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Table A Table D
Standard Temperature and Pressure Selected Units
Table C
Selected Prefixes
Table E
Selected Polyatomic Ions
Factor Prefix Symbol
103 kilo- k H3O+ hydronium CrO42– chromate
10 –1 deci- d Hg22+ dimercury (I) Cr2O72– dichromate
10 –2 centi- c NH4+ ammonium MnO4– permanganate
10 –3 milli- m C2H3O2– NO2– nitrite
10 –6 micro- µ CH3COO– } acetate
NO3– nitrate
10 –9 nano- n CN– cyanide
O22– peroxide
CO3 2– carbonate
10 –12 pico- p OH– hydroxide
HCO3 – hydrogen
carbonate PO43– phosphate
130
KNO3
120
110
Solute per 100 g of H2O (g)
100
90
80
NH4Cl
70
HCl
60
KCl
50
40
NaCl
30
KClO3
20
NH3
10 SO2
0
0 10 20 30 40 50 60 70 80 90 100
Temperature (°C)
2 Reference Tables for Physical Setting/ Chemistry
Table H
Vapor Pressure of Four Liquids
200
propanone
ethanol
water
150
Vapor Pressure (kPa)
ethanoic
acid
101.3 kPa
100
50
0
0 25 50 75 100 125
Temperature (°C)
gamma radiation 0γ γ
0
neutron 1
0n n
proton 1H or 11p p
1
positron 0 or +10 β β+
+1e
Table P
Organic Prefixes
Prefix Number of
Carbon Atoms
meth- 1
eth- 2
prop- 3
but- 4
pent- 5
hex- 6
hept- 7
oct- 8
non- 9
dec- 10
Table Q
Homologous Series of Hydrocarbons
General Examples
Name
Formula Name Structural Formula
H H
alkanes CnH2n+2 ethane H C C H
H H
H H
alkenes CnH2n ethene C C
H H
alkynes CnH2n–2 ethyne H C C H
F (fluoro-) R X
halide Cl (chloro-) (X represents CH3CHClCH3
(halocarbon) Br (bromo-) any halogen) 2-chloropropane
I (iodo-)
CH3CH2CH2OH
alcohol OH R OH
1-propanol
CH3OCH2CH3
ether O R O R′
methyl ethyl ether
O
O O
aldehyde CH3CH2C H
C H R C H
propanal
O O O
ketone CH3CCH2CH2CH3
C R C R′
2-pentanone
O O O
organic acid CH3CH2C OH
C OH R C OH
propanoic acid
O
O O
ester CH3CH2COCH3
C O R C O R′
methyl propanoate
R′ CH3CH2CH2NH2
amine
N R N R′′ 1-propanamine
O
O O R′
amide CH3CH2C NH2
C NH R C NH
propanamide
C
Symbol Relative at
+4 on 12C = 1
Group
1 2 Note: Mas
6.941 +1 9.01218 +2
Atomic Number
6 are mass n
Electron Configuration 2-4 stable or co
2
3
Li 4
Be
2-1 2-2
22.98977 +1 24.305 +2
3
11
Na Mg 12
Group
2-8-1 2-8-2 3 4 5 6 7 8 9
39.0983 +1 40.08 +2 44.9559 +3 47.88 +2 50.9415 +2 51.996 +2 54.9380 +2 55.847 +2 58.9332 +2
+3 +3 +3 +3 +3 +3
4
19
K 20
Ca Sc 21 22
Ti +4
23
V +4
+5
24
Cr Mn Fe +6
25
+4
+7
26 27
Co
2-8-8-1 2-8-8-2 2-8-9-2 2-8-10-2 2-8-11-2 2-8-13-1 2-8-13-2 2-8-14-2 2-8-15-2
85.4678 +1 87.62 +2 88.9059 +3 91.224 +4 92.9064 +3 95.94 +3 (98) +4 101.07 +3 102.906 +3
+5 +6 +6
5
37
Rb 38
Sr 39
Y 40
Zr 41
Nb Mo Tc Ru Rh42 43
+7
44 45
2-8-18-8-1 2-8-18-8-2 2-8-18-9-2 2-8-18-10-2 2-8-18-12-1 2-8-18-13-1 2-8-18-14-1 2-8-18-15-1 2-8-18-16-1
132.905 +1 137.33 +2 138.906 +3 178.49 +4 180.948 +5 183.85 +6 186.207 +4 190.2 +3 192.22 +3
+6 +4 +4
6
55
Cs Ba La 56 57 72
Hf 73
Ta 74
W 75
Re Os +7
76 77
Ir
2-8-18-18-8-1 2-8-18-18-8-2 2-8-18-18-9-2 **18-32-10-2 -18-32-11-2 -18-32-12-2 -18-32-13-2 -18-32-14-2 -18-32-15-2
(223) +1 226.025 +2 227.028 +3 (261) (262) (263) (264) (265) (268)
7
87
Fr 88
Ra Ac 89 104
Rf 105
Db Sg Bh Hs 106 107 108 109
Mt
-18-32-18-8-1 -18-32-18-8-2 -18-32-18-9-2
58
Ce 59
Pr 60
Nd Pm Sm 61 62
90
Th Pa 91 92
U +5
+6
93
Np Pu +5
+6
94
+5
+6
xidation States
2
He
2
omic masses are based
2.000
Group
s numbers in parentheses 13 14 15 16 17 18
umbers of the most 10.81 +3 12.0111 –4 14.0067 –3 15.9994 –2 18.998403 –1 20.179 0
+2 –2
ommon isotope.
