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US CEMENT
STANDARDS:
ACCELERATING
THE GREEN
TRANSITION
BY ROBERT SHENK,
GENERAL MANAGER, FLSMIDTH
®
X-600
X-FLUXER
®
HEAVY DUTY
BORATE FUSION
be the equivalent of taking over 3 million cars off the road. Moving the market mindset GENERAL MANAGER, FLSMIDTH
WWW.HEKO.COM YEARS
CONVEYOR SOLUTIONS
COMMENT
Managing Editor: James Little DAVID BIZLEY, EDITOR
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Editor: David Bizley ith the World Health
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Organisation (WHO) recently
Editorial Assistant: Emily Thomas declaring that COVID-19 or
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the ‘coronavirus’ has officially
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any avoiding the fact that this disease will, over
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budget, will likely be delayed for the most part. This, in turn, will likely dampen
the demand for cement production – throwing off many predictions which had
2020 being something of a turnaround year for the industry.
There is, however, a silver lining to this cloud. Or at least, the references
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10
G
rowth figures for Sub-Saharan Africa (SSA) d’Ivoire and Guinea could act as catalysts for
often vary from month to month. The World social unrest. This is not surprising when one
Bank and others seem to have settled notes that Cote d’Ivoire’s citizens enjoy a high
on 2.9% for this year. Six West African level of income compared with neighbouring
countries will hold elections in 2020. These countries, especially Guinea which, while rich in
could increase tensions between different mineral resources, is the poorest in West Africa.
parties and between ethnic groups. They Fitch Solutions suggests that infrastructure
certainly will test political stability in that part limitations and security challenges will continue
of the region. For example, elections in Côte to constrain trade.
11
The East Africa Monitor at the beginning of have four cement producers. The other three
this year reporting on research by The Institute are HeidelbergCement (CIMTOGO), WACEM
of Chartered Accountants in England and and Diamond Cement.
Wales (ICAEW), said East Africa’s economic In October 2019, GE and Dangote signed an
growth was expected to remain robust this year agreement to deploy GE’s Asset Performance
and then ease from 6.3% to 6.1% in 2021. The Management (APM) digital solution to reduce
region will continue to be the biggest growth unplanned downtime and enhance performance
prospect for African economic development. at the Obajana and Ibese cement plants. The
The following is a brief selection of project includes extending the current service
Sub-Saharan countries, some of which are agreement for an additional 50 000 operating
experiencing mixed fortunes. hours for the seven aeroderivative gas turbines
installed at the sites.
Nigeria Nigeria’s other billionaire with major
A regional superpower it may be, but Nigeria interests in the cement industry through his
continues to deal with many monetary and control of BUA Group, Abdulsamad Rabiu,
fiscal challenges this year and these could announced the merging of the privately owned
stretch further ahead. At the beginning of Obu Cement with the publicly traded Cement
2020 Nigeria’s debt was over US$80 billion Company of Northern Nigeria (CCNN). In
with inflation at about 12% and rising. The reporting this, Forbes confirmed that the
economist and corporate finance expert, move will create the country’s second largest
Tilewa Adebato, in a TV interview with Arise cement producer. Rabiu had previously
News, confirmed the debt was being serviced merged Kalambaina Cement with CCNN
by about 55% of the country’s revenue. at the beginning of 2019. Meanwhile, work
Adebato suggested that with the population is progressing on the construction of the
increasing at 3% pa, growth should be running 3 million tpy Sokoto Kalambaina II plant which
at 5 – 6% to lift 100 million people out of is expected to be completed in the second half
poverty, not at last year’s rate of 2.5%. Amid of this year. Once that plant is up and running,
these thoughts, there are some positive signs. BUA Cement’s total installed capacity will be
Steve Johnson, in a recent article for the 11 million tpy. BUA signed an EPC contract
Financial Times, wrote: “Despite global prices, with China’s CBMI in January 2019 for the
the oil sector had made modest progress. construction of the Sokoto plant. Analysts
Production is up thanks to the Egina oilfield speak of the cement market growing by 6 – 7%
coming online and fewer acts of sabotage in this year based on trends reported in 2019.
the Niger Delta.” The planned Train-7 project,
part of the expansion at the Bonny LG plant South Africa
is scheduled to start up in 2024. This will If the reader feels sorry for Nigeria’s problems,
increase Nigeria’s LNG output by 35% to then spare a thought for the ongoing woes
over 30 million tpy, to provide much needed of South Africa, also regarded as a regional
revenue. superpower. By the end of 2019, economic
growth in the country had flat-lined, with
Cement update the IMF confirming that the economy would
In September 2019 Aliko Dangote announced experience “sluggish growth” this year – below
that the Dangote Group was looking to expand population growth for the sixth consecutive
its cement production in Africa by 29% to year. There was talk of a ratings downgrade
62 million t. Dangote plans to add 6 million from Moody’s, risks to the rand and the
t in Nigeria thereby raising the home market ongoing challenges presented by state-owned
to 35 million t. Earlier in 2019, Dangote enterprises. As professor Raymond Parsons
spoke of exporting clinker to Cameroon of NWU Business School wrote in Business
and West Africa. The rest of the expansion Report at the beginning of 2020, “South
programme will be in West Africa, including Africa’s domestic outlook remains a tough
Niger and Côte d’Ivoire. Two months later and sombre one, with poor growth prospects.
came the news via Reuters and local press The contours of the economic and financial
agencies that Dangote had signed two major landscape dictate that this is a pivotal year, if
deals with Togo. One involved the investment economic recovery is to be fostered, more jobs
of US$2 billion in the country’s phosphate must be created, public finances brought under
industry and the other, an investment of control and business confidence lifted.”
US$60 million in the cement industry to build a Last year the country’s ailing economy was
new 1.5 million tpy plant, utilising Togolese and severely affected by load shredding. Even
Nigerian clinker. When completed, Togo will as the president, Cyril Ramaphosa, spoke of
+1 740.374.6726 www.molemaster.com
tackling the crisis at Eskom, the utility that Zimbabwe operations due to hyperinflation in
generates 95% of electricity in the country, the country, a difficult trading environment in
power cuts returned at the beginning of South Africa and one-off restructuring costs.
this year. On a more positive note, Reuters,
as reported by Moneyweb, said that the Ethiopia
president’s drive to raise US$100 billion The World Economic Forum regards the country
worth of investments into South Africa will as Africa’s new growth engine, with a rate
be keenly watched by South African market running at about 7.5%. There are, as ever, many
participants and businesses. At an African challenges for the population of 100 million.
Investment Forum last November, 56 deals These include: a low per-capita GDP of less
worth US$67.6 billion made it into boardroom than US$800, rising external debt (especially to
discussions at the forum, an increase of China) and ethnic tensions, particularly in the
44% since 2018. As Moneyweb notes, “For build-up to next month’s general election. On the
these investments to be sustainable, there positive side, the construction industry has been
needs to be a change in approach from the experiencing a boom. For example, in 2017 – 18
government.” it accounted for 18% of the country’s GDP
with millions of US dollars pouring into social
Cement update housing. This proved to be a windfall for foreign
It was back in August 2019 that Bryan Perrie, and local contractors. Many will want to see what
MD of The Concrete Institute (TCI) acting the newly elected government has in store for
on behalf of Africam, Dangote Cement SA, Ethiopia.
Lafarge Industries South Africa, Natal Portland
Cement Company and PPC, announced that Cement update
TCI had applied to the International Trade Last September, Ethiopian newspapers and
Administration Commission (ITAC) of South agencies reported that the Abay Industrial
Africa to investigate the surge of imports Development SC had secured a 20-year licence
of low-priced cement. The industry has also from the Ministry of Mines & Petroleum to source
approached the Department of Trade and raw materials for its new 5000 tpd cement plant
Industry (DTI) to apply for special designation currently under construction in Eastern Gojam
status, without which, it says, it will not Zone, Dejen Wereda, Amhara Regional State.
be able to benefit from the government’s The civil works are being undertaken by the
ambitious infrastructure plan. Xolisa Phillip Chinese Hengyuan Group while FLSmidth will
writing in The Africa Report pointed out the supply engineering, design and full equipment.
industry has capacity to produce 20 million Completion is scheduled for 2022.
tpy but is currently producing 13 million t. It is
grappling with a tough operating environment Ghana
and cheap imports from Vietnam and China At this time last year, the World Economic Forum
as financially-squeezed consumers are driving reminded us that three decades ago Ghana
up demand for cheap blended alternatives to was in crisis and on the verge of collapse. Fast
regular cement. The industry is hoping that forward to 2019 and the Forum predicted the
the ITAC will impose a tariff of at least 45% to country would be the world’s fastest growing
curb imports. economy. The World Bank, on the other hand
The other major talking point from the says the same but also adds in three other fastest
industry is whether PPC will be successful growing economies: Côte d’Ivoire, Ethiopia and
in its third attempt to merge with Africam. In Rwanda. Whatever the argument, Ghana has
his article published in Business Maverick made gigantic strides to be where it is today. Its
in November 2019, Ray Mahlaka reminded economy is expected to expand 6.2% this year
readers that since 2014 both companies had and 5.4% in 2021.
twice attempted to combine their operations, As part of a memorandum signed between
the last one collapsing at the end of 2017. China and Ghana in 2018, Beijing will finance
He suggests that PPC still has not ruled out US$2 billion worth of rail, road and bridge
prospects of reviving the merger talks. Mahlaka networks, and in exchange, China will be granted
suggests, arguably, it could be opportunistic access to 5% of Ghana’s bauxite reserves. The
for PPC to launch the bid even though there is first US$649 million has been released by the
a distressed business environment which can Sinohydro Group.
be good for acquisition opportunities.
In November PPC reported that headline Cement update
earnings per share had dropped by 65 – 85%. Dangote Cement operates a 1.5 million tpy bulk
The company attributed the deterioration in cement terminal at Tema. It has been investing
its interim financial results to the impact of its US$100 million in a new clinker grinding plant at
Mozambique Sources
Last year the daily newspaper Correio da Manha News agencies, company news, World Bank,
reported that Chinese investors will spend Focus Economics, Local press reports.
T
he relatively slow growth in 2019 was African Outlook. Overall, Africa’s growth
mainly due to the modest expansion fundamentals have improved, driven by a
of the continent’s ‘big five’ – Algeria, steady shift toward investments and net
Egypt, Morocco, Nigeria, and exports and away from private consumption.
South Africa – whose joint growth was an Over the longer term, Africa has huge
average rate of 3.1%, compared with the potential for growth, as the average annual
average of 4.0% for the rest of the continent. growth rate for 53 African countries will be
Africa’s economic growth stabilised in 2019 6.2% between 2010 and 2040, with 37 of
at 3.4% and is on track to pick up to 3.9% in these countries expected to grow by more
2020 and 4.1% in 2021 as revealed by the than 5% as predicted by the Programme for
African Development Bank (AfDB)’s 2020 Infrastructure Development in Africa (PIDA).
