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Advances in Water Resources 62 (2013) 207–214

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Advances in Water Resources


journal homepage: www.elsevier.com/locate/advwatres

Anomalous dispersion, renormalization groups, scaling


laws and classification: A reflection on recent efforts
John H. Cushman a,b,⇑, Daniel O’Malley a, Moongyu Park c
a
Department of Earth, Atmospheric and Planetary Sciences, Purdue University, West Lafayette, IN 47907, USA
b
Department of Mathematics, Purdue University, West Lafayette, IN 47907, USA
c
Department of Mathematics, University of Alabama in Huntsville, Huntsville, AL 35899, USA

a r t i c l e i n f o a b s t r a c t

Article history: Motivated by the need to understand the dynamics of motile particles in porous media, our team has
Available online 10 July 2013 applied renormalization group techniques to both upscale and classify anomalous dispersive/diffusive
behavior. Central limit theorems, which lead to a specific type of renormalization group, are employed
Keywords: in several cases to upscale transport of motile particles in porous media that display a specific type of
Anomalous diffusion/dispersion fractal character. The old standby classification for diffusion (which we use interchangeably with disper-
Central limit theorems sion) says a particle is anomalous if its mean square displacement is not linear in time. This physically
Renormalization groups
intuitive concept, is shown to be inadequate, and so is replaced by a scheme that relies on the fixed points
of specific renormalization group operators. Various asymptotic limits are examined, and scaling laws for
the limits are derived. A random renormalization operator is introduced for processes with multiple
asymptotes and unknown self-similarity index, and a Bayesian tool is employed to obtain scaling laws
that are weighted averages of power laws.
Published by Elsevier Ltd.

1. Introduction coefficients that may be related to fractal properties of the aquifer


[30,47]. In some cases, a transition from a preasymptotic, anoma-
In this article we review a number of techniques and results to lous regime on a short time scale to a classical regime on a long
characterize anomalous diffusion (we will use diffusion and dis- time scale is observed [16]. A number of different models have
persion interchangeably). We begin with an example motivated been devised for anomalous diffusion including continuous-time
by an atmospheric observation by Richardson [42] almost random walks (CTRWs) [3,26,29,44], fractional advection–disper-
100 years ago. He turned a group of balloons (tracer particles) lose sion [1,2], a nonlocal integral flux approach that includes the frac-
in the atmosphere and recorded their relative separations with tional advection dispersion equation and the CTRW master
time. Subsequently he computed the expected value of their equation as special cases [8–10], multi-rate mass transfer models
squared separation, hrðtÞ2 i, and observed that hrðtÞ2 i  t3 . In the with memory functions [17,44], and stochastic hydrology [13].
standard language of diffusion theory, this is a category of anoma- An overview of and perspective on these various theories can be
lous diffusion called super diffusion. Classical diffusion (as opposed found in [32].
to anomalous) being when hrðtÞ2 i  t1 , subdiffusion is when the Let us see if there is a simple way to mathematically generate
exponent is less than 1 and superdiffusion occurs when the expo- the Richardson scaling law and see how we might generalize it
nent is greater than 1. Later in this article we will illustrate why [11]. Our basic construct will be a random particle with velocity
this is an inadequate definition of anomalous diffusion, and pro- vðtÞ in a Lagrangian reference frame. In this frame an observer
vide a more general definition. rides an infinitesimal piece of matter as it traverses space. As moti-
Anomalous diffusion occurs in a wide range of physical phe- vation for subsequent generalizations we first consider the case of
nomena [7,21,24,27,28,41]. In hydrology, anomalous diffusion a Brownian velocity which we label v b ðtÞ ¼ ðv b1 ; v b2 ; v b3 Þ. The veloc-
can arise in many different ways including, e.g., particle retention ity is thus continuous in time, but nowhere differentiable. Further,
[14], heterogeneous velocity fields [15,20,23], nonstationarity it has stationary increments, i.e. the distribution of v b ðtÞ  v b ðsÞ de-
[3,31,46], and non-Gaussian distributions [4]. Anomalous diffusion pends only on t  s; t > s. More specifically, the distribution of
in heterogeneous aquifers can display scale-dependent diffusion vb ðtÞ  vb ðsÞ is normal Nð0; ðt  sÞQ Þ, where Q ¼ ðQ ij Þ, with each
Q ij independent of t and s. ðt  sÞQ is the covariance matrix of
vb ðtÞ  vb ðsÞ. To see if this process gives Richardson diffusion one
⇑ Corresponding author. must examine
E-mail address: jcushman@purdue.edu (J.H. Cushman).

0309-1708/$ - see front matter Published by Elsevier Ltd.


http://dx.doi.org/10.1016/j.advwatres.2013.07.001
208 J.H. Cushman et al. / Advances in Water Resources 62 (2013) 207–214

