(1921) TEST # 1-4

10. If A  B = C + D , then select the correct alternative

(A) Component of C along B = component of D along B
(B) Component of C along B = – component of D along B
(C) Component of C along A = component of D along A
(D) Component of C along A = – component of D along A

x t3
11. A particle moves along positive branch of the curve, y = , where x = , x and y are
2 3
measured in metres and t in seconds, then
1
(A) The velocity of particle at t = 1s is ˆi + ˆj
2
1
(B) The velocity of particle at t =1s is ˆi + ˆj
2
(C) The acceleration of particle at t =1s is 2iˆ + ˆj
(D) The acceleration of particle at t = 2 s is ˆi + 2jˆ

12. Two vectors A and B are drawn from a common point and C = A + B
(A) If C2 = A 2 + B2 , the angle between vectors A and B is 90°
(B) If C2  A 2 + B2 , the angle between A and B is greater than 90°
(C) If C2  A 2 + B2 then angle between the vectors A and B is between 0° and 90°
(D) If C = A − B, angle between A and B is 180°

13. A train starts from rest at S = 0 and is subjected to acceleration a(m/s)2

as shown 6
(A) Change in velocity at the end of 10 m displacement is 50 m/s.
(B) Velocity of the train for S = 10 m is 10 m/s.
(C) The maximum velocity attained by train is not greater than S(m)
14 m/s 30
(D) The maximum velocity of the train is between 15 m/s and
16 m/s.

SECTION – C
(Integer Type)
This section contains 5 questions. The answer to each question is a single-digit integer, ranging from 0 to
9. The correct digit below the question number in the ORS is to be bubbled.

1. A 2m wide truck is moving with a uniform speed v0 = 8 m/s

along a straight horizontal road. A pedestrian starts to cross
the road with a uniform speed v when the truck is 4 m away 2m Truck v0 v
from him. The minimum value of velocity so that he can cross
5 man
the road safely is v then the value of v is 4m
2
Space for rough work

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CM(1921) TEST # 1-5
V(m/s)

20

2. Referring to v –s diagram, find magnitude of

acceleration of the particle when its velocity becomes
half of the initial velocity

s(m)
O 50

3. Two cars leave one after the other and travel with an acceleration of 0.4 m/s2. Two minutes
after the departure of the first, the distance between the cars becomes 1.9 km. If time
a
interval between the departure of the cars is min, then a =
6

4. If A  B = A  B and A & B are 2 2 and 3 respectively, determine C = A  B .

v2
5. A particle is moving in a straight line and it velocity (v) and
1
displacement are related as shown. If acceleration (in m/sec2)
n (3m/s)2
of particle when its velocity is 3 m/s. Find the value of ‘n’. 450
s

Space for rough work

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CM(1921) TEST # 1-6

P
PAAR
RTT –– IIII:: C
CHHE
EMMIIS
STTR
RYY
SECTION – A
(Single Correct Choice Type)
This section contains 5 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out
of which ONLY ONE is correct.

1. A silver coin weighing 11.34 g was dissolved in nitric acid. When sodium chloride was added
to the solution all the silver (present as AgNO3) was precipitated as silver chloride. The mass
of the precipitated silver chloride was 14.35 g. Calculate the percentage of silver in the coin.
(A) 4.8% (B) 95.2%
(C) 90% (D) 80%

2. For a 3s-orbial, value of  is given by following relation:

3/2
1  1 − /2 2r.Z
(3s) =   (6 − 6 +  )e ; where  =
2

9 3  a0  3a0
What is the maximum radial distance of node from nucleus?
(3 + 3)a0 a
(A) (B) 0
Z Z
3 (3 + 3)a0 2a 0
(C) (D)
2 Z Z

Kn2
3. Balmer gave an equation for wavelength of visible region of H-spectrum as  = .
n2 − 4
Where n = principal quantum number of energy level, K = constant in terms of R (Rydberg
constant).
The value of K in terms of R is:
R
(A) R (B)
2
4 5
(C) (D)
R R
Space for rough work