18
19
The drivers of this growth are expected to be is the most ambitious road network on the
rapid urbanisation and economic diversification continent. It comprises nine interlinked highways
beyond resource-based activities. Achieving this with a total length of 56 683 km. 16 corridors
growth potential will require investment in new also have railway lines of around 20 000 km, and
infrastructure and African governments are focusing some corridors, such as the Central Corridor and
on the development of regional economic corridors, the Beira/Shire/Zambezi Corridor, include lake or
interlinking highways, railways and ports in the river transport. All of these corridors finish at ports
region. This will provide connectivity between and/or link to ports. Major transport corridors
international, national and rural networks. The lack such as the Northern Multimodal Corridor, which
of infrastructure is a serious obstacle to growth will facilitate the travel of people and goods
and development, and results in a low level of across the borders between Kenya, Uganda,
intra-African trade and trade with other regions. Rwanda, Burundi and the Democratic Republic of
The continent accounts for 12% of the world the Congo (DRC), with a spur to South Sudan;
population, but generates a mere 1% of global the North South Multimodal Corridor between
GDP and only 2% of world trade. Studies such as South Africa, Botswana, Zimbabwe, Zambia,
those by the Infrastructure Consortium of Africa Malawi and the DRC; and the Central Corridor
(ICA) have shown that poor road, rail and port between Tanzania, Uganda, Rwanda, Burundi
infrastructure adds 30 – 40% to the costs of goods and the DRC, all three will transform logistics in
traded among African countries. Sub Saharan Africa (SSA).
0$6f.LOQ%XUQHU_&DOFLQHU%XUQHU_+RW*DV*HQHUDWRU_)XHO6XSSO\6\VWHP
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assistance in order to mobilise funds for the Transport corridor infrastructure in the
development of these corridors. The two main pipeline
transit corridors in East Africa that facilitate import GlobalData is tracking nine major corridors with
and export activities in the region are the Northern 26 roads and railways that are being proposed
Corridor (2038 km long) commencing from the or are underway with a combined value of
port of Mombasa, which serves Kenya, Uganda, US$93.1 billion. At the heart of each corridor
Rwanda, Burundi and Eastern DRC, and the is a road or railroad or a combination of both,
Central Corridor (1300 km long) that begins at sometimes accompanied by a power line. The
the port of Dar es Salaam, and serves Tanzania, projects have a variety of proponents, including
Zambia, Rwanda, Burundi, Uganda and Eastern national governments, donors and private lenders.
DRC, requiring nearly US$20 billion to revamp In East Africa, for example, the Northern and
them. Central transport corridors serve nine countries
(Tanzania, Kenya, Rwanda, Burundi, Ethiopia,
Supporting transport corridor the DRC, South Sudan, Sudan and Djibouti).
infrastructure in West Africa They cover approximately 5000 km of trunk roads
The Bamako – San Pedro corridor between Mali of various grades, 4500 km of railway lines,
and Côte d’Ivoire provides an alternative route to 17 major border crossings and two major seaports
open up access from landlocked countries in the (Mombasa and Dar es Salaam). Only 34% of
vicinity to the Gulf of Guinea and its international the Northern Corridor’s network of roads can be
ports. The project will connect Mali and the considered to be in good condition.
northern part of Guinea to San Pedro, an important In total, 53.9% of the corridor project pipeline
international port in Côte d’Ivoire. The project by value is being funded by various joint financing
comprises improvement and maintenance work arrangements between the public and private
on 140 km of the corridor in Mali and 135 km in sector. While 22.8% of these projects by
Côte d’Ivoire. The works are expected to reduce value are solely publicly funded, only 23.3%
travel times by 70% and significantly lower the of these projects by value are privately funded.
cost of transportation between Mali and the Building roads and railways remains a priority
port of San Pedro. This will result in increased for China in Africa, where Chinese contractors
opportunities for economic development and such as China Railway Construction, China
trade, both between Mali and Côte d’Ivoire and for Communication Construction, Power Construction
communities living along the route. With large areas Corporation of China and others are involved
of land unused due to a lack of access to efficient in projects connected with these corridors
transport links, the project will also help the region worth US$25.8 billion. The rest of the contracts
develop its untapped economic potential. (in projects worth US$79.3 billion) have been
The Abidjan – Lagos Corridor is an essential awarded to various contractors headquarted in
link in the Dakar – Lagos Corridor, which is Turkey, Brazil, South Korea, the US, the UK and
part of the TAH of the Economic Community others. When completed in their entirety, the
of West African States (ECOWAS) region, tracked projects identified under these corridors
whose development is one of the 16 priority will total over 28 200 km in length (for roads
continental infrastructure projects identified 11 490 km and 16 788 km for railways), of which
on the continent’s scale. The plan to build a 18 459 km will be newly constructed, 7258 km will
6259 km highway between Mombasa port and be upgraded and 2561 km will have an element of
Lagos in Nigeria is one of the most ambitious both construction and upgrade. Some individual
infrastructure projects in the pipeline, and part corridors in the pipeline are over 4000 km long.
of the TAH network. The road is planned to pass To support the development and maintenance
through six countries: 737 km in Nigeria, 1044 km of Africa’s ‘hard’ transport infrastructure (such
in Cameroon, 1319 km in the Central African as roads and railways), ‘soft’ infrastructure – the
Republic, 1561 km in the DRC, 740 km in Uganda financial, regulatory and governance systems,
and 1100 km in Kenya. Only Nigeria, Cameroon, and institutions to manage the transport systems
Uganda and Kenya have completed their roads, to their full aptitude – needs to be developed
but there are missing links in the Central African simultaneously. A key cause of lengthy transit
Republic and the DRC. One of them is identified times through Africa, hindering intra-regional trade,
as the Mbarara – Kisangani project, a 940 km has been the often long procedures involved in
road project of which 108 km is in Uganda passing through two sets of identical controls on
and 760 km is in the DRC. Some bottlenecks each side of the border. As well as causing delays,
hampering the project include difficult terrain and lengthy transit times increase the cost of trade,
climate conditions, inadequate funding for road and make African businesses less competitive.
maintenance and upgrades, as well as insecurity Given that 16 African countries out of 54 are
due to civil conflicts that have also damaged roads land-locked, the adverse impact of inefficient
that now require reconstruction. border controls on the economy is substantial.
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C
ement Plants use many critical pneumatic or low-pressure compressors is not able to
conveying processes that rely on provide the necessary flow to sustain the
specialised equipment, such as blowers plant’s operations, temporary equipment
and low-pressure compressors, to move may need to be rented and installed. Proper
raw material and finished cement through their selection and installation of this rental
plants. This equipment is typically designed equipment is critical to ensure the project cost
to operate efficiently in a pressure range is minimised while the need is fulfilled. This is
from 5 to 60 PSIG. Most plants simply cannot relevant to any cement plant that has utilised
afford an interruption in these processes. temporary compressed air equipment for
If one of the permanently installed blowers pneumatic conveying processes in their facility.
31
Before exploring the details of common low-pressure compressor operating on
mistakes made when renting equipment to a VFD can be utilised to try out these
replace permanently installed blowers or theories prior to taking on a costly and
low-pressure compressors, the first question complex capital project.
to address is: ‘In what situations would a
rental blower or low-pressure compressor be Common mistake #1: renting more
required?’ Several scenarios arise where the machines than needed
permanently installed equipment is unable to Identifying the true flow and actual operating
sustain plant operations: pressure needed to replace a permanently
f Unplanned outage = Rotating equipment is installed machine can have a significant
prone to many modes of failure and while impact on the cost and complexity of the
most plants place a strong emphasis on temporary solution. Some plants will take the
predictive maintenance, failures do occur. name plate ratings from the existing blower
In some instances, the timeline to repair the or low-pressure compressor that needs to
failed blower or low-pressure compressor be replaced and use those to specify the
is longer than the plant can tolerate, and a temporary system needed. This approach is
temporary solution is needed. certainly the most conservative approach.
f Planned outage = While most blower Permanently installed equipment is typically
or low-pressure compressor system specified for the ‘worst case scenario’ and
upgrades are completed during planned few, if any, cement plants need that full flow
turnarounds, there are scenarios where and full pressure all the time. Many plants can
this is not always possible and upgrade operate with less flow and a machine capable
projects need to be completed during of delivering a lower operating pressure for a
a time when the plant is operating. This temporary project. Only the plant operators
could be a complete machine replacement, can specify how much less. Certainly,
component replacement, electrical supply specifying rental blowers or low-pressure
power upgrade, or a piping upgrade. In compressors off the name plate of the machine
these instances, a temporary blower or being replaced maximises the rental project
low-pressure compressor solution may be spend and complexity. This critical step
needed. should not be overlooked. A best practice for
f Proof of concept = Some plants want any cement plant is to have these minimum
to prove that their processes can be required flows and actual system operating
improved or sustained with more or less pressures prepared in advance of an emergent
flow. In these cases, a rental blower or need.
Table 1. Comparison of energy consumption and cost for a need of 3200 cfm @ 35 PSIG.
Estimated Energy
Consumed for Estimated Energy Cost for 1
Technology
1 Week of 24/7 Week of 24/7 Operation
Operation
Notes:
1. Assumed cost of electricity is US$0.11/kWh
2. Assumed cost of diesel fuel is US$4/gal.
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37
As is well known, the inhalation of cement The National Fire Protection Association has its
dust has been linked to silicosis, a serious own set of standards for combustible dust.3
and sometimes deadly lung disease.1 This is in The issue of dust containment is particularly
addition to a number of other illnesses attributed significant to commercial, high-capacity
to dust inhalation. The cleaner the facility’s construction and transloading facilities.
environment, the more the health of employees High-volume conveying of any material can create
can be protected. With an outdoor facility, a situation where dust emissions are a concern.
being able to cut down on dust emissions can Current open types of belt conveyors generate
decrease the negative health effects experienced excessive dust or material spillage during the
by neighbouring residents. It can also decrease loading or discharge process.
the common complaints from locals about soot
and residue blanketing their homes. Furthermore, Enclosed belt conveyors
the importance of complying with the Enclosed belt conveyors help to minimise
Occupational Safety and Health Administration’s this effect by containing the product within
silica standard should not be forgotton.2 an enclosed load skirt system, and capturing
Keeping silica within permissible exposure much of the material in the discharge area to
limits will help cement companies avoid hefty avoid pileups in the equipment below. This
fines. Having fewer particles in the air also also prevents loss of product, along with
works to prevent fire and dust explosions. belt scrapers in the head that reduce carryover
towards the tail. Enclosed belt conveyors also
typically include self-cleaning tails and wing
pulleys with reclaim flaps for better clean-out in
the tail. Most enclosed belt conveyors feature
external rather than internal bearings, which
help to contain product on the inside and extend
the life of the bearings as well as certain wear
parts. In addition, enclosed belt conveyors have
the ability to move large volumes of material
while simultaneously minimising product
movement points, preventing unwanted aeration.