Z t
fusion. Subsequently we generalize to fractional Brownian motion
rb ðtÞ ¼ vb ðsÞds: ð1Þ
run with a non-linear clock. Next we introduce a single scale ren-
0
ormalization group classification of nonstationary and/or infinite
It is important for the reader to note that rb ðtÞ is not a Brownian second moment processes, which is followed by a two-scale ap-
process and in fact it is absolutely continuous with probability proach. Finally, we introduce random renormalization group oper-
one. The reader should also note that in Richardson’s original exper- ators and apply them to multiscale stochastic dynamics with
iments he tracked pairs of particles whereas rb ðtÞ is for a single par- Bayesian conditioning on data.
ticle. This however causes no problem because the difference of two
independent Brownian velocities is just another Brownian velocity.
2. Apparent Fokker–Planck equations for 3-dimensional
Using the characteristic function for v b ðtÞ, and the fact that the inte-
systems with fractal mesoscale and motile particles
gral above can be taken in the Riemann sense, a central limit theo-
rem (CLT) can be derived to evaluate the integral [11]. The result is
Natural porous systems often display fractal functionality or
hjrb ðtÞj2 i  t3 as we hoped. It can further be shown that the apparent
structure over some range of scales. In this section we consider
Fokker–Planck equation is a diffusion equation with diffusion coef-
porous systems with fractal functionality on the mesoscale, which
ficient proportional to t 2 .
is assumed to be bounded by upper and lower cutoffs. Above the
This result begs a generalization in the sense of Mandelbrot’s
upper cutoff (the macroscale) and below the lower cutoff (micro-
intermittency [25]. Assume in an Eulerian frame that the momen-
scale) the system is non-fractal. On the microscale the trajectory
tum change, and hence energy dissipation, is concentrated on a
of a particle is assumed to be the solution of a stochastic ordinary
fractal set so that it has an Eulerian fractal character. An Eulerian
differential equation (SODE) with stationary, ergodic, Markov drift
frame is one where the observer is fixed in space and watches as
velocity. To account for particles that might be self-motile, such as
the surroundings change. Qualitatively an Eulerian fractal is self-
microbes, the microscale diffusion is assumed to be driven by an a-
similar (as for example, a self-similar conductivity (or velocity)
stable Lévy process. When a ¼ 2 the process is Brownian and so it
field in subsurface hydrology). Further, assume the Eulerian veloc-
can account for non-motile particles as well. On the mesoscale the
ity field has homogeneous increments, that is, the distribution of
Eulerian velocity is assumed to be fractal. If the system is Darcian,
v ðx; tÞ  vðy; tÞ depends only on x  y and t. It is reasonable then then the hydraulic conductivity is assumed to be fractal in space
to assume a Lagrangian particle will take on a fractal character of
and the conductivity is assumed to induce a fractal Eulerian veloc-
its own, i.e. its graph will be a fractal and its increments will be sta-
ity. The flow is considered steady and incompressible. Hence the
tionary. The a-stable Lévy processes have these two latter charac-
Lagrangian drift velocity satisfies VðtÞ ¼ v ðXðt; x0 ÞÞ; Xð0Þ ¼ x0 ,
teristics and thus without significant loss of generality, we may
where v ðxÞ is the steady state Eulerian velocity. If v ðxÞ is assumed
assume the Lagrangian velocity is a-stable Lévy and we denote it
to have spatially homogeneous increments, then it is reasonable to
by v L ðtÞ. It should be noted that when a ¼ 2, the process reduces
expect v ðXðtÞÞ to have temporally stationary increments. The diffu-
to Brownian motion, and like Brownian motion, sums of Lévy’s
sive structure on the mesoscale is dictated by the asymptotics of
with identical a are Lévy, with the same a.
the microscale process. On the macroscale we assume the physics
In one dimension, a stochastic process LðtÞ is said to be an a-sta-
are controlled solely by the mesoscale asymptotics. Thus there is
ble Lévy motion [43] if
no additional drift at the macroscale. The mesoscale flow field is
assumed periodic on the macroscale, i.e., the mesoscale flow field
1. Lð0Þ ¼ 0 with probability 1.
is mapped to a periodic lattice.
2. L has independent increments.
The SODE on the microscale takes the form
3. Every increment Lðt þ sÞ  LðsÞ  Sa ðt1=a ; b; 0Þ
Z t
Xð0Þ ðtÞ ¼ Xð0Þ ð0Þ þ Vð0Þ ðXð0Þ ðrÞÞdr þ Lð0Þ ðtÞ; t P 0; ð3Þ
where Sa ðr; b; lÞ is used to denote an a-stable random variable 0
with spread parameter r, skewness parameter b and shift param-
where Lð0Þ ðtÞ  Sal ðtM; t ll Þ with al ; M and ll constants. Park et al.
eter l. Because Lévy motions have only a countable number of dis-
[40], using CLT results of Bhattacharya and Gupta [5] and a CLT
continuities, the integral of the velocity can be taken in the
for Lévy processes, show that this SODE converges in distribution
Riemann sense and hence can be evaluated as an infinite sum. As
for long times to an al -stable Lévy process. Specifically, with
was the case for a Brownian velocity, a CLT for the integral of a ~ ð0Þ ðtÞ ¼ Xð0Þ ðtÞ  Xð0Þ ð0Þ, they showed
X
Lévy process can be derived [40]. From there it follows that the  
apparent Fokker–Planck equation is fractional in space, classical ~ ð0Þ ðntÞ  nt hVð0Þ i  l
X l
in time, and with a diffusion coefficient proportional to t a [40]. ; ð4Þ
It remains to determine a. This problem was solved numerically n1=al
in [22] and analytically in [38]. The solution involves a quantity converges to an al -stable Lévy process in distribution as n ! 1. What
called the finite-size Lyapunov exponent (FSLE) which we denote this implies is that the diffusive process on the mesoscale (the scale
as ka ðxÞ. The FSLE is defined by the equation labeled by a superscript 1) is Lévy. Let VðtÞ ~ ¼ VðtÞ  Vð0Þ and let
Rt
~ ~
YðtÞ ¼ 0 VðsÞds. By introducing a scale change Park et al. [40] show
a ¼ expðka ðxÞT a ðxÞÞ; ð2Þ
~ ð2Þ ðtÞ has the same distribution as thVð1Þ i þ limk!1 Y
that Y ~ ð1Þ ðktÞ. From
where the a-time, T a ðxÞ, is the average time it takes a pair of parti- ~ ð2Þ ðtÞ has
there they argue that the macroscale Lagrangian trajectory X
cles to separate from a distance x to a distance ax. When a ¼ 2 this ð1Þ ð1Þ ~
the same distribution as tð½V  þ l Þ þ Y ðtÞ where ½ indicates
ð2Þ
is called the doubling time. As it turns out, for an a-stable Lévy pro- l

cess, ka ðxÞ  xa , independent of a. Thus a can be determined by a volume average [48] over a unit cell on the macroscale and an average
simple tracer test with x the magnitude of the initial difference be- over time. Next using characteristic functions of Lévy motions, they
tween two material particles velocities. prove a CLT that leads in real space to the apparent Fokker–Planck
equation for the macroscale probability density for X~ ð2Þ :
In the next section we generalize these results to an isotropic
three-scale porous medium and then subsequently to an aniso- @f
tropic medium. In the third section we introduce a nonstationary ¼ r  q; ð5Þ
@t
extension of Brownian motion to illustrate some problems with
q ¼ Vð2Þ f  Dð2Þ ðtÞra1 f : ð6Þ
the mean-square displacement characterization of anomalous dif-
J.H. Cushman et al. / Advances in Water Resources 62 (2013) 207–214 209

