What is general formula of alkanes?

Arrange 1o, 2o & 3o carbonium ions in increasing order of stability.

Atoms of which group in the periodic table have a valence shell electron configuration of ns2np3?
Based on their positions in the periodic table, predict which has the largest atomic radius: Li, Rb, N, F, I?
Based on their positions in the periodic table, predict which has the largest mono valent ionic radius: Li, Na, K, Rb, Cs?
Based on their positions in the periodic table, predict which has the smallest atomic radius: Mg, Sr, Si, Cl, I.
Define Bronsted-Lowry acid. Give example.
Define dipole moment of a bond.
Define electron affinity.
Define ionization energy?
Give an example of coordinate bond.
Give an example of intermolecular hydrogen bonding plays role.
How is bond order related to bond dissociation energy of a molecule?
How many sp3, sp2, and sp hybridized carbon atoms are present in (CH3)2CH-CH=CH-C≡C-CH=CH2 ?
Identify the atom with electron configuration of 2s22p3?
Identify the type of Organic reaction given as follows:CH4+Cl2→ CH3Cl+HCl
If the pressure of a given mass of gas is reduced to half and temperature is doubled simultaneous the volume will be (A) Same
In what state the n-pentane exist in room temperature?
Liquefied petroleum gas (LPG) contains ________and __________ .
Name the CH2=CH- group.
Name the metal used in Wurtz reaction.
State Heisenberg’s uncertainty principle.
State Pauli’s exclusion principle.
What are Annulenes? Give an example.
What are free radicals? Give an example.
What is Boyle’s temperature write equation.
What is critical temperature of CO2
What is ionization energy?
What is the Bohr radius of Hydrogen atom?
What is the maximum number of electrons that can be accommodated in a set of “d” orbitals?
What is the range of wave lengths for visible light?
What is the shape of CH4 molecule
What is the shape of methyl carbocation (+CH3)?
Which atom and/or ion is (are) iso electronic with Br+: Se2+, Se, As–, Kr, Ga3+, Cl–?
Which is the most acidic compound among 1-butyne, 2-butyne, 1-butene and butane?
Which main group atom would be expected to have the lowest second ionization energy?
Which of the species, H2O, SO3, AlCl3, ROH are electrophile and why?
Which quantum number determines the energy associated with an orbital in an atom?
Which quantum number specifies shape of an orbital?
Write down the possible resonating structures of CO_3^(2-) ion.
Write the C-C bond length in acetylene.
Write the electronic configuration of Cr atom.
Write the electronic configuration of Cu+ ion.
Write the electronic configuration of Ni2+ ion.
Write the electronic configuration of V3+ atom.
Write the possible structure of Bromine as electrophiles.
Write the product CH3-CH= CH2 + HBr
(B) Twice as before (C) 1/4 the as (D) None before
Give the products of CH4+ Cl2 (excess)
Compare the ozonolysis product of 1,3-pentadiene and 1-pentyne.
How ethylene react with following reagents
(i)                 Br2/CCl4
(ii)               Dil H2SO4
(iii)             Dilute cold KMnO4
(iv)              Conc. H2SO4
(v)                HBr
Arrange 1o, 2o & 3o carbonium ions in increasing order of stability. How its stability order can be explained
Arrange the element in increase electronegativity Cl, F, Br and I.
At what condition real gases can behave as ideal gases?
Based on their positions in the periodic table, rank the following atoms in order of increasing first ionization energy:
your prediction.
Calculate de-Broglies wave length of a cricket of mass 100 gm moving at a speed of 160 km/h. Calculate de-Broglies
electron moving with the same speed. Using this example explain why don’t we see wave property of matter on eve

Calculate the % of ionic character of a bond having length = 0.83 Å and 1.82 D as it's observed dipole moment.
CCl4 has no dipole moment but CHCl3 has. Why?
CCl4 has no dipole moment but CHCl3 has. Why?
Clearly describe each term and write the equation of states of ideal gas.
Deduce Daltons law of partial pressure from fundamental kinetic equation
Define average velocity, most probable velocity, and root mean square velocity of a gas with appropriate mathematical expres
Define compressibility factor? Explain with diagram of compressibility factor Vs Pressure.
Define Huckel’s Rule.
Define lattice energy.
Derived the fundamental kinetic equation from the postulates of kinetic theory of gases.
Draw the all possible isomers of n-pentane.
Draw the molecular orbital energy diagram for NO molecule and predict the Bond order and magnetic behavior (dia or para m
Draw the molecular orbital energy diagram for NO molecule and predict the magnetic behavior (dia or para magnetic
NO-.
Draw the shape of five “d” orbital.
Draw the shapes of the five d orbitals: dxy, dyz, dzx, dz2, dx2-y2
Electron Affinity, ΔEAHo(G, g)=-328 kJmol-1
Enthalpy change per mole of dissociation of fluorine to form F, Δ dissHo(F, g)=79 kJmol-1
Enthalpy change per mole of Sublimation of Ca, ΔsubH o(Ca, s)=178 kJmol-1
Explain and arrange O2, O2-, O22-, O2+ in the order of their increasing bond strengths. Also comment on the stabil

Explain the directive influence of methyl group in benzene.