Configuring the accompanying elevator for a
continuous (gravity) discharge will also help
Overhead view of the Sweet® enclosed belt
ensure that the product is not aerated at the time
conveyor.
of discharge.
www.worldcement.com
over other belt conveyors. The construction of thick-gauge material is more durable and thus
an enclosed belt conveyor lends itself to more long-lasting.
adaptable system designs, as it can be horizontal
or inclined and can have multiple discharge and Hazard monitoring
loading points. Most enclosed belt conveyors The company’s enclosed belt conveyor features
feature CEMA C6 idlers, allowing users to built-in sensor ports that can be paired with
move a wider range of products from the light a number of optional sensors, either selected
(concrete and ready-mix) to the extremely heavy separately, or integrated together with the
(sand and gravel mixtures). In addition, CEMA 4B Watchdog™ Super Elite Hazard Monitoring
C6 idlers are a standard off-the-shelf part, System. This system incorporates shaft speed,
available from a multitude of suppliers. Enclosed bearing temperature, plug chute, and belt
belt conveyors also generate much less noise misalignment sensors. The ability to monitor
than other belt conveyors. EBCs do not have equipment condition and performance is critical
exposed parts like open conveyors, and shafts to ensuring timely repair of certain parts that may
that are exposed have the necessary guards to deteriorate over time. Sweet® elevators have
prevent catching points. similar hazard monitoring available. The company
has several different elevator models; pairing an
A solution enclosed belt conveyor with the right infeed and
Sweet Manufacturing Company’s takeaway equipment will allow for smoother and
enclosed belt conveyor is well-suited for the safer operation.
commercial and high-capacity industrial sectors,
as maintenance can be performed with minimal Conclusions
use of tools and without entry. This solution was In summary, the major advantages of an enclosed
designed with plant maintenance and operation belt conveyor over a standard belt conveyor are
personnel in mind. Maintenance parts are on the three-fold:
outside of the company’s enclosed belt conveyor. f Dust emissions are minimised, providing
The design allows users to repair and replace greater health and safety.
the CEMA C6 troughing idlers and return rollers f Product is better contained, with less chance
without having to remove the top or bottom panels for unwanted aeration or leakage.
and unsplice the belt. This greatly decreases f Enclosed belt conveyors are more
the number of tools required and the amount of substantial, heavy-duty machines with longer
downtime in the unfortunate event of a breakdown. life spans.
More importantly, it increases safety as the repairs High-capacity concrete facilities could therefore
can be done while maintenance personnel are benefit from incorporating enclosed belt
standing on a platform or catwalk rather than conveyors into their systems.
climbing inside the machine. It is similarly easy to
access the bearings for lubrication, removal, or References
replacement from the outside of the enclosed belt 1. ‘Silicosis Symptoms, Causes, and Risk Factors’,
conveyor without dismantling the belt. American Lung Association, Chicago, Illinois –
www.lung.org/lung-health-and-diseases/lung-disease-
Holding up to harsh conditions lookup/silicosis/silicosis-symptoms-causes-risk.html
Built with 10-gauge steel, the Sweet® enclosed 2. ‘Standards: 1926.1153 - Respirable Crystalline
belt conveyor is a particularly heavy-duty piece Silica’, US Occupational Safety and Health
of commercial-grade equipment. The conveyor Administration (OSHA), Department of Labor,
utilises a design of US prime G140 galvanised Washington D.C. – https://www.osha.gov/laws-regs/
steel construction, not only to hold up to harsh regulations/standardnumber/1926/1926.1153
plant conditions, but also to allow for outdoor 3. ‘Codes & Standards: NFPA 654- Standard for
installations. The G140 steel will withstand rough the Prevention of Fire and Dust Explosions from
working environments; it may be particularly the Manufacturing, Processing, and Handling of
advantageous to any facilities near ports, salt, Combustible Particulate Solids’, National Fire Protection
and rough weather. The hip roof serves to further Agency (NFPA), Quincy, Massachusetts – https://
protect the conveyor from rain and snow. Inside www.nfpa.org/codes-and-standards/all-codes-and-
the conveyor, loading and discharge points that standards/list-of-codes-and-standards/detail?code=654
are lined with polyurethane, AR, ceramic chip, or
ceramic tile, allow for added equipment longevity. About the author
The EBC design also includes a heavy-duty Brandon Fultz is the Business Development
horizontal pulley on the troughing or carrying Specialist at Sweet Manufacturing Company.
side of the conveyor. A heavy duty pulley will He has 10 years of OEM experience in industrial
allow a belt to carry the heaviest loads while the applications.
41
Another two hours may go by while the information sharing. Time zones, different
Account Manager checks with customer public holidays and information gathering from
service and production, and waits for a various departments can pose a challenge for
response before he is able to provide a delivery even the best customer service team. A digital
confirmation to the customer. sales tool can provide customers immediate
New digitalisation tools can make the access to their data, while also increasing
customer ordering process work more transparency, and maintaining strong customer
efficiently and transparently, turning this relationships through improved quality,
five-hour exchange into a five-minute session. convenience and productivity.
The many benefits of digitalisation initiatives
such as an online customer platform, The digital way of working has arrived
include streamlining communication and A new digital way of working is here. Not
just for millennials, who are driving this
change, but the entire workforce has
different expectations about how to
order their products. A Gartner study1
estimates that 75% of B2B procurement
spending will happen via an online
marketplace until 2025. A salesforce.
com study found that 82% of B2B
buyers want their business purchasing
experiences to be similar to personal
shopping, which means, digital, flexible
and available at all times.2 Mondi, a
leading global paper and packaging
group, also conducted a customer
satisfaction survey in 2019 with almost
3000 customers, which found that more
than half (57%) answered that they
would find digital ordering and tracking
useful.
Direct feedback
Sometimes customers need to
make a claim. myMondi offers
myMondi’s ordering function. users the ability to make claims
E L E VAT E .
The customer can upload images and
explanations directly, and can track the
status of the claim. This provides customer
service with all the correct information
customer service colleagues need, so
issues can be processed swiftly.
Who’s who?
.
D O N ’T C L IM B
Using the system, the company sales team
can assign roles within the customer’s
team or organisation to streamline
processes. For example, finance can
access the invoices and payables, while
procurement can focus on products, stock
and certifications for the bags ordered.
Each relevant team member can access
the information they need, maintaining
confidentiality where necessary. For
globally operated cement producers with
complex structures, this makes it possible
to maintain oversight and clarity.
Conclusions
Just as customers are used to performing
transactions digitally in their everyday life,
new B2B developments are the logical
step for digitalising the cement industry,
allowing full transparency and access to
information, which improves the quality
and speed of decision-making.
The future is here, just a simple ‘log in’
away.
References
1. Gartner Research 2018 – https://www. ARE YOU PAYING SKILLED STAFF TO CLIMB STAIRS
supplychaindive.com/news/gartner-trends-2018- OR TO PRODUCE CEMENT?
AI-b2b-marketplaces-chatbot/514389/
DON’T CLIMB.
2. Salesforce.com/State of the Connected
Customer 2018 – https://c1.sfdcstatic.com/
content/dam/web/en_us/www/documents/e-
ELEVATE.
books/state-of-the-connected-customer-report-
second-edition2018.pdf
46
Testing
the W ater
Water
Ricardo Gonzalez, GlobBULK, discusses the logistics of
efficient cement plant capacity expansion using waterways.
E
xpanding production capacity is less and emissions and a revision of the ETS (Emissions
less an exercise of mere duplication. Trading Scheme).
Twin lines have the obvious advantage of How this will affect the cement industry, in
scale with a shared pool of resources, Europe and elsewhere, remains to be seen, but
from the construction team to the operations clearly the playing board will be modified.
management. But the cement business is not One obvious lever for change is logistics,
about producing a grey powder anymore; many whose related costs in a cement plant are
additional layers are relevant nowadays and often a substantial fraction of the delivered
need to be considered. price, typically in the range of 10 – 15% but
This article presents some considerations sometimes reaching up to 30%.
regarding waterways logistics, interweaved Figure 1 presents the average efficiencies
with a capacity expansion project in Vietnam of different transport modes as measured by
for which the logistics have recently been CO2 emissions per ton-km. From this point
assessed. These ‘additional layers’ may also of view, the conventional 250 km distribution
have relevance elsewhere. radius around a factory, by truck, may become
a 5000 km circle by ship.
The European Green Deal There are more factors affecting a logistics
In December 2019 the EU presented setup, but half of the world’s population lives
‘The European Green Deal’, a response to the within 100 km of the coast or inland waterways
climate and environmental related challenges.1 and the share will likely increase (Figure 2),
It includes a strategic roadmap in which the CO2 efficiency in transportation has come
target is achieving a ‘climate neutral and to stay, and the IMO (International Maritime
circular economy’, with special focus on Organisation) is pushing for further and more
resource-intensive sectors and an overall target aggressive GHG emission reductions in the
for carbon neutrality by 2050. It requires the fleet of vessels that are expected to maintain
further reduction in GHG (greenhouse gas) the relative efficiencies presented in Figure 1.
47
Inland waterways transport materialised as there is scarcity of large units in
The EU is also favouring IWT (Inland Waterways Vietnam and elsewhere. Additionally, in Bangladesh,
Transport) solutions. In addition to environmental there is an effective cartel on the ship supply side
externalities (Figure 3) there is also a threat of road which precludes the introduction of economic
congestion which could be alleviated by a larger incentives linked to performance. Some parts of the
share of IWT. Overall, so far, the actual success of Vietnamese waterways network are congested, and
the European initiatives has been limited,2 but IWT a rationalisation might be required together with a
is important in certain countries and regions such as long-term investment plan to maintain and increase
Vietnam, Bangladesh or the US southeast around their transport capacity (Figure 5).
the Mississippi river, just to name three. The capacity expansion of GloBULK’s Vietnamese
Vietnam carries approximately 40% of its freight client was designed so that most of the clinker (~4
(50% of the cement) by internal and coastal Mt/y) would be manufactured near the quarries and
waterways, along the Red River and the Mekong transported by barge to a grinding station located in
deltas, with numerous riverine ports and over the area surrounding Ho Chi Minh City, in a trip of
40 000 km of navigable channels, of which 4500 km almost 400 km.
of major routes extend across borders. Designing a new facility for today’s barges may
The evolution of the IWT Vietnamese system is prove to be an expensive decision in 10 years’ time,
accelerated, as presented in Figure 4, but is still when the fleet structure will likely be quite different
far from the average barge size of 2.4 kDWT in again; a ‘no-regrets’ forecast is needed here to
the Netherlands and Germany, or the usual 15 estimate the future barge fleet, together with a
barge trains in the Mississippi carrying 22.5 kt. flexible design that can be adapted to the varying
Bigger barges have clear operational advantages realities.
for cement producers which cannot always be
Sea level rise
The financial return periods requested from
-)%
new investments are becoming shorter;
.)%
30 years ago, planning with a time frame
!" of 20 years was not unheard of, but today
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for longer periods, often even by legal
requirements – only temporary or minor
' infrastructures and buildings are designed
for a lifetime of less than 50 years.
