MODEL SOLUTIONS TO IIT JEE 2011

Paper I
1 2 3 4 5 6 7
A D A B D C C

8 9 10 11
A, B, D A, D A, C, D A, B, C

12 13 14 15 16
D B B A C

17 18 19 20 21 22 23
9 5 5 4 6 5 7

Section I O

1. 27 Al + 4 He → 30 P + 1n( Y ) C
13 2 15 0
↓ ↓ N CH2 Br
30 Si + 1H( X ) 30 Si + 0 e( Z )
14 1 14 1 C

+ O
2. Since the mobility of K is nearly same as that of
+
Ag which it replaces, the conductance will 2– 2–
4. [NiCl4] is tetrahedral, [Ni(CN)4] is square
remain as more or less constant and will 2+
planar & [Ni(H2O)6] is octahedral.
increase only after the end point.
5. Ba(N3)2 → Ba + 3N2
O
Very pure N2 is produced by the thermal
3. C decomposition of Barium or sodium azide.
KOH
NH 2 × 1.15 × 1000
6. M=
C 1120
= 2.05 M
O
O
7. o-hydroxy benzoic acid: pKa = 2.99
C p–hydroxy benzoic acid: 4.58
Br CH2 Cl
p–toluic acid = 4.34
NK p–nitrophenol = 7.15
C
Section II
O
8. Adsorption is always exothermic.
Chemisorption is more exothermic than
physisoprtion and it requires activation energy.
9. A, D
Section IV
10. Cassiterite contain 0.5 – 10% of metal as SnO2
the rest being impurities of pyrites of Fe, Cu & 17. Maximum no. of electron with n = 3 is 18, of
wulframite. which are having −1 spin
2
11. In a, b & c all atoms are in the same plane.
18. 3Na2CO3 + 3Br2 → 5NaBr + NaBrO3 + 3CO2
Section III
19.
H3C dil.H2SO4 Br
H3C C C CH HgSO 4
12. alc.KOH
H3C (P) C CH2 CH 2 CH3
CH3 CH 2
H 3C (i) NaBH4
H3C C C CH3
(ii) dil.acid
H3C O
OH CH3 CH C CH 2 CH2 CH3
H 3C (2 isomers)
H3C C C CH 3
H3C
H (Q)
CH3 CH2 C CH CH2 CH3
(2 isomers)
OH
H3C
H+
13. H3C C C CH3
(-H2 O) C CH2 CH 2 CH3
H3C CH3 CH2
H (1 isomer)
H 3C
1, 2-shift
H3C C C CH3
of -CH3
H3C H
(2°) 6.626 × 10−34 × 3 × 108
20. hυ =
CH3 300 × 10 −9 × 1.6 × 10 −19
H3C -H +

C C CH3
= 4.14 eV
H 3C
H
CH3 CH3 ozonolysis E = hυ – hυ0
C C For Li, Na, K and Mg hυ0 values are less than
CH3 CH3
4.14 eV
O
2
C 21. Let the number of glycine units be x
H 3C CH3 Total mass of the hydrolysed products
= 796 + 9 × 18 = 958
75 x × 100
% by mass of glycine = = 47
1 958
14. 2AgNO3 + Cu → Cu(NO3)2 + Ag
2 ∴x=6
The metal dipped is Cu.
22. S4O26− has sulphur atoms with oxidation states
2+
Blue colour due to formation of Cu
‘0’ & +5.
15. The solution in which the metal is dipped in
AgNO3. 2.24
23. Vol. of 0.1 mole at 0.32 atm = =7L
0.32
16. The deep blue colour due to formation of
2+
[Cu(NH3)4] and the white precipitate of AgCl
+
dissolve due to formation of [Ag(NH3)2]
 PART II

24 25 26 27 28 29 30
D D D A A A B

31 32 33 34
B, D A, B, C, D A, B, C, D A

35 36 37 38 39
C B D C B

40 41 42 43 44 45 46
3 5 6 3 9 4 1

Section I 1  1 1 
= Z2R 2 − 2 
λ2 2 4 
24. x component of area vector is
5
a2 E 0a 2
∴φ = λ2 = λ1 × 36 × 22
2 2 3
16
2 0
25. T sinθ = mω Lsinθ
T = 1215 A
324 L
ω= θ
0 .5 × 0 .5 X 52 + 1
30. =
= 36 10 48 + 2
mg
Section II
26. Position (1): Let charge on 2 µF be Q. Then
Q2 31.
energy = µJ
4 electron
•B
Position (2): Ceq = 10 µF
Q2
Total charge = Q. ∴ Energy = µJ
20
Loss % = 80%
proton
1
27. n = (Θ 22.4 λ = 1 mole)
4 2πm
T= , different for them.
1 3 qB
W = nCV∆T = × R.∆T
4 2
T1V1γ − = T2V2γ − ⇒
1 1 dQ
32. is same for A and E and both are maximum.
T2 = 4T1 ∴ ∆T = 3T1 dt
   λ 
  Thermal resistances   are as below.
28. f’ = 
f  × 1 + v 0   KA 
 vs   c 
 1−  RB
 c 
8 × (320 + 10 ) RC
=
320 − 10 RA RE
RD

