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1st Term:
4. Chemical Bonding
24th – 4.1 Electrovalent/ionic 1.explain electrovalent and covalent 1. Draw ‘dot and cross’
26th bonding bonding in terms of ‘dot and cross’ diagrams.
4.2 Covalent bonding diagrams. 2. Do the worksheets
(a) Covalent bonding in 2. explain the Lewis structure of SO42- , 3. Discuss the
SO42- , CO33- , NO3- and CO32- , NO3- , and CN- ions. answers
CN- ions. 3.predict and explain the shape of 4. Refer to textbooks
(b) Hybridisation of the molecules and ions using the principle of for exercises.
s and p orbitals for the electron pairs repulsion, eg linear, trigonal 5. Form teams to surf
C, N, and O atoms planar, tetrahedral, trigonal bipyramidal, the internet and do
(c) The existence of octahedral, V-shaped and pyramid. their presentation on
ionic propertiess in 4. explain the concept of overlapping and MSPowerPoint.
molecules and covalent hybridization of the s and p orbitals for the
properties in ionic C, N, and O
compounds. 7. explain the covalent properties of ionic
(d) Co-ordinate compounds such as Al2O3, AlI3 and LiI.
covalent bonding 8. explain typical properties associated with
(e) VSEPR Model. electrovalent and covalent bonding.
4.3 Metallic bonding 9. explain hydrogen bonding, van der
4.4 Intermolecular Waaals’ forces and metallic bonding.
forces between 10. explain metallic bonding, the formation
molecules. of conduction and valency bands.
(a) Van der Waals’
forces
(b) Hydrogen bonding
and its effect on
physical properties
5. Reaction Kinetics
26th – 5.1 Rate of reaction 1. explain and use the terms rate of 1. Explanation and
28th 5.2 Collision theory reaction, rate equation, order of reaction, notes taking.
5.3 Rate law rate constant, half-life of first-order reaction, 2. Draw the Boltzman
5.4 The effect of rate determining step, activation energy, Distribution.
temperature on rate and catalyst. 3. Explanation by
constants, rates of 2. explain qualitatively, in terms of collision examples.
reaction, and activation theory, the effects of concentration and 4. Written exercises.
energy; Arrhenius’s temperature on the rate of a reaction. 5. Do short notes by
equation and the 3. calculate a rate constant from initial own references.
Boltzmann distribution. rates.
5.5 The role of catalyst 4. predict an initial rate from rate equations
in reactions and experimental data.
5.6 The order of 5. suggest and experimental technique for
reaction and rate studying the rate of a given reaction.
constants for zero-, 6.calculate t for a first-order reaction
first- and second-order 7.use integrated forms of rate equations to
reactions. determine zero-, first- and second-order
5.7 The determination reactions.
of the orders of 8. deduce the order of a reaction by the
reaction and the rate initial rates method and from concentration-
constants. time graphs.
5.8 Half-lives of first- 9. explain the relationship between the rate
order reactions constants with the activation energy and
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temperature using Arrhenius’s equation.
10. explain the distribution of molecular
energy with the Boltzmann distribution.
11. explain the effect of catalysts on the
rate of a reaction.
12. explain how a catalyst lowers the
activation energy of a reactions
and enzymes as biological catalysts.
29th – 6.1 Chemical equilibria 1.explain a reversible reaction and dynamic 1. Explanation and
30th 6.1.1 Reversible equilibrium in terms of forward and notes taking.
reaction, equilibria backward reactions. 2. Discussion of past
6.1.2 Mass action law 2. calculate the quantities present at year questions.
and derivation of equilibrium from given appropriate data. 3. Written exercises.
equilibrium constants. 3. deduce expressions for equilibrium
6.1.3 Homogenous and constants in terms of concentration, Kc and
heterogenous partial pressures, Kp.
equilibrium constants,
Kp and Kc .
6.1.4 Factors affecting
chemical equilibriaL Le
Chatelier’s principle.
6.1.5 Equilibrium
constant in terms of
partial pressures and
concentrations.
31st – 6.2.1 The Arrhenius, 1. State examples of equilibria which are 1. Explanation and
33rd Bronsted-Lowry, and referred to and studied in general. notes taking.
Lewis theories of acids 2. explain the effect of temperature on 2. Calculate the values
and bases. equilibrium constants and the equation lnK of Ka, pH, pOH ,pKa ,
6.2.2 the degree of = -H/RT + C. pKa
dissociation of weak 3. Show awareness of the importance of an 3. Give exercises on
acids and bases as the understanding of chemical equilibrium in the calculations.
basis of strong/weak chemical industry. 4. Explain the graphs
electrolytes. 4. use Arrhenius, Bronstead-Lowry, and drawn.
6.2.3 Dissociation Lewis theories to explain acids and bases. 5. Written exercises.
constants. 5. identify conjugate acids and bases.
6.2.4 Titration 6. explain qualitatively the different
indicators as acids or properties of strong and weak electrolytes.
bases. 7. explain and use the terms pH, pOH, Ka
6.2.5 Buffer solutions ,pKa , Kb and pKb.
6.2.6 Heterogenous 8. calculate pH from the H3O+ ion
equilibria of ions, Ksp concentration for acids(monobasic) and
and the common ion strong and weak bases.
effect. 9. explain changes in pH during acid-base
titrations in terms of strengths of acids and
bases.
