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Journal of Food Engineering 62 (2004) 417–423

www.elsevier.com/locate/jfoodeng

A fracture mechanics analysis of the texture of fried potato crust


Kelly A. Ross 1, Martin G. Scanlon *

Department of Food Science, The University of Manitoba, Winnipeg, Manitoba R3T 2N2, Canada
Received 4 October 2002; received in revised form 12 June 2003; accepted 24 June 2003

Abstract
Texture is critical to french fry quality. Because french fries possess a composite structure, textural optimization during pro-
cessing must focus on adjusting the texture of both the interior and the crust. The aim of this work was to investigate the effect of fry
time on the mechanical properties of the fried potato crust. Slabs of processed potatoes were fried for varying lengths of time,
frozen, and thawed. Fracture stress, fracture strain, elastic modulus, and fracture toughness values were obtained from excised crust
specimens using a tensile test. Generally, elastic modulus increased as fry time increased while fracture strain and fracture toughness
decreased. Fracture stress and elastic modulus were in the range of 100 kN m2 and 2 MN m2 , respectively, while fracture strain
was low for a food material (2–7% strain). Two techniques were used to measure fracture toughness: a brittle fracture technique and
Andrews’ generalized fracture mechanics approach. Fracture toughness measured by the former technique was of the order of 10
J m2 . As length of fry time increased the crust material changed from a ductile or pliant material to a more brittle material, in line
with reported sensory studies on the development of crispness during frying.
Ó 2003 Elsevier Ltd. All rights reserved.

Keywords: Mechanical properties; French fries; Potato processing; Elastic modulus; Texture; Frying; Fracture

1. Introduction the emergence of a market for coated french fry products


(Friedman, Shinsato, & Kerfin, 1999).
The potato is the world’s root and tuber crop grown in The method of french fry texture evaluation is sen-
the greatest quantities (FAO, 1999). Recent trends in the sory analyses, usually performed by experienced indus-
worldwide consumption of potatoes show that frozen try personnel. However, sensory evaluation of a finished
french fries have contributed to enormous expansion of product is labour intensive, and is considered by food
international trade in this commodity (a 16-fold increase processors to be an inefficient means of texture evalua-
between 1980 and 2001 (FAO, 2003)), and much of tion for quality assurance purposes (Finney, 1969;
Canada’s export production is being increasingly centred Kamyab, Chakrabarti, & Williams, 1998; Ross & Por-
in Manitoba. In Manitoba, french fry production con- ter, 1969). In contrast, Mohsenin (1970) has advocated
sumes nearly 80% of all potatoes grown in the province, objective fundamental engineering definitions of the
and, in 2001, they contributed $128 in export revenue for mechanical attributes associated with texture in food
every individual in the province (Manitoba Agriculture, products. These fundamental mechanical parameters
2003). In spite of their economic importance, the potato include fracture stress and strain, yield stress, elastic
processing industry has had difficulty in evaluating and modulus, Poisson’s ratio, coefficient of friction and
controlling one of the french fry’s most important fracture toughness; Kamyab et al. (1998) particularly
quality attributes––fry texture (Ross & Porter, 1971; emphasised toughness evaluations, although viscoelastic
Singh, 2000). Fundamental characterizations of fry tex- parameters (Krokida, Oreopoulou, Maroulis, & Mari-
ture and crust properties are additionally motivated by nos-Kouris, 2001; Lima & Singh, 2001b) are also of use
for food material characterization.
*
With regards to fracture toughness, a generalized
Corresponding author. Tel.: +1-204-474-6480; fax: +1-204-474- theory of fracture mechanics (Andrews, 1974) permits
7630.
E-mail address: scanlon@cc.umanitoba.ca (M.G. Scanlon).
measurement of fracture properties without the limiting
1
Present address: Department of Agricultural and Biological assumptions of linearity, elasticity and infinitesimal
Engineering, Purdue University, West Lafayette, IN 47907-2093, USA. strain (Holt & Schoorl, 1983): desirable attributes when
0260-8774/$ - see front matter Ó 2003 Elsevier Ltd. All rights reserved.
doi:10.1016/S0260-8774(03)00274-7
418 K.A. Ross, M.G. Scanlon / Journal of Food Engineering 62 (2004) 417–423

Nomenclature

c crack (notch) length (mm) rf fracture stress (strength) (kN m2 )