1  1 1  1 4 1 4
29. = R 2 − 2  RA = , RB = , RC = , RD =
λ1 2 3  8 3 2 5
1
RE = . So C is also correct.
24
 1 1/ 3
(Θ Eq.R (RC, RB, RD) is .  q2  4+ 2 
4 ⇒a=    
 r   16 πε0 
D also correct Θ RB parallel    
RD is equal RC ⇒N=3
Note: It is assumed that there is no radiation
loss. 41. Fd = mg sinθ − µmg cosθ
Fu = mg sinθ + µmg cosθ
33. On interconnecting V same Fu = 3Fd
Q Q 1
⇒ A = B ∴ (B) correct. ⇒µ=
R A RB 2
σR 1
V= is standard formula ∴ N = 10 µ = 10 × = 5
ε0 2

∴ (C) correct
V V 42. L
V same ⇒ EA = , EB = x x x x x x x x
RA RB
B
∴ (D) correct.
−−−−−−−−−−

34. Under case (B) eventhough the disc is free to µ0 Ι

rotate, it will not rotate. ∴ Cases (A) and (B) are B=
L
identical in all respects.
µ0 πr 2gΙ
φcoil = Bπr =
2
L
Section III dφ E
− = E, i = ; M = iπr
2
dt R
 e2 
35. [N] = L−   = Force × area
3 ⇒N=6
 ε0 
MgL
43. ∆λ =
36. Find ω by the given formula AY
c L’ = L + ∆λ
λ=
ω L'  Mg 
⇒ = 1 + 
2π L  AY 
L'−L
α=
37. As ball goes up, x is positive and increasing, v is (L × 40 − L'×30 )
positive and decreasing. Symmetrical for ball Mg
=
coming down.   Mg  
AY 40 − 1 + 30 
  AY  
p2 Solving, we get M ≅ 3 kg
38. At x = 0, E = K.E =
2m
∴ E varies as p
2
2  2 
44. N × 10− = 2  mr 2 + md2  + 2  mr 2  ;
4
∴ E1 = 4E2  5   5 
4 2
× 10− = 2 2 × 10− m
2 2
39. Starting from positive positions (i.e. in air), Here d =
2
amplitude in air will be more than amplitude in
5 1
water. Momentum is negative for downward × 10− m; m = kg
2
r=
journey. Also water produces damping. 2 2
⇒ graph is spiralling in. ⇒N=9

Section IV 45.
a = 0.3

40. U =
q2
4πε0a
[
4 + 2 + 2a r
2
] α
2N
f2

f1
dU
For equilibrium, =0
da
 f1R − f2R a ∴ M = mN0 = 10− × 10 kg
25 19
α= ,α=
= 10− × 10 × 10 mg
2 25 19 6
mR R
f1 − f2 2 − f1 = 1 mg
⇒ = a = 0 .3 = ,m=2
m m
⇒ f1 = 1.4, f2 = 0.8 ⇒ µ.2 = 0.8 ⇒ µ = 0.4

s−
10 1
46. A0 = |−λN0| = 10
1010
∴ N0 =
λ
= 10 × 10 = 10
10 9 19
 PART III

47 48 49 50 51 52 53
C B B A C D C

54 55 56 57
QUESTION
B,D A,D B,C
INCORRECT

58 59 60 61 62
B D D A B

63 64 65 66 67 68 69
7 9 8 6 1 2 5

Section I (b − 1)3 1
= +
3 3
ρ
47. Let v = Ai + B j + C k 1
 ( x − 1)3 
1

∫
R2 = ( x − 1) dx =  2
a×b. v = 0 
b  3 b
1 1 1
1  (b − 1)3 
1 −1 1 = 0 R1 − R2 = gives = 0 −  
A B C
4  3 

