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VERSION – A
Sol: At maximum compression, no relative Sol: For a disc of charge density σ and radius
velocity. R the electric field at a distance a
v1 = v2 = v’ for conservation of momentum,
σ a
1−
( )
v =
2 mv’ = mv ⇒ v’ = 2ε 0 2 1/ 2
R +a
2
2
→ → → Hence in the given problem, subtract from
v1+ v 2 = v 0 σ
the field of the infinite sheet the
2ε 0
2. A particle moves in the first quadrant of the x-y above value.
plane under the action of a ----------- σ a
Hence E =
2ε 0 R + a2
2
Ans : vx = u(1 + t / t0)
•
B
Points A, B and C are at the same
O h
potential. Hence no charge on R, S and T.
Sol: Higher density liquid is lower.
As the cylinder is getting immersed, the 6. The figure shows a wire mesh of infinite extent,
buoyancy force increases from zero linear such that the resistance ---------------------
till it is fully immersed. Once fully immersed,
until it reaches the interface buoyancy force 1
Ans : A
is constant. 2
7. In a Young’s double slit experiment, the 11. In a column of air at a given temperature T, the
separation between the slits --------------------- density ρ is found to vary with the ------------------
Ans : 0.25 mm 2
k T
Ans : B
mg
Sol: Position of the first dark fringe is given by
β λD
= Sol: Probability of finding a molecule at height
2 2d
The least distance of the dark fringe from z is
∞
the centre is for the smaller wavelength. − mgz
500 × 10 −6
×1
P(z) ∝ ∫ zρ0e dz
kBT
∴ = 0.25 mm 0
−3
2 × 10 2
1
2
→ → ∝ = kBT
mg
8. The electric field E r , t and the magnetic field - mg
k T
B
-----------------
12. The mass density in a nucleus near its center, in
c 3
units of kg/m , is in the range ----------------
Ans : .ε 0 E 02 k̂
2
15 20
Ans : 10 to 10
Sol: The rate of energy flow across a unit area
is the time average over a cycle of the Sol: Density at the centre
pointing vector. ρ0 ρ0
1 ∝ =
∴ S = ε 0 cE 02 −
R
1 + e −2
2 1+ e a
0.17 3
= nucleons / fm
9. A transverse wave travels on a taut string 1.135
stretched along the x-axis. The linear mass ------- 0.15 × 10 −27
≅ ~ 1.5 × 10 kg m−
17 3
-------- − 45
10
Ans : 6 to 7 fm
0 x ρ0 ρ0
µ ⇒ e− [e − 2] = 1
12 r/a
(e − 2) = e
r/a 12
Since energy independent of x,
1 r
A ∝ ≅ 12
2
∴
µ a
12
(neglecting of no comparison to e )
10. A spherical soap bubble of radius R is blown ∴ r = 12 a = 0.55 × 12 fm = 6.6 fm
from a tiny drop of a soap ---------------
2
Ans : 8πTr
28
14. The plots of p(r) versus r for Si and another Sol: The electron current occurs above the
nucleus X are shown ------------------ threshold voltage. Initially the current rises
steeply and then slowly attains saturation.
142
Ans : Ba
18. In the following statements,
ρ0 ρ0 A Ideal gases are liquids only
=
Sol:
1+ e (r / a −10 )
2 1 + e −10 ( )
( )
∴ 1 + e r / a −10 = 2(1 + e− )
10 Ans : B, C, D
e− (e − 2) = 1
10 r/a
Sol: Ideal gases cannot be liquefied as there is
∴ (e − 2) = e ⇒ r ≅ 10 a = 5.5 fm
r/a 10
142
no attraction between the molecules. Real gases
nearest value of A is Ba show ideal behavior at low pressure and high
temperature. None of the gas is ideal.
15. A vessel, fitted with a weightless, frictionless
2
piston of 0.025 m …
19. The correct order for the rule of SN…….
Ans : 75%
Ans : B> C > A> D
Sol: Work done = −P∆V
= −1 (atm) × 0.025 × 10 (dm )
3 3 Sol: The relative stability of carbocation formed
Fe + 2HCl → FeCl2 + H2 by hydrolysis is B> C > A> D
Number of moles of Fe = Number of moles of H2
Work done = −nRT 20. The aromatic species among the following are…
= −n × 0.0821 (L atm mol− K− )× 300 K
1 1
25 Ans : D & E
∴n= =1
0.0821 x 300
Sol: (D) is tropyllium cation which is aromatic
mass of Fe = 55.85
according to Huckel’s rule. (E) is aromatic
55.85 x 100
% purity = ≅ 75% because is forms cyclobutenyl dication with 2
75
delocalised π electrons.
Ans : A, C & D
Ans : 250.20 K
∆Tf = Kf × m
Sol: The compound contains two double bonds
= 30 × 3.5 × 10− = 0.1
3
and the group linked to the two double bonds are
∴ F. P = 250.2 K
different. Hence four stereoisomers are possible.
They are E-E, Z-Z, E-Z and Z-E.
