keyAI IITJEE MODELTEST 06

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key AI - IITJEE - Model test - 06
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PAGE - A Premier Institution for IIT - JEE & AIEEE at the National Level 1 of 21
Paper - I : Physics - 1 to 50
Solutions
1.d. Just by looking at the equation ,what would decrease How does one suply energy to the
TL ?” Decreasing d ( the numerator ) or increasing photoconductor?By electromagnetic radiation. If
no electron-hole pair is produced, the radiation
µ or V0 .From this ,we could elimainate choice A may not be energetic enough.
.Coices B and C are incorrect because they have How can one increase the energy? Again,
todo with the creation of electron - hole pairs in the analogous to the photoelectric effect, the only way
photocoductor , they do not deal with the movement to do this is by decreasing the wavelength (of
of these charge carriers . Choice D is correct increasing the frequency) of the radiation. this is
because in the number of gaseous ions adsorbed choice D.
on the surface increase, it is analogous to increasing Choice A is incorrect because increasing the
the charge on the plates of a capacitor . The voltage intensity only increases the number of photons; it
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between the plates would also increase since C = Q does not increase the energy of each photon.
/ V. This voltage is the dark voltage ,and sowe have Choice B is incorrect because the gaseous ions are
increased the deniminator in the expression for the there only to create the external electric field. If does
transit time ,thus decreasing its value. not take part in the process of generating the
2.c. Solve the force equation for ε0 . The net result is electron-hole pairs.
simply the interchanging of F and ε0 . The 4π has di di
no effect since they are dimensionless pure number 6.c. ε−L = Ri ; ε − Ri = L
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. ε0 ,therefore, has units of charge squared divided
by the quantity newtons times distance suqared . i
dt
t
dt
di dt
This is exactly choice C
or ∫ = ∫L ; −1 log e ( ε − Ri ) = t
3.d. One needs to combine the qeuation given in the 0
ε − Ri 0 R L
passage for the capacitance with the general one
for capacitors C = Q / V . As given in the passage t R −t R
log e ( ε − Ri ) = − ; L
C=
ke 0 A ke 0 A Q
=
L e = ε − Ri
d d V
The surface charge density , Q / A is therefore 1 −
tR

i=  ε − e L tR
 or i.e., iR = ε − e − L
Q ke 0 V 3ε 0 (800) R 
: = = = 1600ε 0 × 10 5 C/m 2
A d 1.5 × 10 5
 −
tR
 − tLR
V2 = ε − Ri = ε −ε −e  = e
L
1m 2
= 1600ε 0 × 10 5 C/m 2 × = 1600ε 0 × 101 C/cm 2  
10 4 cm 2
⇒ induced emf decays exponentially.
Hence graph (c) is the choice.
= 1600ε 0 C / cm 2
7.b. V1
4.b. If light of the correct wavelength is shone on the V2 cos θ = V1 ; = cos θ .
photoconductor, electron-hole pairs would be V2
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generated, as stated in paragraph 1.
If no gaseous ions were adsorbed, however, there
would be no external electric field, and so the V2 V1
electrons and the holes would not move in opposite
V2cos
directions. they would eventually recombine and
annihilate one another. m
Choice C is incorrect because the dark voltage V2
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changes to the light voltage as the holes migrate to
the surface and neutralize the ions. If there were no
ions adsorbed, the dark voltage would in fact be 0,
and there whould be no change to this value even 8.b. mu m×0=0 mv
1
mv
as light were shone. 1

1
v 2 v
m
5.d. Since the creation of electron-hole pairs requires m m m
some minimum energy to raise the electron to
another state, it is analogous to the photoelectric mu + 0 = mv1 + mv — (1)
effect.
from (1), (2) E = 40 volts
v − v1 10.c. In both upward and downward motion function
e= ; v − v1 = eu, v1 = v − eu .
u force at every point is identical, work done against
friction in 2 cases are same i.e., mgh.
mu = m(v − eu ) + mv = 2mv − meu ; ∴ Total work done by the force F is against
2 mv = mu (1 + e) . gravitational force + work done against friction=
2mgh
 1+ e  11d. It displacement will increase after every rebound
∴V = u  . and finally becomes maximum displ. becomes
 2  maximum as it comes to rest after several rebounds.
mu(1+e) V V
2 2 3 2 3 3
m m 2
mu(1 + e)
= mV2 +, mV3 ; ymax
2
u (1 + e)
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V3 − V2 = ⋅e ;
2 −do −∂  ke 2  −ke 2
12.a. F= =  = 4 =
u (1 + e) dA dr  3r 3  r
V2 = V3 − e
2
mv 2 mv 2 ke 2
u (1 + e) eu (1 + e) − = KE = 2
= V3 − + V3 ; r 2 2r
2 2
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1 ke2 nh
 1+ e 
2
KE = mv = 3 ; But mv =
2
V3 =   2 2r 2πr
 2 
n2h2 ke 2 4π2 ke 2 m
n = ;r=
 1 4π2 ⋅ 2mr 2r 3 n2 h 2
1+  n.
 
