AMOCO MITSUI PTA INDONESIA

Material Safety Data Sheet

Pengenal Cepat (Nama Umum dalam pabrik)

Perusahaan pembuat :
AJAX CHEMICAL
BAGIAN 1- IDENTIFIKASI PRODUK
Nama Umum (digunakan pada label) (Nama Dagang & Sinonim): CAS No:
BENSEN; 71-43-2
Benzene D6 UN : 1114
Nama Kimia : Keluarga Kimia :
BENSEN HidrokarbonAromatik

Rumus Molekul :
C6-H6

URAIAN FISIK / SIFAT

TAMPILAN :
Bening, zat cair dengan bau aromatik. AMBANG BAU 5 ppm
PERINGATAN (BAU/IRITASI) Sedikit – tidak mudah dideteksi dengan bau taua iritasi pada TLV.
Titik didih ......: 80 deg C (176 deg F)
Titik leleh......: 5.5 deg C (42 deg F)
Tekanan Uap.....: 100 mm Hg at 26.1 deg C
SPECIFIC GRAVITY...: (SG) 0.879 at 15 deg C (water = 1)
Titik Nyala........: -11 deg C (12 deg F)
Batas Nyala: No Data
Batas ledakan ...: (LEL) 1.3% - (UEL) 7.1%
Temp. nyala otomatis ..: 498 deg C (928 deg F)
Tekanan uap REL.: 2.7 (air = 1)
Berat MOLEKUL...: 78.11
pH.................: Tidak digunakan
Bentuk ...............: Cairan

OTHER PROPERTIES:
CONVERSION FACTOR 1 ppm = 3.242 mg/m3; 1 mg/m3 = 0.3085 ppm at 20 deg C
SAT. VAPOUR CONC. 13% or 130000 ppm (calculated at 26.1 deg C)
EVAPORATION RATE Not available
CRITICAL TEMPERATURE Not available
SOLUBILITY IN WATER Slightly soluble (about 0.7 g/litre of water)
SOLUBILITY IN OTHER LIQUIDS Miscible with: alcohol, chloroform, ether,carbon disulfide, acetone, oils, carbon tetrachloride and glacial
aceticacid.
OCTANOL/WATER PARTITION COEFFICIENT (P): log P = 1.56-2.15 VISCOSITY: 0.6468
mPa.S at 20 deg C BLOOD/AIR PARTITION COEFFICIENT: 7.8

USE:
Used in the manufacture of medicinal chemicals, dyes, plastics, textiles,detergents, artificial leather, varnishes, paints, lacquers, waxes and
manyother materials. Solvent for inks, paints, rubber, adhesives, coatings,detergent and pesticides. Benzene is found in coal tar
distillates,petroleum naphtha and gasoline.