Explain the following curve of liquid water (H2O) on the basis of H-Bonding.
Explain why H2S (Molecular weight 34) is gas while H2O (Molecular weight 18) is liquid at room temperature.
Explain why H2S is gas at room temperature while H2O is liquid.
Explain why Pyridine & Cyclopentadienyl anion are aromatic compounds?
Give hydrolysis product of ethyl magnesium bromide.
Give one example of each alkane, alkene, alkyne and draw structure. Write the C-C bond length in each and hybridis
structure.
Give three methods of preparation of alkanes.
Give two methods to test the alkenes compound with example.
Given that the standard enthalpy of formation [Δ fHo(CaF2, s)] at 298 k of CaF2 is -1228 kJmol-1, by constructing a Born
determine the lattice energy [ΔlatticeHo(CaF2, s)]for CaF2 using following information in standard state.

How acetylene react with following reagents H2SO4/HgSO4, Ozone, Dilute alkaline KMnO4, O2 (combustion), HBr

How isomers are defined? Draw the all possible isomers of pentane.
If the observed bond moment of O – H bond is 1.6 D, then find the percentage
ionic character of O – H bond in water if the bond length is 0.96 Angstrom.
Ionization Energy IE, IE1(Ca, g)= 590 kJmol-1, IE2(Ca, g)= 1145 kJmol-1
On the basis of electron gas model of metallic bonding, explain the origin of following metallic properties (i) high electronic an
On the basis of electron gas model of metallic bonding, explain the origin of following metallic properties (i) high ele
conductivity of metals, and (ii) softness-malleability-ductility.
On the basis of H-bonding effect, explain why NH3 posses a higher boiling point than expected?
On the basis of H-bonding effect, explain why NH 3 posses a higher boiling point than expected?
On the basis of MO theory, schematically draw the energy level diagram for O2.
Predict the shape of PCl5, and H2O using VSEPR theory.
Predict whether following molecules will be polar or non polar. Explain your answer. Methane, dichloromethane, ch
State and explain d-Broglies hypothesis. Calculate the de-Broglies wave lengths for an electron and a cricket ball m
m/s.
State and explain Heisenberg's uncertainty principle. Calculate the uncertainty of position for an electron and cricke
of 50 m/s.
State and explain Hund's rule.
The expression of Maxwell distribution of velocities is given by dN/N=4?(m/2?kT) C^2 e^(-(mC^2)/2kT) dc Calculate the root m
Two van der Waal gases have the same values for 'b' but different 'a' values. Which of the gas would occupy greater volume u
Using VSEPR model, deduce the shape of CCl 4 molecule.
Using VSEPR model, deduce the shape of SF6 molecule.
What are cis and trans isomers? Explain with example.
What are the basic postulates of kinetic theory of gases. Derived the gas equation.
What are the significance of Ψ and Ψ2 . What is orbital of an atom?
What happens when calcium carbide reacts with water? Give reaction.
What is compressibility factor? Explain with diagram of compressibility factor Vs Pressure.
What is Lindlar's catalyst? Explain it utility with an example.
What is Saytzeff elemination rule explain with example.

What is the essential difference between Inductive & Mesomeric effects?

What is Vander Waals equation. Why it needed to modify the ideal gas equation derived it.
Which of the following atoms and ions is (are) isoelectronic with S 2+: Si4+, Cl3+, Ar, As3+, Si, Al3+?
Why Boiling point of Ortho nitrophenol is lower than p-nitrophenol? Explain
Write a note on Nucleophilic reagent.
Write any two methods of preparation of alkanes with examples.
Write down the time dependent and independent Schrodinger equation in general form. Clearly describe the each
Write short note on ‘Van der Waals’ forces

Write short notes on (a) Afbau principle, (b) Pauli’s exclusion principle, and (3) Hund’s rule.
Write short notes on (i) principle quantum number, (ii) agimuthal quantum number, (iii) magnetic quantum numbe
number.

Write short notes on four types of "Quantum number".

Write the basic postulates of kinetic theory of gases.
Write the equation of ideal gas.
Write the product CH3-CH= CH2 + HBr

Account for the bond angles in the following molecules:

Molecule
CH4
NH3
NF3
H2O
 2
3+2
5

2.5
2
2
2

3
3
3
2
3
6+1
2+2
3
1
5
3
10
2+2

5
3

2+2

2.5
5
3
2
 5
2
3+2
6
5
4+2

1+2
3

4
1.5+

2
2

2.5+2.5
3
2+3

2+3

2
ed of the molecules.
2
2
3
3
10
2+2+1
2
1+2
2.5
5

2
10
3

2
 2.5
2
2
3

1.5+1.5
2.5×4

8
5
1

2.5×4
Bond angle
109.5°
107°
102°
104.5°
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