n
 1 + e 2 u =3
∴Vn = x  =
     1 ke2 1 ke 2
 2   2   4 ∴ TE = ⋅ 3 = ⋅ (n h )
2 2 3
 
( )
3
6 r 6 4π2 RC 2 m
E
9.a. In a circuit, current i = i = ∴TE α n
6
R+r m3
.
Power consumed (P) is the external resistance 13.d. With respect to infinity TE of hydrogen atom in
2 ground state = –13.6eV
=i R
2 ∴ PE = 2(TE ) = −2 × 13.6 = −27.2eV
 E  E2 of the ground state is taken as zero PE, PE of the
P =  R = R
 R+r  (R + r)2 atom and ∴ TE increases by 27.2 eV.
dP −13.6
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This becomes maximum when =0 ∴ E2 = 1 + 27.2 =
dR n2
( R + r 2 )1 − 2 R( R + r ) −13.6
= 0 ; ( R + r ) ( R + r − 2 R) = 0 + 27.2 = 23.8eV
(R + r)4 22
energy is first excited state.
∴R = r
dQ dv dw
∴ Power consumed is a circuit is maximum when
the external resistance is equal to the internal
www.aieeepage.com 14.b. C=
dt
= +
dt dt
VT = constant;
resistance dv
T⋅ = 0 (PV = RT )
E 2
E 2
E2 dt
∴ Pmax = 2
.R = 2
= = 100 ...(1)
(R + r ) ( R + R) 4R dv  −V 
C = CV + P ⋅ = CV + P   = CV − R
E E E dt  T 
Current = i = = = = 10 ...(2)
R + r R + R 2R
hc hc A
15.d. λ= = ; F1
2E − E E B
hc 3 ⋅ hc F
λ1 = = = 3λ .
2E − E E
C
16.c. R = 2 h(2 − h) . As the value of h lies between D F2
2 and 1.5; R1 is maximum for h=1.5m. 22.a. Path different (for bright finge) =
17.a. From A → B . V decreasting and temperature
d
increases, means pressure should increase and ⋅d
xd 2 d2 d2
from B → C ; V α T = = = nλ; n =
D D 2D 2λD
∴ pressure should be constant.
v2 1 1 1
∆ Q = ∆ U + ∆ W = ∆ U + 2 R log e ∆ T = ∆ U + 2R + = ;
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18.b. 23.b. for point A ;
v1 v m f
2V0 1 1 3
n ⋅∆T + = ;
v 20 40 v = 40 − 0 A
1
V0
∆ QA→ B = ∆ U A→ B + 2 R | n 2 ⋅ (500 − 0) = 1000 R ln 2

