Campus!

Hi broxiliei
 Compare; hidsoxilici -
OH
• a
"

Composer hidsaxilia -

au O
pi una san mai multi gbepanihidsoxiee.ee in molecule C- Em)

EM
Company hidsoxieia Akali
Ry
-

atone
'
. - :

\\FENk
's

( gu )
op
R - -
Chez I R
→
q og

I
-
, -

:
Ar In aditia Hou G
-

END
y a

fr
:

qq )
-

care I , ACdehe.de I atone

Aedehida
↳ .

IR -
Ch
Z
-
-
CH
dy ) t, R -

of -
ca -
o

r -

In i. Akali
=

Compass '

organic
hidroxile.ci care cost
.in in molecule ghupareahidsoxiec-E.ae) legato de une hibsidizat op
's

Sant iotoric

Acceded ethic Cetanol ) a dat nuncle intugii clase de compress '

Calcooli) , amosaetngfolosit dim antichitate .

Aleool casaba ) piedra fine

Lichideelobtinutdimdesk@areauinului.us
Kohl hasta lucre unni
= =
→
-

,
-

Vechi egipteni abt din otuegede I vin inca dim 9. H

;mean
'

see .
.

Denumirea alcoole.la :

→
Legarea nefixului C- Ol) la nuncle alcameki ,
preazoimdpozitia ghupahii €04) .

→ Mod ueahi de dennmine = Ahead + radical hidsacasbonottsufx.ie "

Sport
glicolsglicerinaclasificareaalcoole.la
E± : alb;

.
A .
satwsati :
Chez -
on

Bupa
'

natura catmeihidsaeasbo.az/-sA.nesatusati--eHz-- ere -

cha -

one

→A
"
429 04
-

aromatic
FI
. "

caked benzilic )
Manali Aioli
functional
-

2 .

Dupe me .

ghepoisilos
Oli Tetrode
Cuz
'

A primari
.
→ -

Chez -
04
Polioli
A secondaries e
-
C -
C
.

'
am
> A testare →
c

3. Bupa natura atm de kaga

'
de
.
' -

e care se >
c-
g e
.
-

CH
I zomeria alcoolilor → fzomerie de catena cnbutanol izobufandl

\
→

\
.

> from erie de poeitie ( t

propanol → 2
propanol)
Izomerie de function Calcaoli ; etui )
n

C C C
¥ c one
- - - -

Iz de function Chey cuz o -

Chea cuz It de Catena C c oh It de

pattie C C c

g
e : c
-
:
-
- -
-
- : - - -

. .
.

Chez -
e -
Chez -

CK -
Chez em

CH CH
Chez e - -

,
-

cuz
 Structure alcoolilor
→ Atomic de O are 2 perechi de e- nepasticipanti = Ee
-

si est
hihridizat op
's

Anemone tort H2o , dintre

unghiul leg lose 20
'
→ e -
o - he =
iar in M -
o -
ne est =
east
,

→
Legatus a C -
o -
H est polara-
Aya degli electronegative talia atomieos .

negative Ideoarea el est cel

.

atomic de dense tale de

gases,te
Pe
→
O a savina mai
atndgoifor dee's
-

re .

>
iar pe atomii de H pi C
apar
dense take de .
sakina
petition .

Tutu atm de M din om al de O al alter foie de atnagfie electrostatic

grape on
'

apar
.
- -

y
→ .

→
Inte molecule de alcaol y
'
molecule de Hae se
;
alcool apai legdturi de H

→ Se stabilise punto de H
y
'
inte alcaol.se alt compas care
confine O .

→ Alcaoli a asaciazd plum leg - dem door in store salida '

t licked -

in
gas oasis moldable mint measoa.at .
T
MOH T
O -
H O -
H . . .
O -
H . . .

Chez EH
.
. . . . .
-

l l l

R R R

PREPRIETAIILEFIZIOE ALE
ALcoolie OR

→ La alcoolii inferior , prop .

fiance influent:b must mai malt de prezesty grape -

C-one) deca ## eli '

mattera radically .
.

