Documente Academic
Documente Profesional
Documente Cultură
1
III B.Tech Supplimentary Examinations, Aug/Sep 2008
CHEMICAL REACTION ENGINEERING-II
(Chemical Engineering)
Time: 3 hours Max Marks: 80
Answer any FIVE Questions
All Questions carry equal marks
⋆⋆⋆⋆⋆
1. Hydrogen sulfide is removed from coal gas by contact with a moving bed of iron
oxide particles which convert to the sulfide as follows:
Fe2 O3 → FeS
In our reactor the fraction of oxide converted in any particle is determined by its
residence time t and the time needed for complete conversion of the particle τ and
this is given by
3
1 − X = 1 − τt when t < 1 hr and with τ = 1 hr and X = 1 when t ≥1 hr.
Find the conversion of iron oxide to sulfide if the RTD of solids in the contactor is
approximated by the curve shown in the figure 1. [16]
Figure 1
2. (a) Write about dispersion model and mention its applications and limitations
(b) An injected slug of tracer material flows with its carrier fluid down a long,
straight pipe in dispersed plug flow. At point A in the pipe the spread of
tracer is 16m. At point B, 1 kilometer downstream from A, its spread is 32m.
What do you estimate its spread to be at a point C, which is 2 kilometers
downstream from point A? [8+8]
3. A reactor has flow characteristics given by the non-normalised C curve in the given
table and by the shape of this curve we feel that the dispersion or tanks-in-series
models should satisfactorily represent flow in the reactor.
1 of 2
Code No: R05320802 Set No. 1
Time Tracer Time Tracer
concentration concentration
0 0 10 67
1 9 15 47
2 57 20 32
3 81 30 15
4 90 41 7
5 90 52 3
6 86 67 1
8 77 70 0
Find the number of tanks in series which will represent the reactor and the conver-
sion expected, assuming that the tanks-in-series model holds. Data: The elemen-
tary liquid-phase reaction taking place is A + B → products, with a large enough
excess of B so that the reaction is essentially first order. In addition, if plug flow
existed, conversion would be 99% in the reactor. [16]
4. Consider a second-order reaction being can-led out in a real CSTR that can be
modeled as two different reactor systems: In the first system a CSTR is followed
by a PFR, in the second system the PFR precedes the CSTR. Let τs and τp each
equal 1 min, let the reaction rate constant equal 1.0 m3 /kmol.min and let the initial
concentration of liquid reactant, CAO , equal 1 kmol/m3 . Find the conversion in each
system. [16]
5. What are the important physical properties of catalysts? Describe a method for
determining the surface area. [16]
6. Discuss the spectrum of kinetic regimes in a porous catalytic reaction system and
explain the factors that influence the rate of reaction of particles. [16]
8. Derive a rate equation for instantaneous reaction of any order between A from gas
and B from liquid i.e A+bB →P, visualizing two-film theory. [16]
⋆⋆⋆⋆⋆
2 of 2
Code No: R05320802 Set No. 2
III B.Tech Supplimentary Examinations, Aug/Sep 2008
CHEMICAL REACTION ENGINEERING-II
(Chemical Engineering)
Time: 3 hours Max Marks: 80
Answer any FIVE Questions
All Questions carry equal marks
⋆⋆⋆⋆⋆
1. A large tank (860 liters) is used as a gas-liquid contactor. Gas bubbles flows up
through the vessel and out at the top, liquid flows in at one part and out the other
at 5 liters/s. To get an idea of the flow pattern of liquid in this tank a pulse of
tracer (M = 150 gm) is injected at the liquid inlet and measured at the outlet, as
shown in figure 1.
(a) Is this a properly done experiment?
(b) If so, find the liquid fraction in the vessel.
(c) Determine the E curve for the liquid.
(d) Qualitatively what do you think is happening in the vessel? [4+4+4+4]
Figure 1
2. (a) Write about dispersion model and mention its applications and limitations
(b) An injected slug of tracer material flows with its carrier fluid down a long,
straight pipe in dispersed plug flow. At point A in the pipe the spread of
tracer is 16m. At point B, 1 kilometer downstream from A, its spread is 32m.
What do you estimate its spread to be at a point C, which is 2 kilometers
downstream from point A? [8+8]
3. Aqueous A (CAO = 1 mol/m3 ) with physical properties close to water ( ρ = 1000
kg/m3 , D = 10 - 9 m2 /s) reacts by a second-order reaction ( k = 10 - 3 m3 /mol.s)
as it flows at 10 mm/s through a tubular reactor (dt = 10 mm, L = 20 m). Find
the conversion of reactant A from this reactor. [16]
4. (a) Find the expression for conversion of a macrofluid in two equal-size mixed
reactors for a zero-order reaction. If conversion is 99% for the microfluid,
what is it for a macrofluid having the same reaction rate?