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CM(1921) TEST # 1-7

4. At room temperature following reaction goes to completion

2AB(g) + B2 (g) ⎯⎯ → 2AB2 (s)
AB2 is solid with negligible vapour pressure below 0°C. At 300 K, the AB in the smaller flask
exerts a pressure of 3 atm and in the larger flask B2 exerts a pressure of 1 atm at 400 K
when they are separated out by a close valve. The gases are mixed by opening the stop
cock and after the end of the reaction the flask are cooled to 250 K

The final pressure is:

(A) 0.156 atm (B) 0.3125 atm
(C) 0.625 atm (D) 3.2 atm

5. Consider a titration of potassium dichromate solution with acidified Mohrs salt solution using
diphenylamine as an indicator. The no. of moles of Mohr’s salt required per mole of
dichromate is:
(A) 3 (B) 4
(C) 5 (D) 6

(Multi Correct Choice Type)

This section contains 8 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out
of which ONE OR MORE may be correct.

6. A gas obeys P(V - b) = RT. Which of the following are correct about this gas?
R
(A) Isochoric curves have slope =
V −b
R
(B) Isobaric curves have slope and intercept b.
P
Pb
(C) For the gas compressibility factor = 1 +
RT
(D) The attraction forces are overcome by repulsive forces.

7. A metal surface having 0 as threshold frequency is exposed by light of frequency 1 then

which are correct.
2h.c ( 0 −  ) 2h (  −  0 )
(A) u = (B) u =
m..0 m
2h (  0 −  ) 2 ( h − w )
(C) u = (D) u =
m m
Space for rough work

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CM(1921) TEST # 1-8

8. Select the incorrect statement(s):-

(A) Compressibility factor for 1 mole of gas at critical conditions is 8/3.
(B) All molecules of gas move with same speed.
(C) The diameter of gaseous molecules are much smaller than the average distance
traveled between collision.
(D) Saturated vapours do not obey gas laws except Dalton’s law.

9. 1 mole of a mixture of CO and CO2 requires exactly 1 litre solution of 1 M NaOH for
complete neutralization. If CO present in mixture is now converted to CO2 and again the
mixtures is treated with NaOH then after this conversion.
(A) mole of CO2 present initially in mixture = 1.
(B) 2 litre NaOH solution of 1 M is more required for neutralization.
1
(C) 2 litre solution of M NaOH is required more for neutralization.
2
(D) 56 gm KOH in aqueous solution is required more for neutralization.

10. Which of the following statement(s) is(are) correct?

(A) The electronic configuration of Cr is [Ar]3d54s1.
(B) The magnetic quantum number may have a negative value.
(C) In silver atom, 23 electrons have a spin of one type and 24 of opposite type
(D) The oxidation state of nitrogen in N3H is -3

11. Which of the following statement(s) is/are true about the effect of an increase in temperature
on the distribution of molecular speeds in a gas?
(A) Area under the distribution curve remains the same as under the lower temperature.
(B) The distribution becomes broader.
(C) Fraction of molecules with most probable speed increases.
(D) The most probable speed increases.

12. When a equimolar mixture of Cu2S and CuS is titrated with Ba(MnO4)2 in acidic medium, the
final products contain Cu2+, SO2 and Mn2+. If the mol mass of Cu2S, CuS and Ba(MnO4)2 are
M1, M2 and M3 respectively then:
M
(A) eq. mass of Cu2S is 1
8
M2
(B) eq. mass of CuS is
6
M
(C) eq. mass of Ba(MnO4)2 is 3
5
(D) Cu2S and CuS both have same equivalents in mixture
Space for rough work

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CM(1921) TEST # 1-9

13. Select the correct curve(s):

If v = Velocity of electron in Bohr’s orbit
r = Radius of electron in Bohr’s orbit
P.E. = Potential energy of electron in Bohr’s orbit
K.E. = Kinetic energy of electron in Bohr’s orbit
(A) (B)

V r

1/n n
(C) (D)

P.E.
K.E.
1/n →

SECTION – C
(Integer Type)
This section contains 5 questions. The answer to each question is a single-digit integer, ranging from 0 to
9. The correct digit below the question number in the ORS is to be bubbled.

1. Root mean square speed of CH4 at TK is 6 times of most probable speed of SO 2 at T1K. The
temperature of CH4 is …. times of SO2?

2. n2 value of IInd line of Humphry series corresponds to ……?