“No Data” in IDENTIFICATION means data not applicable in this field. In all other fields, it means not available
BAGIAN 2- INFORMASI BAHAYA TERHADAP KESEHATAN
ACUTE EFFECTS
SWALLOWED:
Moderate doses can cause dizziness, excitation and pallor, followed byflushing, weakness, headache, breathlessness, and feelings of
constrictionin the chest. Visual disturbances are frequent. Large doses can causestaggering gait, vomiting, sleepiness, shallow and rapid pulse,
anddelirium. In severe cases, unconsciousness, convulsions and death may occur.Severe lung damage (chemical pneumonitis) may occur if
ingested benzene isaccidentally drawn into the lungs (aspirated).
EYE:
No human data. Benzene might irritate the eyes.
SKIN:
Benzene is absorbed slightly through the skin. By defatting the skin it cancause irritation, inflammation, blistering, drying and scaling.
INHALED:
Benzene acts on the nervous system. It can cause drowsiness, dizziness, headache, lightheadedness, nausea, and decreased coordination.
Benzenevapour can cause mild irritation of the respiratory tract. Very high levelscan cause decreased judgement, feelings of well-being, loss of
balance and ringing ears (tinnitus). Unconsciousness or death may result.
CHRONIC EFFECTS
HEALTH EFFECTS BLOOD AND BLOOD-FORMING SYSTEM: Benzene can impair thformation of red and white blood cells and
platelets. There may beconsiderable variability from person to person in the specific types of cells affected and the extent of deficiency. The
bone marrow (where bloodcells are made) may be affected. The severity of the disease is not directlyrelated to the duration or intensity of
exposure. NERVOUS SYSTEM: Prolongedlow level exposure can damage the nervous system characterized by impairmentof hearing,
chronic headache, dizziness, fatigue, visual disturbances,decreased balance and pallor. SKIN: Repeated or prolonged contact can cause
inflammation, dry scaling and blisters. Prolonged exposure may cause lesions
resembling first or second degree burns.
CARCINOGENICITY Benzene can cause cancers of the white blood cells(leukemias). Cancer may or may not be preceded by other blood
disorders.
TERATOGENICITY AND EMBRYOTOXICITY Benzene crosses the placenta and is present in the foetal blood. It can cause menstrual
disorders.
MUTAGENICITY Benzene can cause chromosomal aberrations in heavily exposed workers. The significance of such mutagenic effects are,
at the present notvery well understood.
POTENTIAL FOR ACCUMULATION Some absorbed benzene is exhaled in the breath.Most is transformed and excreted in the urine.
Benzene is stored temporarily in fat. The elimination of benzene may take more than five days afterexposure has stopped.
FIRST AID
SWALLOWED:
Never give anything by mouth if victim is rapidly losing consciousness, or is unconscious or convulsing. Have victim rinse mouth thoroughly
with water . DO NOT INDUCE VOMITING. Have victim drink 240 to 300 mL (8 to 10 oz.) ofwater. If vomiting occurs naturally, have victim
lean forward to reduce risk of aspiration. Repeat administration of water. If breathing has stopped, trained personnel should begin artificial
respiration or, if the heart has stopped, cardiopulmonary resuscitation (CPR) immediately. Obtain medical attention immediately.
EYE:
Immediately flush the contaminated eye(s) with lukewarm, gently flowing water for 20 minutes, by the clock, holding the eyelid(s) open. Take
care not to rinse contaminated water into the non-affected eye. Obtain medical attention immediately. Protect the contaminated eye(s) from
light if painful.
SKIN:
Remove contaminated clothing, shoes and leather goods (e.g. watchbands,belts). Wash gently and thoroughly with water and non-abrasive
soap. If irritation persists, obtain medical attention immediately. Completelydecontaminate clothing, shoes and leather goods before re-use or
discard.
INHALED:
Take proper precautions to ensure your own safety before attempting rescue; e.g., wear appropriate protective equipment, use the "buddy"
system. Remove source of contamination or move victim to fresh air. If breathing has source of contamination or move victim to fresh air. If
breathing has stopped, trained personnel should begin artificial respiration or, if the heart has stopped, cardiopulmonary resuscitation (CPR)
immediately. Obtain medical attention immediately.
FIRST AID FACILITIES:
Provide general supportive measures (comfort, warmth, rest). Consult a physician and/or the nearest Poison Control Centre for all exposures
except minor instances of inhalation or skin contact. All first aid procedures should be periodically reviewed by a physician familiar with the
material and its conditions of use in the workplace.
ADVICE TO DOCTOR:
No Data
TOXICITY DATA:
ANIMAL TOXICITY DATA LD50 (oral, rat): 4894 mg/kg LD50 (oral, rat): 5.6 g/kg
LC50 (rat): 16000 ppm/4 hr LC50 (rat): 10000 ppm/7 hr SKIN AND EYE
IRRITATION: Pure benzene applied to rabbit skin caused slight to moderate skin irritation. When applied in the eyes, it caused a moderate to
severe eye irritation and temporary corneal injury. REPRODUCTIVE EFFECTS: In several animal species, doses which are toxic for the
mother have not caused birth defects or fetal death. It may cause reduced fetal weight and retarded growth. There is some indication of
fetotoxicity with doses which are not necessarily toxic to the dam (1). EFFECTS ON THE BLOOD: Rats exposed to 200 ppm, 8 hours per
day, 5 days per week for 90 days, developed a severe decrease in the number of white blood cells (leukopenia) (1).
Oral Lowest Lethal Dose(man): 50 mg/kg
Inhalation LCLo(human): 2 ppm/5 min

