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DATE: 03-12-2018
Q.No. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15
Ans 2 3 3 2 2 1 3 1 2 3 2 1 2 3 3
Q.No. 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30
Ans 1 2 1 2 2 2 2 3 3 3 3 4 2 4 3
PC OC IOC PC OC IOC PC OC IOC PC OC IOC PC OC IOC
Q.No. 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45
Ans 4 1 4 4 4 2 2 1 2 2 2 4 3 1 2
PC OC IOC PC OC IOC PC OC IOC PC OC IOC PC OC IOC
Q.No. 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60
Ans 2 3 4 1 2 3 2 2 1 4 4 2 4 3 1
Q.No. 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75
Ans 2 3 4 2 3 1 4 3 2 2 3 4 3 3 1
Q.No. 76 77 78 79 80 81 82 83 84 85 86 87 88 89 90
Ans 1 1 2 2 1 2 3 1 3 2 2 2 2 2 4
B A 3k
Q.6 P(A) · P = P(B) · P – k2 = – 2h + h2
A B 2
1 1 1 3y
× = P(B) × + 2x = x2 + y2
4 2 4 2
2x2 + 2y2 – 4x – 3y = 0
1 1 1
P(B) = ; P(A) = and P(A B) =
2 4 8
x 2
A P ( A B) Q.10 (y – 4)2 = 100t2 = 100
5
P =
B P ( B) (y – 4)2 = 4 · 5 (x – 2)
length of LR = 20
1 1 1
1 P(A B) 1 2 4 8 3
= = = Q.11 L1 : y = 3 · x – 4 · 3 ·
1 P(B) 1 4
1 (y – 3 x) = –4 3
2
L2 : y = – 3 · · x + 4 · 3
100 r r
Q.7 Tr + 1 = 100Cr 5 2 · , 11 4
4 3 4 3
where r = 0, 1, 2, ........, 100 y=– 3·x+ (y + 3 x) =
r must be 0, 4, 8,........,100 N = 26 terms
(y – 3 x) (y + 3 x) = – 16 · 9
y2 – 3x2 = – 144 3x2 – y2 = 144
Q.8 OP = 2cos 30º = 3
1
1
e= 1 = 1 3 = 2
P (X, Y)
3
2
h (– ae, 0) (ae, 0)
Q.9 Line is (y – k) = (x – h)
k
3 b2 1
P 2, 3e2 = 2 =1–e e = 4
2 2
2 a
3 h 1
k = (2 – h) e=
2 k 2
2
1 1 1 1 e2 1
Q.13 =1 = 1 =
e 2 e' 2 e' e2 e2
P (h, k)
h e
k
m=h m' = k e' = 2
e 1
O
L
XII MT-7 [JEE Main] Page # 2
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9 5 1
e = 1 = Q.21 g' ( f(x) ) =
4 f ' (x )
16
1
Q.15 L1 through Point A (1, 1, 1) and dir <1, 1, 1> g' (ln x + 2x3 + 3x5) =
1
L2 through point B (1, – 1, 0) and dir 6 x 2 15x 4
x
<1, – 1,– 1>
1 1
0 2 1 put x = 1 g' (5) = =
1 6 15 22
1 1 1 2 1
S·D = 1 1 1 = =
2 2 2
440 2
x sin 2 x
Q.22 I= sin 4 x cos 4 x dx
Q.16 Line joins P(3, – 4, 1) 0
2
(2,1, –2) L1 I=
8
(4,–3,0) L2 1
1 2 n n
Q.23 L = Lim 1 1 .....1
n n n n
2 2
P= =
1 4 9 14 1 n r
ln L = Lim
n
ln 1
n r 1 n
Q.18 | (2x) + i (2y + 1) |2 (x) + i(y + 2)
1
4x2 + 4y2 + 4y + 1 x2 + y2 + 4y + 4
= ln (1 x ) dx
3x2 + 3y2 3 x2 + y2 1 and Area =
0
4
ln L = 2ln 2 – 1 L =
e
XII MT-7 [JEE Main] Page # 3
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N=C NH–CH3
1
x 2 LiAlH
4
A = x ·e · x
x
Q.27 dx = H 2O
0 e e
(X)
dy y
Q.28 =2·
dx x Q.33 (1) [Cu(PPh3)4]+ Tetrahedral ; SFL; ;
dy dx Intensity
=2 ln | y | = 2 ln | x | + c
y x (2) [Zn(H2O)6]2+ Octahedral complex
x2 = y (3) [Cu(NH3)4]SO4 Tetrahedral ; ;
Intensity ; SFL
cos10 3 (4) MnO4¯ d3s, Tetrahedral complex ;
sin 10 2 purple coloured due to LMCT
2 2
Q.29 + =
1 Q.34 Theory based
2 cos10 sin 10
2
Cl Nu
cos(60 10)
+ = 4 · =4 O2N NO2
sin 20
2 sin 25 cos 60 Q.35
and · = =1
cos 65 NO2
x2 – 4x + 1 = 0
= 16 – 4 = 12 (Not perfect square) Rate of SNAR stability of C¯
r4 a 0 16 / Z
d8 Q.40 r a 0 4 / Z r4 = 4r
and 2r4 = 4
no distortion no distortion
2r4
= = 2r
4
d10
O
no distortion no distortion Q.41 I 2 NaOH
C – CH3
2/3 HC CH
3Vi
Ai = 4ri2 = 4 ....(i)
4 Q.42 Na + (x+y) NH 3(l) [Na+(NH3)x] + [e–
(NH3)y]
8RT 8PV
Vavg = =
M nM Q.43 CH4 + Br2 CH3Br + HBr
But, if Vavg becomes twice n = 0.5 mol 0.25 mol 0 0
then volume becomes 4-times keeping P and n
constant (L.R.)
