19-07-2020

Brilliant
STUDY CENTRE
Batch: IIT- 2021
REPEATERS JEE MAIN EXAMINATION
Puliyannoor P.O., PALA
Ph - 04822 206416, 206516, 206459 PHYSICS + CHEMISTRY
www.brilliantpala.org

PHYSICS-Modern Physics
Section I - Straight objective type (4, -1)

1. If the intensity of light in a photoelectric effect experiment is doubled, then the stopping potential will

1) be doubled 2) halved

3) becomes more than doubled 4) remains unchanged

2. Let K1 be the maximum kinetic energy of photo electrons emitted by a light of wavelength 1 and K 2 .
Corresponding to  2 . If 1  22 then

K2
1) 2K1=K2 2) K1=2K2 3) K1  4) K1  2K 2
2

3. By increasing the intensity of light keeping frequency constant, their

1) Kinetic energy of photoelectron increases

2) Number of emitted electron increases

3) Kinetic energy and number of electron increases

4) No effect

4. A proton and electron are accelerated by same potential difference, having de broglie wavelength  p and  e .
Then

1)  e   p 2)  e   p 3)  e   p 4) None

5. The radius of the bohr’s first orbit is a0. Then the electron in the nth orbit has a radius

a0 a0
1) na0 2) 3) n 2a 0 4)
n n2

6. When a hydrogen atom initially at rest emits a photon resulting in transition n = 5 to n=1, then its recoil
speed is about,

1) 10–4m/s 2) 2×10–2m/s 3) 4.2m/s 4) 3.8×10–2m/s

7. The wavelength of the K  line for an element of atomic number 57 is  . What is the wavelength of the
K  line for the element. Whose atomic number 29 (take b=1).

1)  2) 2  3) 4  4) 8 

8. Consider the spectral line resulting from the transition n=2 to n=1. In the atoms and ions given below. Then
the shortest wavelength is produced by

1) Hydrogen atom 2) Deuterium atom 3) Singly ionized helium 4) doubly ionized lithium
FT21G/TP/JEE MAIN/P+C 2 Brilliant STUDY CENTRE
9. The equation represents

411 H  42 He2  2e1  26MeV

1)  -decay 2)  -decay 3) fusion 4) fission

10. The maximum kinetic energy of photoelectrons emitted from a surface when photons of energy 6eV fall on
it is 4eV. Then the stopping potential in volts will be

1) 2 2) 4 3) 6 4) 10

11. A particle of mass M at rest decays into two particles of masses m1 and m2 having non zero velocities. The
ratio of de broglie wavelength of the particles

1) m1/m2 2) m2/m1 3) 1 4) None

12. Two radio active materials x1 and x2 have decay constants 10 and 1 respectively. If initially they have the
same number of nuclei, then the ratio of number of nuclei of x1 to that of x2 will be 1 e after a time of

1 1 11 1
1) 2) 3) 4)
101 111 101 9

13. A proton has kinetic energy E. Which is equal to that of the photon. The wavelength of the photon is  2
2
and that of proton is 1 . Then the ratio  is
1

1 1
1) E2 2) E 2 3) E–1 4) E  2

14. K  wavelength emitted by an atom of atomic number z=11 is  . Find the atomic number for an atom that
emits K  radiation with wavelength 4 

1) z=6 2) z=4 3) z=11 4) z=44

15. The ratio of longest and shortest wavelength of the Lyman series is approximately

4 9 9 16
1) 2) 3) 4)
3 4 5 7

16. As the mass number A increases, which of the following quantities related to the nucleus do not change

1) Mass 2) Volume

3) Density 4) Binding energy

17. The main source of solar energy is

1) Nuclear fission

2) Nuclear fusion

3) Gravitational contraction

4) Combustion
FT21G/TP/JEE MAIN/P+C 3 Brilliant STUDY CENTRE

18. The activity of a sample of radio active material is A1 at t1 and A2 at time t2.(t2>t1). Its mean life is T, then

A A
2) t  t  const
1 2
1) A1t1  A 2 t 2
2 1

 t1  t 2   t 
3) A 2  A1e  4) A 2  A1e  t T 
1

 T   2 

19. Two radio active substances x and y initially contain equally number of nuclei. X has a half life of 1hour and
y has a half life of 2 hour. After 2 hours ratio of activity of x to that of y is

1) 1:4 2) 1:2 3) 1:1 4) 2:1

20. A radio active nuclei can decay simultaneously by two different processes. Which have decay constants
1 and  2 . Then effective decay constant of the nuclei will be

1)   1   2 2)    1   2  / 2

1 1 1
3)      4)   1 2
1 2

Section 2 - Numerical type (4,0)

[The answer to each question is a NUMERICAL VALUE. Each question carries +4 marks for
correct answer and 0 mark for wrong answer. Answer is the integer lies between 0 to 9.

