Documente Academic
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January 2011
GCE
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January 2011
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Question Correct Answer Mark
Number
9 (c) D 1
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Section B
Justification
AlCl3 is soluble or graphite is insoluble /different
state / different phase
OR
Mark independently
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Question Acceptable Answers Reject Mark
Number
15 (c) (ii) Greater electron density in ring / ring is Just more susceptible 2
activated / more susceptible to electrophilic to attack
attack
(1)
Mark independently
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Question Acceptable Answers Reject Mark
Number
16 (a) (i) (COOH)2 → 2CO2 + 2H+ + 2e− (1) 2
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Question Acceptable Answers Reject Mark
Number
16 (a) (v) Any two from: 2
OR
EITHER
Suitable use of Eθ (+0.34V)
OR
MnO4− ions are a strong enough oxidizing agent to
oxidize Cl− ions (1)
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Question Acceptable Answers Reject Mark
Number
17 (a) (i) (Ligands cause) d orbitals / sub-shell / sub level Description of flame 3
to split (1) test
Mark independently
Mark independently
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Question Acceptable Answers Reject Mark
Number
17 (b) (ii) The concentration of oxonium / hydrogen ions is Just chromium 2
less in the [Cu(H2O)6]2+ / fewer hydrogen ions complex more acidic
produced or reverse argument based on Cr ion (1)
The concentration of
ALLOW oxonium / hydrogen
ions is greater in the
[Cr(H2O)6]3+ / chromium ion deprotonates more [Cu(H2O)6]2+ / more
easily if H3O+ shown in equation in (b) (i) hydrogen ions
produced
OR
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Section C
OR
Moles of CO2 0.88/44 = 0.02
Moles of H2O 0.216/18 = 0.012 (1)
OR
C10H12O2 = 164 (1)
OR
Mass of C in CO2 = 12/44 x 0.88 = 0.24 g
Mass of H in H2O = 2/18 x 0.216 = 0.024g (1)
C10H12O2 = 164
Percentage carbon is 120/164 = 73.2%
Percentage hydrogen is 12/164 = 7.3%
Percentage oxygen is 32/164 = 19.5% (1)
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Question Acceptable Answers Reject Mark
Number
18 (a) (ii) Add (small amount of) Br2 / bromine (1) 2
(Br2 turns from orange / yellow / red-brown to) clear
colourless / decolourised (1)
OR
OR
OR
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Question Acceptable Answers Reject Mark
Number
18 (b) (ii) Mix organic solvent and oil-water mixture in a 3
separating funnel then separate (1)
OR
‘no as clove oil has been in use for many years in No, because of
many ways so tests on animals not necessary to objections to animal
confirm it’s safe to use at current levels’ / no, as testing in general
humans would have to consume large amounts
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Question Acceptable Answers Reject Mark
Number
18 (d)* 4 clear justified comparisons – 1 mark each 5
ScCO2
oil obtained seems purer (as colour closely
matches that of eugenol) produces pale yellow
oil
requires no further purification, (others use
solvent extraction) Just no organic
solvent
greater yield per hour
Only two hours /
shorter time than
yield 15.3g per 100g of buds other methods
Just higher
percentage yield
no organic solvent (because it is chlorinated) and
so environmental problems / harmful / damage Just no organic
ozone layer solvent
Steam distillation
steam distillation can be done using standard lab
equipment /does not require high pressures
Soxhlet
produces greater yield of oil but has a smaller
percentage of eugenol /eugenol ethanoate
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Order Code UA026203 January 2011
6CH05/01
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