3. Total number of electrons involved per molecule in oxidation of FeC2O4 to Fe3+ and CO2 is

4. The magnitude of the orbital angular momentum vector of an electron in an orbital is

h
expressed as 6 . Into how many components will the vector split if a magnetic field is
2
applied on it?

5. A vessel contains CH4 and SO2 in the molar ratio 3: 4. The mixture of gases is allowed to
effuse through a small orifice. If the simplest ratio of rates of effusion of CH4 to SO2 is
expressed as x : y, then x + y is
Space for rough work

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 CM(1921) TEST # 1-10

P
PAAR
RTT –– IIIIII:: M
MAAT
THHE
EMMA
ATTIIC
CSS
SECTION – A
(Single Correct Choice Type)
This section contains 5 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out
of which ONLY ONE is correct.


2
cos x
1. The value of the integral  cos x + sin x dx is
0


(A) 1 (B)
2

(C) 0 (D)
4

2. The largest number among the following numbers is

(A) tan47o + cos47o (B) cot 47o + 2 sin47o
(C) 2 cos 47o + sin 47o (D) tan47o + cot 47o

 
  sin2  x − 
tan x −   4
3. The set of values of x  0, 2 satisfying the equation, 2  4
− 2  ( 0.25 ) cos2x + 1 = 0 , is
(A) an empty set (B) a singleton set
(C) a set containing exactly two values (D) an infinite set

4. As shown in the figure AD is the altitude on BC and A Q

AD produced meets the circumcircle of ABC at P
y
where DP = x. Similarly EQ = y and FR = z. If a, b, c R
respectively denotes the sides BC, CA and AB then z F E
a b c
+ + has the value equal to
2x 2y 2z
(A) tan A + tanB + tanC D
C
(B) cot A + cot B + cot C B

(C) cos A + cosB + cosC x

(D) cos ec A + cos ec B + cos ec C P

5. For the given equations cos ( 4y − 3x − 2) − cos ( 4y + 3x + 2) = 2 + 2  ln2 k 4 − 255 and ( )

cos ( 4y − 3x − 2 ) + cos ( 4y + 3x + 2 ) = 2k + 8 to have real solutions ( x, y ) , the possible
value of k is
(A) 4 (B) −4
(C) −5 (D) none of these
Space for rough work

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CM(1921) TEST # 1-11

(Multi Correct Choice Type)

This section contains 8 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out
of which ONE OR MORE may be correct.

6. Which of the following, when simplified, reduces to unity?

(A) log3 log27 log4 64 (B) 2log18 ( 2+ 8 )
(C) log2 10 + log2 
 2 
 5
 (D) − log 2 −1 ( 2 + 1)

( )
n
1
7. Let fn (  ) =  sin4 2r  . Then which of the following alternative(s) is/are correct?
r =0 4r
  1  2+ 2
(A) f2   = (B) f3   =
4 2 8 4
 3 
(C) f4   = 1 (D) f5 (  ) = 0
 2 

8. If A, B, C are the three angles in the triangle such that 2sinBsin ( A + B) − cos A = 1 and
2sinCsin (B + C) − cosB = 0 , then:
(A) A = 120o (B) B = 120o
(C) C = 30o (D) B = C

9. Which of the following is/are correct?

xn+1
(A)  x dx =
n
+ c  n R (B)  sec x dx = − ln sec x − tanx + c
n +1

(( ))
x
(C) 
dx
1 + ex
= − ln c e− x + 1 (D)
d
dx
( x)= , x0
x

10. Which of the following is INCORRECT ?

d  1+ x + x 
2 4
(A) If   = ax + b , then a + b = 3
dx  1 + x + x 2 
dy
(B) If y = etan x , then =0
dx x =0
x −1
(C) lim =0
x →1 2x 2 − 7x + 5

x +h − x 1
(D) lim =
h→0 h x
Space for rough work

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CM(1921) TEST # 1-12

 3   6  4
11. Let , ,  0,  such that sin   = and cos   = , then the correct options is/are
 2   3  11 3 9
(A) cos   0 (B) sin   0
(C) cos (  + )  0 (D) cos   0