Figure 1. Transport efficiency.
Climate change is also here to stay.
There are many associated impacts of
climate change, but it can be assumed
that the sea-level rise will have a large and
deep effect on numerous coastal areas.
For Vietnam, there are recent (extreme
case) estimates suggesting that the land
home to one third of Vietnamese people
may fall below the high-tide line by 2050.3
There is much uncertainty regarding the
amount of this level rise, but the industry
Figure 2. Percentage of the country’s population within a is uncertain, not fully blind (Figure 6).
100 km coastal strip. The industry’s shore facilities need to
be designed to at least maintain their
operational levels under a scenario of
sea-level change. A formula proposed by
visit martin-eng.com
call 800.544.2947 or 309.852.2384
email info@martin-eng.com
® Registered trademark of Martin Engineering Company in the US and other select locations. © 2020 Martin Engineering Company.
Additional information can be obtained at www.martin-eng.com/trademarks and www.martin-eng.com/patents.
Ordinary water level variations
GlobBULK’s Vietnamese grinding
station receives all its inbound products
by waterways, in all sizes of vessels,
such as barges from 500 to 1500 t, and
ocean-going ships from 25 to 50 kDWT.
Barges are unloaded with shore-based
mobile cranes, and ships discharge the
product with their own gear on eco-
hoppers installed on the jetty – a quite
usual practice (Figure 7).
Figure 4. Evolution of carrying capacity of Barge Fleet, That tides exist is a known fact, but
Vietnam. some related aspects are eventually
missed by designers and traders. Figure 8
presents the frequency distribution of
water levels at the Vung Tau port in
Vietnam. It is a semi diurnal tide (2 cycles
per day), with a range that exceeds 4 m.
It is important is to realise that low water
levels may have a large range: in this case
more than 3.0 m (for 80% of the most
frequent tidal cycles the difference is 2.5
m).
Figure 9 presents the relative position
of two typical geared bulk carriers and
the reach of their cranes at full load.
Depending on the particularities of the
ship, the quay elevation and the position
in the cycle tide, the cranes may not reach
the receiving hoppers. The problem will
Figure 5. Congestion along the Cho Gao canal, near Hoh often just last a few hours, until the high
Chi Minh City. tide is back, but eventually reduced low
water can be associated with a reduced
high-water level and the ship may have to
wait for several tide cycles.
There are projects where the hoppers
could not be used because of this
mismatch, although not in Vietnam to
GlobBULK’s knowledge.
Multi-product handling
One main lever to CO2 emissions
reduction in the cement industry is
clinker substitution. The last two decades
have seen a surge in the utilisation of
supplementary cementitious materials
(SCMs: from slag, fly-ash and pozzolan
Figure 6. Port Managers’ top concerns on climate change. to limestone filler). The utilisation of these
products will continue, although it can be
argued that their additional role in clinker
substitution is limited because of their
relative scarcity. 5
GlobBULK’s Vietnamese grinding station
receives all these SCMs, plus clinker and
gypsum/anhydrite, through its waterfront.
Most of the equipment is shared for
all the products (with the exception of
pulverised fly-ash). This requires special
attention in the material handling design:
Figure 7. Eco-hoppers in Vietnam. GGFBS is finer than the rest (excluding
Global Presence,
Local Service.
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PFA), gypsum can be quite sticky, clinker is often engineers. The toolkit does however need to be
very dusty and most of them are very abrasive – their sensibly used with accumulated experience.
densities are different.
A routine design of the associated materials Capacity increase through ship arrivals
handling equipment for all these products will likely Doubling the manufacturing capacity of a cement
fail: needle gates that work with clinker will let the plant can be achieved by doubling the inbound
slag pass uncontrolled, chutes and deviators that are receiving facilities or capacities. It is a safe solution,
suited for clinker will get blocked with gypsum, and but typically expensive and often not viable because
discharge operations that go smooth with slag will be of space constraints. From a logistics perspective,
stopped because of clinker dust clouds. the question to be answered for a capacity
Some problems are trickier than others, but expansion is: What are the minimum changes
the solutions are within the toolkit of mechanical needed to reach the expected results?
Finding an efficient solution to this
question requires the analysis of the
customer-server model of the operations, a
queuing or networking problem which can
be tackled through computer simulation.
In the case of the Vietnamese factory
it involved, among other aspects, the
probabilistic analysis of the ship and barge
arrivals, which yielded detailed information
(of probabilistic nature) on relevant
operational aspects on ship handling
performance (eg. estimates for the waiting
times or demurrages for the vessels), or
the design of the minimum storage capacity
for the different products (derived from the
modelled ship arrivals and the expected
consumption – Figure 10).
Figure 8. Frequency distribution of water levels (Vung Tau
Port, Vietnam).
References
22.00 24.00
1. https://ec.europa.eu/info/strategy/
priorities-2019-2024/european-green-deal_en
2. https://www.eca.europa.eu/Lists/
ECADocuments/SR15_01/SR15_01_EN.pdf
11.98
7.08
3. https://coastal.climatecentral.org/, based on
30.00
9.97
Programs, 2013
MV SEA HORSE 29 kDWT MV PANTELIS 25 kDWT
5. https://www.lc3.ch/wp-content/
uploads/2017/03/2016-UNEP-Report-
Figure 9. Crane reach of bulk carriers. Complete6.pdf
6. Figure 1: With data from: Second IMO GHG
Study 2009
7. Figure 2: With data from: Gridded Population
of the World, GPW4, 2017.
8. Figure 3: With data from: Economical and
Ecological Comparison of Transport Modes: Road,
53
But of course, fillers do not want to compromise requirements of cement producers also in terms
on the performance of their packaging in of shelf life, CEPI Eurokraft and EUROSAC
favour of a sustainable solution. They must also requested the independent Norwegian research
respond to their customer’s high expectations organisation Sintef to investigate the shelf life
and requirements and, at the same time, tap of cement paper sacks and form-fill-seal (FFS)
economic advantages. Whether filling speed, polyethylene cement sacks. The outcome
product protection, pack cost, cleanliness or shows: paper sacks perfectly preserve cement,
shelf life – all these aspects must be considered even when stored for 1 ½ years. They provided
when choosing the perfect packaging. A equivalent protection for cement to plastic
comprehensive study among fillers and retailers sacks when stored under the same adequate
of cement and other building materials by RISE conditions. Whether total weight, level of
(formerly Innventia) has revealed that fillers hydration, mortar strength, initial flow behaviour
especially profit from lower packing costs and or 28-day compressive strength – the quality
higher filling speeds when using paper sacks and performance of the cement from both types
(World Cement, April 2016). When it comes to of sacks was well within the requirements for
shelf life, stakeholders have claimed that plastic the cement industry. This article will explain the
bags provide a better shelf life than paper bags. design of the study and present the results in
However, there is no reliable data available. To detail.
ensure that the paper sack industry meets the
About the study
For the investigation, a standard 25 kg
European cement paper valve sack
made of two paper layers of 80 g and
70 g with a 12 μm perforated high
density polyethylene (HDPE) free film
barrier and a standard plastic sack
made of three layers of COEX PE film
(LDPE, HDPE and LLDPE) with a total
thickness of 120 µm were used. All
sacks were filled with Portland cement
CEM I 52.5 R according to European
standard EN 197-1 cement. Due to
their smaller capacity, two plastic
sacks were employed for each batch
of 25 kg cement.
Although the typical storage time for
bagged cement in Europe is estimated
Paper sacks protect the product quality and performance to be no longer than 2 to 3 months,
for at least 18 months in storage. Image storage depot: the study set out to determine how
Sika Deutschland, Rosendahl, Germany. the sacks perform throughout longer
storage periods of up to 18 months.
Storage conditions
Stored in an outside storage house
in Norway, a total of three sacks per
type were tested. Representing the
typical secondary packaging, the
sacks were stored on a wooden pallet
and covered by a plastic stretch film.
The sacks were exposed to changing
climatic conditions. Temperatures
varied between –17.9˚C and 32.1˚C
and the relative moisture ranged from
28% to 96% (sampling of humidity on
a random basis).
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collected and analysed. The sampling and water in the cement was measured by
homogenisation of the cement were conducted registering the weight of the sample as it
as follows: In the first step, the cement was was heated from 30˚C to 950˚C. A weight
divided into four equal parts. Secondly, two loss (loss on ignition) would indicate the
diagonally opposed quarters were recombined formation of a hydrate product due to the
and manually homogenised (mixed). Step 1 release of H2O (decomposition of hydrates)
and 2 were repeated three times, resulting in or CO2 (decomposition of carbonates). The
sampling approximately 3 kg of cement from temperature region 50 – 350˚C corresponds
each sack which was sent for analysis. to the decomposition (loss of water from
hydrates) of gypsum and cement hydration
Test methods to evaluate cement properties phases such as calcium silicate hydrate gel,
The samples were subjected to three different ettringite or calcium monosulfoaluminate
test methods to determine the water content in hydrate. Mass loss in the range of 400 – 500˚C
the cement and the performance of the cement corresponds mainly to the decomposition
after each storage period. of calcium hydroxide, while the range
600 – 950˚C corresponds to the decomposition
Thermogravimetric analysis of calcite, vaterite and aragonite, as well as
In a thermogravimetric analysis, the total complex carbonate phases like calcium hemi-
amount of physically and chemically bound and mono-carboaluminate hydrates.
Calorimetric analysis
Secondly, a calorimetric analysis
was conducted on the cement paste
mixed externally from the samples to
measure the amount and rate of heat
which evolved during cement hydration.
Measurements were performed up to
24 hours from the point of first contact
between dry powder and water against a
calibrated reference of similar mass and
heat capacity. As the hydration reactions
proceed, heat is released. The heat
production rate, which is proportional
to the hydration rate of the cement, is
recorded in the isothermal calorimeter.
www.koeppern.de
Global Cement
World Publication
App
Subscribe now
www.worldcement.com/magazine/world-cement/app/
Laurent Moret, Standard Industrie,
outlines the benefits of equipment
designed to improve efficiency,
production and safety in bulk
handling.