C B
 2V 0  20m
∆ QB →C = ∆ U BC + 2 R | n2 ⋅ 
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 ⋅ (300 − 500)
C1
 2V 0  D A
D
10m
∆ QC → D = ∆ U CD + 2 R | n2 ⋅ (0 − 300) = 0 − 600 R / n 2
D1
∆ QD → A = ∆ QB →C
v v 40
∴ ∆ Q = ∆ Q A→ B + ∆ QB →C + ∆ QC → D + ∆ QD → A = 400 R / n 2 ∴ A1 B1 = × AB = × AB = × 10 = 20cm
19.d. Heat capacity of gas n n 20
dQ dv + dw dv dv 1 11 3
=C = = = + p⋅ for point D1: + = ;
dt dt dt dt v 30 40
RT α dt α v
But P α V ;
V
=αV ;T = V2 ;
R dv
= 2V
R
v = OD1 = 24cm ; C 1 D1 = × CD
u
dv R dv 24
∴ = ; = CV . C1 D1 = × 10 = 8cm ;
dt 2α V dt 30
R R α VR A1 D1 = 40 − 24 = 16m ;
C = CV + P ⋅ = +
2 αV r −1 2 αV
8 + 20
area of A B C D = 16 + = 224cm 2 .
1 1 1 1
R R R(2 + r − 1) R(r + 1) 2
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C= + = = 24.d. amplitude of incident and reflected wave are a1, a2
r −1 2 2( r − 1) 2(r − 1)
respectively amplitude of antinode =
20.a. The energy omitted by this shell = a1+a2, amplitude of node = a1– a2 given.
4 3 dT
πr ⋅ U = − K 4πr 2 a1 + a2 3 a22 1
3 dr = ; a1 = 5a2 ; 2 =
a1 − a2 2 a1 25
T0 R
U (R2 − r 2 )
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U % of energy transmitted =
∫ dT = − 3K ∫ r ⋅ dr ; T = T0 + 6K
T r
 a  2
1 − 2  ×100 = 96% .
2
21.c. Since foca lengths of the 2 parts will increase, the
parallel rays on the region AB and that on the region  a1 
CD will focus away from F towards right. But the 25.c. Let the source emitted I pulse when it is at A. Then
rays passing through the region BC will still focus
at F. d
time taken by the pulse to reach observer = t1 =
v
A B O Fx
−(2 − y ) ∴ ax = = −(2 − y )
m
−dv Fy
Source 1 a T2 Observer Fy = = −(2 x − 1) ; ay = = −(2 x − 1)
2 dy m
At (2,1) :
d
Let the second pulse be emitted when it is at B. ax = −1, a y = −3 : a = ax 2 + a y 2 = 10
∴ time taken by pulse to reach B = T 29.c. Path difference between light rays reflected=
 1 µ t + µ t = 2µ t from 2 surfaces of coating.
T = 
 f  λ
= time taken by source to reach B (=T)
∴2µ t = (for maximum)
2
1 2 1 2
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∴ AB = at (∵ u = 0) BO = d − at λ
2 2 ⇒t = = 10−7 m. =10-5cm .
4µ
30.d. n1, n2 be the refractive indices of 2 lenses when
1 1 2 lenses are immersed in water.
d − at 2 d at
1, T + 2 ;t1 = v ;t2 − t1 = V − 2 1  n1
=
 2 
− 1   and
1  n2
=
 −2 
− 1  
2 v F1  nw   R  F2  nw   R 
∴ Frequency heard by observer = www.aieeepage.com (Say converging) (Say diverging)
2 Combined focal length =
1 2vf
. 1 1 1 2  n −n 
t2 − t1 2vf − a F= = + =  1 2
F F1 F2 R  nw 
1  q2 q2 
26.b.  −  + mgx = R nw 20 4 1 5
4πF0  r0 − x r0  n1 − n2 = ⋅ = × × =
2 F 2 3 24 9
1 2 λ 2λ λ λ
kr ; x = 0.1m . 31.a. Path diff. = , ∴ Phase diff. = × =
2 8 λ 8 4
27.a. Volume of elemental shell = (2πx 2 ) dx Intensity at this point
π
Charge at shell = dQ = ρ ⋅ 2πx 2 dx = I = 2 I + 2 I ⋅ I ⋅ cos = 2 I ( 2 + 1)
Potential energy
4
1 ( − q ) ( dQ) q ρ Intensity at this centre = 4 I (= I C )

= dU = ⋅ = x.dx
4πε0 x 2ε 0 I 2 I ( 2 + 1)
= = 0.853
IC 4I
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 V + V0   V − V0  m
x 32.b. 10 =  n −  n ; u = 2.5
 V + VS   V + VS  s
R
dx
33.b. From B → A chose the path containing the cells
;
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V − V = 8 − 3 + 10 = 15V .
R
−q ρ = q ρR 2
U = ρdU = ∫ x ⋅ dx =
A B
2ε 0 0
4ε 0 34.b. E and B are mutually perpendicular
Work done =
E = Ei ; B = B j and V = Vx i + Vy j + Vz k .
 −q ρ R 2  −q ρ R 2 Since the charged particle goes undeviated, net
∆U = U α − U = 0 −  =
 n ε0  4 ε0 force on the charge is zero.
− dv ∴ F = qE + q (V × B ) = 0
28.a. U = 2 x − y ; Fx = =
dx
= EL + i j k
= E L + i( − BVz ) + k ( BVx ) − q0 ⋅ e− t / CR
Vx Vy Vz (q0 = CV )
= i ( E − BVz ) + kBVx = 0 CR
O B O
CV e − t / CR V − t / CR
E = BVz and Vx = 0 means component of i= = ⋅e
CR R
velocity along E (which is in x-direction = 0)
V
35.b. Due to induction q charge flows to the inner side of at t = 0 ; i = .
1 plate As A, B are exposed to same medium. R
Q1 − q = Q4 + Q3 + Q2 + q V
Q1 − Q2 − Q3 − Q4 ρd VA k ε A V CV .
q= i= = = 0 =
2 A ρd d ρkε0 ρkε0
Q1 + Q2 + Q3 + Q4 39.d.
∴ Q1 − q =
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V
2
Q2 + q Q3 + Q2 + q Q4 + Q3 + Q2 + q dx
Q1 - q
- (Q2 + q) - (Q3 + Q2 + q )
A B Consider an element (d λ ) at distance x from centre.
This element is moving with speed, v = wx .
36.c. F =−
dv
;
www.aieeepage.com ∴ Induced emf across
dx = B ( dx )v = Bwx ⋅ dx
dx
∴ emf between centre and edge of disc =
Force between & Plates of Condenser =
b
1 1
∫ Bwxdx = 2 Bw (b − a2 )
2 2
k ε 0 AE 2
2 0
1 40.c. When free end which is at distance l moves with