12. If sin  + sin  = a and cos  + cos  = b, (a  b, a  0, b  0 ), then

(a )
2
8ab
2
+ b2 − 4a2
(A) tan  + tan  = (B) cos  .cos  =
(a 2
+ b2 )
2
+ 4b2 (
4 a2 + b2 )
b2 − a2 4ab
(C) cos (  +  ) = (D) sin (  +  ) =
b2 + a2 (a 2
)
+ b2 + 2b2

( ) ( )
x2 −15 x2 −15
13. The roots of the equation a + b + a− b = 2a, where a2 − b = 1 are
(A) 2 (B) 4
(C)  14 (D)  3

SECTION – C
(Integer Type)
This section contains 5 questions. The answer to each question is a single-digit integer, ranging from 0 to
9. The correct digit below the question number in the ORS is to be bubbled.

1. The value of tan2 27o + 2tan27o tan36o is equal to

tan (  +  )
2. Consider 3 sin  = sin ( 2 + ) . Let K be the value of and W be the value of the
tan 
product ( cot  + cot (  +  ) ) . ( cot  − 3 cot ( 2 +  ) ) . The value of (K + W ) is equal to

( )( )
x2 + 4x −60
3. The sum of all real values of x satisfying the equation x2 − 5x + 5 = 1 is

4. If tan15o tan25o tan35o = tan  and 0o    180o , then the value of  (in degrees) is

1 1 1 1 1
5. Let S = + + + ..... + + .
sin8 sin16 sin32 sin 4096 sin8192
1
If S = where   (0, 90°), then find  (in degree).
sin 
Space for rough work

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 CM(1921) TEST # 1-13

ANSWERS KEY
SR.
PHYSICS C.CODE CHEMISTRY C. CODE MATHS C.CODE
NO.
1. B P110310 B C111101 D M112409

2. C P110222 C C110113 D M111430

3. C P110324 C C110104 A M111406

4. C P110327 C C111202 A M111402

5. B P111605 D C111102 B M111431

6. BCD P110203 ABC C111204 BD M112403

7. ACD P111624 ABD C110106 CD M111430

8. AB P110310 AB C113507 ACD M111407

9. ABC P110310 CD C111101 BCD M112408, M112407

10. BD P110221 ABC C112806 ABCD M112407, M112406

11. AC P111605 ABD C111206 BCD M111410

12. ABCD P110219 AB C111102 BC M111406

13. BC P111606 ABCD C112803 BC M112403

1. 4 P110320 6 C111206 1 M111409

2. 4 P110325 8 C110104 8 M111408

3. 5 P110301 3 C111112 3 M111403

4. 6 P110204 5 C112806 5 M111407

5. 2 P110325 5 C111208 4 M111406

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CM(1921) TEST # 1-14

Hints & Solutions

Physics
SECTION – A
1. B
u gt
Sol. = u
Sin(30 + ) sin 60o
 gt
60°

(30° + )
2. C
Sol. a  a = Constant
da
2 a = 0
dt

3. C
Sol. y = ax – bx2
dy
= a − b(2x)
dx
m = a – 2bx
Straight line

4. C
1  1
Sol. 3  t1v max  = t 2 v max
2  2 V
3t1 = t2
1 2s Vmax
t v max = s ; t1 =
2 vmax
t – 4t1 = t1 s 2s 3s
t = 5t1
t1 (t – 4t1) t2 t t
2s 10s
 Vmax = =
t/5 t

5. B
Sol. Area v-t will be zero when displacement is zero. v
1 1 v
So ( 2t 0 ) v 0 − ( t − 2t 0 )( t − 2t 0 ) 0 = 0 1
2 2 t0
( 2t0 ) t0 = ( t − 2t0 )
2 v0

2t0 t
2t 0 = t − 2t 0 t0
time

(
t = 2t 0 + 2t 0 = 2 + 2 t 0 )

6. BCD
Sol. r1  r2 = 2 − 2 = 0
r1  r2 its means perpendicular vectors
i j k
r1  r2 = 2 1 0 = 70
1 2 3

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CM(1921) TEST # 1-15

7. ACD
Sol.
d v

u
d
t min =
v

8. AB
Sol. Time of light = 6 sec.

9. ABC

Sol. Range is same then  +  =
2
2usin  2usin 
T1 = , T2 =
g g
u2 sin2 
R=
g
u2 sin2  u2 sin2 
h1 = ; h2 =
g g

10. BD
Sol. ( ) ( )
A B B = C + D B

( A  B )  A = ( C + D)  A
11. AC

12. ABCD

13. BC
SECTION – C
1. 4
Sol. v = v0 sin  v
2
 1 
v = v0   
 5 4 vo
1 vo sin 
Tan  =
2

2. 4
2
Sol. v = 20 − s
5
vdv
a=
ds
 2   2
 20 − 5 s   − 5  = a
  
When s = 25
 a = 4.