Pre-homogenisation
In the mixer and before being sent to the
kiln, raw cement is mixed with additives.
In the case of one customer, additives had
to be transported from outside through a
conveyor belt located 44 yd high. During the
transportation of product, some of it can fall,
causing emanation at the chute level. Moreover,
when the conveyor is outside, this can often
lead to product flying away in the wind. This
loss of product (especially ash) causes many
LIFTUBE installed on crusher conveyer belt. belt stoppages linked to rollers getting dirty,
belts shifting, and product accumulating
between the belt and the structure.
In this case, the customer’s requirements
were to:
f Optimise productivity by stopping dust
emissions.
f Avoid degradation of equipment due to
accumulation of product.
f Lessen the cleaning cost of the belt
(1 to 2 times a month).
f Stop the contamination of the environment
due to flying product.
Cement mill
At the mill area where the products are mixed
with additives to produce cement, significant
material losses were occurring for one
customer (more than 110 lb per day) on a
conveyor belt.
It was causing loss of product as well as
significant cleaning costs.
The customer’s requirements were to:
f Decrease waste of product and reduce
AIRCHOC on a cooler. costs related to cleaning operations.
Total Lubrifiants is an expert in the cement industry. Many years of field experience and R&D developments
allow us to provide a full range of products, services and tools. Tailor-made solutions to optimize lubrication
and operational costs in general maintenance and special applications. Thanks to our partnership
with LUBRILOG, Total offers to its clients the latest technologies for open gear lubrication and cleaning.
lubricants.total.com ms.industry.lub@total.com Total Lubricants - Industry
f Guarantee the sealing of the conveyor
and improve its environmental
footprint.
The answer was to install 14 yd of
LIFTUBE in 30 in. width around the chute
and the product drop point – places
where a lot of material is usually lost.
The customer now has a contained
installation and the costs linked to
cleaning operations around this area have
been reduced by half.
The customer has also planned to
assign a second LIFTUBE project in one
other area.
www.trimecvalves.com / info@trimecvalves.com
to build ups. The high temperature AIRCHOC Regular compressed air blasting from the
system has now been installed on the preheater AIRCHOC into the different points of the
and cooler for the new lines and helps the cement plant allow the material to remain in
cement plant to run with full capacity. motion and maintain its flow in the production
process. This is a preventive solution, however,
Installation and efficiency curative solutions that result in the cleaning and
Each installation of air cannons is different, as unclogging of storage units are available.
a range of accessories are available, such as:
f Deflectors: These direct the air flow (straight, Silo and hopper cleaning services
inclined or 90°) towards the sensitive After a complete analysis of the clogged
clogging points. storage area, breakdown teams will place
f Stainless steel bevelling pistons: These their equipment outside, respecting safety
increase service life and help resist standards.
aggressive atmospheres (chemistry, The POWERNET® deep drilling equipment
incineration, cement works.) offers a solution for bridging problems. Its
f Blowpipes: These allow air to be channelled properties are as follows:
during firing, and are available in steel, f Diameter for piercing storage units from the
stainless steel, refractory stainless steel, top or bottom: 65 to 300 mm.
ceramic etc. f Intervention depth: up to 45 m.
f Isolators: These secure maintenance f Controlled from outside.
operations from high temperature, aggressive f Cleaning without pollution of the product.
product, or risk of material return. f To be used before GIRONET®.
OF
RETROFIT
IGS discusses the
advantages of retrofitting air
cannons over replacing the
equipment entirely.
R
oanoke Cement, like many cement
plants, was faced with an unexpected
operational problem. The manufacturer
of the air cannons that they depended
upon for many years to help prevent process
blockage and improve efficiency, stopped the
supply of replacement spare parts. Instead of
purchasing inexpensive replacement parts, the
new recommendation was to completely replace
the plant’s air cannons.
65
Air cannon life cycle amount of money to replace the internals with a
The lifetime of an air cannon varies greatly and is new design, and addressing the installation issues
mainly determined by the location and environment which cause the maintenance problems.
where it is mounted. Air cannons installed close
to the extreme heat and possible contamination Is replacement necessary?
from the cement process will not fare as well as Many air cannons that have been successful at
those mounted in ambient temperatures with a low solving buildup problems only ever require the
firing frequency. Yet even air cannons installed in replacement of a few spare parts. However,
the worst locations in most cases do not require recently, several cannon suppliers made the
complete replacement, but just a replacement decision to no longer supply spare parts for their
of the internals. Instead of spending money to high-performance air cannons. This has led to the
replace the air cannon, the plant would receive a only (expensive) alternative left for the plant – to
greater return on investment by investing a small replace their old cannons with new models.
This move has not been particularly well
received by many cement plants, as many of the
originally installed cannons are still performing
well. The need to completely replace air cannons
has caused plants to spend money, perhaps
unnecessarily, in order to ensure they continue to
have air cannons operating in their plant.
Retrofit solution
One supplier of air cannons and their components
has chosen to supply the necessary retrofit
solutions, which do not require a full replacement.
Integrated Global Services (IGS) has developed a
retrofit kit that replaces the internal components,
allowing plants to keep their existing air cannons
operating. The cost of a retrofit is also significantly
lower than the cost of installing a new air cannon.
T
mills or rotary kilns is usually a very
oday, cleaning open-gear drives dirty and time-consuming process,
is a huge time consumer for especially when people are using
cement plants and a significant ‘black grease or oil’ (aluminium
cost in terms of production complex greases with graphite or
loss. In order to help the cement asphaltic product).
69
Open gears generally need to be cleaned for
three reasons:
f When a maintenance shutdown is due to
take place, in order for an inspection to be
performed.
f To prevent abrasive wear by removing
contamination. Efficient lubrication must
be performed on clean and unpolluted
surfaces. Abrasive wear may cause the loss
of material on the gear drives due to the
presence of hard particles suspended in the
lubricant. This may cause serious damage
Figure 1. Effects of abrasive wear. to the gears working flanks (Figure 1).
f When switching from a ‘black product’ to
a high-viscous transparent or white fluid,
which are becoming the most common
service lubricants in the field.
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is essential for it to be successful. Preparatory After the cleaning, the teeth are covered
meetings with representatives from the company with an extreme pressure protection film. The
and personnel from across cement plant equipment can either be stopped for maintenance
engineering and maintenance teams must take or inspection or can continue in operation, using
place before the operation. Every aspect, from the lubrication spraying system continuously for
timings to safety, must be thoroughly planned to a few hours or refilling the tank in case of splash
ensure the most successful outcome. lubrication.
Total Lubrifiants is able to supply a cleaning kit
Cleaning methodology including PPE, High Pressure Pump, and drums of
Cleaning during operation can be performed Lubriclean EP for one operation (Figure 5).
on any type of lubrication system (permanent or
intermittent). The job begins with the preparation Case study
of the operation by installing waste product Recently a cement plant found that
collection tanks. using LUBRICLEAN EP saved them
After having stopped the spraying system 48 hours of downtime. In that time, kilns can
or draining the lubricant in case of splash or produce 5600 t of clinker, therefore the ability to
circulation lubrication, the Lubriclean EP will be keep production running while the cleaning took
sprayed by an operator using a high-pressure place benefitted the plant.
pump through the inspection door of the Out The plant also found that using the product
(lifting) pinion and In (pressing) pinion if double allowed dirt and grease to be removed from the
drive. It will be sprayed from one side to another girth of the gear in less than two hours, allowing
of the gear as well as on the edges. This operation them to begin the cleaning process while the kiln
will take around 1 hr using three or four drums of was still cooling, and restart the kiln soon after the
Lubriclean EP to fully clean the gear and casing. cleaning intervention.
The solution was seen to be an efficient
method of cleaning gears in this type of
industrial setting. The plant found that
their bottom line was not affected as no
loss of production was experienced, and
using the product allowed the plant to
implement a more proactive preventative
maintenance schedule. As the plant was a
key site for the group and the kiln usually
had a very high uptime, it was important
that it remained in peak condition and ran
reliably and efficiently.
The average cost of clinker is
approximately US$30/t; the company
saved 5600 t of lost production which is
Figure 4. Kiln open-gear drive after one hour cleaning. an approximate saving of US$168 000.
Conclusion
Lubriclean EP has been used in more than
100 cement (and mining) plants, and has
cleaned more than 200 mills and kilns,
saving end users shutdown hours.
C
ement production accounts for around Energy consumption reduction
5% of global greenhouse gases solutions are well understood by cement
emissions. As a result, emissions manufacturers and include: energy efficiency
reduction and reduced energy improvements, switching to lower-carbon
consumption have become key objectives fuels, reducing the clinker-to-cement ratio
for cement producers. and innovative processes and technology.
73
On the theme of energy efficiency, In dry process cement plants, exhaust kiln
recovering wasted heat from the production heat is used primarily for raw material and coal
process is one of the single-most impactful drying and heating. Remaining waste heat both
long-term investments that can be made from the kiln exhaust and clinker cooler can be
in terms of energy savings and economic recovered for power generation or for thermal
benefits for the cement plants. energy direct use including district heating
networks, process uses or district
cooling with absorption chillers.
Cement plant power generation
can provide recovered heat from
two main sources:
f Kiln exhaust gas heat, ranging
from 320 – 450˚C that is
ideally recovered before
being used for raw material
drying, by cooling it down to
approximately 250˚C. Heat
recovery can also use a part
of the gas flow, cooling it to
200°C while the remaining part
is used for drying purposes.
f Clinker cooler hot air, ranging
from 280 – 420˚C, cooled to
A 2 MW Enertime ORC module in Colombelle incinerator approximately 150˚C.
(Caen, France).
The ABC of ORC
In Organic Rankine Cycle (ORC)
projects, the recovered heat is
transferred to a thermal oil loop
at 315°C in heat exchangers
equipped with automatic
cleaning systems, ensuring a
continuous dedusting, safe and
efficient operation. Thermal oil
makes it possible to reach high
temperatures while maintaining
low pressures, generally below
10 bar throughout the circuit. The
absence of evaporation, no water
use, and the low pressures offer
significant advantages for industrial
waste heat recovery.
A 3 MW Enertime ORC module installed in a sintering plant of The recovered heat is then
Baosteel steel mill in Baoshang (Shanghai, China). transferred to an ORC machine
A typical schematic for an Enertime high temperature ORC module installed in a cement plant.