Here Vð2Þ ¼ ½Vð1Þ  þ ll ; Dð2Þ ðtÞ ¼ t a =cosðpa=2Þ and ra1 f is the a-1
ð1Þ
equation with time-dependent diffusivity given by hðtÞ=2. In a por-
fractional gradient of f. Also, 1 < a 6 2 and a is the stability param- ous media, this time-dependence of the dispersivity would arise
eter for Vð1Þ ðtÞ. There are a few more technical constraints on a that when the hydrodynamic dispersion coefficient is evolving in time.
we will not discuss here (see [40] for details). This would arise, e.g., if the average velocity changes, the molecular
To summarize this section, we have reviewed a method to up- diffusion coefficient changes (due to, perhaps, temporal changes in
scale pore scale information on the transport of motile particles, temperature), or the dynamic dispersivity changes (due to, per-
to a porous structure with fractal mesoscale and then subsequently haps, temporal changes in porosity). Some special cases include
to upscale this to a macroscale periodic structure. This was accom- (i) power law diffusion hðtÞ ¼ t a ; hjXðtÞj2 i ¼ t aþ1 =ða þ 1Þ, which is
plished using central limit type theorems which are essentially subdiffusive when 1 < a < 0, classical when a ¼ 0, and superdif-
equivalent to renormalization group type operations. This was all fusive when a > 0; (ii) logarithmic subdiffusion, hðtÞ ¼ ðt 0 þ tÞ1 ,
accomplished assuming the system is isotropic. The authors have where t0 > 0 and hjXðtÞj2 i ¼ logðt 0 þ tÞ; (iii) multifractal diffusion,
extended these results to anisotropic systems by employing oper- hðtÞ ¼ ðt 0 þ tÞaðtÞ with aðtÞ P 1 and t0 > 0. While we call this last
ator stable processes [39]. The basic form of the Fokker–Planck process multifractal in analogy with classical practice, we must
equation is that presented earlier, only now the order of the deriv- point out that the fractal dimension remains unchanged irrespec-
atives changes with direction and the diffusion coefficient is tive of the exponent.
tensorial. It was stated in [28] on page 6 that a power-law mean square
displacement ‘‘is intimately connected with a breakdown of the
3. Nonstationary extensions of classical processes (nonlinear central limit theorem, caused by either broad distributions or long
clocks) range correlations.’’ Brownian motion run with a non-linear clock
involves neither a breakdown of the central limit theorem, nor
Recall that a diffusive/dispersive process is called anomalous if broad distributions, nor long range correlations. In fact, we have re-
the mean square displacement is proportional to t b ; b – 1. In this lied solely on the Lyapunov version of the CLT for our analysis. The
section we illustrate why this is an incomplete characterization increments are Gaussian and uncorrelated. Despite this, the mean-
of anomalous processes. We do so by introducing the concept of square displacement obeys a power-law. It has been known for
a nonlinear clock, a type of deterministic subordination. many years that upscaling (via projection operators, renormaliza-
A process, BðtÞ, is Brownian if (a) every increment Bðt þ sÞ  BðsÞ tion groups, matched asymptotics, volume averaging in the sense
is normally distributed with mean zero and variance r2 t where r is of Whitaker [48]) may give rise to spatially nonlocal and non-Mar-
fixed; (b) for every pair of disjoint time intervals ðt1 ; t2 Þ and kovian processes, many of which have long range correlations and
ðt3 ; t4 Þ; t 1 < t 2 6 t3 < t4 , the increments Bðt 4 Þ  Bðt3 Þ and power law moments. What we have described here is a spatially
Bðt 2 Þ  Bðt1 Þ are independent random variables with distribution local and Markovian process which also may possess power-law
given by (a); (c) Bð0Þ ¼ 0 and BðtÞ is continuous at t ¼ 0. A standard moments. Thus while long range correlations and a breakdown
Brownian motion has r ¼ 1; hence by the properties of a normal of the CLT often lead to anomalous diffusion; they are by no means
distribution, any Brownian motion, XðtÞ, can be made standard a necessary prerequisite and are not intimately connected with a
by replacing BðtÞ by BðtÞ=r. The Fokker–Planck equation for a breakdown of the CLT.
Brownian process is the classical diffusion equation with constant An alternative to studying the limiting distributions in CLTs is to
diffusion coefficient. study the fixed points of certain renormalization group (RG) oper-
Let HðtÞ be absolutely continuous with non-negative derivative ators [6,19]. Although the CLT and RG approaches are formally and
hðtÞ, i.e., conceptually similar, CLTs are often linked with processes that
Z have independent increments while the RG approach is more often
t
HðtÞ ¼
0
hðt 0 Þdt : ð7Þ used with processes that have dependent increments, e.g., frac-
0 tional Brownian motion (fBm) [45]. Next let us consider fBm run
with a non-linear clock (fBm-nlc). FBm-nlc gives us a family of sto-
A process XðtÞ is said to be a Brownian motion (Bm-nlc) run with a
chastic processes with nonstationary, correlated increments that
non-linear clock, HðtÞ – at þ b, if XðtÞ ¼ BðHðtÞÞ. From the defini-
allow a priori independent selections of both the fractal dimension
tion of a Gaussian we have XðtÞ  XðsÞ  N½0; HðtÞ  HðsÞ and so
and mean square displacement.
unlike Brownian motion, XðtÞ has non-stationary increments.
In one dimension, a process BH ðtÞ is said to be fBm with Hurst
However, it can be shown that the fractal dimension of the graphs
exponent H ð0 < H < 1Þ, if (a) with probability 1, BH ðtÞ is continu-
of XðtÞ and BðtÞ are both 3=2 [12]. Now with BðsÞ a standard
ous and BH ð0Þ ¼ 0 and (b) for any t > s P 0 the increment
Brownian motion
BH ðtÞ  BH ðsÞ is normally distributed with mean 0 and variance
Z t qffiffiffiffiffiffiffiffiffi
ðt  sÞ2H . The second condition implies the increments are station-
XðtÞ ¼ hðsÞdBðsÞ ð8Þ ary. The correlation structure is given by
0