E elastic modulus (MN m2 ) TB strain energy release rate (brittle fracture
0 strain, measured at points remote from the toughness) (J m2 )
crack TG apparent critical energy release rate (gener-
Fc=w function relating crack length to specimen alized fracture toughness) (J m2 )
width (geometric correction factor) w specimen width (mm)
k1 dimensionless function of strain (or input W0 input energy density associated with un-
energy density) cracked specimen (J m3 )
Kc stress intensity factor in the critical case W0c input energy density when crack propagation
(MN m3=2 ) occurs (J m3 )
v Poisson’s ratio
r0 stress, measured at points remote from the
crack (kN m2 )

determining the fracture properties of food materials, a commercial crop grown on a site near Carberry,
since considerable inelastic deformation can occur dur- Manitoba. Potatoes delivered from commercial storage
ing fracture development (Fahloul & Scanlon, 1996). in January 1997 were stored at the Horticultural Storage
The applicability of the generalized theory of fracture Research facility at the University of Manitoba. The
mechanics to characterize failure in biological materials potatoes were held at 8  1 °C and at a minimum rela-
has been demonstrated (Fahloul & Scanlon, 1996; Holt tive humidity of 90% until used for processing. Potato
& Schoorl, 1983; Scanlon, Sapirstein, & Fahloul, 2000). processing was performed in May 1997 so that the total
Other researchers have used Gurney’s work area method average storage time of the raw potatoes prior to pro-
(Gurney & Hunt, 1967) to characterize fracture in bio- cessing was seven months.
logical materials (Dobraszczyk, 1994; Dobraszczyk,
Atkins, Jeronimidis, & Purslow, 1987; Purslow, 1985).
Gurney’s work area method makes the assumption that
2.2. Potato processing
any inelastic deformation associated with fracture is
confined to a small region contiguous with new crack
All tubers were removed from storage just prior to
surface area. It discounts global energy losses, which are
processing and were randomly assigned into one of five
included in the generalized fracture mechanics analysis
groups processed according to fry times of 1, 2, 4, 7 or
method. Linear elastic fracture mechanics techniques
10 min. Slices (slabs) of thickness 1 cm were sliced
(Williams, 1984) have also been used to study fracture in
lengthwise off potatoes from the stem end to the bud
biological specimens (Lucas, Choong, Tan, Turner, &
end. These potato slabs were processed according to
Berrick, 1991; Vincent, 1982). In this case, only linear
procedures followed in the commercial potato process-
elastic deformations are assumed to operate.
ing industry as described by Agblor and Scanlon (2000).
This study was an investigation of the fracture
Immediately after blanching and drying the potato slabs
properties of the crust of fried potato. As stated by Lima
were placed in a wire frying basket and fried for the
and Singh (2001a), there is a paucity of information on
specified length of time in a thermostat-controlled deep
the mechanical properties of this component of a very
fat fryer (Garland Model 80-03, Mississauga, ON) set at
popular processed food. Well defined measurements of
185  2 °C. The frying oil was hydrogenated canola oil
mechanical properties are especially important for en-
with the trade name of Crisco Professional Frying Oil
gineering modelling of the effect of given unit operations
(Procter and Gamble, Toronto, ON). The fried potato
on the texture of individual regions of the fry (Farkas,
slabs were placed on a metal tray in a single layer and
Singh, & Rumsey, 1996; Pedreschi, Aguilera, & Pyle,
frozen. For freezing, the trays were placed in a walk-in
2001; Scanlon & Ross, 2000).
air freezer (Model WTD, Coldstream Refrigerator Mfg.
Ltd, Winnipeg, MB) at )20 °C. The freezer temperature
2. Materials and methods was set and maintained at )20 °C although temperature
fluctuations (if they occurred) were not recorded. The
2.1. Potatoes fried potato slabs were placed close to a fan to simulate
conditions in a blast freezer (Agblor & Scanlon, 1998)
Potatoes of the cultivar Russet Burbank were used as and frozen overnight before being transferred to pre-
the experimental material. The crop was obtained from labelled ziploc freezer bags and stored at )20 °C. All
K.A. Ross, M.G. Scanlon / Journal of Food Engineering 62 (2004) 417–423 419