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and converted to electrical power with net Economics & financing
efficiencies of between 20% and 25%. Because the ROI for an ORC project is usually
High pressure organic fluid is preheated, longer than what is acceptable for the cement
evaporated and expanded in the ORC turbine, industry, and because ORC technology
driving a generator. The low-pressure organic remains non-core for cement producers, the
vapour is de-superheated in the regenerator future of ORC deployment falls under the
by preheating the high-pressure organic liquid, ESCO model where third-party investors
significantly improving the efficiency. After finance, build and run the ORC facility and
condensing in an air-cooled condenser, the provide energy efficiency services to the
fluid is pumped at high pressure and sent to industry. This model, which is highly popular
the regenerator, preheater and evaporator. in Asia, is beginning to see deployment in
Europe and America – it will likely become the
Advantages of ORC standard for energy efficiency projects in the
An ORC system can cover up to 30% of industry.
a plant’s power requirements, significantly
increasing the operating profits. A cement Technologies
plant with 3000 tpd of clinker production can Enertime is one of the few suppliers able
generate 1.5 – 3.0 MWe with an ORC machine. to offer high-temperature large-scale
Prior to the appreciation of, and demand for, ORC systems to the cement industry, with
ORC systems, Steam Rankine Cycle (SRC) unit sizes of up to 10 MW. The company is
systems had been the preferred waste heat based in Courbevoie, France, adjacent to
recovery technology. The main reasons for Paris la Défense Central Business District with
dissatisfaction with SCR are: ORC references also in China, Thailand and
f Lower and variable exhaust temperature Ukraine in Waste Heat Recovery and Biomass
at modern preheater and clinker cooler applications.
make it difficult to reach safe operational The key component in a large ORC is
temperature for SRC or require Mid Tap the turbine. Enertime has specialist turbine
Exhaust heat recovery with a loss of technologies that offer:
potential. f Optimised load distribution on journal
f Higher operation and maintenance cost bearings.
especially in higher income countries. f Low vibration and low maintenance cost.
f Higher installation cost per MW for f Easy maintenance on mechanical seals.
standard capacity at €3 million/MW typical f No risk of blade loss.
in OECD countries for a 2 – 3 MW plant.
f Efficiency of around 18 – 22%. Strategy
f Industrial water costs. In the Waste Heat Recovery market, the
ORC-based systems with high density fluids company has developed a differentiated
are specifically designed and adapted for strategy, depending on geography, for the
power generation from 1 – 10 MW, especially supply of its ORC technology:
with variable heat sources and heat recovery f In France and Western Europe, the
projects. The systems are fully automated, company offers turn-key projects
low-maintenance, modular, easy to install and including waste heat recovery system
do not consume water, therefore they are well supplied by partners and whenever
suited to meet the heat recovery needs of required, third-party financing with
cement industry. investors partners on the ESCO model
ORC heat recovery systems in cement plants f In Eastern Europe, Eurasia and South Asia
are cost-effective in OECD countries with the company works with turn-key contractor
stable electrical grids and typical grid electricity partners and provide them with ORC basic
costs of €50/MWh or above (with energy engineering, ORC turbine and generator
efficiency projects incentives) or €80/MWh and critical components
without incentives. They also offer important f In China, the company supplies basic
fuel savings for off-grid remote locations. ORC engineering and turbines.
In addition to the direct economic benefit This approach can lower the cost of
given by such investment, the average CO2 ORC system installation, without jeopardising
emissions for plants in OECD countries will quality and performance. It has been found to
represent 3000 t per installed MW per year. At be successful in China, for example, where the
€50/t of CO2, the net present value for 15 years company has a good track record and repeat
could amount to the investment value. orders.
T
he topic of climate
change and the actions
to mitigate it is becoming
more prominent in daily
discussions. Recently, the European
Union announced a green deal to
invest in a climate-neutral and circular
economy in the next 30 years.
The target is ambitious and
challenging, however many green
technologies are already available
and are installed worldwide, even
in some cement plants.
Besides increasing cement
production process efficiency,
focusing on carbon capture and
industry 4.0, waste heat recovery
(WHR) could have an important role
to play in moving towards a greener
clinker product.
77
Increasing the efficiency of cement Normally, two separate heat recovery exchangers
production are installed in by-pass to the main gas duct.
The efficiency of the cement production process Following the different characteristics of the exhaust
has been improving in the last few decades but, gas (sticky gas from the pre-heater and abrasive
despite this trend, the temperature of the exhaust dust from the clinker cooler), the technical features
gas is high enough to install a WHR plant that of the heat exchangers are different and are
converts the recoverable heat into electricity. optimised case by case.
The Organic Rankine Cycle (ORC) technology, The heat contained in the exhaust gases is
with which Turboden has 40 years of experience, typically transferred indirectly by an intermediate
is recognised as a competitive alternative to loop (thermal oil or pressurised water circuit)
steam technology, especially in sizes between to the ORC plant, which produces electric
5 –15 MWe. This is due to several advantages, power. The amount of electric power accounts
such as: no water consumption, low operation and for 10 – 30% of the cement plant’s electricity
maintenance, and no need for supervision. The consumption, leading to a consequent reduction of
increase of efficiency leads to a decrease in exhaust the monthly electric bill.
gas temperature, so in future, it is expected that Besides the lower cost for electricity, in most
lower temperatures will need to be dealt with. This of the cases studied there are other benefits.
trend benefits ORC technology as it can exploit low In fact, in many cement plants, the gas from
temperature sources better than steam technology both the pre-heater and clinker cooler has to be
and with a high electrical efficiency. cooled down before entering the filtration system.
Nowadays, the cooling of the gas is done using
Waste heat in cement plants quenching towers in the PH side and air-to-air
Waste heat, in the form of exhaust gas, is heat exchangers in the CC gas. Cooling the gas
available at two points: the pre-heater tower (PH) temperature in the heat exchangers instead of in
and the clinker cooler (CC). In cement plants, these systems helps to further reduce the electric
depending on the preheater stage number, the consumption of air-to-air exchanger fans and save
gas temperature at the outlet of the PH tower a significant amount of water that can be very
varies between 250 and 400˚C and at the outlet valuable in arid countries, by not spraying it in the
of the CC, it varies between 250 and 350˚C. quenching tower. Cement plants with their own
power plants based on engines or gas turbines
can consider recovering heat from the power plant
and from the cement production, feeding a single
ORC unit. In this way power plant fuel consumption
reduces, leading to a reduction of CO2 emissions
as well as lower costs of self-produced electricity.
Advantages of ORC
Turboden was founded in 1980 in Italy and it
is now part of Japanese company, Mitsubishi
Heavy Industries group. Today, there are currently
about 400 Turboden ORC plants, and 34 out of
those 400 are used in WHR plants. The average
availability of the operating fleet exceeds 98% and
more than 15 000 000 operating hours have been
reached.
Clients using the ORC system recognise several
advantages. Firstly, the system can operate in
fully automatic mode without risk, and there is
no requirement for supervision personnel, thus
reducing operational cost. In addition, the ORC has
flexible operation in a wide range of thermal power
loads. In fact, it can be operated very quickly and
automatically at partial loads, following the cement
plant production programme without interruption
of the electricity production, thus increasing the
power plant reliability. On this point, an important
feature is the high efficiency even at partial load.
Çimko Turkey (top) and Holcim Slovensko, The ORC needs minimal maintenance. In particular,
Slovakia (bottom) – electric power production from no partial condensation occurs at the level of the
waste heat in the cement production process. turbine. The blades are not exposed to wear or
Case studies
With regards to heat recovery from the cement
production process, there are several references
from successful projects deployed in the last
10 years. The first plant was for Italcementi,
now Heidelberg group, in Morocco. A 2 MWe
Turboden ORC unit was installed to recover
the heat from the PH. After this, Holcim group
developed two projects – one in Alesd, Romania,
with a 4 MWe ORC started up in 2012, and
a second one in Rohoznik, Slovakia, now part
of CRH group, in 2014. In Slovakia, the ORC
installed has a capacity of 5 MWe. A second
4 MWe plant in Romania was installed in 2015
in Carpat Cement (Heidelberg group). Also in
Switzerland, there are 2 WHR plants based on
Turboden ORCs. In both cases, the heat source is
hot water at a temperature lower than 200°C. The
size is smaller; 2.3 MWe in Wildegg, Jura cement, Energy-efficient
and 1.4 MWe in Holcim Eclepens. The last WHR
projects with ORC have been awarded in Turkey separation, flexible
where there are several WHR systems based on
steam turbines. Cimko, part of Sanko group, and and compact
Sonmez selected ORC because of its reliability,
high performance, lack of water consumption and With the new optimized high-performance
no need for additional personnel. Since 2019, the separators of the third generation, Intercem
ORC working in Cimko has been producing more has the appropriate product for each specific
than 6.5 MWe while the ORC under construction application.
for Sonmez will produce 7 MWe later in 2020.
A low bypass-rate ensures the highest possible
Conclusions separation grade. Robust construction, minimal
ORC technology is a proven technology in the maintenance, easy accessibility to bearings
field of cement WHR, helping to increase the and wear parts and extremely wear resistant
sustainability of cement production, thanks to its materials result in the highest wear protection
ability to recover heat even at low temperatures and are state-of-the-art.
and with good efficiency. Considering the trend
We can either exchange old separators in
towards a greener industry, adopting a broader
vision that accounts for the environmental existing plants or integrate our high-efficiency
benefits of reducing wasted energy and global separators into
CO2 emissions, and the benefits of decreasing completely new
electrical energy consumption, is a smart plants. References
decision. all over the world
prove this.
About the author
Sabrina Santarossa is Sales Manager for
And all that: Fast
ast Fair Fle
Flexible
exible
e
Industrial Heat Recovery at Turboden with
focus on projects in the cement, glass and steel
production process. Sabrina helps potential
customers to find an optimised solution for each Intercem Engineering GmbH
project. She holds a Masters degree in Chemical Intercem Installation GmbH
Engineering and has worked at Turboden since Carl-Zeiss-Straße 10 | 59302 Oelde
2008. She enjoys reading, sport, and travelling. Germany | Tel.: +49 2522 92058-0
E-Mail: info@intercem.de | www.intercem.de
On The Road
M. Rovetta, CTP Team, highlights
the benefits of waste heat recovery
systems and discusses a range of
applications.
A
modern cement kiln is already optimised to
ensure the maximum thermal efficiency and keep
specific consumptions under control; this target
is reached by reusing as much high temperature
exhaust gas from the kiln as possible, for drying raw
materials, grinding or for use in the coal mill. Sometimes
hot air is also taken from the clinker cooler (mid-air).
Despite this, the thermal energy produced in the kiln
is not completely reused; according to the specific
characteristics of the process, as well as raw materials
80
To Recovery
and fuel, part of the heat exceeds the internal needs or is
not suitable for a profitable reuse in the internal processes
(e.g. cement additives drying).