4 3 n CH3Br = 0.25 mol.
rf 4Vi Af = 4rf2 =
3
1
2/3 m CH3Br = × 95 g
3 4Vi 4
4 4
= 23.75 g Ans.
Af
A = 42/3 = 24/3 Ans. 1 ( 5) ( 2 ) ( 0)
i Q.45 (1) KO2 H 2O
KOH H 2O 2 O 2
5 ( 5)
H Br (2) N 2O5 H 2O
HNO3
H 3C D 4 0 6
alc.KOH (3) Xe F4 + H2O Xe + Xe O3 + HF + O2
Q.38 H H
RT
(4) K2O2 + H2O KOH + H2O + O2
H Br
H 3C H3C
H Q.46 Theory based
H H
Q.48 IF7 + 4H2O HIO4 + 7HF (complete
hydrolysis)
Q.39 (1) Na Golden yellow, Mg does not
IF7 H 2O 2HF IOF5
H 2O
show colour with flame.
(sp3d 3 ) (sp3d 2 )
(2) Ba Apple green, Sr Crimson red.
(3) Sr Crison red, Ba Apple green 2HF IO H 2O 2HF IO FH 2O HF IOF
3
2 F3 4
(4) Ca Brick red, Na Golden yellow ( sp3d ) (sp3 ) ( sp3 )
0 .1 O O
Q.49 F– concentration = × 106 ppm
500 Q.59 H3 C H
= 200 pm Ans.
O
Q.51 No. of monovalent oxygen = no.of divalent
oxygen = (2)
H
Name : Pyroxene (single chain) 10
%NaOH
OH
k E 1 1 O
Q.52 ln 32C a
k 27C R 300 305
H
Ea 5
ln 1.5 =
R 300 305 , unsaturated
aldehyde
0.4 8 300 305
Ea = kJ/mol
5 1000
Q.60 at T < 1400°C at T > 1400°C
= 58.56 kJ/mol Ans. III 3Mg + Al2O3
3MgO + 2Al G < 0 G > 0
Me IV 3MgO + 2Al
(i) MeMgBr H 3Mg + Al2O3 G > 0 G < 0
H (ii) H3O
OH G
Q.53 O
H
(i) MeMgBr/CuBr
III
(ii) H3O
Me O
G=0 400 800 1200 1600 T (in°C)
IV
Q.54 Li + air Li3N+ Li2O + Li2O2
H2O
NH3 + LiOH
P H YS I C S
(Basic-turns
Q.61 In the reference frame of infinity, U = 0
red litmus into blue) E1 = –13.6 eV, K1 = 13.6 eV, U1 = –27.2 eV
E2 = –3.4 eV, K2 = 3.4 eV, U2 = – 6.8 eV
Q.55 Theory based Now for U1 to be zero,
we have to add 27.2 eV to U1.
Hence E2 = – 3.4 + 27.2 = 23.8 eV
O
O
When u V f
1 .6 1 .5 1 .2 1 .6 1 .5 R1 1 1
HR2 CV B l 2
CV02
f 30 30
R1 R 2 2
0 0 0 0
2
f = 240 cm R1 1
CV0 [B0l020 V0 ]
R1 R 2 2
220 2
1 1
Q.64 2 = CV02
R X c2 2
R 2 X C2 220 220 2
Q.67 Magnetic moment M NIA
X c2
2 220 2202
2
3 3
M I0 ( 2a ) 2 I 0a 2
X C 220 4 2
Xc 220
tan 1
R 220 R
Q.68 Resistance between opposite corner is and
2
450
R
which is parallely connected.
