3 mark questions ATOMIC STRUCTURE

1. What do you mean by dual nature of matter? 2. Differentiate between particle and wave? 3. State Heisenbergs uncertainty pinciple? 4. What is the significance of negative electronic enegy? 5. What is the significance of de Broglie equation? 6. Define hydrogen bonding and state the conditions of effective hydrogen bonding. 7. What are molecular orbitals? 8. What are bonding and anti bonding molecular orbitals? 9. Define an orbital. 10. What is a nodal plane? 11. Why He2 is not formed? 12. Based on electrons in bonding and anti bonding molecular orbital , comment on the staility of molecule. 13. Explain bond order.

PERIODIC PROPERTIES
Study the questions in the Xerox copy

P block elements
1. Action of air on lead. 2. Write notes on plumbo solvency. 3. What is the action of dil HCl on lead? 4. What is potash alum.How it is prepared? 5. Preparation of PCl 3 , PCl 5, P 2O3,P 2O5,PH3, H3PO3 H3PO4 6. Action of water on P 2O3, P 2O5. 7. Action of heat on H 3PO3 8. H3PO3 is diproticExplain. 9. Reducing nature of H 3PO3 PH3 10. P2O5 is a dehydrating agent. Prove with 3 examples. 11. Oxidising nature of F 2. 12. What are interhalogen compounds? How are they prepared? 13. All the uses of rare gases. 14. Etching of glass? 15. How HF is prepared? 16. Write notes on Holmes signal. 17. H3PO4 is triprotic . Explain. 18. Electron dot formula for all compounds 19. Study the Xerox given for book back 3 marks.

d block elements
1. What are transition elements? 2. Why most of the d block elements have variable oxidation state? 3. Why most of the d block elements form coloured ions? 4. Why most of the d block elements form complexes? 5. Explain about the magnetic nature of d block elements 6. Why d block elements act as catalyst? 7. Why do d block elements form alloys? 8. For Cu - Action of air, Action of air and moisture, Action of acids 9. Explain chrome plating. 10. For Zn action of HNO 3, NaOH and air.

11. Extraction of silver from coins. 12. Silver with dil HNO3 and Cl2. 13. Gold with aqua regia and Cl2. 14. K2Cr2O7 with alkali and example for oxidising nature. 15. Chromyl chloride test. 16.Action of heat on CuSO4 , ZnCO3 , K2Cr2O7, AgNO3. 17. Uses of CuSO4, ZnCO3 18. Blue vitriol with KI , KCN , NH4OH , H2S. 19. Study answers for book back questions. 20. What is spitting of silver and how it is prevented?

NUCLEAR CHEMISTRY
1. Define Q value of nuclear reaction. 2. Define binding energy of nucleus. 3. Define spallation reaction. 4. Uses of radioactive isotopes in medicine and mechanisms of reaction. 5. Define nuclear fusion and fission reaction. 6. Define radioactivity. 7. What is half life period. 8. See the problems regarding number of alpha and beta particles emitted and half life period and average life. 9. What is the principle behind hydrogen bomb? 10. What is the decay constant for Ag 108 if its half life is 2.31 minutes. 11. The half life period of U 238 is 140 days. Calculate the average life time. 12. The half life period of a radioactive element is 100 seconds. Calculate the disintegration constant. 13. The decay constant for 6 C14 is 2.31 x 10 4 years . Calculate the half life period. 14. Half life period of 79 Au 198 nucleus is 150 days. Calculate its average life. 15 .Calculate the molar heat of vaporisation of the ideal liquid CCl 4 .Boiling point is 76.7 0C and S = 87.864 J 16. Calculate the disintegration constant in seconds if half life period is 100 seconds.

THERMODYNAMICS
1. Limitations of I law of thermodynamics. 2. Define entropy. 3. Define Gibbs free energy. 4. When does entropy increase in a process? 5. Define Troutons rule. 6. Notes on liquids which deviate from Troutons rule. 7. Conditions of spontaneity. 8. See problems relating 3 marks. 9. For a chemical reaction the values of H and S at 300K are 10 Kcal mol 1 and 20 cal deg 1 mol 1 respectively . What is the value of G .Predict the nature of the reaction. 10. Calculate the change in entropy for the process,water (liq) to water (vapour373 K) involving H vap = 40850 J mol 1 at 373 K. 11. What is the entropy change of an engine that operates at 100 o C when 453.6 Kcal of heat is supplied to it? 12. Calculate the entropy change involved when 1 mol of ice at 0 o and 1 atm is converted to liquid at 0oC and 1 atm. The enthalpy of fusion per mole of ice is 6008 J mol 1

CHEMICAL EQUILIBRIUM
1. Define equilibrium constant. 2. Why equilibrium is called dynamic ? 3. Book back questions.

