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Japan Society of Color Material 90th Anniversary Conference Proceedings

J. Jpn. Soc. Color Mater., 91 [3], 109–111 (2018)

30-year marine exposure test in Suruga Bay-observation of deteriorated surface morphology

Sano true *, † ・ Atsushi Miyata ** ・ Kiyoto Masuda *** ・ Sadahito Tomiyama ＊＊＊＊

* Kansai Paint Co., Ltd. Higashiyawata, Hiratsuka City, Kanagawa Prefecture Four Chome 17-1 (〒 254-8562 )

** Nippon Paint Co., Ltd. Minamishinagawa, Shinagawa-ku, Tokyo 4-1-15 (〒 140-8675 )

*** Dai Nippon Toryo Co., Ltd. Shimoishigami, Otawara City, Tochigi Prefecture 1382-12 (〒 324-8516 )

＊＊＊＊
(PWRI) Public Works Research Institute Minamihara, Tsukuba City, Ibaraki Prefecture 1 address 6 (〒 305-8516 )

† Corresponding Author, E-mail: sano05@als.kansai.co.jp

( 2017 Year 11 Moon 28 Day reception, 2018 Year 1 Moon 28 Accepted by Japan)

Need To the effect

Various heavy-duty anticorrosion coating specifications off the coast of Suruga Bay 30 Yearly exposure results were obtained. From the elemental analysis results of the coating film appearance and the coating film cross section, it was confirmed

that the durability of the system consisting of zinc rich paint + thick film type undercoat + fluororesin paint topcoat was excellent.

keyword : Heavy-duty anticorrosion paint specifications, zinc rich paint

Is. Assuming new specifications Ten Heavy-duty anticorrosion coating system for seeds ( table- 1 ) To
1. 1. O Words
And paint ( 1986 Year), and the progress of deterioration was observed thereafter.

The Marine Technology Research Facility is a permanent facility located off the Oi River in Suruga Bay.
3. 3. Results and discussion
It is a typical marine test facility, and various rust and corrosion prevention tests in the ocean

The test is being conducted. Public Works Research Institute is a paint manufacturer 3 Company (Kansai Pay 3.1 Visual appearance observation

In collaboration with Nto Co., Ltd., Dai Nippon Toryo Co., Ltd., Nippon Paint Co., Ltd.) 1 ) Heavy-duty anti-corrosion coating specifications with zinc rich paint as the undercoat A ， D ，

Using the main steel pipe and diagonal material of the main body, 1984 Heavy-duty anticorrosion coating system at the timeHof，the
I， J ， B ， C Is the same as in the previous survey 30 Edge part over the years
year

And a coating system with a fluororesin paint, which was a new paint at that time, as a top coat Some of them are rusted, but generally rust, swelling, etc.

Various types from the splash zone to the maritime atmosphere No abnormalities were found, and it was confirmed that the rust preventive effect was excellent.

Long-term durability in a corrosive environment 30 Validated for over a year Ta. Especially thick film type inorganic zinc rich paint and excellent blocking performance

ing. In this report, exposure 30 Appearance survey results and coating over the years It turns out that it is effective to combine thick film type paints.

We mainly report the results of elemental analysis of the membrane cross section. Ta. Also, do not use zinc rich paint as an anticorrosion base.

Rust growth from the edges and formation of layered rust compared to the specifications
2. Experimental section
It was recognized as a characteristic phenomenon that this was not done.

Suruga Bay Marine Technology Research Facility Figure- 1 Maritime structure shown in the photo 2 ) Painting specifications that do not use zinc rich paint for the undercoat E ， G ，

F Both have a film thickness 800 μm Designed as above, but the coating film is secured

Rust is generated from the edges that are difficult to rust, and the rust grows in layers.

Was allowed to do. Anti-corrosion base like zinc rich paint

This facility does not have a coating system, even if the total film thickness is increased.

To maintain long-term rust prevention performance in the marine environment where is installed

It turned out to be difficult. the above 1 ) Along with the result

It is possible to preferentially adopt a paint system that uses Nclitch paint.

is necessary.

3 )specification A Then, rusting and peeling of the coating film from damage caused by external causes

Other than this, no defects have been found. Therefore, long-term rust prevention

As a topcoat paint with long-term weather resistance for thick film type undercoat paints

By combining fluororesin paint, beauty is added.

It is a coating system with long-term durability.