21. The percentage of original quantity of radio active material left after 5 half lives is approximately is

22. The wavelength of the first line of the Balmer, series of hydrogen atom is  . The wavelength of the

corresponding line of doubly ionize lithium atom is , then n is
n

23. The ionization potential of ‘a’ hydrogen atom is –13.6eV. An electron in the ground state of hydrogen atom
absorbs a photon of energy 12.75eV. How many different spectral line can one expect when the electron
makes a downward transition.

24. Suppose a 226

88 Ra nucleus at rest and in ground state undergoes  decay to 222
86 Rn nucleus in its excited
state. The kinetic energy of the emitted  particle is found to be 4.44 MeV. 222
86 Rn
nucleus then goes to the
270
ground state by  decay. Then the energy of emitted  -photon is KeV , then x = _____
x

(atomic mass of 226

88 Ra  226.005 U
, atomic mass 222
86 Rn
=222.000U, atomic mass of  particle = 4.000U)

1
25. The half life of 215 At is 100 s . The time taken for the radio activity of a sample of 215At to decay to of
16th
its initial value is 100x sec , then x will be
FT21G/TP/JEE MAIN/P+C 4 Brilliant STUDY CENTRE
CHEMISTRY-States of matter
Section 1 - Only one correct option type (4, –1)

26. An open vessel containing air is heated from 300 K to 400 K. The fraction of air originally present which
goes out of it is :

3 1 2 1
1) 2) 3) 4)
4 4 3 8

27. If air contains N2 and O2 in volume ratio 4 : 1. The average vapour density of air is:

1) 14.5 2) 16.5 3) 14.4 4) 29.0

28. Which of the following gases would have the highest rms speed at 00C?

1) O3 2) CO2 3) SO3 4) CO

29. If volume of a given mass of gas at constant T, becomes three times, the pressure will be:

1) 3P 2) P/3 3) 9P 4) P

30. A 2.24 litre cylinder containing O2 gas at 270C and 2 atm is found to develop a leakage. When the leakage
was repaired, the pressure dropped to 100 cm of Hg at 270C. The number of mole gas escaped out during
leakage is;

1) 0.06 2) 0.05 3) 0.07 4) 0.08

31. 2 g of hydrogen diffuses from a container in 10 minute. How many gram of oxygen would diffused through
the same container in the same time under similar conditions?

1) 5 g 2) 4 g 3) 6 g 4) 8 g

32. 32 g of oxygen and 3 g of hydrogen are mixed and kept in a vessel of 760 mm pressure and 00C. The total
volume occupied by the mixture will be nearly.

1) 22.4 litre 2) 33.6 litre 3) 56 litre 4) 44.8 litre

33. For a given mass of a gas, if pressure is reduced to half and temperature is increased two times, then the
volume would become:

1) V/4 2) 2V2 3) 6V 4) 4V

34. Air contains 79% N2 and 21% of O2 by volume. If the barometric pressure is 750 mm Hg the partial
pressure of oxygen is:

1) 157.5 mm of Hg 2) 175.5 mm of Hg 3) 315.0 mm of Hg 4) None of these

35. Total kinetic energy of one mole of an ideal gas (monoatomic) at 270C is:

1) 600 cal 2) 900 cal 3) 800 cal 4) 300 cal

36. Which set of conditions represents easiest way to liquefy a gas?

1) Low temperature and high pressure 2) High temperature and low pressure

3) Low temperature and high pressure 4) High temperature and high pressure
FT21G/TP/JEE MAIN/P+C 5 Brilliant STUDY CENTRE
37. For a real gas, deviations from ideal gas behaviour are maximum at:

