Tahun 2009 2008 2007

No.
1  Graph deviation from ideal gas  Hund’s rule  Mass spectroscopy, isotope
 Electronic structure, ionization  Valence shell diagram  Complex ion, structure
energy  Rate of reaction, overall
equation, catalyst (graph)
2  Boiling point-composition  Periodic table, Mendeleev  Phase equilibrium, enthalpy
graph  Ionization energy (graph), why change when liquids are mixed
 Raoult’s law, azeotrope 1st i.e higher than 2nd i.e  Ideal solution, calculate mole
 Electrolysis of NaCl  Rate equation, half-life, fraction, separation of liquids
cyclopropane, propene
3  Ammonia, bonding, shape,  Silicon compounds, soda glass  Aluminium, electrical
orbital hybridization, qualitative (equation), borosilicate glass conductivity, AlCl3 sublimes,
analysis  Silicone, structure, properties, structure
explain uses (waterproof  Bauxite
fabric)  LiAlH4, Lewis structure
4  Naming tertiary alcohol  Phenylamine, benzene  Reactions of phenol and
 Prepare tertiary alcohol from diazonium salt (equation), dye, aliphatic alcohol
haloalkane, name mechanism coupling reaction  Haloalkane  aldehyde
 Optical isomer (structure)  Polypeptide, basic unit, bond  Alcohol  ketone*
 Glucose, reduced
5  Define ionization energy, why  VSEPR, shape of ∙CH3, CH4  Hund’s, Pauli, Aufbau, using
i.e K lower Cu  ∆H for homolytic dissociation O2- as example
 Born-Haber cycle KBr of CH4 + ∙Cl  Rate equation for
 Enthalpy diagram decomposition of ozone
 Chlorofluorocarbon and ozone
6  Chemical equilibrium  Calculate Kc for Haber process  Hybridization, ethyne, C2H2
(calculation)  Oxides of N, N2O4 ⇋ 2NO2  ∆H for hydrogenation of
 Le-Chatelier’s, right or left  Le Chatelier’s, pressure butane
7 
Group 14, oxidation state +2 
Graph ionic radius period 3 
Explain how SEP of Mg2+//Mg
and +4 
Liquefaction of nitrogen, NO2 half cell is determined

Diamond and graphite from lighting 
Electrolysis of copper(II) nitrate

Group 17, bp halides 
AlCl3 monomer, Al2Cl6 dimer and aluminium nitrate
8  Explain Cu+ + water using  Transition element  Explain variation of mp in
standard reduction potentials  Complex ion, draw shape Period 3
 Formation of [CuCl4]2- from [Fe(CN)6]4-  Group 14 oxides, acid-base
conc. HCl and Cu2+  Complex ion of Cu2+, (Cl-, NH3,  PbO2 + KMnO4 + HNO3
 Ethylenediamine and Cu2+ EDTA), stability constant  Structure silicate
9  Define electrophile  Identify compound, optical,  Steroisomerism
 Addition of Br2, mechanism alumina, KMnO4, aqueous  Determine molecular formula
 Cracking process NH3, LiAlH4, cis-trans, of CH, from combustion and
equation* reaction with anhydrous CaCl2
and KOH (aq), draw structural
isomer, stereoisomer
10  hydroxybenzene to dopamine  polymerization of propene  identify aromatic compound,
(amine)  haloalkane+ethanolic KOH, Br2(aq), HCl
 chemical test for OH and NH2 Saytzeff’s rule, cis trans  phenylalanine, amino acid
 thermoplastic  synthesis of nylon-6,6
* extra info
 Tahun 2006
No.
1  period 4, electrical conductivity
 Calculate ∆H from Born-Haber
2  Electronic structure, draw
orbital shape, Hund’s rule,
shape of phosphate ion
 Type of bond based on
electronegativity, ionic bond
3  Properties of PbO2, PbO
 Standard reduction potentials
(Group 17, iodine)
4  Benzenediazonium salt,
amine+HCl, dye
 IUPAC name aspartic acid,
dipeptide, separate aspartic
acid and glycine
5  Aufbau’s
 Rate,draw graph, rate constant
6  HNO3 + H2O, negative
deviation from Raoult’s, sketch
bp-composition diagram
 SEP to explain corrosion of Ti,
why Ti use as alloy
7 
RAM Ti, spectroscopy,
properties of Ti oxide, chloride

Colour of complex of Cu2+ in
H2O and Cl-
8  SEP to explain oxidation-
reduction of Na, Mg, Cl
 Determine ∆H of Thermite
reaction, industrial use
9  Empirical formula, identify
compound, alcohol
dehydration, bromination
alkene
 Equation for hydrolysis of
chlorobutane, chlorobenzene,
ethanoyl chloride, compare
rate of hydrolysis
10  Identify compound, thionyl
chloride + alcohol, iodoform,
equation
 Reaction scheme, 1-propanol
to 2-hydroxybutanoic acid
2005
 Write electronic configuration,
valence electron Na
 Lewis structure SF4, shape,
polar/non-polar
 Orbital overlap diagram CN
 Ksp and chemical cell E
 Phase diagram CO2
 Ksp and RMM, name precipate
from RMM
 Ammonia (Group 15)
 Benzene, toluene,
nitrobenzene with FeCl3,
mechanism, order of reactivity
 Draw structure of major
product haloalkane+NH3,
+NaOH, aldehyde+Grignard
 pV=nRT calculation, deviation
from ideal gas (sketch graph)
 rate, determine Ea from graph,
order, decomposition N2O
 Enthalpy of vapourisation Na,
Al, Cl, NaCl, AlCl3
 Formation of stalactites and
stalagmites, calculate pH of
H2CO3