5
B 6
C +4
7
N –1
+1
+2
+3
8
O 9
F 10
Ne
+4
2-3 2-4 2-5 +5 2-6 2-7 2-8
26.98154 +3 28.0855 –4 30.97376 –3 32.06 –2 35.453 –1 39.948 0
+2 +3 +4 +1
13
Al 14
Si +4
15
P +5
16
S +6
17
Cl +3
+5
+7 18
Ar
10 11 12 2-8-3 2-8-4 2-8-5 2-8-6 2-8-7 2-8-8
8.69 +2 63.546 +1 65.39 +2 69.72 +3 72.59 –4 74.9216 –3 78.96 –2 79.904 –1 83.80 0
+3 +2 +2 +3 +4 +1 +2
28
Ni 29
Cu Zn Ga Ge As Se
30 31 32
+4
33
+5
34
+6
35
Br +5
36
Kr
-8-16-2 2-8-18-1 2-8-18-2 2-8-18-3 2-8-18-4 2-8-18-5 2-8-18-6 2-8-18-7 2-8-18-8
06.42 +2 107.868 +1 112.41 +2 114.82 +3 118.71 +2 121.75 –3 127.60 –2 126.905 –1 131.29 0
+4 +4 +3 +4 +1 +2
46
Pd Ag Cd 47 48 49
In 50
Sn Sb 51
+5
52
Te +6
53
l +5
+7
54
Xe +4
+6
78
Pt 79
Au Hg 80 81
Tl 82
Pb 83
Bi 84
Po 85
At Rn 86
18-32-17-1 -18-32-18-1 -18-32-18-2 -18-32-18-3 -18-32-18-4 -18-32-18-5 -18-32-18-6 -18-32-18-7 -18-32-18-8
269) (272) (277) (285)
*The systematic names and symbols for elements of atomic numbers above 109
will be used until the approval of trivial names by IUPAC.
63
Eu Gd Tb Dy Ho
64 65 66 67 68
Er Tm Yb Lu
69 70 71
95
Am Cm Bk +5
+6
96 97 98
Cf 99
Es Fm Md No100 101 102 103
Lr
Reference Tables for Physical Setting/ Chemistry 9
Table S
10
Properties of Selected Elements
Atomic Symbol Name Ionization Electro- Melting Boiling Density** Atomic
Number Energy negativity Point Point (g/cm3) Radius
(kJ/mol) (K) (K) (pm)
1 H hydrogen 1312 2.1 14 20 0.00009 208
2 He helium 2372 — 1 4 0.000179 50
3 Li lithium 520 1.0 454 1620 0.534 155
4 Be beryllium 900 1.6 1551 3243 1.8477 112
5 B boron 801 2.0 2573 3931 2.340 98
6 C carbon 1086 2.6 3820 5100 3.513 91
7 N nitrogen 1402 3.0 63 77 0.00125 92
8 O oxygen 1314 3.4 55 90 0.001429 65
9 F fluorine 1681 4.0 54 85 0.001696 57
10 Ne neon 2081 — 24 27 0.0009 51
11 Na sodium 496 0.9 371 1156 0.971 190
12 Mg magnesium 736 1.3 922 1363 1.738 160
13 Al aluminum 578 1.6 934 2740 2.698 143
14 Si silicon 787 1.9 1683 2628 2.329 132
15 P phosphorus 1012 2.2 44 553 1.820 128
16 S sulfur 1000 2.6 386 718 2.070 127
17 Cl chlorine 1251 3.2 172 239 0.003214 97
18 Ar argon 1521 — 84 87 0.001783 88
19 K potassium 419 0.8 337 1047 0.862 235
20 Ca calcium 590 1.0 1112 1757 1.550 197
21 Sc scandium 633 1.4 1814 3104 2.989 162
22 Ti titanium 659 1.5 1933 3580 4.540 145
23 V vanadium 651 1.6 2160 3650 6.100 134
24 Cr chromium 653 1.7 2130 2945 7.190 130
25 Mn manganese 717 1.6 1517 2235 7.440 135
26 Fe iron 762 1.8 1808 3023 7.874 126
27 Co cobalt 760 1.9 1768 3143 8.900 125
28 Ni nickel 737 1.9 1726 3005 8.902 124
29 Cu copper 745 1.9 1357 2840 8.960 128
30 Zn zinc 906 1.7 693 1180 7.133 138