and thus
Z t qffiffiffiffiffiffiffiffiffi 2 Z t hBH ðsÞ½BH ðtÞ  BH ðsÞi ¼ ½t2H  s2H  ðt  sÞ2H =2: ð11Þ
hX 2 ðtÞi ¼ h hðsÞdBðsÞ i ¼ hðsÞds ¼ HðtÞ; ð9Þ
0 0
Let BH ðtÞ be an fBm with Hurst exponent H and let FðtÞ be an abso-
2 lutely continuous function with non-negative derivative f ðtÞ, so that
since hðtÞ is deterministic and hðdBÞ i ¼ dt. It may be helpful in Rt
understanding this calculation to recall that the stochastic integral FðtÞ ¼ 0 f ðsÞds. Given the fBm and the function FðtÞ, the fBm-nlc is
can be approximated as a finite sum: XðtÞ ¼ BH ðFðtÞÞ. From (a) and (b) above it can be shown that XðtÞ has
the following properties:
Z t N1   
X   
tn tðn þ 1Þ tn
f ðsÞdBðsÞ  f B B : ð10Þ 1. With probability 1, XðtÞ is continuous and Xð0Þ ¼ 0.
0 n¼0
N N N
2. For any t > s P 0, the increment XðtÞ  XðsÞ is normally distrib-
XðtÞ is a limit of linear combinations of Gaussians, and hence it uted with mean zero and variance ½FðtÞ  FðsÞ2H . The second
is Gaussian with mean 0 and variance HðtÞ. Hence it follows that condition implies that increments are non-stationary unless
the Fokker–Planck equation for Bm-nlc is the classical diffusion FðtÞ is linear in t.
210 J.H. Cushman et al. / Advances in Water Resources 62 (2013) 207–214

It has been shown [33] that the fractal dimension of fBm-nlc is the In the above K H and K H;a are constants independent of x1 and x2 .
same as the underlying fBm, 2  H, which is dependent only on H. These quantities relate the time scale associated with hitting walls
Thus the MSD (which depends strongly on FðtÞ and H) and the frac- to the length scale initially separating the particle from the walls.
tal dimension can be chosen independently. They can also be related to the FSLE (a measure of the mixing zone)
If FðtÞ ¼ t, the original fBm is obtained. The case of H ¼ 1=2 cor- for these processes. Next we compute the FSLEs for fBm, kH;a , and
responds to Bm-nlc. If FðtÞ ¼ t and H ¼ 1=2 the result is a Brownian fBm-plc, kH;a;a , which may provide additional physical insight into
motion. The correlation structure for fBm-nlc follows from that of the meaning of these quantities. We do this by relating the MFPT
fBm: to the a-time, T a ðrÞ. Recall that physically the a-time is the average
time it takes two particles separated by a distance r initially, to sep-
1n o
hXðsÞ½XðtÞ  XðsÞi ¼ ½FðtÞ2H  ½FðsÞ2H  ½FðtÞ  FðsÞ2H ð12Þ arate to a distance ar. Parashar and Cushman [38] cast the a-time in
2
terms of MFPTs. Using this correspondence, closed forms for the
It is worth studying a few examples to see the flexibility of fBm-nlc. FSLEs were obtained in [37]. For fBm we have
Let us first look at an example possessing a power law MSD. Fix H
and set FðtÞ ¼ t b=2H with b > 0, then by property (1), T a ðrÞ ¼ hTðða  1Þr; ða þ 1ÞrÞi; ð17Þ
XðtÞ  Xð0Þ  Nð0; t b Þ. Therefore hX 2 ðtÞi ¼ t b , and the fractal dimen-
which leads to the approximations
sion and power-law MSD may be chosen arbitrarily. By employing
the classical classification scheme we see when b > 1 it is superdif- 1=2H
kH;a ðrÞ ¼ ln a=½21=2H K H r1=H ða2  1Þ  ð18Þ
fusive while when b < 1 it is subdiffusive and when b ¼ 1 it is clas-
sical (though if H – 1=2 the process is not Brownian). This latter and
point shows a significant weakness in the MSD classification
1=2aH
scheme. When b ¼ 1 but H – 1=2, the process has correlated incre- kH;a;a ðrÞ ¼ ln a=½21=2H K H;a r 1=aH ða2  1Þ : ð19Þ
ments and a fractal dimension different than Brownian motion, yet it
is still considered classical diffusive because its MSD exponent is one.
We next consider the logarithmic case. Fix H and set 5. Single-scale renormalization group classification of
1=2H
FðtÞ ¼ ½logðt þ t 0 Þ  logðt0 Þ with t0 > 0, so that dispersive processes
2
hX ðtÞi ¼ logðt þ t 0 Þ  logðt 0 Þ. The result is a very slow subdiffusion
whose fractal dimension can be varied at will by changing H. In earlier sections we illustrated how Brownian and fractional
Finally consider the case of arbitrary MSD. Fix H and set Brownian processes run with non-linear clocks can have
1=2H
FðtÞ ¼ ½r2 ðtÞ where r2 ðtÞ is the desired MSD. The only require- MSD ¼ t, even though they are not classical. They can have fractal
ments that need be placed on r2 ðtÞ are the same as those placed on dimension different from Brownian motion and they can have cor-
FðtÞ above. Hence fBm-nlc can reproduce any increasing MSD with related increments, and thus though classified as classical, they are
any fractal dimension between 1 and 2. truly anomalous. In this section we will get at the crux of the flaws
associated with the MSD classification of anomalous diffusion/dis-
4. Scaling laws for fBm-nlc with a power-law clock persion. The first question we will ask and subsequently answer is
‘‘what are the origins of power-law MSDs?’’
In this section we determine scaling laws for fBm with a power- We begin our analysis of the origins of the power-law MSD by
law clock, fBm-plc. Specifically, we are interested in the mean first observing that if a stochastic process has zero drift with wide-
passage times, MFPT, on a finite interval with absorbing bound- sense stationary, independent increments and finite variance, then
aries. Subsequently we use MFPT to obtain scaling laws for the the MSD grows linearly in time. Mathematically, we let XðtÞ be a
FSLE. Let the clock, FðtÞ, take the form FðtÞ ¼ ta for some a > 0. It stochastic process with independent, wide-sense stationary incre-
follows that hXðtÞ2 i  t2Ha and therefore fBm-plc can be used as a ments such that h½XðtÞ  Xð0Þ2 i ¼ f ðtÞ < 1 and hXðtÞ  Xð0Þi ¼ 0,
model for anomalous diffusion for all values of b ¼ 2Ha. and show f ðtÞ ¼ ct for some constant c [34]. To see this, note that
Consider the distribution of first passage times for crossing the f ðt þ sÞ ¼ f ðtÞ þ f ðsÞ. From this it follows that f ðtÞ is linear with
boundary of the interval ½x1 ; x2 , where x1 ; x2 > 0. Let f ðt; x1 ; x2 Þ be f ð0Þ ¼ 0. Hence f ðtÞ has the form f ðtÞ ¼ ct for constant c. It follows
the probability density function, PDF, for the first passage time dis- trivially that if XðtÞ is a stochastic process such that
tribution, i.e. the distribution of times at which the motion first hits h½XðtÞ  Xð0Þ2 i ¼ ct b , for some constants b – 1 and c, then at least
either of the points x1 or x2 . The goal is to determine the scaling one of the following conditions hold:
behavior of the first passage time distribution in terms of x1 and x2
and find a functional form for the mean first passage time (MFPT) 1. The increments of XðtÞ are not independent.
when the motion is given by an fBm or an fBm-plc. 2. The increments of XðtÞ are not wide sense stationary.
Let Tðx1 ; x2 Þ denote a first passage time across the boundary of 3. hXðtÞ  Xð0Þi – 0.
½x1 ; x2 . The scaling property of fBm, cBH ðtÞ  BH ðc1=H tÞ, where
c > 0 implies [37] that the density for the first passage times That is, for power-law MSD to occur, the process must have either
satisfies increments that are non-stationary, or increments that are not
independent, or non-zero mean drift. The latter of these is not
f ðt; cx1 ; cx2 Þ ¼ c1=H f ðc1=H t; x1 ; x2 Þ: ð13Þ
important in practice since we can replace any process with a zero
In the case of the power law clock [37] also found mean drift process by subtracting its mean. Every process with a
power-law MSD exhibits at least one of these characteristics.
fa ðt; cx1 ; cx2 Þ ¼ c1=aH fa ðc1=aH t; x1 ; x2 Þ: ð14Þ We have already illustrated that there are an uncountable num-
From these latter two results [37] found the approximate relations ber of processes that have linear MSD, but that are anything but
normal (classical). Next we provide a process that has infinite
hTðx1 ; x2 Þi ¼ K H x1=2H
1 x21=2H ð15Þ MSD and yet it comes to a stop in the long time limit. This process
would be classified as super diffusive in the MSD classification
and
scheme; however it is clearly not super diffusive.
hT a ðx1 ; x2 Þi ¼ K H;a x11=2aH x21=2aH : ð16Þ Let XðtÞ ¼ Lð1=½1 þ expðtÞ  1=2Þ, that is XðtÞ is a a-stable Lévy
process run with a very special nonlinear clock HðtÞ ¼
J.H. Cushman et al. / Advances in Water Resources 62 (2013) 207–214 211

