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1. In the reaction
Ag2O +H2O2 →2Ag + H2O + O2, H2O2 acts as:
(a) Reducing agent
(b) Oxidizing agent
(c) Bleaching agent
(d) None of these
Ans. (a)

2. Which of the following is strongest base?

Ans. (a)

3. Which of the following is the most stable compound?

Ans. (a)

4. In the reaction

The term Y is
(a) Acetone
(b) Ethyl amine
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(c) Acetaldehyde
(d) Dimethyl amine
Ans. (c)

5. The angular momentum of the electron in first excited energy state of hydrogen atom is
(a) h/Π
(b) h/2Π

(d) None of these


Ans. (b)

6. For a gaseous reversible reaction, which of the following expressions is correct?


(a) Kc =Kp(RT) ∆n
(b) Kp =Kc + ∆nRT
(c) Kp = Kx (p) ∆n
(d) Kp = Kc (RT/∆n)
Ans. (c)

7. For a zero order reaction, A → P. t 1/2 is (k is rate constant)

Ans. (a)

8.
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(a) Antiseptic
(b) Antibiotic
(c) Analgesic
(d) Pesticides
Ans. (c)

9. Which reducing agents of the following can be used for the following transformation?
CH3 —CH = CH—COOH —> CH3 —CH = CH—CH2OH
(a) L1A1H4
(b) B2H6/THF
(c) H2/Ni
(d) Na + C2H5OH
Ans. (a)

10. The angular momentum of the electron in first excited energy state of hydrogen atom is (a)
h/Π
(b) h/2Π

(d) None of these


Ans. (b)

11. For a gaseous reversible reaction, which of the following expressions is correct?
(a) Kc =Kp(RT) ∆n
(b) Kp =Kc + ∆nRT
(c) Kp = Kx (p) ∆n
(d) Kp = Kc (RT/∆n)
Ans. (c)
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12. For a zero order reaction, A → P. t 1/2 is (k is rate constant)

Ans. (a)

13

(a) Antiseptic
(b) Antibiotic
(c) Analgesic
(d) Pesticides
Ans. (c)

14. Which reducing agents of the following can be used for the following transformation?
CH3 —CH = CH—COOH —> CH3 —CH = CH—CH2OH
(a) L1A1H4
(b) B2H6/THF
(c) H2/Ni
(d) Na + C2H5OH
Ans. (a)

The following compound is used as:


(a) Analgesic
(b) Hypnotic
(c) Antiseptic,
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(d) Antimalarials
Ans. (a)

16. The refluxing of(CH2)2NCOCH3 with acid gives:


(a) 2CH3NH2 + CH3COOH
(b) 2CH3OH + CH3CONH2
(c) (CH3) 2NH + CH3COOH
(d) (CH3 )2 NCOOH + CH4
Ans. (c)

17. Which of the following has pΠ — dΠ bonding?

Ans. (b)

18. At STP the order of mean square velocity molecules of H2, N2, O2 and HBr is
(a) H2 > N2 > O2> HBr
(b) HBr> O2> N2> H2
(c)HBr> H2>O2> N2
(d) N22> O2> H2 HBr
Ans. (a)

19. Molecule having least dipole moment is:


(a) (CH3 ) 2CH2
(b) CH2=CH—C CH
(C) CH3CH2C CH
(d)H3C.C C—CH3
Ans. (d)

20. Hybridization of 1 and 2 •carbon atom in

(a) sp, sp
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(b) sp2, sp2


(c) sp2, sp
(d) sp3, sp2
Ans. (c)

21. C(diamond) + O2→CO2 ;∆H = -395.4 kJ/mol


C(graphite) + O2→CO2 ;∆H = -393.5 kJ / mol
C (diamond) + C (graphite); ∆H =?
(a) -3.8
(b)-1.9
(c) +3.8
(d) +1.9
Ans. (d)

22. In an isothermal process:


(a) ∆H=∆E+P∆V
(b) ∆H=W
(c) ∆H = ∆E
(d) ∆H = S∆T
Ans. (b)