31 Ga gallium 579 1.8 303 2676 5.907 141
32 Ge germanium 762 2.0 1211 3103 5.323 137
33 As arsenic 944 2.2 1090 889 5.780 139
34 Se selenium 941 2.6 490 958 4.790 140
35 Br bromine 1140 3.0 266 332 3.122 112
36 Kr krypton 1351 — 117 121 0.00375 103
37 Rb rubidium 403 0.8 312 961 1.532 248
38 Sr strontium 549 1.0 1042 1657 2.540 215
39 Y yttrium 600 1.2 1795 3611 4.469 178
11
Table T
Important Formulas and Equations
d = density
m
Density d= m = mass
V
V = volume
mass of part
Percent Composition % composition by mass = × 100
mass of whole
grams of solute
parts per million = × 1 000 000
grams of solution
Concentration
moles of solute
molarity =
liters of solution
K = °C + 273 K = kelvin
Temperature
°C = degrees Celsius
t
1
fraction remaining =
2 ( ) T
t = total time elapsed
Radioactive Decay
T = half-life
number of half-life periods = t
T
DET (7–01-450,000)
91-80515 91-109 CDC
S . P = 1 atm = 1013
. kPa = 760. torr = 760. mm Hg
GMV = 22.4 L mol
U
V
W STANDARD ENERGIES OF FORMATION
OF COMPOUNDS AT 1 atm AND 298 K
Heat Free Energy
(Enthalpy) of of Formation
Compound
Formation * kJ/mol (∆GfE)
kJ/mol (∆HfE)
Aluminum oxide Al2O3(s) –1674.1 –1580.9
Ammonia NH3(g) –46.0 –16.3
Barium sulfate BaSO4(s) –1471.8 –1361.0
Calcium hydroxide Ca(OH)2(s) –985.2 –897.9
Carbon dioxide CO2(g) –393.3 –394.2
Carbon monoxide CO(g) –110.4 –137.1
Copper (II) sulfate CuSO4(s) –770.8 –661.3
Ethane C2H6 (g) –84.4 –33.0
Ethene (ethylene) C2H4(g) 52.3 68.1
Ethyne (acetylene) C2H2(g) 226.6 209.0
Hydrogen fluoride HF(g) –270.9 –273.0
Hydrogen iodide HI(g) 26.3 1.7
Iodine chloride ICl(g) 18.0 –5.4
Lead (II) oxide PbO(s) –215.3 –188.1
Magnesium oxide MgO(s) –601.1 –568.9
Nitrogen monoxide NO(g) 90.3 86.5
Nitrogen dioxide NO2(g) 33.0 51.4
Potassium chloride KCl(s) –436.4 –408.8
Sodium chloride NaCl(s) –410.9 –383.7
Sulfur dioxide SO2(g) –296.4 –299.7
Water H2O(g) –241.6 –228.2
Water H2O(R) –285.5 –237.0
* Minus sign indicates an exothermic reaction.
Sample equations:
2AI(s) + 3/2 O2(g) ÿ Al2O3(s) + 1674.1 kJ
2AI(s) + 3/2 O2(g) ÿ Al2O3(s) ∆H = –1674.1 kJ/mol
∆G = ∆H – T∆S
Period Periodic Table of the Elements
1 18
1.00794 +1 4.00260 0
–1 KEY
1
1
H Atomic Mass 12.011 –4 Selected Oxidation States
2
He
1 +2 2
C
Symbol Relative atomic masses are based
+4 on 12C = 12.000
Group Group
1 2 Note: Mass numbers in parentheses 13 14 15 16 17 18
6.941 +1 9.01218 +2
Atomic Number
6 are mass numbers of the most 10.81 +3 12.0111 –4 14.0067 –3 15.9994
–2
–2 18.998403 –1 20.179 0
Electron Configuration 2-4 +2
2
3
Li 4
Be stable or common isotope.