testing of mechanical properties took place within a the effect of gluing orientation by gluing the specimens
week of freezing. to the grips with either the core or the crust side. This
was performed in a completely random order and the
2.3. Crust removal data recorded from the load–displacement curves (not
presented in this paper) indicated that gluing orientation
The crusts of the potato slabs were removed by slicing had no effect.
the frozen potato slabs with a Hobart slicer (Model 410, The experimental plan for generating the load–dis-
Hobart Manufacturing Co., Cincinnati, OH). Crusts placement curves for this study was that each fry time
were removed from the frozen potato slabs for two with a specific crack length was to be replicated five
reasons. The first reason was a practical one––slicing the times in completely random order. However, some
frozen potato slabs facilitated the procurement of crusts specimens tore at the grips. The data from these defec-
with less potato core adhering to them. The second tive trials were discarded, and the same fry time/crack
reason was that this helped eliminate moisture migration length combination was retested. Therefore, more than
from core to crust. Each batch of potato slabs fried for a 125 load–displacement curves were generated yet the
certain fry time had a different crust thickness. The slicer data in this study were obtained from 125 load–dis-
was calibrated for each fry time by initial trial and error placement curves (i.e., data from the samples that did
experiments in order to cut off a crust slice from the slab not tear at the grips).
with a minimum of inner core adhering to the crust.
Crust slices were placed on paper towels and stored in
plastic freezer bags to prevent moisture loss. Crust slices
3. Results and discussion
were allowed to thaw for 10 min before being tested.
3.1. Mechanical response of the fried potato crust
2.4. Crust specimen preparation
The original load–displacement curves were con-
Specimens (length of 80 mm and width of 10 mm) verted into engineering stress (r0 )–strain (0 ) curves.
were excised from the crust slices so as to prevent in- Both stress and strain were measured from points re-
corporation of the pith in the specimen. The dimensions mote from the experimentally imposed crack, indicated
were such that they complied with those recommended by the 0 subscript. The mechanical parameters of frac-
by ASTM-E8-93 (ASTM, 1993). Specimen thickness ture stress, fracture strain and elastic modulus were
was dependent upon fry time, and was measured with a obtained from the individual stress–strain curves for
set of digital calipers. For some specimens, single not- each potato crust fried for varying times with no ex-
ches (i.e., cracks) were cut into one side of the specimen perimental cracks (i.e., c ¼ 0). The fracture stress and
(as shown in Fahloul & Scanlon, 1996). Notch lengths fracture strain values were taken from the point on each
were 0, 2, 4, 6 or 8 mm. of the stress–strains curve where fracture was observed
to occur. For fry times of 4 min or longer, the generation
2.5. Mechanical testing of a brittle fracture meant that the load declined pre-
cipitously. The elastic modulus values were obtained
Fried crust specimens were tested in tension on a from the initial linear elastic region of each of the stress–
Lloyd L1000 universal testing machine equipped with a strain curves. For some curves, an initial compliance
20N load cell (Lloyd Instruments Ltd, Fareham, En- was apparent, and so the modulus was obtained on
gland). A crosshead speed of 1 mm min1 was used for average in the 1–4% strain level. Values for the me-
testing. All testing was performed at room temperature. chanical properties are shown in Table 1, as well as crust
The specimens were attached to aluminum grips with thicknesses. Although it is not possible to directly
cyanoacrylate adhesive (Viachem, St. Laurent, PQ) and compare values with those of other researchers (because
allowed to set for 1 min before testing was performed. of different specimen preparation techniques and dif-
Preliminary experiments were performed to determine ferent testing methods), trends of increasing modulus

Table 1
Effect of frying time on the mechanical properties of the crust of processed and fried potato (means  standard deviation)
Fry time (min) Crust thickness (mm) Elastic modulus (MN m2 ) Fracture stress (kN m2 ) Fracture strain
1 0.69  0.03 1.61  0.97 96.7  13.3 0.069  0.011
2 0.79  0.23 2.05  0.30 98.3  21.6 0.049  0.010
4 1.21  0.11 1.75  0.30 80.9  5.8 0.051  0.006
7 1.48  0.43 2.69  1.60 79.6  33.9 0.033  0.006
10 1.98  0.27 3.72  1.05 92.3  21.2 0.026  0.006
420 K.A. Ross, M.G. Scanlon / Journal of Food Engineering 62 (2004) 417–423

with increase in fry time concur with studies of Lima


and Singh (2001a, 2001b), and an increase in fracture
strength with fry time for the crust fried for the longer
times concurs with the studies of Lima and Singh
(2001a), Pedreschi et al. (2001) and Pinthus, Weinberg,
and Saguy (1995b). The growth of crust thickness with
frying time is corroborated by the work of Du Pont,
Kirby, and Smith (1992) and that of Rice and Gamble
(1989). In the latter study it was stated that the growth
of the crust corresponds to a major increase in oil con-
tent resulting from increased exposure to the frying
medium. The concomitant dessication of the cellular
assembly within the crust (Aguilera, Cadoche, L opez, &
Gutierrez, 2001) would be expected to cause the
observed stiffening of the crust.