“No Data” in IDENTIFICATION means data not applicable in this field. In all other fields, it means not available
BAGIAN 3 –TINDAKAN PENCEGAHAN
EXPOSURE STANDARDS:
(TLV-TWA) 5 ppm (16 mg/m3); Worksafe Aust.
BIOLOGICAL EXPOSURE INDICES (BEIs): The ACGIH has adopted a BEI for this chemical. BEIs provide an indication of worker
exposure by measuring the chemical or its breakdown products in the body or by measuring biochemical changes resulting from exposure to
the chemical. Consult the BEI documentation for further information. SAMPLING & ANALYSIS Use appropriate instrumentation and
sampling strategy (location, timing, duration, frequency, and number of samples). Interpretation of the sampling results is related to these
variables and the analytical method. COLORIMETRIC-INDICATING (DETECTOR) TUBES: Commercially available
DIRECT READING INSTRUMENTS: Commercially available devices: portable flame ionization meter; portable gas chromatograph;
portable spectrophotometer; UV air sampling analyzer.
EXPOSURE CONTROL Note: Exposure to this material can be controlled in many ways. The measures appropriate for a particular worksite
depend on how this material is used and on the extent of exposure. Use this general information to help develop specific control measures.
Ensure that control systems are properly designed and maintained. Comply wit occupational, environmental, fire, and other applicable
regulations. *Category 1 Carcinogen, Worksafe Aust. - Established human carcinogens are those substances known to be carcinogenic to
humans. There is sufficient evidence to establish a causal association between human exposure to these substances and the development of
cancer.

ENGINEERING CONTROLS:
Maintain concentration below recommended exposure limit.
ENGINEERING CONTROLS Engineering control methods to reduce hazardous exposures are preferred. Methods include mechanical
ventilation (dilution and local exhaust), process or personnel enclosure, control of process conditions, and process modification (e.g.,
substitution of a less hazardous material). Administrative controls and personal protective equipment may also be required. Because of the
high potential hazard associated with this substance, stringent control measures such as enclosure or isolation may be necessary. Use a non-
sparking, grounded ventilation system separate from other exhaust ventilation systems. Exhaust directly to the outside. Supply sufficient
replacement air to make up for air removed by exhaust systems.

PERSONAL PROTECTION:
RESPIRATORY PROTECTION
If engineering controls and work practices are not effective in controlling exposure to this material, then wear suitable personal protective
equipment including approved respiratory protection. Have appropriate equipment available for use in emergencies such as spills or fire. If
respiratory protection is required, institute a complete respiratory protection program including selection, fit testing, training, maintenance
and inspection.

RESPIRATORY PROTECT. RECOMMENDATIONS FOR BENZENE VAPOUR CONCENTRATIONS:

AT ANY DETECTABLE CONCENTRATION: Self-contained breathing apparatus with a full facepiece and operated in a pressure-demand
or other positive-pressure mode. Supplied-air respirator with a full facepiece and operated in pressure-demand or other positive-pressure
mode in combination with an auxiliary self-contained breathing apparatus operated in pressure-demand or other positive-pressure mode.
ESCAPE: Air-purifying full facepiece respirator (gas mask) with a chin-style or front- or back-mounted organic vapour canister.Appropriate
escape-type self-contained breathing apparatus.

EYE/FACE PROTECTION :
Chemical safety goggles. A face shield may also be necessary.

SKIN PROTECTION :
Impervious gloves, coveralls, boots, and/or other resistant protective clothing. Have a safety shower/eye-wash fountain readily
available in the immediate work area. An impervious full-body encapsulating suit and respiratory protection may be required in some
operations. Work clothes should be changed at least twice weekly.

RESIST. FOR PROTECTIVE CLOTHING (Guidelines for related materials.)

VERY GOOD: Viton GOOD: NBR POOR: Butyl rubber, natural rubber, neoprene,nitrile rubber, polyethylene, polyurethane, PVA, PVC
NOTE: Resistance of specific materials can vary from product to product. Evaluate resistance under conditions of use and maintain clothing
carefully.

PERSONAL PROTECTION COMMENTS

Remove contaminated clothing promptly. Keep contaminated clothing in closed containers. Discard or launder before rewearing. Inform
laundry personnel of contaminant's hazards. Do not smoke, eat or drink in work areas.

FLAMMABILITY:
Highly flammable.