1=½1 þ expðtÞ  1=2. It is not hard to show the MSD of this process distinct, because one has Gaussian increments and the other has
is infinite [34]. Yet non-Gaussian increments. Use of the exact, limiting fixed point
illustrates how the RG scheme is able to distinguish between pro-
lim XðtÞ ¼ lim LðtÞ  x1 ; ð20Þ
t!1 t!1=2 cesses that are both p-diffusive with the same value of p.
Finally, it can be shown [34] that if a process is p-self similar
where x1 is some finite constant. That is, though XðtÞ is superdiffu- then it is also p-diffusive. These authors also discuss how to esti-
sive in the mean square sense, it comes to a screeching halt. We will mate p from data.
see that the renormalization group approach to classification of dif- To summarize this section, the MSD is not sufficient to charac-
fusion will classify this correctly as very slow diffusion. terize the richness and variety of all diffusive processes, and this
The remainder of the discussion in this section will concern a approach often runs into trouble when nonstationary increments
classification scheme based on a RG approach. Let the RG operator, or infinite second moments are present. The examples presented
Rp;n , act on a countably infinite set of random variables I0 ; I1 ; I2 ; . . ., clearly illustrate the problems with the MSD classification scheme.
the ordered list of which will be denoted I. The intuitive picture The renormalization group scheme classifies processes with sta-
from the perspective of diffusion is that each Ii corresponds to an tionary increments the same as does the MSD approach. However,
increment of the diffusive process over a certain period of time. it is also capable of classifying processes with nonstationary incre-
The use of an infinite set of random variables is required to account ments and/or infinite second moments. The effectiveness of this
for things like correlations between increments and nonstationary approach, compared to the MSD scheme, lies in the fact that a se-
increments. The renormalization operator is defined by quence of increments is considered rather than a single number.
X
ðiþ1Þn1
Ik
ðRp;n IÞi ¼ : ð21Þ 6. Two-scale renormalization group classification of diffusive
k¼in
np
processes
Intuitively, when we apply the operator, we are scaling time by a
factor of 1=n and space by a factor of 1=np . This operator is closely So far we have discussed two schemes for classifying diffusion/
linked to self-similar behavior [43]. A process XðtÞ is said to be p- dispersion, MSD and single-scale RG. What we next examine is a
self-similar when XðtÞ and rp XðrtÞ have the same finite dimen- two-scale RG classification scheme. This is important because
sional distributions for all values of r. many processes behave differently on different scales, say short
Let ZðtÞ be an arbitrary diffusive process and define and long times. We begin by defining two renormalization group
Ii ¼ Zði þ 1Þ  ZðiÞ. Thus I represents the increments of ZðtÞ which operators [35].
may be correlated, nonstationary or both. We note that each Rp;n Let XðtÞ be a stochastic process, a and b positive real numbers,
has a trivial fixed point given by taking each Ii to be a delta distri- and define
bution, d0 , with all its mass at the origin. Ra;b XðtÞ ¼ XðatÞ=b: ð23Þ
Definition. We say that ZðtÞ is p-diffusive if
These operators form a group: R1;1 is the identity, closure and asso-
p ¼ inffq P 0 : lim ðRq;n IÞi ! d0 ; 8ig: ð22Þ ciativity follow from the fact that
n!1