Calculate ∆H from calorimeter

PbCl2, PbCl4, observation
when X+Cl2 with Pt, physical
 Silver bromide, photography
 Triamminetrichlorocobalt(III),
draw isomers, add AgNO3
 Optical, geometrical isomer
 Hydrogenation, LiAlH4,
I2/NaOH with compound with
multiple functional groups
 Separate naphthalene and
benzoic acid
 Amino acid, amide and phenol
in same molecule + HCl and
NaOH
 Synthesis amino acid from 2-
nitrotolunene
2004
 Lyman series, emission
spectrum, draw energy level
diagram
 Complex blue, why?
 Haber process, dynamic
equilibrium and catalyst
 Calculate Kp for Haber
 Freon (CCl3F), why Freon a
coolant, reagents to prepare
freon, equation of O3 depletion
 Lighting and N2, from NH3
 Synthesis of carboxylic acid
from haloalkane
 Benzoyl chloride+amine,
phenol, name according to
IUPAC
 Aspirin
 vapour pressure and
temperature, ethanol, water
 deviation from Raoult’s law,
fractional distillation, azeotrope
 Hydrogen-oxygen fuel cell,
calculate voltage, advantage
 Disproportionate of MgCl, use
Born-Haber cycle to explain
MgCl stability

Calculate rate from data given
in a table, write rate equation

K2CO3 + Al3+ observation,
equation
 Halogen X + H heat with Pt
form HX, add AgNO3, halogen
in aqueous and CHCl3
 +2 and +3 of transition, Fe2+
 Define Markovnikov Draw
major product
 Mechanism for chlorination of
propane
 Preparation of organometallic
(butyllithium), Prepare 2-
phenyl-2-hexanol from
butyllithium, RMg and RLi
 IUPAC name for phenylalanine
 Isoelectric point, structure of
amino acid at pH=2, equation
formation of tripeptide, amide,
acid, explain 1o, 2o protein
 Tahun 2003
No.
1  Subatomic particles in
electrical field
 Lattice energy
2  Rate of decomposition N2O5,
calculate order, sketch energy
profile diagram, calculate Ea’
3  Purification of silicon
 Kaolinite
4  Compare mp of nitrotoluene
and amino acid, prepare
nitrotoluene, zwitterion
5  Orbital, orbital diagram of H2O
 H=mc, Q=It (electrolysis)
6  Weak acid, CH3COOH,
Br∅nsted-Lowry acid, buffer
from CH3COOH
 Acid base indicator (HPh),
explain its function in titration
 pH after neutralization
7 
Nitric acid, regia aqua reacts
on gold

Fe2O3 and TiO2, explain which
more stable using electronic
configuration
8  SO2 polar, SO3 non-polar
 Explain NO and Pt as catalyst
in Contact process
9  Stereoisomerism in 3-methyl-
4-hexen-3-ol
 Structural formula of glucose,
Fehling solution, preparation of
sorbitol from glucose
10  Bp and solubility in water of
ester and carboxylic acid
 Dehydration of alcohol,
esterification to prepare
monomer of Perspex
 Mechanism of polymeristion to
form perspex
2002 2001
 Energy level diagram with n=1 
to n=3, orbital diagram C3H6,
repeating unit polypropene
 Atomic radius, ionization 
energy, Lewis structure SF6, I3-
 Cl2+NaOH, bleach 
 Fe2+, Fe3+, explain which
stable, Fe2+ as acid
 Photochromic glass, black
white photography, AgBr
 Carboxylic acid with different 
functional group, compare
acidity, polymers, buffer
 Boric acid as Lewis acid, 
phenol as weak acid, calculate
Ka of phenol
 pV=nRT, calculate RMM 
antimony pentachloride and
predict the shape

N2H4 in calorimeter bomb, 
calculate temperature change,
∆Hf

Electrolysis of conc NaCl,
titrate with HCl, calculate
current
 Amphoteric nature or Al2O3, 
AlCl3 + H2O
 Explain N2 inert, CO2 gas but
SiO2 solid under normal cond
 Draw structural, equation of 
oxidation of alcohol,
hydrogenation of alkene
 Amino acid, explain solubility
of glycine, balanced equation
of formation of peptide bond,
glycine + HCl/ NaOH
 Empirical, molecular formula, 
2,4-DNPH, oxidation
 Mechanism of hydrolysis of
tertiary haloalkane, [OH]
effect on rate
 Tahun 2000 1999
No.
1  
2  
3  
4  
5  
6  
7  

8  
9  
10  