Safety Data Sheet 1907/2006/EG (GB)

fischer 1-Component Polyurethane Foam B2

Prepared on: 26.09.2006 Reviewed on: 27.02.2008 Printing date: 27.02.2008
Version: 3.0 Page: 1 von 5

1 Identification of the substance/preparation and of the company:

Product: fischer 1-Component Polyurethane Foam B2

Use: Filling of cavities between solid parts of buildings made from metal or mineral building
materials. Isolation between walls and windows, doors or shutters.
Company: fischerwerke Artur Fischer GmbH & Co. KG
Address: D-72178 Waldachtal, Weinhalde 14 - 18
Phone: 0049 (0)7443 12-0
Fax: 0049 (0)7443 12-4222
Homepage: www.fischer.de
E-Mail: info-sdb@fischer.de
Emergency Phone: 0049 6132-84463 GBK Gefahrgut Büro GMBH Ingelheim

2 Hazard identification

Hazard designation:

Xn Harmful F+ Extremely flammable

Information pertaining to particular dangers for man an environment:

R12 Extremely flammable

R 42/43 May cause sensitisation by inhalation and skin contact.
R 36/37/38 Irritating to eyes, respiratory system and skin.

Contains Isocyanates. See information supplied by the manufacturer.

Pressurized container. Protect from sunlight and do not expose to temperature exceeding 50°C. Do not pierce, burn, even after
use. Do not spray on a naked flame or any incandescent body. Keep away from sources of ignition. No smoking. Keep out of
reach of children. Without adequate ventilation formation of flammable/explosives vapour – air mixture may be possible.

Classification system:
The classification is in line with current EC lists. In addition it is supplemented by data taken from technical literature and by
company data.

3 Composition/Data on components

Chemical characterisation
Dangerous components:
CAS-No. / EINECS-No. Designation, danger sign, R-phrases Contents
13674-84-5 / 237-158-7 Tris(2-chloroisopropyl)phosphate 10 – 25 %
Xn; R22
9016-87-9 / -- diphenylmethanediisocyanate,
isomers and homologous 2,5 – 10 %
Xn, R 20 – 36/ 37/38 – 42/43
75-28-5 / 200-857-2 isobutane 2,5 – 10 %
F+, R 12
74-98-6 / 200-827-9 propane 1 – 10 %
F+, R 12
115-10-6 / 204-065-8 dimethylether 2,5 – 10 %
F+, R 12

Advice: Description of mentioned risk phrases please see chapter 16.

Safety Data Sheet 1907/2006/EG (GB)
fischer 1-Component Polyurethane Foam B2
Prepared on: 26.09.2006 Reviewed on: 27.02.2008 Printing date: 27.02.2008
Version: 3.0 Page: 2 von 5

4 First aid measures

General information:
After inhalation: Supply fresh air; consult doctor in case of symptoms.
After skin contact: Instantly wash with water and soap and rise thoroughly.
After eye contact: Rinse opened eye for several minutes under running water. Then consult doctor.
After swallowing: Do not induce vomiting. Instantly call for medical help.

Information for the doctor:

Following symptoms can appear: allergic reaction

Danger: Irritant effects by pasting. Danger of sticking eyes and skin caused by cured foam. Sensitization by inhalation and skin
contact possible.

5 Fire fighting measures

Suitable extinguishing agents:

CO2, extinguishing powder or water jet. Fight larger fires with water jet or alcohol-resistant foam. Cool down endangered
containers.
For safety reasons unsuitable extinguishing agents:
Water with a full water jet.
Special hazards caused by the material, its products of combustion or flue gases:
Can be released in case of fire.Cyanic acid (HCN), carbon monoxide (CO), hydrochloric acid (HCl), danger of bursting.
Protective equipment:
Use a respirator with a own air supply. Do not inhale explosion gases on combustion gases.
Additional information:
Cool endangered container with water spray jet. Please do not release fire water into the canalisation.