→ In store lichida solidi alcaoli fomeaza legation '

'

de H asociaza (R oh )w wide molecule

x x
+
-
-
,
n
,

associate prom payt de hi este in continua modified

dragon
'
ne . .

→
Malleable asocial prom legatus de H pantile de au f.esben pi top in T
,
vdncozitak T
go tense une
'

de supsafata ' T
→
Alcoolii inferior car mase molar d) must lichizi ,
de Ex : metanol ; etanolsglicerema

e) Stare de aggregate .
. Alcoolii imf sunt lichizi .

,
ios ai superiore sunt oolizi
'

. → "
-

mene're

ptcamoea .

Minos Ce Cee In Colosi minoseasacterest.ae de alcool adore

2) : - →
cu
la peretiivasului
dueaag Etanol Glicerima
'
Ca -
Ca →
Minor

→ Cu
crest req me de grape hidsoxie dis
pale minored apare genteel dulce '
reade toxicities
y
-

,
.

R em
Benoitate
from pre
-

s) a -
on d

fr on >
Pennants Pf casey < Pf <
Pf
funk EY EY
-

- -

ons
gun
-

, Panet defiesbore de tropine " Akane

u
pi
.

→ Ca n
; apa , alcooli pfn; ptanosmal de ride.cat dim
an canta leg H .

→ Formarea leg . de H eaplicdzi contract; de U la dizoluoaa in 's H2o a R on-

.

→ Cree cu oesterea ne de
grupa 're
. -
OH -

Bale primal Pflc Pfalqespias CHECK ok 78°C

' - →

secunda 16,6°C
NK
.

CK
→
.

CHS
fiesbere
-
-

Temperature ee de M
proportional de
.

desc a ng
sing grape d
→
City Chez →
hoc
.
- -

Gust
.

Un data western ns.degbeperi cuz CH's

51
gust C- Eid as
→
declare cu
-

a
-
:
→

CH
z OH → 658
Solubilitatee
-

a) General → 2904
Pasafima one
-
dizolua in cdy Etanol omen -

dizoluoi in Cdg Chicoine → nu se dialed incl,

→
nee in Hze →ne
dizolua '
in H2o →
ne dizolua in H2O

→ Alcaolii inferior must oobebili in

apai .

→
Chez -
OH
pi CHz -

Chez -

on fosmeata amateur oncogene . cu

apa .

→ Solubilitatia crest cu
cresting mr de ghupahe
.

hidsaxie
y
'
Kade cu marina Catena .
.

→
bilotti alcooli sunt oolubiei in solvent -

organic .
1) Dim alcani :
METODE
-
DE OBIINERE
de nteza ( cot 2K )
I sat
n'

cm, ay 46¥ CHU t

k
-

02
Goof

2) Dim
alchemic :

a) Midsatarea alclemeeor condition Here la alchemy → Catalizata acid ( Maso, ; Hypos )

CHE CH Chez t HOH Es CH z Chez

fire
- -
-

CH

Hf Here Hye ( React 's Butera ) Metoda industriala-

'
=
Chez + -

of one =

;
b) Oxidase a blonde a alckneeor cu KANG 1mi ( Bayer )
R -
CH =
CH -
R
'
t fo] t Mote ¥' R -
CH -
CH - R
'
t Mn Oz
Ho - '
'
em on
c) Hf=cHz Cha Chez + HoH t
1/202 A¥c -
- s cha Ck -

\ / ere
'
HH
o Jeter ciccio
-
) Bin alcadiene 3 Epoxid :

OH
'

a) Aditi a
apei d. u ) . C - c -
c
-
-
c + More c -
c -
e -
c

b) Oxidase blanda '

cu
Bayer
:
c - c -
c -
c +10J + who # C
'
-
C
'
-
c -
c
on ore by '
on

4) Bin
eompugi halogenate '
:

primate
Pfe'mIdas
'

, Hoh
Is Secunda
+
thx
monohalogen.at ↳ - Accad
a) Borivali Iteration
.