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CM(1921) TEST # 1-16

3. 5
1
Sol. s1 = 0 + (0.4) (120)2
2
1
s2 = 0 + (0.4) (120 − t)2
2
s1 – s2 = 1900
(240 – t)t = 9500
t = 50 sec.

4. 6
Sol. AB cos  = AB sin 
 = 45°
A × B = AB sin 
1
= 6 2
2
 6

5. 2
dv 2 dv dv 1
Sol. = 1 , 2v = 1, v = m/s2
ds ds ds 2

Chemistry
SECTION – A
1. B
Sol. Ag + HNO3 ⎯⎯
→ AgNO3
AgNO3 + NaCl ⎯⎯ →NaNO3 + AgCl
POAC on Ag
Mole of Ag in coin = mole of Ag in AgCl
14.35
a= = 0.1 mole
143.5
Mass of Ag in coin = 0.1  108 = 10.8 g
10.8
 % silver in coin =  100% = 95.2%
11.34

2. C
Sol. Radial node occurs where probability of finding e– is zero.
 2 = 0 or  = 0
 6 − 6 + 2 = 0; =3 3
3 (3 + 3)a0
For max. distance r =
2 Z

3. C
1 1 1  n2 − 4 2 
Sol. =R 2 − 2  =R 
 2 n   4n 
2

4 n2
=  2 …(1)
R n −4
n2
Given:  = k  ...(2)
n2 − 4
Comparing equation (1) and (2) we have

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CM(1921) TEST # 1-17

4
K=
R

4. C
3  8.21
Sol. nAB = = 1;
0.0821 300
1 8.21
nB2 = = 0.25
0.0821 400
2AB + B2 ⎯⎯→ 2AB2
Initial moles 1 0.25
After reaction 0.5 0.5
PAB (8.21 × 2) = 0.5 × 0.0821 × 250
 PAB = 0.625 atm

5. D
Sol. Following reaction occurs:
6Fe2+ + Cr2O72− + 14H+ ⎯⎯ → 6Fe3+ + 2Cr 3+ + 7H2O
Mohr’s salt (FeSO4.(NH4)2SO4.6H2O) and dichromate reacts in 6 : 1 molar ratio.

6. ABC
Sol. P(V - b) = RT
R R
P = T Slope =
( V − b) ( V − b)
PV – Pb = RT
RT R
V= +b Slope = and int ercept b
P P
PV Pb
Z= = 1+  Z 1
RT RT
i.e. repulsive forces predominates.

7. ABD
1
Sol. h = h0 + mu2
2
2h (  −  0 ) 2hc (  0 −  )
u = =
m m ( 0   )
1
h = w + mu2
2
2 ( h − w )
u =
m

8. AB
PC VC 3
Sol. Z= =
RTC 8
Each molecule move with altogether different speed.

9. CD
Sol. CO + CO2  a + b = 1
Let a b
CO2 + 2NaOH ⎯⎯ →Na2CO3 + H2O
Meq of CO2 = Meq of NaOH = 1  1000

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CM(1921) TEST # 1-18

1 1000
 Mole of CO2 = = 0.5 (V.f of CO2 = 2)
2  1000
1
CO + O2 ⎯⎯→ CO2
2
 0.5 mole CO2 is formed more.
 NaOH required more = 2 litre of M/2 NaOH = 56 g KOH = 1 mole KOH

10. ABC
Sol. (A) 24Cr [Ar]3d54s1
(B) For magnetic quantum number(m), negative values are possible
For s-subshell,  = 0, hence m = 0
For p-subshell,  = 1, hence m = -1, 0, +1
(C) For 47Ag = 1s22s22p63s23p63d104s24p64d105s1
Hence 23 electrons have a spin of one type and 24 opposite type
1
(D) Oxidation sate of N is N3H is −
3

11. ABD
Sol. Distribution of molecular velocities at two different temperature is as shown in graph.
Most probable
velocity


Fraction
of
molecules 300K

600K
Molecular Velocity →
At higher temperature more molecules have higher velocities and less molecules have low
velocities.
It is clear that, with increase in temperature the most probable velocity increases but the
fraction of such molecules decreases.

