UNIVERSIDAD NACIONAL DEL

CENTRO DEL PERÚ

FACULTAD DE INGENIERÍA QUÍMICA
ESCUELA PROFESIONAL DE
INGENIERÍA QUÍMICA
CÁTEDRA: Termodinámica de los Procesos Químicos II
NOMBRE: Canchanya Huaman Yamerson

TAREA 3
disp('Realizado por yamerson canchanya huaman')
disp('=======================================================')
disp('***EQUILIBRIO LIQUIDO-VAPOR DE UN PROCESO ISOBARICO***')
disp('________________________________________________________')
disp('')
disp('________________________________________________________')
T=15;
disp('Las constantes de la ecuación de Antoine)
A=4.64930;B=1395.140;C=182.739;
fprintf('A=%2.5f B=%2.5f C=%2.5f\n',A,B,C)
Pvp1=10^(A-B/(T+C));
disp('Las constantes de la ecuación de Antoine)
A1=3.93646;B1=1257.850;C1=220.767;
fprintf('A=%2.5f B=%2.5f C=%2.5f\n',A1,B1,C1)
Pvp2=10^(A1-B1/(T+C1));
fprintf('T=%2.5f K \n',T)
disp('_____________________________________________________________________')
disp(' x1 x2 Pvp1 Pvp2 P(bar) y1 y2')
disp('_____________________________________________________________________')
a=linspace(0,1,26);
%Datos experimentales
x=[0.0473,0.0797,0.1015,0.102,0.1066,0.2291,0.2917,0.3039,0.3492,0.3633,0.3638,0.3837.
.. ,
0.4933,0.5821,0.5897,0.6242,0.6624,0.6657,0.7458,0.8359,0.8623,0.8831,0.9191,0.92
3,0.9483,0.9751];
y=[0.0719,0.0991,0.0960,0.1012,0.1013,0.1700,0.1420,0.1572,0.1463,0.1671,0.1691,0.1700
... ,
0.1768,0.1647,0.1888,0.1905,0.2011,0.2033,0.2220,0.2470,0.2524,0.2574,0.2834,0.29
36,0.3532,0.4642];
P1=[16.40,16.40,16.40,16.40,16.33,16.27,16.07,16.13,16.00,16.00,15.93,15.87,15.53...
,15.27,15.27,15.07,14.93,14.93,14.40,13.60,13.60,12.53,11.40,11.27,9.33,7.20
for x1=0:0.1:1
x2=1-x1;
P=x1*Pvp1+x2*Pvp2;
y1=(x1*Pvp1)/P;
y2=1-y1;
disp([x1,x2,Pvp1,Pvp2,P,y1,y2])
end
x1=0:0.1:1;x2=[1-x1];
P=x1*Pvp1+x2*Pvp2;y1=(x1*Pvp1)./P;
disp('_____________________________________________________________________')
subplot(1,2,1), plot(a,a,'m',x,y,'ko',x1,y1,'m')
title('Diagrama ELV x1-y1')
subplot(1,2,2), plot(x,P1,'ko',y,P1,'ko',x1,P,'m',y1,P,'m')
title('Diagrama ELV x1,y1-P')
grid