1) -100C and 5.0 atm 2) -100C and 2.0 atm

3) 00C and 1.0 atm 4) 1000C and 2.0 atm

38. The rates of diffusion of SO2, CO2, PCl3 and SO3 are in the following order:

1) PCl3  SO 3  SO 2  CO 2 2) CO 2  SO 2  PCl3  SO3

3) SO 2  SO3  PCl3  CO 2 4) CO 2  SO 2  SO 3  PCl3

39. The cooling caused by the adiabatic expansion of a compressed gas below its inversion temperature (Ti)
without doing external work is called:

1) Joule - Thomson effect 2) Adiabatic demagnetism

3) Tyndall effect 4) Compton effect

40. The inversion temperature (Ti) for a gas is given by:

a 2a Rb 2Rb
1) 2) 3) 4)
Rb Rb a a

41. The relationship between Pc,Vc and Tc is:

3 3
1) Pc Vc  RT 2) Pc Vc  3RTc 3) Pc Vc  RTc 4) Pc Vc  RTc
5 8

42. Use of hot air balloons in sports and meterological observations is an application of:

1) Boyle’s law 2) Newtonic law 3) Charles’ law 4) Brown’s law

 a 
43. At low pressure, van der waals’ equation is reduced to  P  V  RT . The compressibility factor can
 V 2 
be given as:

a RTV a RTV
1) 1  2) 1  3) 1  RTV 4) 1 
RTV a a

44. A closed vessel contains equal number of nitrogen and oxygen molecules at a pressure of P mm. If nitrogen
is removed from the system, then the pressure will be:

1) P 2) 2P 3) P/2 4) P2

45. For 1 mole of gas, the average kinetic energy is given as E. The u rms of gas is:

1 1
 2E  2
 3E  2
1)   2)  
M M

1 1
 2E  2
 2E  2
3)   4)  
 3M   2M 
FT21G/TP/JEE MAIN/P+C 6 Brilliant STUDY CENTRE

Section 2 - Numerical type (4,0)

[The answer to each question is a NUMERICAL VALUE. Each question carries +4 marks for
correct answer and 0 mark for wrong answer. Answer is the integer lies between 0 to 9.

46. In two separate bulbs containing ideal gases A and B respectively, the density of gas A is twice that of gas
B while molar mass of gas A is half that of gas B at the same temperature, pressure ratio PA / PB will be:

47. Two gases A and B, having the mole ratio of 3 : 5 in a container, exert a pressure of 8 atm. If A is removed
what would be the pressure in atm due to B only, temperature remaining constant?

48. The ratio of rate of diffusion of helium and methane under identical conditions of pressure and temperature
is :

49. If two moles of an ideal gas at 546 K occupies a volume of 44.8 litres the pressure must be

50. Ratio between the r.m.s velocity of H2 at 50K and that of O2 at 800K is
 19-07-2020
Brilliant
STUDY CENTRE
Batch: IIT- 2021
REPEATERS JEE MAIN EXAMINATION
Puliyannoor P.O., PALA
Ph - 04822 206416, 206516, 206459 PHYSICS + CHEMISTRY - KEY WITH HINTS
www.brilliantpala.org

PHYSICS
1. 4
2. 3 K.E max  h  

c
K1  h 
1

hc
K2  
2

hc
K1  
2 2

1
K1   K2    
2

K2 
K1  
2 2

K 2    2K1

K 2  2K1    K 2  2K1

K2
2K1<K2; K1 
2
3. 2

h 1
4. 3  
2mqV m

e mp
q and v same 
p m2

e
1;   
p e p

5. 3 Radius of nth orbit is given as

n2 0
rn  0.53 A
z

12 0.53
Radius of 1st orbit r1  0.53   a0
2 2

 rn  a  n 2  n 2a
FT21G/TP/JEE MAIN/P+C 2 Brilliant STUDY CENTRE

1 1
Energy of the photon  13.62  n 2  n 2  eV
2
6. 3
 1 2

1 1   25  1  24
 13.6 12  2  2   13.6   = 13.6  =13.05eV
1 5   25  25
Momentum of nucleus = Momentum of photon

h hc 13.05eV
MV  ; MV  Mv 
 c c

13.05 1.6  1019 13.05

1.6 1027  V  V  4.3m / s
3  108
3

c
7. 3 K   a  z  b   (29  1)
 K
2

c c
 a  57  1  a  28    (2)
 K  K
1 2

c
 a  56    (1)