6 Accidental release measures

Person-related safety precautions:

Wear protective clothing. Ensure adequate ventilation. Remove any source of ignition, no smoking, avoid inhalation, eye- and
skin contact. Keep away unprotected persons.
Measures for environmental protection: Do not release into the canalisation. Prevent contamination of soil and water.
Measures for cleaning/collecting:
Allow to solidify. Collect mechanically.
Further advices: see item 8 and item 13

7 Handling and storage

Handling

Information for safe handling:

Ensure good ventilation/ exhaustion at workplace.
Do not use in enclosed rooms.
Ensure good interior ventilation, especially at floor level (fumes are heavier than air).
Information about protection against explosions and fires:
Pressurized container. Protect from sunlight and do not expose to temperature exceeding 50°C. Do not pierce, burn, even after
use. Do not spray on a naked flame or any incandescent body. Keep away from sources of ignition. No smoking. Without
adequate ventilation formation of flammable/explosives vapour – air mixture may be possible. Keep away from children.

Storage
Requirements to be met by storerooms and containers:
Observe official regulations on storing packaging with pressurised containers.
Store at a dry, cool and good ventilated room.
Information about storage in one common storage facility: not necessary
Further information about storage conditions: Protect from heat and direct sunlight. Best storage temperature: 18 – 22 °C.
Storage class (VCI): 2B pressurized containers
Class according to regulation on inflammable liquids: not applicable
Safety Data Sheet 1907/2006/EG (GB)
fischer 1-Component Polyurethane Foam B2
Prepared on: 26.09.2006 Reviewed on: 27.02.2008 Printing date: 27.02.2008
Version: 3.0 Page: 3 von 5

8 Exposure controls and personal protection

Components with critical values that require monitoring at the workplace:

CAS-Nr. description TLV
9016-87-9 diiphenymethanediisocyanate in form of breathable aerosols
Isomers and homologous TLV: 0,05 mg/m3, 0.005 ppm
115-10-6 dimethyl ether TLV: 1900 mg/m3, 1000 ml/m3
75-28-5 isobutane TLV: 2400 mg/m3, 1000 ml/m3
74-98-6 propane TLV: 1800 mg/m3, 1000 ml/m3

Additional information:
The list that were valid during the compilation were used as basis.
Personal protective equipment
General protective and hygienic measures:
Avoid contact with eyes and the skin.
The usual precautionary measures should be adhered to in handling the chemicals.
Breathing equipment: Not necessary if room is well-ventilated.
Protection of hands: Protective gloves (material: butyl rubber).
Eye protections: Safety glasses.
Body protection: Protective work clothing.

9 Physical and chemical properties

Form: aerosol
Colour: light yellow
Smell: weak, characteristic
Value/Range Unit Method
Change in condition
Melting point/ Melting range: Not applicable as aerosol

Boiling point/ Boiling range: Not applicable as aerosol

Flash point: Not applicable

Ignition temperature: > 230 °C

Decomposition temperature:
The cured foam may decompose at temperature above 100 °C. At temperatures above 300 °C self-ignition is possible.

Self-inflammability: Product is not self-igniting

Danger of explosion:
Product is not explosive, however, formation of explosive air/steam mixture is possible.

Critical values for explosion: Applicable for the propellant

Lower: 1,5 Vol. %
Upper: 18,6 Vol. %

Steam pressure: at 20 °C 5,5 – 6 bar

Density: at 20 °C n.a.

Solubility in / Miscibility with Water: not miscible

10 Stability and reactivity

Thermal decomposition/ conditions to be avoided

No decomposition if used as stored according to specifications.

Dangerous reactions:
By warming up over 50°C due to increasing inside pressure there is danger of bursting.

Dangerous products of composition:

Cyanic hydrogen (HCN) (at combustion), hydrochloric acid (HCl)
Safety Data Sheet 1907/2006/EG (GB)
fischer 1-Component Polyurethane Foam B2
Prepared on: 26.09.2006 Reviewed on: 27.02.2008 Printing date: 27.02.2008
Version: 3.0 Page: 4 von 5

11 Toxicological information

Acute toxicity:
Primary irritant effects:
On the skin: Irritant for skin when pasting. Sensitisation by skin contact possible.
On the eye: Irritant effect: danger of pasting.
Inhalation: Sensitisation possible Not applicable for the cured foam.