17. Ans :
Electron current
Sol: In Na2[Cr[NCS]4 [NH3]2] the central atom is Sol: SO2 is present in Troposphere. It is a
in +2 oxidation state and the hybridization is component of classical smog. It is also
2 3
d sp . There are two unpaired electrons. responsible for acid rain.
th
29. Let x be the 7 term from the beginning and y be
th
the 7 term ….
2 3
d sp
Ans : 9
2+ n
Cr 1 1
Sol: x = T7 ; y = Tn−6; 3 3 + 1
25. The most stable species among the following is 4 3
n −r r
1
Cl Cl Cl n
Tr+1 = Cr . 3 3 4
1
4 3
Ans : Al Al
n− 6 6
1 1
Cl Cl Cl n
C6 . 3 3 . 1
x 1 4 3 1
Sol: Al2Cl6 is a stable species existing in solid = ⇒ n− 6
=
y 12 12
1 1
state. n
Cn −6 . 3 3 . 1
4 3
26. According to the VSEPR model, ……… n − 4 +n − 4 1
⇒ 3 3 .4 3 = = 3 −1.4 −1
12
X
⇒n=9
Ans :
30. The number of functions f: {1, 2, …n} →
X
{1, 2, …m}, where m, n, are positive….
Sol: lone pair arrange at 120° to each other to n−1
form linear molecule. Ans : m
27. Cyclohexanol is converted to Nylon-6 by…… Sol: {1, 2, …n} → {1, 2, …m}
f(1) = 1
Ans : Cu(250°C)/NH2OH/H /250°C
+ ∴ for the remaining (n−1) elements there
are m choices each ⇒ m −
n 1
O
OH
Sol: Cu/250°C
31. The number of real roots of the equation in the
interval
(1/(x − 1)) + (1/(x − 2)) + …+1/(x − 5) = 1…
NOH
Ans : 4
NH2OH H+
Sol: In the question ‘in the interval’ is repeated
twice. Please read after deleting the phrase
the first time it appears
O 1 1 1
+ + ... + =1
250° C
Nylon 6 (x − 1) (x − 2) (x − 5)
NH
It is obvious that f(x) → −∞ when x → 1− , 2−,
Caprolactum 3−, 4−, 5−. Also that f(x) → +∞ when
x → 1 , 2 , 3 , 4 , 5 and in (1, 2), (2, 3),
+ + + + +
⇒ (2 + i) × (1 + i)
1
2
7
Ans : −
2 =
1
(1 + 3i)
2
1 3
Sol: The general solution is ∴ The point is ,
5 2 2
y = Ce − 1 − e − x
x
2
7 35. The equation of the plane passing through the
y(0) = y0 ⇒ C − = y0
2 intersection of the planes x + 2y + z − 1 = 0..
7
C = y0 +
2 Ans : −4
But given lim | y( x ) | is finite
x →∞
Sol: Equation : plane through intersection is
7
⇒ C → 0 ⇒ y0 = − (1 + 2λ)x + (2 + λ)y + (1 + 3λ)z − 1 − 2λ=0
2
1 + 2λ + 2 + λ + 1 + 3λ = 0
4 + 6λ = 0
33. The distance from a point (k, 0) on the positive x-
−4 −2
axis to the tangent …. λ= =
6 3
x + 2y + z − 1 − (2 x + y + 3z − 2) = 0
2
19
Ans : 3
4
3x + 6y + 3z − 3 − 4x − 2y − 6z + 4 = 0
−x + 4y − 3z + 1 = 0
2 1 4
Sol: y = 4x y = x − 4y + 3z − 1 = 0
2y
∴ k = −4
36. The principal value of 1 2 0
5π π 5π π
1 39. Let P = − 1 1 2 and Q be such that …
sin− sin cos + cos sin is …
9 9 9 9 1 2 1
π
Ans : Ans : real numbers
3
Sol: Qx = λX ⇒ (Q − λI) X = 0
5π π 6π
sin− sin + = sin−1 sin ⇒ |Q − λI| = 0 (Θ X is non zero)
1
Sol:
9 9 9 |P| = 1(1 − 4) − 2(−1 −2) = −3 + 6 = 3
2π − 3 − 2 4
= sin−1 sin , 1
3 Q = − 3 1 − 2
3
2π π π − 3 0 3
i.e., sin− sin π − = sin−1 sin =
1
3 3 3 −3 − λ − 2 4
1
Q − λI = −3 1− λ − 2
3
37. Four numbers are chosen at random without
−3 0 3 − λ
replacement from the first 15 …
|Q − λI| = −3(4 − 4 (1 − λ)
8 + (3 − λ) [−(−3−λ) (1 − λ) −6]
C4
= (1 − λ) (9 − λ + 6λ) = 0
2
Ans : 1− 15
C4 ⇒ All real roots ⇒ λ ∈ R
4
1 0 0 0 0
Sol: |adj M| = |M|
a x−a 0 0 0
1
M−1 =
M
(x + 4a ) a 0 x−a 0 0
a 0 0 x−a 0
4 1 −4
|adj M− | = M−1 = =M x−a
1
a 0 0 0
4
M
(x + 4a) (x − a)
4