ENVIRONMENT:
Pollutant. Contain.

“No Data” in IDENTIFICATION means data not applicable in this field. In all other fields, it means not available

SECTION 4 – SAFE HANDLING INFORMATION

STORAGE AND TRANSPORT:
STORAGE CONDITIONS Store in a cool, dry, well-ventilated area, out of direct sunlight, away from incompatible materials and heat and
ignition sources.Store in suitable, labelled containers. Keep tightly closed when not in use and when empty. Protect from damage. Use
suitable, approved storage tanks, buildings, rooms and cabinets. Consider leak detection and alarm systems, as required. Use non-sparking
ventilation systems and electrical equipment that does not provide an ignition source. If storing small quantities under refrigeration, use an
approved, explosion-proof refrigerator. Limit quantity of material in storage. Restrict access to storage area. Post warning signs when
appropriate. Keep storage area separate from populated work areas.
Inspect periodically for deficiencies such as leaking containers. Comply with all applicable regulations for the storage and handling of
flammable materials.
HANDLING Use approved flammable liquid storage containers in the work area.
Ground drums and bond transfer containers. (Grounding clips must contact bare metal.) Keep material away from sparks, flames and other
ignition sources. Post "NO SMOKING" signs in area of use. Do not use near welding operations, flames, or hot surfaces. Prevent release of
vapours into workplace air. Use smallest possible amounts in designated areas with
adequate ventilation. Have emergency equipment (for fires, spills, leaks, etc.) readily available. Label containers. Keep containers closed
when not in use. Empty containers may contain residues which are hazardous. Not to be loaded with Class 1, 2.1, 2.3, 4.2, 5.1, 5.2, 6*, 7. (*
where flammable liquid is nitromethane).
Packaging and Labelling:
As required by the ADG Code.
As required by the Standard for the Uniform Scheduling of Drugs and Poisons.
SPILLS AND DISPOSAL:
PRECAUTIONS Restrict access to area until completion of clean-up. Ensure clean-up is conducted by trained personnel only. Wear adequate
personalprotective equipment. Ventilate area. Extinguish or remove all ignitionsources. Notify authorities.
CLEANUP Do not touch spilled material. Prevent material from entering sewer or confined spaces. Stop or reduce leak if safe to do so.
Contain spill with earth, sand, or absorbent material which does not react with spilled material. Small spills: Soak up spill with absorbent
material which does not react with spilled chemical. Put material in suitable, covered, labelled containers. Flush area with water.
Contaminated absorbent material may pose the same hazards as the spilled product. Large spills: Contact fire and emergency services and
supplier for advice.
DISPOSAL Review federal, state and local government requirements prior to disposal. Disposal by controlled incineration may be
acceptable.
FIRE/EXPLOSION HAZARD:
FIRE EXTINGUISHING AGENTS Dry chemical, foam, carbon dioxide Water may be ineffective due to the low flash point.
FIRE FIGHTING PROCEDURES Use water to keep fire-exposed containers cool.
Vapours are heavier than air and can accumulate at ground level; vapours may travel considerable distance to source of ignition and
flashback.
COMBUSTION PRODUCTS Carbon monoxide and carbon dioxide
PROTECTIVE CLOTHING Firefighters to wear full body protective clothing with breathing apparatus.
CONSIDER EVACUATING AREA
Reactivity Data:
STABILITY Normally stable
INCOMPATIBILITY -MAT'LS TO AVOID STRONG OXIDIZING AGENTS (e.g. chlorine,
bromine, pentafluoride, chlorine trifluoride, diborane, nitric acid, nitryl
perchlorate, liquid oxygen, ozone, silver perchlorate) - May react
explosively.
HAZARDOUS POLYMERIZATION Does not occur
CORROSIVITY TO METALS Not corrosive

This MSDS summaries our best knowledge of the health and safety hazard information of the product and how to safely handle and
use the product in the workplace. Each user should read this MSDS and consider the information in the context of how the product will
be handled and used in the workplace including its use in conjunction with other product. If clarification or further information is
needed to ensure that an appropriate risk assessment can be made, the user should contact Ajax Chemicals. Our responsibility for
products sold is subject to our standard term and conditions, a copy of which is sent to our customers and is also available on request.