Additional toxicological notice:

After foaming the prepolymer cures with air moisture out of the environment to neutral polyurethane.

12 Ecological information

Common advices:
Information about elimination ( persistence and degradability )
The cured foam is not biodegradable.
water hazard class: none

13 Disposal considerations

Product: observe your local disposal regulations

Refuse code:
refuse code 1605: Chemicals and gases in containers
160504: Pressurized containers containing dangerous substances and gases
Fully emptied containers:
refuse code 08 04 09: Adhesives and Sealant disposals, containing organic solvents and other dangerous substances

Cured product pieces

refuse code: 170203 Polymers
refuse code : 170604 insulationg material with exception of these mentiond at item
170601 and 170603
Uncleaned packages:
Recommendation: Disposal must be made according to official regulations.
In Germany: recycling by PDR without additional costs. PU-Dosen GmbH & Co. Betriebs KG (PDR), Am alten Sägewerk 3, D-
95349 Thurnau
Order and pickup at phone number: 0800-7836736 or fax 0800-7836737

Recommended cleaning agent: HAGO Polyurethane Cleaner

14 Transport information

Land-transport ADR/RID und GGVS/E:

- ADR/RID GGVS/E class: 2.1
- Classifying code: 5F
- UN- number: 1950
- Description: pressurized container
- Notice: transport according chapter 3.4 ADR

Sea transport IMDG/GGVSee:

- IMDG/GGVSee-Klasse: 2
- UN- number: 1950
- EMS number: F-D; S-U
- Marine pollutant: no
- correct technical name: aerosols, limited quantity

Air transport ICAO-ti AND IATA-DGR:

- ICAO/IATA class: 2.1
- UN/ID number: 1950
- notice: aerosols, flammable
Safety Data Sheet 1907/2006/EG (GB)
fischer 1-Component Polyurethane Foam B2
Prepared on: 26.09.2006 Reviewed on: 27.02.2008 Printing date: 27.02.2008
Version: 3.0 Page: 5 von 5

15 Regulatory information

Designation according to EC guidelines:

The product has been labelled in accordance with EG Directives / relevant national laws.

Code letter and hazard designation of product:

Xn Harmful F+ Extremely flammable

Hazard-determining components of labelling:

Risk phrases:
R12 Extremely flammable
R 42/43 May cause sensitisation by inhalation and skin contact.
R 36/37/38 Irritating for eyes, respiratory system and skin.

Safety phrases:
S2 Keep out of the reach of children.
S23 Do not breathe gas/fumes/vapour/spray
S25 Avoid contact with eyes.
S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S28 After contact with skin, wash immediately with plenty of water and soap.
S37/39 Wear suitable gloves and eye protection.
S45 In case of accident or you feel unwell, seek medical advice immediately
S 51 Use only in well-ventilated areas

Special designation of certain preparation:

Pressurized container. Protect from sunlight and do not expose to temperature exceeding 50 °C. Do not pierce or burn, even
after use. Do not spray into a naked flame or any incandescent object. Keep away from sources of ignition – no smoking.
Without adequate ventilation formation of explosives mixtures may occur. Contains Isocyanates. Observe manufacture’s
instructions.

National regulations:
TA-Luft: not determined
Störfallverornung: not determined
water hazard class: none

16 Other information

These data are based on our present knowledge. However, they shall not constitute a guarantee for any specific product
features an shall not establish a legally valid contractual relationship.

Risk phrases (listed in paragraph 2 and 3):

R12 Extremely flammable; R 20 Harmful by inhalation; R 36/37/38 Irritating for eyes, respiratory system and skin; R 42/43 May
cause sensitisation by inhalation and skin contact

Changes against earlier versions: completely revised