10. select suitable indicators for acid-base
titrations.
11. explain the significance of the ionic
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product of water, Kw , and its use in
calculations.
12. define buffer solutions, uses and its
importance in biological systems.
13. calculate the pH of buffer solutions.
14. explain and use the term solubility
product, Ksp and calculate Ksp from given
concentration.
15. explain the common ion effect including
buffer solutions.
16. predict the possibility of precipitation
from given data of concentration of
solutions.
Mid-term break 4-12 September 2010
Hari Raya Puasa 10 & 11 September 2010
7. Electrochemistry.
34th – 7.1 Oxidation and 1. explain the functions and cell diagram of 1. Explanation and
36th reduction reactions in the Daniel cell notes taking.
the Daniel cell. 2. construct redox equations using half- 2. Explain the concept
7.2 Half-reaction and equations. of Nernst equation.
half-cell. Redox 3. explain the standard hydrogen electrode 3. Discussion of past
potential. 4. calculate the emf of a cell using the E0 year questions.
7.3 Redox reactions values and write the redox potentials. 4. Written exercises.
and electromotive force 5. explain the methods used to determine
(emf) – of cells and the standard electrode redox potentials.
standard hydrogen 6. predict the stability of aqueous ions from
electrode. E0value
7.4 electrode 7.determine the direction of electron flow in
potentials and the a simple cell of given electrode potentials.
formation of the 8. predict the feasibility of a reaction from
electrochemical series. E0cell value.
7.5 Cell potentials from 9. Calculate E0cell from the concentration
the combination of value of solutions using the Nernst
various electrode equation.
potentials, 10. explain the electrochemistry principle in
spontaneous and non- the prevention of rusting and in dental
spontaneous electrode filling.
reactions. 11. describe the importance of the
7.6 Nernst equation development of better improved batteries
and its use. for electric cars in terms of smaller size,
7.7 The use and lower mass and higher voltage.
principles of 12.Calculate the quantity of product
electrochemistry in the liberated during electrolysis.
prevention of corrosion. 13. Predict the product liberated during
7.8 The mechanism of electrolysis based on electrochemistry
electrolysis as opposed 14. Define and explain the the relationship
to an electrochemical between the Faraday constant, the
cell. Avogadro constant, and the charge on the
7.9 Faraday’s first and electron
second laws and their 15. Calculate the number of coulomb used,
use. the mass of material, and/or gas volume
7.10 Extraction and liberated during electrolysis.
manufacturing of 16. explain the uses of electrolysis in the
aluminium, recycling of manufacturing of aluminium, treatment of
aluminium. effluent(Ni, Cr, and Cd), electroplating of
7.11 Manufacturing of plastics, and anodisation
chlorine by the 17. explain the advantages of recycling
electrolysis of brine aluminium compared with extracting
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either by mercury aluminium
cathode cell or 18. explain the manufacturing of chlorine by
diaphragm cell. the electrolysis of brine
41st – 8.1 Enthalpy changes, 1.explain that most chemical reactions are 1. Explanation and
42nd ∆H of reactions, accompanied by energy changes, notes taking.
formation, combustion, principally in the form of heat energy, the 2. Draw the Born-
neutralization, energy changes can be exothermic or Haber Cycle.
hydration, fusion, endothermic. 3. Give exercises on
atomization, solution. 2. calculate the heat energy change from the calculations.
8.2 Hess law experimental measurements using the 4. Explanation by
8.3 Lattice energies for relationship energy change = mc ∆T examples.
simple ionic crystals. A 3. define the terms enthalpy change of 5. Written exercises.
qualitative appreciation formation, combustion, hydration, solution, 6. Do past year
of the effects of ionic neutralization, atomization, ionisation questions.
charge and ionic radius energy.
on the magnitude of 4. explain the terms enthalpy change of
lattice energy. reaction and standard conditions.
8.4 The Born-Haber 5. calculate the terms enthalpy change from
cycle for the formation experimental results.
of simple ionic crystals 6. State Hess’ law and its use to find
and their aqueous enthalpy changes that cannot be
solution. determined directly, eg. an enthalpy change
8.5 The solubility of of formation from enthalpy changes of
solids in liquids. combustion.
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Mid-term break 4-12 September 2010
Hari Raya Puasa 10 & 11 September 2010
33rd Experiment 3: Students should be able to: 1. Brief introduction of
Volumetric Analysis – 1. use the correct technique of using today experiment.
acid base and redox the burette, and pipette to measure the 2. Explanation of
volume of a solution. procedure.
Purpose: To determine 2. follow the procedure systematically. 3. Practical session.
the mass of sodium 3. employ the correct method of 4. Assessment.
ethanedioate used to heating. 5. Answering
prepare a solution 4. employ the correct technique of questions.
containing sodium titration.
ethanedioate and 5. employ the correct method of
hydrated ethanedioic washing off the solution from the sides
acid. of the titration flask with distilled water
before reaching the end-point.
6. calculate the percentage of sodium
ethanedioate in solution KA1.
……………………………. ……………………………………..
(Ms. Lau Chai Wee) (En. Ibrahim B. Kadir)
(Subject teacher) Pre U Senior Assistant
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