Four ) Specifications using ultra-thick film epoxy resin paint J Is a specification H Standard

Figure- 1 Marine Technology Research Facility Supports specifications for special parts such as edges and splicing parts,

It is a material that is expected to be used in areas that are easily corroded. This key

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 110 Japan Society of Color Material 90th Anniversary Conference Proceedings J. Jpn. Soc. Color Mater., 91 [3] (2018)

table- 1 Test heavy anticorrosion coating system ( Ten seed)

specification No. 1 layer No. 2 layer No. 3 layer No. Four layer No. Five layer No. 6 layer Total film thickness

Thick film epoxy resin polyester polyester Fluororesin Fluororesin

A Zinc rich paint Glass flakes Glass flakes Paint topcoat Paint topcoat 815 μ μ m

( 75 μ μ m ) ( 350 μ μ m ) ( 350 μ μ m ) ( 20 μ μ m ) ( 20 μ μ m )
Thick film type For fluororesin paint Fluororesin Fluororesin Fluororesin
B Inorganic zinc rich paint Mist coat Primer Middle coat for paint Paint topcoat Paint topcoat 265 μ μ m

( 75 μ μ m ) ( 100 μ μ m ) ( 50 μ μ m ) ( 20 μ μ m ) ( 20 μ μ m )
Epoxy resin Modified polyester Modified polyester Modified polyester resin
C Zinc rich primer Resin primer Resin paint paint 255 μ μ m

( twenty five μ μ m ) ( 100 μ μ m ) ( 50 μ μ m ) ( 50 μ μ m )

Thick film type Thick film type Vinyl resin paint
D Inorganic zinc rich paint Mist coat Vinyl resin paint Topcoat 255 μ μ m

( 75 μ μ m ) ( 150 μ μ m ) ( 30 μ μ m )
Polyester resin Polyester resin Polyester resin Polyurethane resin Polyurethane resin
E Primer Glass flake paint Glass flake paint Middle coat for paint Paint topcoat 800 μ μ m

( 40 μ μ m ) ( 350 μ μ m ) ( 350 μ μ m ) ( 30 μ μ m ) ( 30 μ μ m )
Epoxy resin Epoxy resin Polyurethane resin Polyurethane resin
F Glass flake paint Glass flake paint Middle coat for paint Paint topcoat 1,100 μ μ m

( 300 μ μ m ) ( 750 μ μ m ) ( 30 μ μ m ) ( 30 μ μ m )
Epoxy resin Epoxy resin Polyurethane resin Polyurethane resin
G Glass flake paint Glass flake paint Middle coat for paint Paint topcoat 1,560 μ μ m

( 750 μ μ m ) ( 750 μ μ m ) ( 30 μ μ m ) ( 30 μ μ m )
Thick film type Thick film type Thick film type Polyurethane resin polyurethane
H Inorganic zinc rich paint Mist coat Epoxy resin paint Epoxy resin paint Middle coat for paint Resin paint topcoat 255 μ μ m

( 75 μ μ m ) ( 60 μ μ m ) ( 60 μ μ m ) ( 30 μ μ m ) ( 30 μ μ m )
Thick film type Thick film type Polyurethane
I Inorganic zinc rich paint Mist coat Epoxy resin paint Resin paint topcoat 255 μ μ m

( 75 μ μ m ) ( 150 μ μ m ) ( 30 μ μ m )
Epoxy resin Ultra-thick film Polyurethane
J Zinc rich primer Epoxy resin paint Resin paint topcoat 2,045 μ μ m

( 15 μ μ m ) ( 2,000 μ μ m ) ( 30 μ μ m )

Figure- 2 30 Surface deterioration state of various coating systems after years (optical microscope observation image)

In the inspection, rust spots were found, but this was due to the large irregularities on the coating film surface. It was a smooth surface. However, both specifications 5 μm Small degree

It is probable that the film thickness of the recess became abnormally thin. Ultra-thick film There is a hole. This is probably due to the pigment falling off.

For shape paint, it is necessary to design and paint with consideration for leveling. specification G Is entirely cracked, from the epoxy glass flake layer

It was suggested that. It seems to be cracked. specification F Is 0.1 ~ 0.5 mm Small cracks

3.2 Observation with an optical microscope It seems that there is a crack from the epoxy glass flake layer. Finish

Specifications with fluororesin paint as the top coat A Is a smooth surface as a whole Mr E Is 0.1 ~ 0.5 mm There are small cracks, and polyester

Met. However, only a small part 10 μm There was a small hole. It seems to be a crack from the le glass flake layer. specification B ,specification C Is

This is thought to be due to the dropout of the pigment. It was a smooth surface.

