t Ca dCa/dt = rA ln(-rA) ln(Ca) Calculado

60 0.600 -0.00236 -6.05 -0.51 0.6

75 0.542 -0.00224 -6.10 -0.61 0.564316415
90 0.506 -0.00211 -6.16 -0.68 0.531003242
105 0.497 -0.00199 -6.22 -0.70 0.499886772
120 0.475 -0.00186 -6.29 -0.74 0.470807201
135 0.432 -0.00174 -6.35 -0.84 0.443617418
150 0.410 -0.00161 -6.43 -0.89 0.418181921
165 0.382 -0.00149 -6.51 -0.96 0.394375819
180 0.365 -0.00136 -6.60 -1.01 0.372083934

suma error

ESTIMACION LINEAL
m b 1.1253221 -5.4319262
se_m se_b 0.0591609 0.0466019
r2 sey 0.9810202 0.0276639

alfa = 1.1253 ± 0,0592

k= 0.0044 ± 0,0466
 Permite encontrar dCa/dt
0.700
Error
1.23E-32 0.600
4.98E-04 f(x) = 4.17027417027417E-06 x² − 0.002864199134199 x + 0.745063203463204
R² = 0.984244061921627
0.500
6.25E-04
8.33E-06 0.400
1.76E-05
Ca
1.35E-04 0.300
6.69E-05 0.200
1.53E-04
5.02E-05 0.100

0.000
0.001554349 40 60 80 100 120 140 160 180 200
t

Chart Title
-1.10 -1.00 -0.90 -0.80 -0.70 -0.60 -0.

f(x) = 1.12532213691947 x − 5.43192619053504

Ln(-dCa/dt)

R² = 0.981020193632162

Ln(Ca)
le
-5.70
0.70 -0.60 -0.50 -0.40
-5.80
-5.90
-6.00
9053504
-6.10
-6.20
-6.30
-6.40
-6.50
-6.60
-6.70
t Ca t (interpolado) Ca (interpolado) dCa/dt = rA ln(-rA)
60 0.600
75 0.542 67.50 0.57 -0.004 -5.56
90 0.506 82.50 0.52 -0.002 -6.03
105 0.497 97.50 0.50 -0.001 -7.42
120 0.475 112.50 0.49 -0.001 -6.52
135 0.432 127.50 0.45 -0.003 -5.85
150 0.410 142.50 0.42 -0.001 -6.52
165 0.382 157.50 0.40 -0.002 -6.28
180 0.365 172.50 0.37 -0.001 -6.78

ESTIMACION LINEAL
m b 1.355 -5.325
se_m se_b 1.5368 1.2065
r2 sey 0.115 0.591

alfa = 1.3545 ± 1,5368

k= 0.0049 ± 1,2065
ln(Ca) Calculado Error
0.6 1.23E-32
-0.56 0.564893301 5.24E-04
-0.65 0.532512267 7.03E-04
-0.69 0.502595225 3.13E-05
-0.72 0.47491024 8.06E-09
-0.79 0.449251231 2.98E-04
-0.87 0.425434658 2.38E-04
-0.93 0.403296688 4.54E-04
-0.98 0.382690757 3.13E-04

Suma 0.00256

Ln(-dCa/dt) Vs. Ln(Ca)

0.00
-1.10 -1.00 -0.90 -0.80 -0.70 -0.60 -0.50
-1.00

-2.00

-3.00
Ln(-dCa/dt)

-4.00

-5.00

-6.00
f(x) = 1.3545272649272 x − 5.3247845851042
R² = 0.114633988609341 -7.00

-8.00
Ln(Ca)
 0.00
60 -0.50
-1.00

-2.00

-3.00

-4.00

-5.00

-6.00

-7.00

-8.00
 2 ORDEN 1 ORDEN 0 ORDEN 2 ORDEN
t Ca (1/Ca - 1/Cao) LN(Cao/Ca) Ca-Cao Calculado
60 0.600 0.00 0 0.000 0.6
75 0.542 0.18 0.101663654 -0.058 0.556385976
90 0.506 0.31 0.170392986 -0.094 0.518682895
105 0.497 0.35 0.188339629 -0.103 0.485765368
120 0.475 0.44 0.233614851 -0.125 0.456776639
135 0.432 0.65 0.328504067 -0.168 0.431052951
150 0.410 0.77 0.380772496 -0.190 0.408072092
165 0.382 0.95 0.451509047 -0.218 0.38741758
180 0.365 1.07 0.497032302 -0.235 0.368753188