5
B 6
C +4
7
N –1
+1
+2
+3
8
O 9
F 10
Ne
+4
2-1 2-2 2-3 2-4 2-5 +5 2-6 2-7 2-8
22.98977 +1 24.305 +2 26.98154 +3 28.0855 –4 30.97376 –3 32.06 –2 35.453 –1 39.948 0
Al
+2 +3 +1
Na Mg Si P Cl Ar
+4
3
11 12
Group
13 14
+4
15
+5
16
S +6
17
+3
+5
+7 18
2-8-1 2-8-2 3 4 5 6 7 8 9 10 11 12 2-8-3 2-8-4 2-8-5 2-8-6 2-8-7 2-8-8
39.0983 +1 40.08 +2 44.9559 +3 47.88 +2 50.9415 +2 51.996 +2 54.9380 +2 55.847 +2 58.9332 +2 58.69 +2 63.546 +1 65.39 +2 69.72 +3 72.59 –4 74.9216 –3 78.96 –2 79.904 –1 83.80 0
+2 +4 +2
K Ca Sc Ti
+3 +3 +3 +1
Cu Zn Ga Ge As Se Kr
+3 +3 +3 +3 +3 +2
4
19 20 21 22
+4
23
V +4
+5
24
Cr Mn Fe +6
25
+4
+7
26 27
Co 28
Ni 29 30 31 32
+4
33
+5
34
+6
35
Br +5
36
2-8-8-1 2-8-8-2 2-8-9-2 2-8-10-2 2-8-11-2 2-8-13-1 2-8-13-2 2-8-14-2 2-8-15-2 2-8-16-2 2-8-18-1 2-8-18-2 2-8-18-3 2-8-18-4 2-8-18-5 2-8-18-6 2-8-18-7 2-8-18-8
85.4678 +1 87.62 +2 88.9059 +3 91.224 +4 92.9064 +3 95.94 +3 (98) +4 101.07 +3 102.906 +3 106.42 +2 107.868 +1 112.41 +2 114.82 +3 118.71 +2 121.75 –3 127.60 –2 126.905 –1 131.29 0
+5 +6 +4 +3 +4
Zr Nb Mo Tc Ru Rh Pd Ag Cd Te
+4
In Sn Sb
+6 +1 +2
5
37
Rb 38
Sr 39
Y 40 41 42 43
+7
44 45 46 47 48 49 50 51
+5
52
+6
53
l +5
+7
54
Xe +4
+6
2-8-18-8-1 2-8-18-8-2 2-8-18-9-2 2-8-18-10-2 2-8-18-12-1 2-8-18-13-1 2-8-18-14-1 2-8-18-15-1 2-8-18-16-1 2-8-18-18 2-8-18-18-1 2-8-18-18-2 2-8-18-18-3 2-8-18-18-4 2-8-18-18-5 2-8-18-18-6 2-8-18-18-7 2-8-18-18-8
132.905 +1 137.33 +2 138.906 +3 178.49 +4 180.948 +5 183.85 +6 186.207 +4 190.2 +3 192.22 +3 195.08 +2 196.967 +1 200.59 +1 204.383 +1 207.2 +2 208.980 +3 (209) +2 (210) (222) 0
+6 +4 +4 +4 +3 +2 +3
Cs Ba La Ta At Rn
+4 +5
Hf W Re Os Ir Pt Au Hg Tl
+4
6
55 56 57 72 73 74 75
+7
76 77 78 79 80 81 82
Pb 83
Bi 84
Po 85 86
2-8-18-18-8-1 2-8-18-18-8-2 2-8-18-18-9-2 **18-32-10-2 -18-32-11-2 -18-32-12-2 -18-32-13-2 -18-32-14-2 -18-32-15-2 -18-32-17-1 -18-32-18-1 -18-32-18-2 -18-32-18-3 -18-32-18-4 -18-32-18-5 -18-32-18-6 -18-32-18-7 -18-32-18-8
(223) +1 226.025 +2 227.028 +3 (261) (262) (263) (264) (265) (268) (269) (272) (277) (285)
7
87
Fr 88
Ra Ac 89 104
Rf Db Sg Bh Hs Mt Uun Uuu Uub
105 106 107 108 109 111 112
Uuq
114
-18-32-18-8-1 -18-32-18-8-2 -18-32-18-9-2
*The systematic names and symbols for elements of atomic numbers above 109
**Denotes the presence of (2-8-) will be used until the approval of trivial names by IUPAC.
for elements 72 and above
140.12 +3 140.908 +3 144.24 +3 (145) +3 150.36 +2 151.96 +2 157.25 +3 158.925 +3 162.50 +3 164.930 +3 167.26 +3 168.934 +3 173.04 +2 174.967 +3
+3
Er Tm Yb Lu
+3
Pr Nd Pm Sm Eu Gd Tb Dy Ho
+4 +3
58
Ce 59 60 61 62 63 64 65 66 67 68 69 70 71
232.038 +4 231.036 +4 238.029 +3 237.048 +3 (244) +3 (243) +3 (247) +3 (247) +3 (251) +3 (252) (257) (258) (259) (260)
+5 +4 +4 +4 +4
Es Fm Md No
+4
90
Th Pa 91 92
U +5
+6
93
Np Pu Am Cm Bk
+5
+6
94
+5
+6
95
+5
+6
96 97 98
Cf 99 100 101 102 103
Lr
8 Reference Tables for Physical Setting/ CHEMISTRY Reference Tables for Physical Setting/ CHEMISTRY 9