Specifications with vinyl resin paint as the top coat D Is on the entire surface 30 ~ 50 μm 3.3 Electron microanalyzer (EPMA) observation

There were many holes of the degree. Pigment because the shape of the hole is circular The cross section of the coating film piece collected from the facility body is shown in the electron beam microana.

It is thought that it is not due to the dropout of, but due to bubbles. Liza ( EPMA ) Is used to observe in detail and evaluate the degree of deterioration of the coating film.

Specifications with polyurethane resin paint as the top coat H ,specification I ,specification J Is did. Taking the oxygen and chlorine mapping images as an example, there is no thick film.

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 In Suruga Bay 30 Annual marine exposure test-observation of deteriorated surface morphology 111

[Oxygen mapping] [Chlorine mapping]

Polyurethane resin paint

225 μm
Specification H Epoxy resin paint

Inorganic zinc rich coating

Steel plate

Polyurethane resin paint

Specification G Epoxy resin glass flake paint

1560 μm
Epoxy resin glass flake paint

Steel plate

Figure- 3 EPMA Elemental mapping by

Machine Zinc Rich Paint-Heavy corrosion protection coated with epoxy resin paint On the other hand 250 μm Even if it is a paint type, it can be used as an anticorrosive base.

Painting specifications H Is thought to be the oxidation of inorganic zinc rich paint Those painted with Nclitch paint even rust from the edges

Oxygen element is recognized ( Figure- 3 ), Zn The rust preventive effect of sacrificial anticorrosion Almost no occurrence, and in terms of edge rust prevention

It is presumed that it is expressed. On the other hand, zinc rich paint It was confirmed that the anticorrosion performance of Chi was excellent. EPMA Also confirmed by

Ultra-thick film type specifications that do not use G Then chlorine gets into the membrane, did it.

There is concern about corrosion resistance in thin film parts such as edges, and visual observation results
Xie Resignation
Consistent with.
In the exposure test at the Marine Technology Research Facility, the central area of the Ministry of Land, Infrastructure, Transport

Four. ConclusionTheory
Great cooperation with the Shizuoka River Office of the Maintenance Bureau for facility maintenance, etc.

Thick film zinc rich paint, thick film to ultra-thick film undercoat paint, I received. We would like to express our gratitude to everyone involved.

Durability of the coating system consisting of fluororesin paint topcoat 30 Yearly exposure fruit
Sentence Dedication
Demonstrated in trials. On the one hand, zinc rich coating as an anticorrosion base
1 ) Susumu Moriya: Structure Painting, 34 ( 1 ), 12 ( 2006 ).
If the film is not painted, even if it is an ultra-thick film specification, the edge part
2 ) Masanori Nagai, Susumu Moriya, Koichi Kanai, Tadashi Nakano, Takahide Osawa: No. 29 Revolving steel structure

Rust is generated at, and further progresses to layered rust from that part. So Proceedings of the painting technology debate ( 2006 ).

Results of Marine Atmospheric Environment Exposure Test for Over 30 Years in the Suruga Bay
～ Deteriorated Surface Morphology

Makoto S ano *, †, Atsushi M iyata **, Kiyoto M aSuda *** and Tomonori t oMiyaMa ＊＊＊＊

* Kansai Paint Co., Ltd., 17-1 Higashi-Yawata 4-choume, Hiratsuka, Kanagawa 254-8562, Japan
** Nippon Paint Co., Ltd., 7-16 Minamishinagawa 4-choume, Shinagawa, Tokyo 140-8677, Japan
*** Dai Nippon Toryo Co., Ltd., 1382-12 Shimoishigami, Ohtawara, Tochigi 324-8516, Japan
＊＊＊＊ Public Works Research Institute, 1-6 Minamihara, Tsukuba, Ibaraki 305-8516, Japan

† Corresponding Author, E-mail: sano05@als.kansai.co.jp

(Received November 28, 2017; Accepted January 28, 2018)

Abstract

In Marine Technology Research Institute (on the coast of Suruga Bay), 30-year exposure test results of different heavy duty coating systems were obtained. From paint
film appearance and EPMA results, we confirmed that zinc-rich paint + super high build base coat + fluorocarbon resin paint coating system is excellent. By coating of
zinc-rich paint, corrosion resistance of thin films (for example at edges) is improved.

Key-words: Heavy duty coating systems, Zinc-rich paint

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