2 0 2 2(b − 1)3 1 1
+ =
⇒ 1 −1 1 = 0 3 3 4
1
A B C ⇒b= satisfies the above equation.
2
⇒ 2 (− C − B) + 2 (B + A) = 0
⇒A=C
49. y + 2 = m (x – 3)
For the vector in (C),
and m = 3
A=C
(
Projection of 3i − j + 3k on C ) y+2= 3 (x – 3)
3 + 1− 3 1 y- 3 x+2+3 3 =0
= =
3 3
ln 3
x sin x 2
48.
y
50. Let I = ∫ sin x 2 + sin (ln 6 − x 2 )
dx
ln 2

Set x = t
1
dx = dt
2 t
x= ln 2 , t = ln2
x x= ln 3 , t = ln3
0 b 1 ln 3
t sin t 1
⇒I= ∫ ×
sin t + sin(ln 6 − t ) 2 t
dt
ln 2
ln 3
b 1 sin t dt
∫
b
( x − 1) 3 =
sin t + sin (ln 6 − t )
∫ (x − 1) dx = 
2
R1 =  2
ln 2
0  3  0
 ln 3 But if
1 sin(ln 6 − t )
=
2 ∫ sin (ln 6 − t ) + sin t
dt The question is reframed in the following
manner;
ln 3
1
2I =
2 ∫ dt “ Let M and N be two nonsingular skew-
ln 2 symmetric matrices…………”
1 3
= log
2 2 The solution is
1 2 2 -1 -1 -1 T
I = log 3 M N (M N) (MN )
4 2 2 2 -1 -1 T T
= M N (-MN) (N ) M
2 2 -1 -1 -1 T -1
= M N (-N M ) (N ) (-M)
log x log 2 2 2 -1 -1 -1
51. = = M N N M (-N) M
log y log 3 2 2 -1
=-M N N M N M=-M NM N M
-1 -1 2 -1 -1
k
⇒ log x = k log 2 ⇒ x = 2 2
= - M N (N M) M
-1
k
log y = k log 3 ⇒ y = 3 2
= - M N(M N) M
-1

(2 )log 2 = (3 )log 3
k +1 k +1 2
=-M NN M M
2
-1 -1

k +1 k +1 =-M
2log 2 = 3log 3
2 2
Choice (c)
⇒ ( k +1) (log2) = (k+1) (log 3)
⇒
k = −1
x 2 y2
⇒ x0 = 2− = 12 + =1
1
55. For
4 1
3
  π  e= and focus = (± 3 ,0)
52. P = θ : sin  θ −  = cos θ 2
  4  
x2 y2 2
  3π  ∴ for 2
− = 1, e =
⇒P = θ : cos θ = cos  − θ  a b2 3
  4  2
b 1
  3π  ⇒ 2
=
∴ P = θ : θ = 2nπ ±  − θ  a 3
  4 
Substitution ( 3,0), a 2 2
= 3, b = 1
 3π 
= θ : θ = nπ +  Focus (2, 0)
 8 
x2
 π π  ∴ required hyperbola is − y2 = 1
Q = θ : θ − = 2nπ ±  − θ  3
 4 2 
 3π  56. j − k = i + j + k  (i + j + 2k)
= θ : θ = nπ + 
 8  & k − j = i + j +2k  (i + 2j +k)
∴P=Q ∴ j − k, k − j coplanar with the given vectors
1 −1 0 1 0 0
a10 − 2a8 α10 − β10 − 2 α 8 − β8 ( ) and ± 1 1 2 = ± 1 1 3 ≠ 0
53.
2a9
=
( 9
2α −β 9
) 1 2 1 0 1 −1
(A) and (D) true.
α8 (α 2 − 2) − β8 (β2 − 2)
=
2(α9 − β9 )
57. f (x +y) = f (x) +f(y)
α8 ,6α − β8 6β ⇒ f(x) = kx
=
(
2 α9 − β9 ) f(x) is continuous ∀ x ∈R
6(α9 − β9 ) and f’ (x) = k
= =3
2(α9 − β9 )

Section II

54. Skew symmetric matrix of order 3 is singular. Its

inverse does not exist. Therefore there is
NO SOLUTION TO THIS QUESTION.
 a + 48 + 7c = 0
Section III a+6+c=0
Solving a = 1 and c = - 7.
∴ The equation is x + 6x – 7 = 0
2
For problems (58) and (59)
1 1 α+β 6
3 ∴ + = = <1
1 α β αβ 7
W 5 ∞ n
1 1
1 ∑  α + β  (is an infinite geometric progression) =
2 n =0
R 1
2 a 1
H = =7
5 2 1− r 6
1−
7

