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c 


cc

  

1. Among the following, the coloured compound is - (a)  

(b)  
(a) c c (b) c c

(c) c

(d) 

(c) c (d) c c c  

8. Hyper conjugation involves overlap of the following


2. uoth c and c ± are diamagnetic. orbital¶s -
The hybridisations of nickel in these complexes, (a) â ± â (b) â ± p
respectively, are - (c) p ± p (d) ʌ ± ʌ
(a) 
 (b) 



(c)  


(d)  

9. „iven that the abundances of isotopes 54Fe, 56Fe and
57

Fe are 5%, 90% and 5%, respectively, the atomic
3. Among the following, the surfactant that will form mass of Fe is
micelles in aqueous solution at the lowest molar (a) 55.85 (b) 55.95
concentration at ambient conditions is - (c) 55.75 (d) 56.06
 
(a) c c 
c 

  10. Among cellulose, poly(vinyl chloride), nylon and


(b) c c 
A



(c) c c c 

 natural rubber, the polymer in which the


intermolecular force of attraction is weakest is
(d) c c 
c 


(a) [ylon (b) Poly (vinyl chloride)


(c) Cellulose (d) [atural Rubber
4. °lectrolysis of dilute aqueous c solution was
carried out by passing 10 mA current. The time
11. The Henry¶s law constant for the solubility of [2 gas
required to liberate 0.01 mol of H2 gas at the cathode
in water at 298 K is 1.0 × 105 atm. The mole fraction
is (1 Faraday = 96500 C mol±1)
of [2 in air is 0.8. The number of moles of [2 from
(a) 9.65 × 104 sec (b) 19.3 × 104 sec
air dissolved in 10 moles of water at 298 K and 5atm
(c) 28.95 × 104 sec (d) 38.6 × 104 sec
pressure is
(a) 4.0 × 10±4 (b) 4.0 × 10±5
5. 2.5 mL of 2/5M weak mono acidic base (Kb=10-12)
(c) 5.0 × 10±4 (d) 4.0 × 10±6
at 25ºC) is titrated with 2/15 M c in water at
25ºC. The concentration of H+ at equivalence point
is (Kw = 1 × 1014 at 25ºC) 12. The complex showing a spin-only magnetic
(a) 3.7 × 10±13 M (b) 3.2 × 10±7 M moment of 2.82 u.M. is

(c) 3.2 × 10±2 M (d) 2.7 × 10±2 M (a) c (b)
c

(c)  (d) c
6. [ative silver metal forms a water soluble complex
with a dilute aqueous solution of c in the
presence of - A[ °R
(a) nitrogen (b) oxygen 1-c, 2-b, 3-a, 4-b, 5-d, 6-b, 7-c, 8-b, 9-b, 10-d, 11-a, 12-b
(c) carbon dioxide (d) argon

7. Aqueous solution of    on reaction with c


gives -
c  
c 
     

  !"


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