In the above, ! means converges in distribution, and inf S denotes Ra;b Rc;d ¼ Rac;bd ð24Þ
the greatest lower bound of the set S. An intuitive picture of this ab-
for any positive integers a; b; c; d. The inverse of Ra;b is R1=a;1=b . A sub-
struse definition can be provided. By applying the operator, Rq;n , the
set of the group will be the operators employed to classify diffusion
process is effectively being observed on a longer time scale, and lar-
with a shorthand notation to describe the elements of the subset.
ger spatial scale. This is natural, because as time progresses, the par-
Define
ticles spread, and a larger spatial domain is required to observe the
particles. The parameter q controls how the spatial scale of observa- Sp;r ¼ R1=r1=p ;1=r ; ð25Þ
tion changes when the temporal scale changes. If q is too large, the Lp;r ¼ Rr;rp : ð26Þ
spatial scale of observation becomes much larger than the scale on
which the particles are distributed (for sufficiently large values of Sp;r will be used to study the short time behavior of a diffusive pro-
n). Therefore, a cloud of particles (represented statistically by a cess, while Lp;r will be used to study the long time behavior. Apply-
probability density function) looks like a delta function when n is ing these maps to a diffusive process when r ! 1 for different
large and q is too big. On the other hand, if q were too small, most values of p, will supply the necessary information for classification.
of the particles would not be in the scale of observation (when n is Important points: The approach for the long time behavior dif-
sufficiently large). The definition given describes ZðtÞ as being p-dif- fers from the previous section because Lp;r acts on the process itself
fusive where p is the value of q that marks the transition between rather than the increments of the process. Also, if XðtÞ and Lp;r XðtÞ
these two types of behaviors. This is achieved mathematically by or Sp;r XðtÞ have the same finite dimensional distributions for all po-
setting p to be the greatest lower bound for the set of q that are sitive values of r, then XðtÞ is p-self-similar [35]. Thus the set of p-
too big. self-similar processes is the same as the set of fixed points of either
Every process is p-diffusive for some value of p, with the caveat Lp;r or Sp;r .
that if the set on the rhs is empty we say the process is 1-diffusive. Consider the long time behavior
A process is subdiffusive if p < 1=2 and superdiffusive if p > 1=2.
Lp;r XðtÞ ¼ XðrtÞ=rp : ð27Þ
We have shown [34] that Brownian motion is 1=2-diffusive, the
very slow a-stable diffusion is 0-diffusive and the fBm-nlc consid- If p is too large, then letting r ! 1 will in general cause the denom-
ered earlier with linear MSD is 1=2-diffusive as are all linear MSD inator to dominate the numerator so that Lp;r XðtÞ ! 0 in
processes. Though a process is 1=2-diffusive, that does not imply it distribution.
is classical. We say a process is classical if and only if R1=2;n I ap- Consider the following pedagogical example: Let XðtÞ ¼ BðtÞ, a
proaches the Brownian motion fixed point as n ! 1. Brownian motion. It is known that BðtÞ is 1=2-self-similar so that
An fBm with H ¼ 3=4 and an a-stable Lévy with a ¼ 4=3 are L1=2;r BðtÞ  BðtÞ for all r. If p > 1=2, then it is easy to see [35] that
both 3=4-diffusive. The increments of these two processes are both Lp;r BðtÞ ! 0 as r ! 1 and hence 1=2 ¼ inffq P 0 : Lq;r BðtÞ ! 0; 8tg.
fixed points of R3=4;n [45]. These two fixed points are clearly This example motivates the following definition:
212 J.H. Cushman et al. / Advances in Water Resources 62 (2013) 207–214

Definition. We say a process XðtÞ is p-diffusive on the long time Brownian noise. Consider the behavior of XðtÞ upon application of
scale if Sp;r :

p ¼ inffq P 0 : Lq;r XðtÞ ! 0; 8tg; ð28Þ Z t=r 1=p Z t=r 1=p pffiffiffiffi
Sp;r XðtÞ  r a½XðsÞds þ r DdBðsÞ
where convergence is taken in the sense of distributions. If the set 0 0