Exhaust gases and air can be released into the
atmosphere only after specific treatments through
suitable equipment in order to eliminate dust particles and
other pollutants. Nowadays, the technologies available,
especially for dust filtration, can provide cost-effective
solutions, but normally they are only applicable in
temperatures ranging between 120˚C and 230˚C, which
is lower than the temperature of exhaust gases.
Therefore, gas cooling systems must be installed before
filters; such cooling systems are also used in different
phases of cement production, such as burning and raw
grinding. In such cases, the temperature of the exhaust
gases, coming from the kiln preheater, must be reduced
at suitable values requested by the mill.
81
Spending energy to waste energy heat could also be recovered from this source by a
The most efficient and suitable gas cooling boiler installed after the air quench.
technologies for cement processing are based The conversion of such heat into electrical
on water evaporation technology (sensible heat power is the main reason that justifies the
to latent heat) or dissipation technology (air-to-air investment in a WHR system. The most
heat exchanger). In general, the first method is suitable and reliable equipment is based on the
most suitable for kiln gas (cooling tower), whereas ORC (Organic Rankine Cycle) technologies.
the second fits clinker cooler waste air. Compared with steam turbine systems, they
Electrical energy is used in the conditioning have a simpler design and lower operating costs,
tower for pumping water and in the compressed also considering the indirect costs related to the
air for the spraying system. Instead, in the air-to-air consumption of natural resources such as water
heat exchanger, electrical power is consumed not used in ORC based systems.
in the cooling air fans motors. Therefore, even However, once the heat has been transferred to
if these systems are well optimised, they all the thermal oil system, it becomes easily available
consume energy, resulting in the spending of to be distributed to all possible internal and
energy, only to waste it. external cement factory utilities.
Table 1 shows an estimation of the electrical For example, the production of sanitary water,
power required in one year for a gas cooling heating factory buildings and district heating,
system in a 5000 tpd cement factory. The are all secondary utilities which can be easily
same table also reports the expected water inserted in the thermal oil loop for useful energy
consumption. optimisation without relevant additional cost for
the customer, especially in locations with severe
Combined waste heat recovery systems environmental conditions during the winter season.
and secondary applications
The boiler technology developed by CTP can Brownfield and greenfield projects
be applied on the exhausted gas stream of the WHR systems, like those previously mentioned,
cement kiln and allows the dust build-up to be are suitable for both brown and green field
controlled, together with the possible abrasion projects; the former are in general, the most
phenomena and other factors that could affect common in the cement industry and in this case
heat exchange efficiency and operation reliability. the boilers are installed in parallel to existing gas
As shown in Figure 1, the boilers can be cooling equipment (air-to-air heat exchanger or
easily installed on the PH down comer and the cooling towers). These devices, during the normal
AQC exhaust air duct in order to work together operation of the WHR system are by-passed and
in synergy (Combined Waste Heat Recovery all the hot gas streams pass through the boiler(s).
System), transferring the available heat from the Considering the brownfield, in addition to the
waste gas to a transfer media, such as thermal oil; savings mentioned, the AQC boiler could also
if an alkali by-pass spillage system is also present, offer possible additional benefits for dust collection
efficiency in cases where one ESP is installed on
Table 1. Yearly energy and water consumption AQC waste air; in fact, due to the reduction of
estimation for gas cooling (5400 tpd.) the gas volume, existing electrostatic precipitators
could even work in better conditions.
Cooling tower
Clinker cooler A combined WHR system could be a very
air-to-air HE Water pumps Comp. air Water challenging solution in greenfield projects; in this
case, the new cement plant would be redesigned,
0.6 MWh 0.0675 MWh 0.58 MWh 165 tph including the whole electricity production system,
starting from the very beginning and avoiding the
installation of gas cooling devices.
This solution can also be evaluated for
brown field projects, in cases where existing
cooling systems need to be replaced or
refurbished due to their poor condition.
Where gas cooling systems are not installed, the
final gas temperature is controlled by dissipating
the heat through air coolers installed along the
thermal oil circuit (Figure 3).
Additional opportunities
CTP WHR systems provide opportunities to
Figure 1. Flow diagram of combined WHR. develop innovative applications for existing
New applications
The WHR system opens up technological
applications and opportunities in many
industrial processes, such as cement;
the recent commissioned installation in
Cimko Narli Cement (Turkey), with an average
monthly production in the range of 3300 MW, and
the new WHR project acquired in Sonmez Cement,
demonstate the reliability of CTP technology.
The integration and combination of such
Figure 3. Air coolers installed along the termal oil systems in the cement process could provide
circuit control the final gas temperature. additional tools for cement producers to improve
the environmental sustainability of their process,
reducing the use of natural resources and limit
emissions of greenhouse gas.
In any case, the explored new potential
possibilities provided by WHR systems, open new
horizons to possible new configurations of the
cement process, where the achievement of global
environment protection targets are given the same
weight as production targets.
85
Monitoring the rotary kiln kiln shell temperature leading to hot spots – and
The rotary kiln is the most important asset in often the need to stop the kiln. This can lead to
the cement manufacturing process, and can expensive downtime for a week or more, resulting
lead to expensive downtime if it is not effectively in a severe drop in production.
monitored.
As the kiln rotates, the clinker works its way Monitoring the kiln shell
down towards the burning zone, heating up Monitoring the exterior kiln shell temperature
as it does so. This arrangement means that is critical. The steel kiln shell is protected from
temperatures may vary considerably through the the extremely high process temperature by one
kiln, making monitoring more difficult. or two layers of refractory brickwork. If this
It is advisable that measurements are taken in brickwork fails, either by erosion or physical
the following areas: the burning zone, the kiln loss of bricks, the metal shell can be severely
shell, and the clinker cooler. Kiln rotation, high damaged, putting the kiln into expensive
temperatures and movement of the sintering downtime.
material along the kiln make thermocouples and Detecting hot spots indicative of refractory
other contact temperature sensors impractical. damage helps to avoid costly maintenance or
There are four main influences on the unplanned shutdowns. Continuous monitoring
temperature within kiln shells, as follows: along the length of the kiln provides early detection
f Increased use of alternative fuels, such as of problems, allowing for repairs to be made
waste derived fuels and agricultural biomass, before serious damage occurs.
can lead to higher wear on the refractories. Traditionally, thermocouples have been used to
f Uneven coatings. take temperature measurements along the moving
f Use of inappropriate refractories. kiln, however, these give poor coverage and are
f Larger kilns with higher mechanical tension, unreliable.
which leads to higher kiln ovality and damage A more effective technique is to use a
to the refractory lining. linescanner to map the temperature of the outer
The challenges to temperature measurement shell resulting in a high-resolution thermal image.
vary from plant to plant, however, the possible Linescanners use a single detector with
impact is the same everywhere – with rises in a scanning mirror to repeatedly scan along
the length of the kiln, giving the equivalent of
1000 pixels along the kiln. Rotation of the kiln
allows the scanner to build up an image of
the kiln shell. Using a single sensor allows for
excellent consistency of measurement when
compared to a thermal imager. Even the best
image sensors exhibit considerable pixel-to-pixel
variability, whereas the scanner uses the same
sensor for every point in the measurement. It is
important to limit the scan angle to 90° or less.
A wider angle allows the scanner to be mounted
closer to the kiln, but the surface emissivity of
the kiln decreases rapidly at high angles, and the
Near infrared borescope thermal imager for imaged spots become very elliptical, leading to
cement kilns. degraded spatial resolution. If required for longer
kilns, image processing software
can stitch the output of multiple
scanners to provide a single
display. This approach also allows
enhanced spatial resolution as it
effectively doubles the number of
pixels in each scan.
AMETEK Land’s solution for
this application is the LSP-HD 62,
a compact, highly homogenous
line scanner designed to produce
high-accuracy thermal images of
moving processes.
Installed to view the rotating kiln
with an 80˚ scan angle, it samples
Critical measurements in cement manufacture. 1000 points along a single line,
A
ll environments weaken Cemfree) could be a more sensible
concrete surfaces over time, alternative to conventional concrete
especially harsh ones, but – and help save the planet. Concrete
a recent study shows that is one of the most commonly used
low-carbon cement could provide an materials used in construction – for good
answer to improving strength and reason. It is economical, sets at ambient
durability. Concrete made using an temperature, is easy to use and it can be
ultra-low carbon cement (in this case, cast into almost any shape.
91
But in nearly every case, concrete is routinely
exposed to highly demanding environments
– whether it be through traffic or weathering,
or through contact with acidic and alkaline
chemicals – man-made or environmental – all of which
take a heavy toll on concrete surfaces.
Structures made using a conventional
cement-based concrete mix are very likely to
deteriorate prematurely. But just how prematurely?
The DB Group technical team investigated this,
and the results proved to be more surprising than
anticipated.
Concrete is made using a mix of water, fine sand
and coarse aggregates which are held together using
a binder. Ordinary Portland Cement (OPC) is the
binder commonly used in concrete. However, OPC
is susceptible to acids commonly found in harsh
environments which react with it, causing premature
failure. To help improve its durability, some concrete
suppliers replace up to 70% of the OPC with ground
granulated blast-furnace slag (GGBS).
Cemfree is an alternative to OPC. It is a proprietary
alkali-activated cementitious material (AACM) that
activates waste materials such as Ground Granulated
Figure 1. Cemfree was chosen due to its Blast-furnace Slag (GGBS) and Pulverised Fly
weather, chemical and road salt resistant Ash (PFA) to create a binder. Its different chemical
properties for the M25 Woodford Viaduct composition means that it has a naturally higher
hardstanding recently. resistance to acids found in chemically
aggressive environments.
To find out how the durability
of concrete made using Cemfree
compared with a conventional concrete
mix, DB Group recently commissioned
a 26-week laboratory-based accelerated
degradation test.
To enable the comparison, two sets
of concrete samples were prepared.
One set was based on the most
durable version of OPC used in harsh
environments – a mix of 70% GGBS,
30% OPC. The other set was made
using Cemfree low carbon cement.
Laboratory tests involved fully and
Figure 2. Effect of acid on Cemfree strength gain. partially submerging the samples for a
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total of 26 weeks in three different acids: lactic, acetic
and sulfuric. The results made for interesting reading
(Figure 2 and Table 1).
Loss of strength
The most notable difference to emerge from
the tests concerned changes in the samples’
compressive strength. Compressive strength is
a measure of the ability of the concrete to carry
loads without cracking or failing. The tests showed
that the OPC sample submerged in sulfuric acid
exhibited a 53% decrease in strength after 26
weeks, while the OPC sample submerged in lactic
and acetic acid showed a decrease in strength of
over 24% in the same time period.
By comparison, the Cemfree samples submerged
in the same acids showed an increase in
compressive strength of up to 22% over the same
test period.