3.2. Fracture toughness of french fry crust

The mean stress–strain curves for the specimens


containing cracks of different lengths for the extremes of
fry times are shown in Fig. 1 to illustrate how crust
specimen compliance increased as cracks of increasing
length were cut into the specimens, as has been observed
for fresh potato tuber tissue (Fahloul & Scanlon, 1996).
Error bars for the c ¼ 0 curve at various strain incre-
ments have been calculated with a 95% confidence in-
terval (n ¼ 5); the error bars for curves with cracks in
them were considerably smaller. It should be noted that
each curve was terminated when the crack was observed
to propagate.
The fracture toughness of the crusts were evaluated
using two different techniques––the generalized fracture Fig. 1. Mean (n ¼ 5) stress–strain curves for processed and fried potato
mechanics theory (Andrews, 1974), which takes into crusts of (A) 1 min fry time, and (B) 10 min fry time, in which cracks
(c) of various lengths were cut into the specimens. Error bars for c ¼ 0
account all non-elastic work expended to propagate a
curves indicate 95% confidence intervals.
crack in the crust specimen, and a technique which as-
sumes that brittle fracture has occurred (Williams,
1984). The linear nature of the stress–strain curves in
Fig. 1, and the brittle behaviour of french fry crust at- propagation occurs (Andrews & Bhatty, 1982; Fahloul
tests to the validity of using the latter approach in ad- & Scanlon, 1996). Just as Fahloul and Scanlon (1996)
dition to the generalized fracture mechanics approach determined the function k1 as a function of the input
which is appropriate for biological materials (Andrews, energy density (W0 ) from the mean stress–strain curves,
1980; Holt & Schoorl, 1983). k1 was determined in the same manner for this study
(Ross, 1999).
3.2.1. Generalized fracture mechanics theory After determining k1 ðW0 Þ, the critical energy release
The generalized fracture mechanics theory (Andrews, rate for the crusts of each of the fry times was evaluated
1974) gives the following equation for fracture propa- from a rearrangement of Eq. (2) to plot k1 ðW0 ÞW0c versus
gation from an edge crack in a tensile specimen: c1 . A plot of k1 ðW0 ÞW0c against c1 will give a straight
line with a slope equal to the apparent critical energy
TG ¼ k1 ð0 ÞcW0c ð1Þ release rate (TG ) providing the critical energy release rate
or alternatively: is constant and independent of c and W0 (Andrews &
Bhatty, 1982). Such a plot is shown in Fig. 2 for the
TG ¼ k1 ðW0 ÞcW0c ð2Þ
three longer fry times (the ordinate values for the 1 and
The input energy density is associated with the un- 2 min fry times were much larger, r2 ¼ 0:95 and 0.99,
cracked specimen. Upon evaluation of k1 , the apparent respectively). The generalized fracture toughness values
critical energy release rate (generalized fracture tough- of the fried potato crusts determined in this way are
ness) may be obtained from the value, W0c , where crack given in the second column of Table 2.
K.A. Ross, M.G. Scanlon / Journal of Food Engineering 62 (2004) 417–423 421

Fig. 2. Evaluation of the apparent critical energy release rate (gener- Fig. 3. Evaluation of the critical stress intensity factor for processed
alized fracture toughness) for processed and fried potato crusts of three and fried potato crusts of 2 and 7 min fry time from plots of the square
fry times from slopes of k1 ðW0 ÞW0c plotted against the reciprocal of of crust strength against a function of the reciprocal of crack length (c).
crack length (c). Error bars represent 95% confidence intervals.