23. Most stable carbanion is:


(a) CH3-
(b) CH3CH2-

Ans. (c)
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Then K’ will be:


(a) K2
(b) √K
(c) 1/√K
(d) 1/ K2
Ans. (a)

25. At NTP, volume of a gas is . The number of molecules is:

Ans. (a)

26. The correct sequence of bond order is:

Ans. (d)

27. The IUPAC name of

(a) 1-chloro-2, 2-diethyl-2-rnethyl ethane


(b) i-chloro-2-ethyl-2-methyl butane
(c) 1-chloro-2, 2-diethyl propane
(d) 3-chloro-2, 2-diethyl propane
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Ans. (b)

28. The volume of 2.8g of carbon monoxide at 27°C and 0.821 atmosphere pressure is
:
(a) 1.5 L
(b) 2 L
(c) 2.5 L
(d) 3 L
Ans. (d)

29. N2 + 3H2’== 2NH3 + heat


In the above reaction Kp and Kc are related as:

Ans. (d)

30. 2HCl (g) H2 (g) +Cl2g)


For the above reaction, the constant is 1.0 x 10-3. If the equilibrium concentration of H2 and Cl2
is 1.2 x 10-3 M and 1.2 x 10-4, respectively, then the concentration of HC1 is
(a) 12x10-4 M
(b) 12x 10-3 M
(c) 12 x 10-2 M
(d) 12 x 10-1 M
Ans. (c)

31. The IUPAC name of

(a) 2-methyl-3-butenol
(b) 3-methyl-2-butenol
(c) 3-methyl-3-butenol
(d) 2-methyl-2-butenol
Ans. (b)
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32. The wavelength of is 2.3:1 x 10-4. Its half life is:


(a) 2xl03 yr
(b) 2.5xl03 yr
(c) 3xl03 yr
(d) 3.5xl03 yr
Ans. (c)

33. Which particle contain I neutron and I proton?

Ans. (d)

34. In the reaction, . The heat of formation of HC1 is:


(a) +97 kJ
(b) —97 kJ
(c) —194kJ
(d) +194kJ
Ans. (b)

35. When lead nitrate is heated it gives:

Ans. (a)

36. The equivalent weight of KMnO4 in alkaline medium is equal to:


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Ans. (d)

37. Which of the following is paramagnetic?

Ans. (a)

38. The wavelength of a moving electron having J of kinetic energy is:

Ans. (a)

39. In a reaction

Here M = molecule and R = reagent. The M and R are:

Ans. (c)

40. The inversion temperature for van der Waals’ gas is:
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Ans. (b)

41. The normality of a mixture obtained by mixing 100 mL of 0.2 M and 200 mL of 0.2
M HCl is:
(a) 0.267 acidic
(b) 0.482 basic
(c) 0.0364 acidic
(d) 0.397 basic
Ans. (a)

42. Cannizzaro’s reaction is exhibited by:


(a) HCHO

Ans. (a)

43. The weight of one molecule of is:

Ans. (c)

44. The first organic compound prepared in lab from its element is

Ans. (b)
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45. The chemical used in photography is:


(a) AgBr

(c) AgC1

Ans. (a)

46. The. Correct order according to size is:

Ans. (c)

47. A first order reaction is 50% completed in 30 mm at 27°C. Its rate constant is:

Ans. (a)

48. For a chemical reaction the enthalpy and entropy change are cal and 7.4 cal
respectively. At 25°C the reaction is
(a) Spontaneous
(b) Non-spontaneous
(c) Reversible
(d) Irreversible
Ans. (a)

49. The organic compound contains 52% carbon is:

Ans. (a)
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50. The IUPAC name of is


(a) 1-bromo-3-methyl butane
(b) 1-methyl-4-bromobutane
(c) 1-bromo-3, 4-dimethyl propane
(d) 1-dimethyl-3-bromopropane
Ans. (a)

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