Q.65 Magnetic flux through the loop A; 2
0I R 2 R
B r 2
r 2 Maximum value
2 R 2 x2 3/ 2 4
R
Induced emf in the loopA; For adjacent corner two resistance and
n
d 0 I R 2 r 2 3 dx
2x n 1
dt 2 2 R 2 x2
5/ 2
dt
n
R are parallel connected
3 0 IR 2 r 2 v x
So minimum resistance is R
n 1
2
R 2 x 2
5/ 2
n2
d V l iR
Induced emf is maximum when 0 E l l
dx Q.69
L L
R 2
x 2 5x 2 0 or x
R
2
E R
E = R R r L l
h
10 5
1 2 E 3 3V
Q.66 Voltage across rod = B0l0 0 5 4 1 5
2
Charge on capacitor = CV0
Q.70 Work done to rotate the ring is equal to work
1 done to return the charge at its initial position.
v q CV02 H R1 H R 2
2
1 1 R Kq Kq
CV0 B0l020 CV02 2 H R 2 H R 2 Q.71 Potential of centre of sphere = Vi
2 2 R1 r r
1 1 H R 2 [R 2 R1 ]
CV0 B0l020 CV02 =
2 2 R1
XII MT-7 [JEE Main] Page # 7
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where Vi = potential due to induced charge at Hence, the apparent frequency of the waves
centre = 0 [ qi = 0 and all induced charges (V v)
are equidistance from centre] striking the surface of the wall is .
Kq Kq The number of positive crests striking per
potential at point P = Vi
r r1 second is the same as frequency.
(For conductor all points are equipotential) In three seconds, the number is [3(V v)] / .
q q
Vi K Q.76 y = 2A cos kx sin t (assuming t = 0, y = 0),
r r1 2l
3
Q.72 Slope of potential from x = 0 to x = d is
dy
4Q 2Q as P = B = B 2Ak sin kx sin t,
dx
2 0 A 0 A
Slope of potential from x = d to x = 2d is B
Pmax B(2A )k also v
3Q
2A = 2.5 cm.
0 A
Slope of potential from x = 2d to x = 3d is
3v
2Q Q.77 f
4(L 0.6r )
0A
df 3v 1 dr
(0.6)
Q.73 Isotherm of maximum temperature has lineAB dt 4 (L 0.6r ) 2
dt
V0
as tangent on it at 3v dr
2 2 0 .6
4 dt
8 dr
y( x , t ) 0.02 cos 50t cos(10x )
Q.74 3v 0.6 dt
2
dr 1
m/s
A cos t cos kx dt 72
2
Q.78 Maximumtensioninstring= T mg m2 A
Node occurs when kx 10x
2 2
2
x = 0.05 m 2
(3mg ) mg m
Antinode occurs when kx = 10x = /2
x = 0.1 m
13
50
Speed of wave (v) = = = 5 m/s 15
k 10
2 Q.79 In 8.5 sec
Wavelength () = = 0.2 m
k 17
= t = = 4 +
4 4
Q.75 The relative velocity of sound waves with
respect to the walls is V v.
a2 a 3V
x=A Q.84 2M Mv = 0 ;
x=0 3 2 4a
x= –A
A
x=
2 Q.85 From Newton's third law, force F will act on
the block in forward direction
A
Distance = 8A + A – F
2 Acceleration of block a1 =
M
A 3 F
9A 27 cm
2 2 retardation of bullet a2 =
m
relative retardation of bullet
dQ Pr 4 F (M m)
Q.80 ar = a1 + a2 =
dt 8 L Mm
2 2
Applying v = u – 2arl
As capillaries are joined in series, so (dQ / dt )
will be same for each capillary. 2F (M m)
0 = v0 2 – .l
Mm
Pr 4 P(r / 2) 4 P(r / 3) 4
Hence,
8L 8(L / 2) 8(L / 3) 2 F l ( M m)
or v0 =
So, pressure difference across the ends of 2nd Mm
capillary Therefore, minimum value of v0 is
p 8P
2F l ( M m )
and across the ends of 3rd capillary
Mm
p 27 P
to first stone ( u ft ) ( u gt )
3mg l 4l 2 3 4l
2
Q.90 mgl l
m m
(g f ) t 8 3 3 8 3
The relative displacement between first and
second stone after time t( h 2 ) 3g
=
4l
(g f ) tt
a=g
1
h1 h 2 (g f ) t 2 (g f ) tt
2
1
(g f )( t 2 t) t
2
N1 N1 N2
F f1
f1 A T B T
f2
mAg mBg
kx F
mg
So block will finally comes to rest while
returning i.e. v 0 & a 0
By work energy theorem while returning
1 1
– kx 2 – kx 2max – F mg x max – x 0
2 2
4mg
x
k