1 of 2
Code No: R05320802 Set No. 2
(b) Discuss about mixing of two miscible fluids. [10+6]
5. What is a catalyst? Explain its role in a chemical reaction with suitable examples.
Describe about the homogeneous and heterogeneous catalytic processes. [16]
6. Calculate the effectiveness factor of a single catalyst pore and of a catalyst slab for
Zeroth - order kinetics. [16]
7. Find the activation energy of the first-order reaction from the following data.
dp (mm) CA (mol/lit) -r′A T(K)
1 20 1 480
2 40 1 480
2 40 3 500
A → R and CAo = 50 mol/lit. [16]
8. Two small samples of solids are introduced into a constant environment oven kept
there for one hour. Under these conditions the 4mm particles are 58% converted.
The 2mm particles are 87.5% converted.
(a) Find the rate controlling mechanism for the conversion of solids.
(b) Find the needed for complete conversion of 1mm particles in this oven.
[16]
⋆⋆⋆⋆⋆
2 of 2
Code No: R05320802 Set No. 3
III B.Tech Supplimentary Examinations, Aug/Sep 2008
CHEMICAL REACTION ENGINEERING-II
(Chemical Engineering)
Time: 3 hours Max Marks: 80
Answer any FIVE Questions
All Questions carry equal marks
⋆⋆⋆⋆⋆
2. (a) Write about dispersion model and mention its applications and limitations
(b) An injected slug of tracer material flows with its carrier fluid down a long,
straight pipe in dispersed plug flow. At point A in the pipe the spread of
tracer is 16m. At point B, 1 kilometer downstream from A, its spread is 32m.
What do you estimate its spread to be at a point C, which is 2 kilometers
downstream from point A? [8+8]
3. A reactor has flow characteristics given by the non-normalised C curve in the given
table and by the shape of this curve we feel that the dispersion or tanks-in-series
models should satisfactorily represent flow in the reactor.
Time Tracer Time Tracer
concentration concentration
0 0 10 67
1 9 15 47
2 57 20 32
3 81 30 15
4 90 41 7
5 90 52 3
6 86 67 1
8 77 70 0
Find the number of tanks in series which will represent the reactor and the conver-
sion expected, assuming that the tanks-in-series model holds. Data: The elemen-
tary liquid-phase reaction taking place is A + B → products, with a large enough
excess of B so that the reaction is essentially first order. In addition, if plug flow
existed, conversion would be 99% in the reactor. [16]
4. (a) Find the expression for conversion of a macrofluid in two equal-size mixed
reactors for a zero-order reaction. If conversion is 99% for the microfluid,
what is it for a macrofluid having the same reaction rate?
1 of 2
Code No: R05320802 Set No. 3
(b) Consider a single reacting macrofluid being processed in turn in batch, plug
flow and mixed flow reactors. How does the degree of segregation affect the
conversion in each case? [10+6]
5. What is a catalyst? Explain its role in a chemical reaction with suitable examples.
Describe about the homogeneous and heterogeneous catalytic processes. [16]
⋆⋆⋆⋆⋆
2 of 2
Code No: R05320802 Set No. 4
III B.Tech Supplimentary Examinations, Aug/Sep 2008
CHEMICAL REACTION ENGINEERING-II
(Chemical Engineering)
Time: 3 hours Max Marks: 80
Answer any FIVE Questions
All Questions carry equal marks
⋆⋆⋆⋆⋆
1. A pulse test on a piece of reaction equipment gave the following results: The output
concentrations rose linearly from zero to 0.5 µmol/dm3 in 5 min, then fell linearly
to zero in 10 min after reaching the maximum value.
(a) Calculate in tabular form the values of E(t) and F(t) at 1 min intervals
(b) What is the mean residence time? If the flow rate were 150 gal/min, what
would be the total reactor volume? A second order reaction with kCA0 = 1.2
min - 1 is carried out in the system. [16]
2. (a) Using the dispersion model calculate the conversion for a closed vessel for the
first order isomerization A→ B with k = 0.18 min−1 . The results of a tracer
test carried out on this reactor are as follows:
t (s) 0 1 2 3 4 5 6 7 8 9 10 12 14
C (mg/liter) 0 1 5 8 10 8 6 4 3 2.2 1.5 0.6 0
(b) Compare your result in part (a) with the conversion calculated from a PFR.
[12+4]
4. (a) For a first-order reaction with ε = 0 show that the performance equations for
a macrofluid in plug flow and a microfluid in plug flow are identical.
(b) Discuss about mixing of two miscible fluids. [10+6]
5. What is the basis for classification of catalyst? Explain about the type of catalysts
used in hydrogenation and dehydrogenation reactions of commercial importance.
[16]
1 of 2
Code No: R05320802 Set No. 4
7. What are the experimental devices used for collecting experimental data to estimate
the kinetic parameters of a catalytic reaction. Explain the strategy of applications
of those devices for different reactions. [16]
8. What is a fluid-fluid reaction? How it differ from fluid-solid reaction? Give some
examples of fluid-fluid reactions of industrial importance, gas-liquid and liquid -
liquid reactions. [16]
⋆⋆⋆⋆⋆
2 of 2