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Lecture 6:
Biopotential Electrodes
This Week in PBS&D
You can’t !
Ag ⇔ Ag + + e − (oxidation )
Ag + + Cl − ⇔ AgCl ( reduction )
Ionic Activity
Relative half-Cell Potentials
E=E +
RT
nF
ln acn +
0
( )
a Ag + × aCl − = K s
0 RT K s
E Ag = E Ag + ln
nF aCl −
E Ag = 0
E Ag +
RT
nF
ln (Ks ) −
RT
nF
( )
ln aCl −
 Apart from the electrode – electrolyte interface, there is also the skin
interface.
 The skin consists of three layers, Epidermis, dermis and
subcutaneous layer. We are most interested at epidermis, as that is
the main contact with the electrode
ª Stratum corneum (I see dead cells…!) Direction of cell aging
ª Stratum granulosum & movement
Skin
Dermis
Yep…You guessed it Right
(The electric Model…)
Ehe
Electrode Cd Rd
Sweat glands
Gel Rs and ducts
Ese EP
If only we could get
Stratum Corneum rid of these ….
Epidermis Ce Re CP RP
Dermis and
subcutaneous layer
Ru
Double-sided
Adhesive-tape
ring Electrolyte gel
in recess
(a) (b)
Snap coated with Ag-AgCl External snap
Gel-coated sponge
Plastic cup Plastic disk
Base
(c)
Examples of microfabricated electrode arrays. (a) One-dimensional plunge electrode array, (b)
Two-dimensional array, and (c) Three-dimensional array
Microelectrodes
A glass micropipet electrode filled with an electrolytic solution (a) Section of fine-bore glass capillary. (b)
Capillary narrowed through heating and stretching. (c) Final structure of glass-pipet microelectrode.
Microelectronic technology
for Microelectrodes
Bonding pads
Silicon probe
Si substrate
Exposed tips
(a) (b)
Miniature
insulating Channels Silicon chip
chamber Hole
Lead via
Silicon probe
Contact
Electrode metal film
(c) (d)
Different types of microelectrodes fabricated using microelectronic technology (a) Beam-lead multiple
electrode. (b) Multielectrode silicon probe (c) Multiple-chamber electrode. (d) Peripheral-nerve electrode