12. AB
Sol. Let nCu2S = a; nCuS = a
Cu2S + CuS+ Ba (MnO4 )2 + H+ ⎯⎯
→ Cu2+ + SO2 + Mn2+
n − factor = 8 6
10

13. ABCD
Z n2 Z2 Z2
Sol. (a) v  ; (b) r  ; (c) P.E.  − 2 ; (d) K.E.  2
n Z n n

SECTION – C
1. 6
3RT 2RT1
Sol. =6  T = 6T1
16 64

2. 8
Sol. For Humphry series n1 = 6, n2 = 7, 8….

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CM(1921) TEST # 1-19

3. 3
Sol. Fe2+ + C2O24− ⎯⎯
→ Fe3 + + 2CO2

− 2e−
− 1e−

4. 5
Sol. Orbital angular momentum of an electron in an orbital is expressed as:
h
( + 1)
2
 = Azimuthal quantum number of the orbital
h h
 ( + 1)
= 6
2 2
or, ( + 1) = 6   = 2
 The electron is present in a d-subshell. The d-subshell splits into five parts or five
components in presence of a magnetic field which are expressed by the magnetic quantum
numbers.
 = 2, m = -2, -1, 0, +1, +2

5. 5
rCH4 x nCH4 MSO2
Sol. = =
rSO2 y nSO2 MCH4
x 3 64 3 3
or, = = 2=
y 4 16 4 2
x+ y=3+2=5

Mathematics
SECTION – A
1. D
1  cos x + sin x cos x − sin x 
 /2  /2  /2
cos x
Sol. 
0
cos x + sin x
dx =  
2  0 cos x + sin x
dx + 
0
dx 
cos x + sin x 

2. D
1
Sol. Use relations sin 47o   cos 47o
2
and tan47o  1  cot 47o

3. A
 
Sol. Put tan  x −  = t
 4

4. A
Sol. Image of orthocenter is any side lies on circumcircle.

5. B
Sol. Use transformation formulae and extreme values.

6. BD
Sol. Use properties of logarithm.

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CM(1921) TEST # 1-20

7. CD

8. ACD
Sol. 2sinBsin ( A + B) = 2sinBsinC = cos (C − B ) − cos (C + B )
= cos ( C − B) + cos A
 cos ( C − B) = 1  B = C

9. BCD

10. ABCD

11. BCD
   
Sol. sin  = 3 sin   − 4 sin3   and cos  = 4cos3   − 3cos  
3 3 3 3

12. BC
Sol. Square and add.

13. BC
SECTION – C

1. 1
Sol. tan2 27o + 2tan27o tan36o
 2 tan 27o 
(
= 1 + tan2 27o 1 + ) tan 36o  − 1
 1 + tan 27
2 o

= sec 2 27o 2 cos2 27o(( )) − 1
= 2 − 1= 1

2. 8
sin ( 2 +  )
Sol. =3
sin 
Use componendo and dividendo
k=2
Also cot  = 2cot (  + )

3. 3
Sol. Case I : x 2 − 5x + 5 = 1 and x 2 + 4x − 60  R
Case II : x2 − 5x + 5  R − 0 and x 2 + 4x − 60 = 0
Case III : x 2 − 5x + 5 = −1 and x 2 + 4x − 60 = even number

4. 5
Sol. Use transformation formulae

5. 4
10
1
Sol. S=
( )
o
r =1 sin 2r + 3
sin ( 2 − 2 ) r +3 r +2

=  cot ( 2 ) ( )
10 10
= r +2
o
− cot 2r +3
o

sin ( 2 ) sin ( 2 )
r =1
r +2 o
r +3
o
r =1 

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