 K a  56
2

 a  28

K  2
4


 K 2  4

1 1 1
8. 4  22 R  2  2 
  n1 n 2 

1 2
2z

  min z  max  lithium
9. 3
10. 2 K.E max  4eV

eV0  4eV

1.6 1019 V0  4 1.6 1019

Vo  4

h 1 p 2
11. 3   1
p  2 p1
FT21G/TP/JEE MAIN/P+C 3 Brilliant STUDY CENTRE

N1 1 N 0e 10t 1
12. 4  
N2 e ; N 0e  t e

1 1 1
rt
 ; 9t=1; t 
e e 9
13. 4

14. 1  K  a  z  b 

e e 4 102
 a  n  1 ;
2 2
 a  z  1 ;
2 2

 4   z  12

100
4
 z  1
2

 z  1
2
 25 ;

z 1  5 ; z  6

1  1 1  3R
15. 1  R 2  2  
1 1 2  4

1 1 1
R 2  R
2 1  

1 4

2 3

16. 3
17. 2
18. 3 A 2  A 0et 2

A1  A0et1

t1  t 2
A 2 e t 2
 t1  e t1  t 2   e T
A1 e

 t1  t 2 
 
A 2  A1e  T 

t
1 t½
19. 2 A  A0  
2

2
1 1
A x  2  1
 2

Ay  1  2 2
 
2

20. 1
FT21G/TP/JEE MAIN/P+C 4 Brilliant STUDY CENTRE

t
1 t½  1  5t ½
21. 3 N  N0   = N0  2  t
2   ½

1 N0
 N0  =
25 32

1 1 1
22. 9  Rz 2  2  2 
 2 3 

1
 z2

2
1  z 2 
 
 2  z1 

2
  3 
  9
2  1  2

2   n  9
9

n  n  1 4  4  1 12
23. 6   6
2 2 2
24. 2
t
1 t½
25. 4 N  N0  
2

t
N0 1 t
 N0   t½

16 2

t 4
t½

t  4  t 1  4 100s
2

 x4
CHEMISTRY
26. 2 On heating gas in open vessel
At 300 K : P1V1 = n1  R  300

At 400 K : P1V1 = n 2  R  400

n1 4 3
  n 2  n1
n 2 3 or 4

n1
Thus, gas is given out.
4
FT21G/TP/JEE MAIN/P+C 5 Brilliant STUDY CENTRE

28  4  32  1
27. 3 Molar mass of sample   28.8
5

 V.D  14.4

1
28. 4 u rms   
M

29. 2 Use P1V1  P2 V2

30. 1 Using PV = nRT
Initially 2  2.24  n1  0.0821  300 ;

100
Finally  2.24  n1  0.0821 300;
76

n1  0.120

Mole given out = 0.182 - 0.120 = 0.062

 M 
Use    M 
1 1
31. 4
2  2

32. 3 Total mole of gases

32 3 5
 (for O2) + (for H2) =
32 2 2

5
 volume   22.4litre  56litre
2

PV T
Use P V  T
1 1 1
33. 4
2 2 2

21
34. 1 PO 2  mole fraction of O2×750 =  750  157.5mm
100

3 3
35. 2 KE  RT   2  300  900cal
2 2
36. 1 Lowering of temperature decreases kinetic energy and increase of pressure increases forces of
attractions.
37. 1 Maximum deviations are noticed at low T and high P

Rate of diffusion   
1
38. 4
M

39. 1 Whenever, gases are allowed to expand through a small jet under adiabatic conditions they suffer
a change in temperature. This is Joule-Thomson effect.
if T > Ti ; heating effect
if T >Ti ; cooling effect

2a
40. 2 Ti 
Rb
FT21G/TP/JEE MAIN/P+C 6 Brilliant STUDY CENTRE

RTc 8 8a a
41. 4   Tc  , Vc  3b and Pc 
Pc Vc 3 27 Rb 27b 2

42. 3 Balloons obey Charles’ law, ie., V  T

 a 
43. 1  P  V 2  V  RT

a
or PV   RT
V

PV a
or  1
RT RTV

PV  a 
or  1   Z
RT  RTV 

44. 3 P  n (V,T constant)

3
45. 1 Average kinetic energy, E  RT
2

3RT 2E
u rms  
M M
46. 4 Use PM = dRT

3 5
47. 5 PM  8atm; PA  PM and PB  PM
8 8

rHe M CH4 16
48. 2   2
rCH4 M He 4

49. 2
50. 1