Concrete Protection Coatings 1. Fundamentals 2. Polyurethane Technology 3. APT Components 4.

System Application

Protection of Investment

Reasons: Waterproofing and Concrete Protection

Hairline crack bridging Prevent entry of water, de-icing salt and chemicals attacking structure Preventing/minimizing rebar corrosion Improving safety and aesthetics

Steel Rebar Corrosion

Crack develops in concrete. Water migrates to steel rebar initiating corrosion Crack continues to deteriorate and corrosion of steel rebar increases Increased loss of structural steel and expansive force of corrosion spalls concrete

Concrete Protection Coatings

1. Fundamentals

2. Polyurethane Technology
3. APT Components 4. System Application

Polyurethane Coatings
1-component moisture cure 2-component solvent-borne 2-component water-borne 2-component Polyurea 2-component solvent free

1-Component Moisture Cure

Technology: NCO + H2O Solvent borne 80% solids contents Cure temperature ambient Coat thickness 0.075 mm

2-Component Solvent Borne

Technology: NCO + OH and solvent evaporation Solvent borne 80% solids contents Cure temperature ambient Coat thickness 0.1 mm

2-Component Water Borne

Technology: NCO + OH and water evaporation 80% solids contents Cure temperature ambient Coat thickness 0.1 mm

2-Component Polyurea
Technology: NCO + NH2 100% solids contents Cure temperature ambient Coat thickness 0.5 mm

2-Component 100% solid

Technology: NCO + OH 100% solids contents Cure temperature ambient Coat thickness: no limitation

Polyurethane Coatings
1-component moisture cure 2-component solvent-borne 2-component water-borne 2-component Polyurea 2-component solvent free

1K PUR Limitations
+ no second component required

curing profile greatly dependent on climate conditions moisture level temperature no thick film applications

1K PUR Limitations (2)

R N H C O H O H O H Heat/Cat. R N C O

H2 O

CO2 1K PUR

N H

+ CO 2

N H H

C N R

H Heat/Cat. R N C HN R O

H O C NH R O C N R N R Heat/Cat. O C N R O

H N R

NH R

high humidity climate danger of blistering low humidity climate danger of incomplete cure

1K PUR Limitations (3)

no thick film applications ( 25-30 mil)
for higher system build-up: multi-layer applications required

solvents generally required in formulation incorrect aggregate selection can substrate preparation important:
No application on wet or damp surfaces

influence / alter curing profile up to failure

2K PUR Technology
2 component (2K) reactive Isocyanate-Alcohol Reaction
H R N H C O R1 O Heat/Cat. R N C O R1 O

2K PUR Technology (2)

Designed chemical cure curing profile independent of moisture levels in environment Temperature dependent curing profile can be tailored by catalyst design based on temperature requirements (i.e. summer vs. winter grade)

2K PUR Technology (3)

Coat thickness: no limitation thin & thick-film applications (10-80mil and higher in one layer) Solvent-free technology 100% solid formulations available Wet mils = dry mils

2K PUR Limitations
Substrate temperature above 40F and below 120 F Substrate moisture content < 4% ASTM D4263 Moisture Test Surface temperature 6 F above dew point temperature Minimum age of concrete 28 days

Dew Point Temperature

120 100

80

Dew point (F)

60

40

20

0 80 -20 90% 85% 80% 75% 70% 65% 60% 55% 50% 45% 40% 35% 30% 60 40 20

120 100

Ambient air temperature (F)

Relative Humidity

Concrete Protection Coatings

1. Fundamentals 2. Polyurethane Technology

3. APT Components
4. System Application

Primer Component --------- 152

2K-PUR,100 % solids Tensile strength 4500 psi Elongation 25 % Zero VOC, odor-free 50 minute pot life 2 hours tack free time 24 hrs cure time

fig. Bond Adhesion Test (Elcometer test)

Membrane Component --------- 252

2K-PUR,100 % solids Tensile strength 1400 psi Elongation 750 % Zero VOC, odor-free 3-4 hours before overcoat 24 hrs cure time

fig. Elongation / Tensile Strength Test (Tensiometer according to ASTM D-412)

Wearcoat Component --------- 372

2K-PUR, 100 % solids Tensile strength 4200 psi Elongation 10 % Zero VOC, odor-free 50 minute pot life 24 hours cure time 7 days chemical exposure

fig. Elongation / Tensile Strength Test (Tensiometer after test run)

Topcoat Component --------- 461

1K-PUR, solvent-based Tensile strength 2500 psi Elongation 200% Low viscosity 24 hrs cure time 7 days chemical exposure

Topcoat Component --------- 502

2K-PUR, >98% solid Tensile strength 4000 psi Elongation 300% Low viscosity 24 hrs cure time 7 days chemical exposure

Concrete Protection Coatings

1. Fundamentals 2. Polyurethane Technology 3. APT Components

4. System Application

Light Duty System

5 mil aggregate in topcoat Qualipur 372 for indoor Mils Top 10 Membrane 20 Primer 5 Product 461 252 152

Medium Duty System

10 mil aggregate in topcoat Qualipur 372 for indoor Mils Top 10 Membrane 25 Primer 5 Product 461 252 152

Heavy Duty System

15 mil aggregate in topcoat Qualipur 372 for indoor Mils Topcoat 10 Wearcoat 15 Membrane 25 Primer 5 Product 461 372 252 152

Crack Repair Detail

461 372 252 152 252HV

Membrane Elasticity
Flexional Elasticity - linear crack at bottom of cube (x,y-plane) - 1/2 cycle movement (stretching) - Vector computed at open crack - no oscillation z

x y
CreateMesh( F , 30)

Requirements for correct Membrane Installation

Qualipur 252 without aggregate Membrane layer 20 mil Preferrably applied over PUR-primer Epoxy-primers require full cure

Aggregate Retention
Sand retention Abrasion resistance Product
---------- 372 Resin + Aggregate

Tensile Elongation

4200 700

10 10

Area Elasticity
Resin-Aggregate Matrix Combination of soft membrane (252) and hard wearcoat (372)

Point Elasticity

Area Elasticity

System Properties
Modulus calculation
Product
152 252 372

M=

Tensile Elongation Modulus M

4500 1400 4200 25 750 10 180 2 420

System Certifications
ASTM C957- Component Testing Tensile, Elongation before/after water, solvent, glycol exposure Walker PEM2000 System Testing Heat Resistance Concrete Adhesion Intercoat Adhesion Wear Resistance

Additional Information
Advanced Polymer Technology
109 Conica Lane PO Box 160 Harmony, PA 16037 (USA) Tel. +1(724) 452-1330 Fax +1(724) 452-1703

www.advpolytech.com