on the right hand side is empty then we say the process is 1-diffu- ! Nðtr11=p a½Xð0Þ; Dtr21=p Þ: ð33Þ
sive on the long time scale.
Again using Brownian motion as our example, we make the fol- Now the normal distribution above approaches a delta distribution
lowing short time definition: if p < 1=2; Nð0; DtÞ if p ¼ 1=2 and diverges if p > 1=2. Therefore, XðtÞ
Definition. We say the process XðtÞ is p-diffusive on the short is 1=2-diffusive on the short time scale.
time scale if Next consider the long time scale, i.e.
Z rt Z rt pffiffiffiffi
p ¼ pfq P 0 : Sq;r XðtÞ ! 0; 8tg; ð29Þ
Lp;r XðtÞ  rp a½XðsÞds þ r p DdBðsÞ: ð34Þ
0 0
where sup S is the least upper bound for the set S. If the set on the
right hand side does not have a supremum (it is unbounded), then If p < 1 then the advective term blows up as r ! 1 because aðXðsÞÞ
we say the process is 1-diffusive on the short time scale. is ergodic. If p > 1, the right hand side goes to a delta distribution
The fixed points of Lp;r and Sp;r are p-self-similar processes, about zero because aðXðsÞÞ is ergodic and the second term goes to
moreover, it can be shown that a p-self-similar process is also p- a delta for p > 1=2. Therefore XðtÞ is 1-diffusive on the long time
diffusive on both the short and long time scales. scale.
Processes without self-similarity can be split into two groups; Next consider the case of infinite MSD. This case really is not
those that have asymptotic self-similarity and those that have no covered by the MSD classification scheme. However it fits nicely
self-similarity. We say a process XðtÞ is p-self-similar on the long into our RG scheme. Consider a-stable Lévy motion which has an
(short) time scale if Lp;r XðtÞ (Sp;r XðtÞ) approaches a nonzero fixed infinite MSD, but as we have mentioned it is 1=a-diffusive on both
point as r ! 1. If a process is asymptotically p-self-similar on the long and short time scales. Since a 2 ð0; 2, these processes are
the long or short time scale it will be p-diffusive as well. Consider super diffusive in the RG scheme except when a ¼ 2 where it is
the process classical Brownian motion.
Finally, let us look at a case with nonstationary increments. We
X
1
XðtÞ ¼ B11=n ðtÞ=2n ; ð30Þ employ an earlier example, XðtÞ ¼ Bðet  1Þ where BðtÞ is a Brown-
n¼2 ian motion. This process does not have a power law MSD and
therefore cannot be classified in that scheme. Further, it is not
where B11=n ðtÞ are independent fBms with Hurst exponent 1  1=n.
self-similar. However, XðtÞ is 1-diffusive on the long time scale
It can be shown [35] that this process is 1-diffusive on the long time
and 1=2-diffusive on the short time scale [35] in our two-scale
scale, but it is not asymptotically 1-self-similar on the long time
RG classification.
scale. Thus there is a subtle difference between being asymptoti-
cally p-self-similar and being p-diffusive.
Any process that is 1-diffusive on a given time scale also lacks 7. Random renormalization group operators
any self-similarity on that same time scale. A simple example that
displays this behavior is Brownian motion run with a nonlinear In this section we introduce the concept of a random RG oper-
clock in the form ator (RRGO) and look at scaling laws under this operator. We also
look at the use of Bayes theorem to determine the weighting used
XðtÞ ¼ Bðet  1Þ: ð31Þ in the scaling laws. What we will find is that scaling laws for the
XðtÞ is 1-diffusive on the long time scale, but it is not self-similar RRGO are not simple power laws, but are a weighted average of
there. power laws. We begin the discussion by reviewing scaling laws
It is instructive to consider several examples of classification for the deterministic counterpart. Specifically, we look at the prob-
based on two scale renormalization groups. We have mentioned ability density, mean first passage times and finite-size Lyapunov
that p-self-similarity implies the process is p-diffusive on both the exponents for fixed points of a deterministic RG operator Lp;r . Recall
short and long time scales. This result allows for immediate classifi- that the fixed points, XðtÞ, of Lp;r are the p-self-similar processes.
cation of many commonly used processes. Brownian motion is 1=2- The fixed points obey simple scaling laws [36]:
diffusive on both time scales, a-stable Lévy motion is 1=a-self-sim-
ilar and hence 1=a-diffusive on both time scales, fBm with Hurst 1. Suppose the probability density, fX ðx; tÞ, for XðtÞ is known at
exponent H is H-self-similar and hence H-diffusive on both scales. time t, then it is also known at any later time s
Even though two different processes have may have the same p, fX ðx; sÞ ¼ ½t=sp fX ð½t=sp x; tÞ: ð35Þ
it is possible to separate them with a sub-classification based on
our RG-scheme. For example, fBm with H ¼ 4=5 and 5=4-stable 2. The mean first passage time satisfies
Lévy motion are both 4=5-diffusive on the long and short time
hTðra; rbÞi ¼ r1=p hTða; bÞi: ð36Þ
scales. However, these two processes are distinct fixed points of
the operators Lp;r and Sp;r and hence we can use fixed points for a 3. The PDF, fT ðt; a; bÞ, of Tða; bÞ satisfies
sub classification.
fT ðt; ra; rbÞ ¼ r 1=p fT ðr 1=p t; a; bÞ: ð37Þ
There is an example that is very relevant to heterogeneous por-
ous media that is worth discussing [35]. Suppose that a stochastic 4. The finite size Lyapunov exponent satisfies
process XðtÞ is determined by the Ito stochastic differential
equation ka ðrÞ ¼ r 1=p ka ð1Þ: ð38Þ
pffiffiffiffi These scaling laws are appealing because of their simplicity. Unfor-
dXðtÞ ¼ a½XðtÞdt þ DdBðtÞ; ð32Þ
tunately many physical stochastic processes are not fixed points of
where aðxÞ is the velocity field that is continuous on the short scale Lp;r . To get around this problem we introduced a random renormal-
and ergodic on the long time scale, and again dBðtÞ is a standard ization group operator, RRGO [36]. The RRGO is defined by
J.H. Cushman et al. / Advances in Water Resources 62 (2013) 207–214 213