ESTIMACIÓN LINEAL ORDEN 2

m b 0.008709786 -0.521099677
se_m se_b 0.000412596 0.0520264217
r2 sey 0.98453447 0.0479393652

alpha 2
k= 0.0087 ± 0,0004

ESTIMACIÓN LINEAL ORDEN 1

m b 0.003998432 -0.218497509
se_m se_b 0.000172862 0.0217971015
r2 sey 0.987085613 0.0200847796

alpha 1
k= 0.0040 ±0,0002

ESTIMACIÓN LINEAL ORDEN 0

m b -0.00186333 0.0912666667
se_m se_b 0.00010419 0.0131378588
r2 sey 0.978582613 0.0121057837

alpha 0
k= -0.0019 ±0,0001
 1 ORDEN 0 ORDEN 2 ORDEN 1 ORDEN 0 ORDEN
Calculado Calculado error error error
0.6 0.6 0.00E+00 0.00E+00 0.00E+00
0.56507201 0.62795 2.07E-04 5.32E-04 7.39E-03
0.532177294 0.6559 1.61E-04 6.85E-04 2.25E-02
0.501197489 0.68385 1.26E-04 1.76E-05 3.49E-02
0.472021121 0.7118 3.32E-04 8.87E-06 5.61E-02
0.444543206 0.73975 8.97E-07 1.57E-04 9.47E-02
0.418664872 0.7677 3.72E-06 7.51E-05 1.28E-01
0.394293001 0.79565 2.94E-05 1.51E-04 1.71E-01
0.371339898 0.8236 1.41E-05 4.02E-05 2.10E-01

Suma 0.0009 0.0017 0.7249

ORDEN 2
1.20 Se asumió alfa = 2
1.00 f(x) = 0.008709785804961 x − 0.521099677271929
R² = 0.984534470041497
0.80
l(1/Ca - 1/Cao)

0.60

0.40

0.20

0.00
40 60 80 100 120 140 160 180 200
t

ORDEN 1
Se asumió un Alpha=1
0.6

0.5
f(x) = 0.003998432046738 x − 0.218497508859803
R² = 0.987085613100824
0.4

0.3

0.2

0.1

0
40 60 80 100 120 140 160 180 200
 ORDEN 0
Se asumió un Alpha=0
0.000
40 60 80 100 120 140 160 180 200
f(x) = − 0.001863333333333 x + 0.091266666666667
-0.050 R² = 0.978582613052737

-0.100

-0.150

-0.200

-0.250
2
677271929

160 180 200

160 180 200

 160 180 200
7
Mas de segundo orden
t (real) Ca (Real) Ca (calculado) error
60 0.600 0.6000 0.00E+00
75 0.542 0.5580 2.56E-04
90 0.506 0.5210 2.24E-04
105 0.497 0.4881 7.93E-05
120 0.475 0.4588 2.64E-04
135 0.432 0.4324 1.89E-07
Comp
150 0.410 0.4087 1.72E-06
0.700
165 0.382 0.3872 2.68E-05
180 0.365 0.3676 6.79E-06 0.600

0.500
suma 0.0008578 0.400

Ca
0.300

0.200

0.100

0.000
40 60
Calculados
k= 0.007441232
alfa = 1.786092431

Utilice el Solver para variar k y alfa y minimizar el valor de la suma de errores

Comparación entre Ca Real y Ca Calculado

0.700

0.600

0.500

0.400
Ca Real
Ca

0.300 Ca Calculado

0.200

0.100

0.000
40 60 80 100 120 140 160 180 200
t
 MÉTODOS
Diferencial Diferencias Integral
Parámetro
Polinomico Finitas Orden 0
Alpha 1.1253 1.3545 0
Error estandar regresion lineal ±0,0592 ±1,5368 --
K 0.0044 0.0049 0.0019
Error estandar regresion lineal ± 0,0466 ±1,2 ± 0,0001

Sumatoria del eror 0.00155 0.00256 0.72492

 Integral Regresión
Orden 1 Orden 2 no Lineal
1 2 1.7861
-- --- ----
0.0040 0.0087 0.0074
±0,0002 ±0,0004

0.00167 0.00087 0.00086