4. Define reaction quotient Q and how it is related to equilibrium constant?. 5. How formation and dissociation equilibrium constant are related? 6. For the reaction A+ B 3C at 25 0 C a 3 litre volume vessel contains 1, 2 and 4 moles of A,B and C respectively at equilibrium. Calculate the equilibrium constant K C of the reaction at 25 0C B(g) is 2.5 x 10 2 . The rate constant of the forward and reaction is 7. The equilibrium constant K C for A(g) 1 . Calculate the rate constant for the reverse reaction. 0.05 sec

SOLID STATE
1. What is Laue diffraction pattern? 2. Sketch different types of cubic cells and find out number of atom per unit cell. 3. What are super conductors? 4. What is superconducting transition temperature? 5. Appilcations of superconductors. 6. Define Braggs law. 7. Applications of Bragg s law. 8. Any question can come from types of crystal, CsCl structure,Type of defect. 9. What is vitreous state? 10. What are glasses? 11. Book back 3 mark questions.

KINETICS
1. Define order of e reaction. 2. What are the characteristics of I order reaction? 3. Define half life period. 4. Write Arrhenius equation and explain the terms. 5. Define activation energy. 6. What are simple and complex reactions? 7. What are parallel / consecutive/ opposing reactions? 8. What is zero order reaction? How rate is related to rate constant for this reaction? 9. What is pseudo first order reaction? Give one example. 10. Problems relating 3 mark. 11. The rate constant for for a first order reaction is 1.54 x 10 3 sec 1.. Calculate its half life period. 12. Show that for a first order reaction time required for 99% completion is twice time r equired for 90% completion. 13. The initial rate of a first order reaction is 5.2 x 10 6 mol lit 1 s 1 at 298 K when the initial concentration of the reactant is 2.6 x 10 3 mol lit 1 s 1 .Calculate the first order rate constant. 14. The hale life period of a first order reaction is 20 minutes. Calculate the rate constant.

SURFACE CHEMISTRY
1. Define physical and chemical adsorption. 2. Define the following terms. Positive catalyst, negative catalyst ,auto catalyst , induced catalyst , promoters, active centres , catalytic poison. 3. Define catalyst and types of catalysis. 4. Factors affecting adsorption. 5. What is tanning? 6. What is electro phoresis and electro osmosis? 7. Why colloid of gas in gas does not exist? 8. Dispersed phase and medium of and colloid can be asked for 3mark. 9. What are emulsions? What are its types? 10. What is peptisation? 11. Explain Bredigs arc method. 12. Explain Brownian movement. 13. Explain Tyndalls effect. 14. Explain Helmholtz double layer.

15. What are emulsifying agents? 16. Why does sky appear blue? 17. How rain is produced? 18. Any three medicinal uses of colloids. 19. How delta is formed?

ELECTROCHEMISTRY I
1. Define pH. 2. What are buffer solution ? 3. What are buffer action ? 4. What is common ion effect ? 5. What are indicators? 6. Define: equivalent conductance, molar conductance, specific conductance. 7. What is cell constant? 8. Define faraday. 9. State faradays I and II law. 10. What is Ostwalds dilution law. 11. Write Debye Huckel equation. 12. What are p type and n type semiconductors? 13. Define electrochemical equivalent. 14. State Kohlrauschs law. 15. What is ionic product of water? 16. The mass of the substance deposited by the passage of 10 ampere of current for 2 hours 40 minutes and 50 seconds is 9.65 g. Calculate electrochemical equivalent.

HYDROXY DERIVATIVES
STUDY THE XEROX GIVEN

CARBONYL COMPOUNDS
STUDY THE XEROX GIVEN

CARBOXYLIC ACID
1. Hydrolysis of cyanides ,amides .esters. 2. H V Z reaction 3. Decarboxylation reaction. 4. Kolbes electrolytic method 5. Reducing property of acids. 6. Chemical properties of lactic acid. 7. Preparation of oxalic acid. 8. Action of heat on oxalic acid. 9. Preparation and properties of salicylic acid. 10. Transesterification. 11. Claisen ester condensation. 12. Mention the uses of oxalic acid. 13. Study the source and trivial name for acids. 14. Tests for carboxylic acid. 15. Preparation of benzoic acid.

ORGANIC NITROGEN COMPNDS

1. Isomerism in nitro methane. 2. Preparation of nitro methane. 3. Chemical properties of nitro methane.

4. Reduction product of nitro benzene. 5. Gabriel phthalimide synthesis. 6. Carbyl amine reaction. 7. Mustard oil reaction. 8. Reaction of amine with nitrous acid. 9. Schotten Baumann reaction. 10. Diazotisation reaction. 11. Oxidation reaction of aniline. 12. Nitration of aniline. 13. Reactions of benzene diazonium chloride. 14. Uses of aniline. 15. Formation of Schiffs base for amines.

CHEMISTRY IN ACTION
1. Book back questions. 2. Anti oxidant analgesic, anti malarial, artificial sweetening agent , nylon 66,

ISOMERISM
1. Difference between meso and racemic form. 2. What are optical isomers? 3. Identification of cis trans isomerism. 4. Conditions for optical activity. 5. Mesotataric acid is optically inactive. Why?