1
1 Section IV
10
T 2W π
63. θ =
3 n
1 2R 1
1 1 1
2 10 3 = +
sin θ sin 2θ sin 3θ
1R+1W 3 2 1 1 1
3 − =
5 sin θ sin 3θ sin 2θ
sin 3θ − sin θ 1
58. Probability =
sin θ sin 3θ sin 2θ
1 3 2 1 3 1 1 3 2
=  × 1+ × + × 1+ × + × 2 cos 2θ 1
2 5 5 2 10 10 3 5 3  =
sin 3θ sin 2θ
1 3 1 3 1 2 ⇒ 2 sin2θ cos2θ = sin3θ
= + + + +
2  5 5 10 30 5 

sin4θ −sin3θ = 0
1 46 23 7θ θ
= × = ⇒ 2 cos sin = 0
2 30 30 2 2
7π π
⇒ 2 cos sin =0
1 3 1 2n 2n
×1+ 25 × 
2  5 7π  π
=  (2k + 1) 
2
59. Probability =
23 2n  2
30 7
12 ⇒n=
= 2k + 1
23
For positive integral values of n
k = 0 or 3
60. 7(a + b+ c) = 0 , ⇒ a + b + c = 0 put k = 0, n = 7
also 2a + b + c = 1
⇒ a = 1, b + c = −1
∴ 7a + b + c = 7 − 1 = 6 sm
5n
[6 + (5n − 1) (a2 − 3)]
64. m = 5n; = 2
sn n
[6 + (n − 1) (a2 − 3)
1 3 2
61. x − 1 = 0 and Im(ω) > 0 ⇒ ω = − +i
3
2 2  9 − a2 + 5n (a2 − 3) 
=5  
a = 2 ⇒ 2 + 8b + 7c = 0  9 − a2 + n (a2 − 3 ) 
14 + 7b + 7c = 0 9 − a2 + 5 (a2 − 3) (9 − a2 ) + 10(a2 − 3 )
∴ = , is
(taking first and third columns) 9 − a2 + a2 − 3 9 − a2 + 2 (a2 − 3 )
Solving we get b = 12 and c = − 14
independent of n
3 1 3
∴ The equation in 2 + 12 + −14 4a2 − 6 9a2 − 21
ω ω ω =
6 a2 + 3
= 3ω + 1 + 3ω
2
(2a2 − 3) (a2 + 3) = (3a2 − 7)
= 3 (ω + ω ) + 1 = − 2
2
2a22 − 24a2 + 54 = 0
Correct choice (a)
a22 − 12a2 + 27 = 0
st rd
62. b = 6. Taking 1 and 3 columns we get a2 ≠ 3, a2 = 9
 a −5 + a −4 + a −3 + a −3 + a −3 + 1 + a8 + a10 68. Extremum point of latus rectum are (2,4) and
65.
8 (2,−4)
1 
( ( ) )
1
∴ Area of triangle so formed with  ,2 
≥ a−5a− 4 a−3 13 a8a10 8 =1 2 
⇒ minimum value of sum = 8. 1
∆1 = (y1 −y2) (y2−y3) (y3−y1)
8a
x 1
(4+4) (−4 −2) (2 −4) = 6
∫ =
3
66. 6 f ( t )dt = 3x f(x) – x 8 .2
1
2
Eqn. of tangent at (2,4) is y = x +2 _______(1)
6f(x) = 3xf’(x) + 3f(x) – 3x Eqn. of tangent at (2, −4) is −y = x +2 _____(2)
2
f(x) = xf’(x) – x 1 
dy Eqn. of tangent at  ,2  is y = 2x +1 _____(3)
y= x − x2 2 
dx
dy dy y Tangent at the extremities of latus rectum
x − y = x2 ⇒ − =x intersect directrix at (−2, 0).
dx dx x
1 Point of intersection of (1) and (2) is (1,3) and of
∫
I. F = − dx
x (2) and (3) is (−1, −1)
e 1 −2 0
1 1 1
∴
x ∫
= x dx = x + c
y.
x
∆2 = 1 1
2
3 = −3 = 3
1 −1 −1
y = x(x + c) = f(x)
∆1 6
f(1) = 2 ⇒ 2 = 1 + c ⇒ c = 1 ∴ = =2
∴ f(x) = x(x + 1) ⇒ f(2) = 6 ∆2 3

 sin θ  69.
67. f(θ) = sin tan
-1
 
 cos 2θ  3,2
 
 sin θ 
tan tan−1 
 cos 2θ 
=
−1 sin θ
1 + tan2 (tan
cos 2θ −5
3,
sin θ 2
cos 2θ sin θ 5
minimum of 2 z − 3 + i
= =
2
cos 2θ + sin θ 2
cos θ − sin2 θ + sin2 θ
2

cos 2θ 5 
= 2  + 2 − 2 = 5
= tan θ 2 
d(f ( θ))
⇒ =1
d(tan θ)