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Section: 9AM or 10 AM
_____ 1. Which weak acid, when dissolved in water at 1.0M, would form the
solution with the highest pH?
_____ 2. Which weak acid would be the best choice to create a buffer with a pH of
5.6?
_______________ 3. Identify ALL the diprotic weak acids in the list above.
_____ 4. Identify the weak acid from the list above who’s conjugate base will have a
kb of 5.6x10-11.
_____ 5. The solubility of which of the following inorganic salts will not be affected
by a change in the pH of the solution?
A) BaC2O2
B) CaF2
C) AgBr
D) PbF2
E) PbS
______ 6. Of the following, only _____ forms a useful buffer system.
A) Co(OH)2
B) Cu(OH)2
C) Zn(OH)2
D) None of these will precipitate
E) All of them will begin to precipitate at the same time
SHORT ANSWER (12 points each, total of 24 points)
8) A 1.000L solution contains 0.044M acetic acid and 0.044M sodium acetate.
What is the pH of the solution? The Ka of acetic acid is 1.8x10-5?
Essay / Problems. Each question is worth 15 points.
What is the pH of the solution after 0.033 moles is HCl are added?
E-3) 50.0mL of 0.1000M formic acid (HCHO2) is titrated with 0.100M KOH. The Ka for
formic acid is 1.8x10-4
a) Accurately sketch the titration curve for the reaction described above. (Hint, make
sure it agrees with the values that you determine in parts b & c below)
b) What is the pH of the solution after a total of 25.0 mL of KOH solution is added?
c) What is the pH of the solution after a total of 50.0 mL of KOH solution is added?
Useful Equations and Data
PV = nRT 1 L = 10-3m3
Cg = kPg
PA = XAP A = (nRT)/V
b b2 4ac
2a
Ea / RT
k Ae