Figure 3. OPC after sulphuric acid test showing Table 1 shows the results of the compressive
deterioration. strength test in detail.
Loss of mass
The tests also showed that both the samples
submerged in sulfuric acid showed signs that
material had been dissolved. However, there was
a significant difference in the amount of material
dissolved: the Cemfree sample suffered a minor
loss of 14 g of material, while the OPC sample
exhibited a much greater loss of 225 g of material.
Change in appearance
After 26 weeks, the appearance of both samples
had been affected by their submersion. However,
discolouration was worse on the OPC samples
and, significantly, mould growth was present.
These results show that the type of binder used
has an impact on the material resistance and
durability of concrete. In particular, the low carbon
Figure 4. Cemfree low-carbon cement after sulphuric cement mix showed an improved resistance
acid test, showing a lot less deterioration.
to organic acids, even gaining strength in this
environment. The tests demonstrate that concrete
made with Cemfree can provide a durable
alternative to OPC concrete.
Environmental benefits
In addition to its durability benefits, there are
major environmental benefits to using low carbon
cement such as Cemfree. Structures built using
Cemfree will have less embodied CO2 compared
to one constructed using OPC-based concrete.
That is because the production of 1 t of OPC
releases almost 1 t of CO2 into the atmosphere.
By comparison, low carbon cement is made from
waste materials and its carbon footprint is ultra-
low.
If concrete made with Cemfree was poured
Figure 5. Formwork being stripped on Cemfree wall in place of OPC concrete, in addition to being
prior to use on A14 major roadway in Cambridgeshire durable, Cemfree concrete would have up to 80%
later this year. less embodied CO2, which would be beneficial
Conclusions
Low carbon cement is becoming a viable choice for
demanding environments such as high vehicle and
foot traffic areas, tidal defenses, major roadways and
peripherals, runways, agricultural precast and other
rural applications, and industrial environments.
Cemfree has been used in various applications, Figure 6. Durability of Cemfree was key to
from Harwich’s tidal sea defense for the Environment being used for tidal sea defence in Woodbridge,
Agency to developments such as the Thames Suffolk.
Tideway project, eco-home builds in environmentally
sensitive areas, and, for the first time in this
application, Cemfree is being commercially used
on the A14 major road development by Highways
England (Figure 5).
www.cem.uk.com
SET FOR
SUCCESS
Nohman Mahmud explains the
process of cement hydration and
how to optimise concrete setting
time, workability and water demand.
96
97
Macroscopic and microscopic views cement are primarily due to calcium silicate
of cement hydration: hydrates.
Because Portland cement is a relatively
Macroscopic view complex mixture, many studies, having the
When cement/aggregates/water/any admixture aim of elucidating its hydration chemistry,
is mixed together, a fluid mix is obtained. After have been conducted on its constituent
casting in frameworks, it gradually increases in phases. For a given particle size distribution
viscosity and gains mechanical strength until and w/s ratio, tricalcium silicate or alite sets
the framework can be removed. It continues and hardens in a manner similar to that of
to harden quickly during the first 28 days after a typical Portland cement. Using XRD and
mixing. During its whole life service, several other methods, it may be shown that about
reactions happen, depending both on 70% of the C3S typically reacts in 28 days
interactions between internal cement/concrete and virtually all of it reacts within 1 year. The
compounds and on interactions with external products are calcium hydroxide (CH) and a
factors (eg. carbonation, degradation). nearly amorphous calcium silicate hydrate with
the properties of a rigid gel. C2S behaves
Microscopic view similarly, but much less CH is formed and the
When cement, aggregates and water are reaction is slower, with about 30% typically
mixed together, the chemical compounds reacting in 28 days and 90% in 1 year. In both
present in cement dissolve and release cases, reaction rates depend on particle size
ions that combine in different chemical distribution and other factors. Development of
compounds (hydration products). The compressive strength runs roughly parallel to
cement/aggregates/water mix is progressively the course of the chemical reactions, and the
converted to a mix of solid substances that strengths at 1 year are comparable to those of
bind the aggregates together. Portland cements of the same w/s ratio, cured
under the same conditions.
The chemistry of cement hydration This precipitation and growth of hydrates
In hydration, the first step is phase dissolution follows the dissolution of phases; the two
(like C3S, C2S, C3A, Gypsum, C4AF) processes are strictly linked, from both
and this dissolution results in ions. Once thermodynamic (which types of phase
the ions are in water, the reaction starts dissolve and which types are produced) and
and precipitation of different hydrates like kinetic (how quickly this happens) points
aluminate hydrates, calcium silicate hydrates of view. According to recent theories, the
(CSH – also known as tobermorite gel), driving force for dissolution and precipitation
and calcium hydroxide (CH) (also known as is always related to ions in solution and
portlandite) results in hardening and strength super/undersaturation conditions. When there
gain along with an increase in viscosity. is undersaturation, the dissolution rate will be
Hydrated Portland cement contains 15 – 25% faster and precipitation rate will be low. When
calcium hydroxide (CH) and about 50% there is super saturation, the dissolution rate
calcium silicate hydrates (CSH) by mass. The will be slow and the precipitation rate will be
strength and other properties of hydrated higher. The most common hydrated phases are
CSH (calcium silicate hydrates),
CAH (calcium aluminate
hydrates), calcium hydroxide
(CH) and ettrignite (tricalcium
sulfo aluminate hydrate), etc.
The dissolution of phases
to give ions is the plastic mix
stage, whereas precipitation
of hydrates (CSH, CH, CAH,
ettrignite) is the hardened mix
stage.
For complete hydration
of Portland cement, only
about 40% water by mass
(a water-to-cement ratio of 0.40)
Figure 1. Heat evolution as a function of time for cement paste. is needed. If a water-to-cement
Stage 1 is heat of wetting or initial hydrolysis. Stage 2 is a ratio greater than about 0.40
dormant period also known as an induction period. Stage 3 is a is used, the excess water not
slow, steady hydration. needed for cement hydration
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remains in the capillary pores or evaporates. temperature rise in mass concrete. When heat
If a water-to-cement ratio less than about generation must be minimised in concrete,
0.40 is used, some cement will remain designers should choose a lower heat
unhydrated. The amount of water added to the cement, such as a type II Portland cement,
mixture controls the strength and durability as with the optional moderate heat of hydration
well. The space initially taken by water in a requirements.
cementitious mixture is partially or completely It may be noted that initial setting time is
replaced over the period of time as the observed approximately, together with the end
hydration reaction proceeds. of the induction period on the heat evolution
In order to make the fresh concrete curve and the final set takes place in the
sufficiently workable for proper placing and middle of the acceleration period.
compaction, slightly more water than is
required for complete hydration of the cement Workability of concrete/consistency of
may be used in the concrete mix. However, cement
too large an excess must be avoided since ‘Workability’ can be defined as the ease
ultimate strength is inversely related to the by which fresh concrete can be mixed,
overall water/cement ratio. An external supply transported, placed, compacted and used
of water must remain available to the cement without segregation of its components.
after setting and during the initial hardening Cement ‘consistency’ refers to the relative
period if the full potential of the cement is to mobility of freshly mixed cement paste or
be realised, since the hydration reaction stops mortar. The water demand of a cement
when relative humidities fall below about 95%. is the amount of water required to form a
As the water-to-cement ratio increases, the paste of standard consistence. The fluidity
capillary porosity increases and the strength of a cement paste may be measured; the
decreases. Transport properties such as smaller the water demand, the greater the
permeability and diffusivity are also increased, fluidity for a given water/cement ratio. During
allowing detrimental chemicals to more readily cement testing, pastes are mixed to normal
attack the concrete or reinforcing steel. consistency as defined by penetration with
a Vicat Needle. Mortars are mixed to obtain
Studying cement hydration behaviour either a fixed water to cement ratio (Vicat
Cement hydration behaviour can also be apparatus) or yield a flow within a prescribed
studied using ‘heat of hydration’ testing. range (flow table). Both the normal consistency
Cements do not generate heat at a constant method and flow table method are used to
rate. The heat output during hydration of a regulate and check the optimum required water
typical type I Portland cement is illustrated contents of pastes and mortars. Whereas the
in Figure 1. The first peak shown in the tests most commonly used for determining
heat profile is due to heat given off by the the workability of concrete, known as a
initial hydration reactions of cement phases ‘slump cone test’, ‘compaction factor tests’ and
such as tricalcium aluminate. Sometimes ‘VEE – BEE consistometer tests’, are also used
called the ‘heat of wetting’, this first heat to determine concrete workability.
peak is followed by a period of slow activity Different factors affect the water demand or
known as the induction period. After several standard consistency of cement; in short, the
hours, a broad second heat peak attributed higher the reactivity of clinker/cement, the more
to tricalcium silicate hydration emerges, water required to form a paste of standard
signalling the onset of the paste hardening consistency.
process. Finally, there is the third peak due to
the renewed activity of tricalcium aluminate. Its Setting time
intensity and location is normally dependent on The object of setting time is to determine,
the amount of tricalcium aluminate and sulfate firstly, the time that elapses from the moment
in the cement. water is added until the paste ceases to be
In calorimetry testing, the first heat fluid and plastic (initial setting), and secondly,
measurements are obtained a few minutes the time required for the paste to acquire a
after mixing the paste. As a result, only the certain degree of hardness (final setting).
downward slope of the first peak is observed Initial setting must not occur too early and
(Figure 1). The second peak (C3S peak) final setting must not occur too late. The
often occurs between 6 and 12 hours. rationale for this is that the initial setting time
The third peak (renewed C3A peak on should be sufficient to provide appropriate
conversion of ettringite to monosulfate) occurs time for the preparation, mixing, transportation,
between 12 and 90 hours. This information and placing of concrete mix. The final setting
can be helpful when trying to control time should not occur too late, as the concrete
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Properties of reactive
clinker/cement
Reactive clinker/cement can be
summarised as having following
properties:
f High blaine, less residues
(90/45 Micron, etc.)
f High C3A
f Orthorhombic C3A – due to
incorporation of alkalis
f High C3S
f Less sulfate
f Different forms of gypsum with regard 223 W. Interstate Road, Addison, IL 60101 USA
to setting behaviour are as under: www.Magneco-Metrel.com
» Natural di-hydrate gypsum –
normal release of sulfate ions.
» Hemihydrate (plaster of paris) and
soluble anhydrite – quick release
of sulfate ions.
» Natural anhydrite gypsum – very
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slow release of sulfate ions.
Conclusion
Normal hydration reactions are required
to ensure that cement/concrete properties
remain within the acceptable limits as far
as workability, setting time, water demand
and strength development/hardening are
concerned. A thorough understanding
of clinker/cement properties is required
to avoid excessive water demand, false
setting and flash setting, and to have
normal setting, strength development and
workability characteristics.