LP;r XðtÞ ¼ XðrtÞ=r P ; ð39Þ L1=4;r and L1=2;r get the short and long asymptotes correct, but neither
gets both correct. The RRGO performs well at both extremes with
where P is a positive random variable that may be dependent on
some error on the short end.
XðtÞ. We have shown [36] that the RRGO’s form a group. The Lp;r
To summarize this section, the fixed points of the deterministic
operators are a special case of LP;r where fP ðpÞ, the PDF for P, is a del-
Lp;r are special cases of the fixed points of the RRGO LP;r . Scaling
ta function centered at p. We can interpret the general LP;r operator
laws for LP;r were presented and shown to be a significant general-
as being one where there is some distribution of self-similarity
ization of their deterministic counterparts. Most importantly, the
which can be described in terms of a probability density for the
RRGOs do not require knowledge of the appropriate value of the
self-similarity index.
self-similarity index. Instead, data may be assimilated from exper-
If XðtÞ is a fixed point of LP;r , then the following scaling laws [36]
iments or simulations via Bayes’ theorem to determine a probabil-
hold. (A fixed point of LP;r is a process XðtÞ such that
ity density for the random self-similarity index. Once fP ðpÞ is
Lp;r XðtjP ¼ pÞ  XðtjP ¼ pÞ, i.e. if after conditioning on P ¼ p; XðtÞ
determined, then so is LP;r and hence scaling laws can be applied.
is a fixed point of Lp;r .)
R 1 s
p  s
p 
1. fX ðx; tÞ ¼ 0 t
fX t x; sjP ¼ p fP ðpÞdp. 8. Discussion
R 1
1=p  r0
1=p 
2. fT ðt; ra; rbÞ ¼ 0 rr0 fT r t; r 0 a; r0 bjP ¼ p fP ðpÞdp. We reviewed and consolidated our recent efforts on upscaling
R 1 h i1=p
3. hTðra; rbÞi ¼ 0 rr0 hTðr 0 a; r0 bÞjP ¼ pifP ðpÞdp. via renormalization groups and central limit theorems. We began
 1 with an example from atmospheric dynamics and showed how
R 1 h i1=p Richardson scaling of dispersive mixing could be obtained if one
4. ka ðrÞ ¼ 0 rr0 ka ðr 0 jP ¼ pÞ1 fP ðpÞdp .
were to model the velocity (not position or force) as a Brownian
In part (4) LP;r is a suitable RRGO for the trajectory given by the dif- process. This example was then generalized, in the spirit of Man-
ference of two particles. When fP ðqÞ ¼ dðp  qÞ, these results reduce delbrot’s intermittency, by letting the velocity be a stable Lévy pro-
to their deterministic counterparts. cess. Subsequently we switched to a three-scale isotropic porous
In practice it may be difficult to determine the probability den- medium example with fractal meso-scale. Central limit theorems
sity for P for which LP;r XðtÞ ¼ XðtÞ. One way to attack this problem were derived and then employed to perform the upscaling. The
is via Bayes Theorem [18]. Bayes’ theorem uses a ‘‘prior’’ distribu- apparent Fokker–Planck equation had a time dependent dispersion
tion for the self-similarity index, combined with experimental data coefficient with fractional spatial derivatives and classical time
to determine an improved ‘‘posterior’’ distribution for the self-sim- derivatives. The generalization to anisotropic media is similar ex-
ilarity index. The posterior distribution is used to define the RRGO. cept the order of the spatial fractional derivatives varies with
In practice the prior distribution for the similarity index comes direction and the dispersion coefficient is a second-order tensor.
from the physics of a given process. We also provided a tool, the finite size Lyapunov exponent, to ob-
Consider the following canonical example: tain the stability constant for a Lévy motion.
Suppose that we wish to upscale the mean first passage time for We then changed directions slightly, and provided some exam-
a Lagrangian particle with trajectory XðtÞ. Assume that we know ples to illustrate how the classical method of characterizing diffu-
fX ðsÞ, the prior distribution for the similarity index, fP ðpÞ; hTða; bÞi, sive processes by their MSD is inadequate. Specifically, we
and that hTða; bÞi is the order of s. Further, assume we know the introduced Brownian motion, Bm-nlc, and fractional Brownian mo-
positions, xi , of a series of independent trajectories at time t. From tion, fBm-nlc, run with nonlinear clocks. Running a stochastic pro-
this information we can generate a posterior density for the simi- cess with a nonlinear clock is novel and allows one to generate
larity index via Bayes’ theorem and apply it to generate the RRGO many counter examples to the standard dogma that exists on dif-
to scale from s to t: fusions. We constructed an uncountable number of processes with
MSD  t1 that were not Brownian and we went onto show how
Qn s
p  s
p 
i¼1 t fX t
xi ; s fP ðpÞ you can construct processes with arbitrary, but known, fractal
fP pjfX i ðtÞ ¼ xi gni¼1 ¼ Q R 1
p 
p  : ð40Þ dimension and independent MSD. These examples illustrate the
n s f s x ; s f ðpÞdp
i¼1 0 t X t i P limitations in the MSD classification scheme.

The right hand side of this equation is written entirely with known
information, while the left hand side is the posterior PDF for the
self-similarity index. By incorporating data for different values of
s and t, it is possible to scale processes that have evolving self-sim-
ilarity. When there is no obvious self-similarity this technique is
still able to upscale the four quantities mentioned earlier.
Consider the following example of a subdiffusive process trans-
forming into a classical diffusive process:
Let X 1=4 ðtÞ ¼ B1=4 ðtÞ þ BðtÞ where BH ðtÞ is an fBm with Hurst
parameter H ¼ 1=4 and BðtÞ is a Brownian motion. We chose the
prior distribution for fP ðpÞ to be uniform on ½1=4; 1=2 because the
fBm is 1=4-self-similar on the short time scale and the Brownian mo-
tion is 1=2-self-similar on the long time scale. We set s ¼ 1, and let
fX ðx; s ¼ 1Þ be equal to the probability density function of a normal
distribution with mean zero and variance two. To obtain the poster-
ior distribution for the self-similarity index density associated with
the transition from s ¼ 1 to some later time t, we applied the Bayes-
ian result, Eq. 40, using 100 positions of independent particles gen- Fig. 1. Scaling behavior of the mean first passage time for X 1=4 ðtÞ ¼ B1=4 ðtÞ þ BðtÞ.
The ‘+’ symbols represent data from direct computations of the mean first passage
erated by XðtÞ. Fig. 1 presents the results of our experiment. The time. The ‘o’ symbols are scaled from hTð1; 1Þi using the RRGO scaling law. The solid
figure makes a comparison between mean first passage times at and dashed lines are scaled using the the renormalization groups R1=2;r and R1=4;r
time t; hTðr; rÞi, using LP;r ; L1=2;r and L1=4;r . As expected the RGOs respectively. Adapted from [35].
214 J.H. Cushman et al. / Advances in Water Resources 62 (2013) 207–214

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