NaOH
Tertian .

b) Derivates dihalogenatg
}
vicinal .
→ Didi vicinal
c) Derivates trihalogenati vicinal → Trial

5) Midroliza estrela acitieor organic k media acid th Sou )

ht
'
R -
Coo -
R t HOH # R -

Coey t R' em -

+ HOH
cuz GHz CH, COOH
Cy Chez
-
-
o
- -

Chez -
t
Chez - -
OH

dead prima
6) Redware a compression casbonilici \aldehide : →

atone alcool seconded

Catalizata de : -
Hz l Ni s Pol ; GO ; ere,
-

LIAM teter
Na 1 Na eter
Amalgam de in R em ;
-

more ; .

Na Bhs in Here Coolidge )

-

Nis Mf Nj Hf
Cy
(Mz Cha Chea C Mz
grey
CH =otHz Chez Hz
guk
t -
CH
- - -
- - -

,
,

F) Reduarea acizieoscasboxile.ci san estniloracestora :

Catalizata de :
-
Hz lui 's cue ; azo, la cooee ,
zoe atm ( se obtains astfelalcaoli superior din acizi
superior)
-
Li AlHu teter

+
acid - Na l eternal san Naleten 81 Reaction Compusilos Grignard en
comprise
'

easbonile.ci
R - Coote t Hz → R -

Chez -
CH THz O

CHz-CHz-ctk-OMg.cl#%eCHz-CHz-C4s-
'
CH z Mg Cl
'
R -
Cee - R t Hz → R -
Chez -
OH t R -

one -
Cha -
t CH z -
- o - >
one

↳ ester ↳ alcool ↳ aloof Aeeoofrimar

1-HOH
(plz Chez -

Mgcl t CH 3- CH - o →
CHS CH -

ftk
-
CH's
Fg Chez
T
-

Chez
-

cuz GH
- -
-

omsd on Aecool
secunda .
 E or
qI?e% ÷%a ÷!gm
'

cuz -
cuz -

Msd toes -
-

→ cuz -
cuz -
CHS enz - -

,
neeool tested

9) React 's amimelor alifatiu primary cu acidul azotoscreowo ) =

Dezaminare
;
↳ Na NOL -
THA
CH CK MHz + MONO →
cuz cha -
on + N, g. + me
}
- -
-

↳ Metoda volumetrica- de dozare a Na ( Van Slyke )

Metode industrial pentru termen representative
.

METANOL : ( CHS -
on )

a) Dim gazed de simtta cmetoda industrials

cot 2Hz ¥293 Chez -

oh
250 atm
3509 got
combustible CCG 's co 's cress Gaj
b) Diotilarea uscata '
alemnului →
→ acid pinoligmos Ct -
2 -1 . metanol )

ETANOL : De la amidon :
↳
sepasat min distilare fractional

AmilaZadinI@6HeeG-Intn12Hz0-IM12CezH220eema.t
incoltit lost , ↳ mattoza
-

I Cgztlzz On t H2O ¥¥ 2641206

Saccharomyces
(
dsojdie) L, glucose
'

II CGH , 206 - 2 CH z -

Chez t 202
Cerevisiae '
on

↳ 12 -
Ht eternal
GLICERINA
.

CH, Cth d Hzc 04

cuz he
-
-

11 5004 4

the
l '

em + da -
t
y
I t Hc -
oh
en on
-

HO
-

I l Mo
-
I
1 l
C. His Hzc Cl 04 Hf OH Hac -
on
Hg
-
- -

Hidroliza bazica a
gsdsimieos :

o
"
CHz -
O -
C -
CetHz5 Crf -
em
'
'
e E- feetHz5 +3 NaOH -
s em -
on
t
3972435 -

e oak
em
-
-

feat Hz5 kHz -

oh
kHz
-

- O -
e