Table 2
in Fig. 3 for crusts of 2 and 7 min fry time; r2 values
Comparison of the fracture toughness of processed and fried potato
crust using different methods of evaluation for all fry times ranged from 0.59 to 0.997.
In order to determine the fracture toughness values
Fry time (min) Fracture toughness (J m2 )
from the critical stress intensity factors obtained from
Generalized fracture Brittle fracture these plots, a value for Poisson’s ratio is needed (Wil-
1 39.3 13.2 liams, 1984). Attempts to measure this on the 2 min fried
2 50.0 12.8 crust specimens were unsuccessful (experimental error
4 29.3 10.2 large, value of 0.55 obtained). To obtain a qualitative
7 35.3 6.5
10 21.3 6.1 estimate of Poisson’s ratio, microscopic examination of
the fry crust specimens was performed for specimens of
the 1, 2, and 7 min fry times. The hexagonal micro-
3.2.2. Assumption of brittle fracture structure of the cells in the crust was very similar to the
The fracture toughness for a linear elastic material is microstructure of cork cells taken perpendicular to the
given by the following equation, assuming that the state radial direction (Ross, 1999). Compression or tension of
of strain at the crack tip is that of plane strain: cork specimens taken from the non-radial direction gave
a Poisson’s ratio of 0.5 (Gibson, Easterling, & Ashby,
TB ¼ Kc2 ð1  v2 Þ=E ð3Þ 1981). It was therefore postulated that the Poisson’s
The stress intensity factor in the critical case, i.e., where ratio of the fried potato crust specimens, when subjec-
the crack propagates in a specimen of given crack length ted to tension, as in these experiments, would be 0.5.
can be related to the strength (or fracture stress) of the Since the elastic moduli and the critical stress inten-
fried crust by: sity factors of the fried potato crusts were experimen-
tally obtained, and the Poisson’s ratio was qualitatively
r2f ¼ Kc2 ð1=½cFc=w
2
Þ ð4Þ evaluated, the fracture toughness values could be ob-
tained from Eq. (3) (third column of Table 2). The
where Fc=w is a function relating crack length to the
fracture toughness values determined by both methods
width of the specimen (Vincent, 1982). This geometric
generally show similar trends: as fry time increased, the
correction factor for a single-edged notch in the speci-
fracture toughness decreased. It has been noted that at
men is given by (Hashemi & Williams, 1984):
longer frying times, more dehydration of the crust re-
Fc=w ¼ 1:99  0:41ðc=wÞ þ 18:7ðc=wÞ2  38:48ðc=wÞ3 gion occurs (Costa, Oliveira, Delaney, & Gekas, 1999;
4 Saguy & Pinthus, 1995), while its porosity increases
þ 53:85ðc=wÞ ð5Þ
(Pinthus, Weinberg, & Saguy, 1995a). Both these factors
By plotting the square of the fracture stress against the will decrease the energy required for fracture (Do-
product of the reciprocals of crack length and the geo- braszczyk, 1994). Interestingly, the brittle fracture ap-
metric correction factor squared, a straight line is gene- proach yielded fracture toughness values that were
rated of slope Kc2 (Vincent, 1982). These plots are shown about 2–5 times lower than those from the generalized
422 K.A. Ross, M.G. Scanlon / Journal of Food Engineering 62 (2004) 417–423

fracture mechanics approach. This indicated that the ASTM (1993). Standard test methods for tension testing of metallic
fried potato crust was not completely brittle and that materials. Annual book of ASTM standards (ASTM-E8-93, Vol.
03.01, pp. 130–149). Philadelphia: American Society for Testing
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Engineering Research Council of Canada (NSERC) for Holt, J. E., & Schoorl, D. (1983). Fracture in potatoes and apples.
funding this work, to the Association of Universities Journal of Materials Science, 18, 2017–2028.
and Colleges of Canada for an Agriculture and Agri- Kamyab, I., Chakrabarti, S., & Williams, J. G. (1998). Cutting cheese
with wire. Journal of Materials Science, 33, 2763–2770.
Food Canada scholarship, and to the Canadian Dairy
Krokida, M. K., Oreopoulou, V., Maroulis, Z. B., & Marinos-Kouris,
and Food Industries Supply Association for a Fred D. (2001). Viscoelastic behaviour of potato strips during deep fat
Thompson Scholarship award. We also thank Midwest frying. Journal of Food Engineering, 48, 213–218.
Food Products Inc. for supplying us with commercially Lima, I., & Singh, R. P. (2001a). Mechanical properties of a fried crust.
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