U = ∫ F ⋅ dr = F ⋅ x = ε0 kAE 2 − x velocity ν , then the element located at x moves
2
v
with velocity ν = x ⋅
1
V .
E= l
x
1 V2 1 1 x
U = ε0 kA ⋅ 2 − x = ε0 kA ⋅V 2   ;
dx V
2 x 2  x
dv 1 1
= + ε0 kAV 2 ⋅ 2 ⋅ velocity l
dt 2 x
m
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dv 1
∴ α 2 λ = mass length ; λ = ;
dt x l
mass of element = dm = λ ( dx)
37.a. ∴ Terminal voltage =
l 2
V = E − ir ; i = 0 ; V = E = 2 Volt 1  xv  mv 2
Slope of the line = KE of spring = ∫ (λ ⋅ dx )   = .
0
2  l  6
2
− r = − ; r = 0.4Ω www.aieeepage.com
41.c. Gravitational force is the internal force
5
38.d. Equation of discharging is, q = q0 e − t / CR M V1
⋅ v1 = M ⋅ v2 ; v1 = 2v2
2
dq  1  from energy conservation :
i= = q0 ⋅ e − t / CR ⋅  − = V2 Earth
dt  CR 
1 M 2 1 M 2.9 × 10 −3
⋅ v1 = M ⋅ v2 2 = gh T= = 7250 K
2 2 2 2 400 ×10 −9
On the other had, an object that emits light at the
∴ v1 = 2 gh 3 .
high end of the visible spectrum has a temperature.
42.b. Max. extension in spring during oscillation =
M ⋅g 2.9 × 10 −3
T= = 4143 K
+A 700 × 10 −9
k
∴ Max. force acting on M during oscillation of The temperature of the blackbody must be
somewhere between these two values, choice (C)
M g  is correct.
M 1 = Fmax = K  1 + A 
 k  48.b. In this problem, you are asked to figure out the
relationship between the color of an object and the
for M2 to be at rest, Fmax ≤ µM 2 g ; surface temperature. Since the color of light
depends on its wavelength, the real question is :
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M1 kA how does wavelength of emission and temperature
M 1 g + kA ≤ µM 2 g ; µ≥ +
M2 M2g . relate?
The passage tells us that the emission spectra of
V t stars are pretty close to the blackbody spectrum.
dv dv
43.c. a=
dt
= −α V ; ∫V v = −α ∫0 dt ; So we can make use of Wien’s displacement law: as
the temperature goes up, the wavelength at
0
maximum intensity goes down. (Not that we aren’t
V = V0 e
αt
;
ds
dt
= V0 e
αt
www.aieeepage.com overlooking the “maximum intensity” requirement
the color of light we see from a thermally radiating
object is generally from the most intense photons.
ρ α Remember that photon intensity depends on the
αt V0
∫ ds = ∫ V0 e ⋅ dt; S =
0 0
α
number of photons, not their energy.)
So we need the color with the lowest wavelength.
That’s blue and violet light, which radiates around
44.d. Power = F.V. = 400 to 450 nm. The correct answer is choice (B).
mg sin θ ⋅ 2 gl sin θ = 2m 2 g 3l sin 3 θ Since the question calls for extremes, we could
probaly have eliminated choices (C) and (D) right
45.d. At any instant, points are situated at the vertices
away, since answer choices (A) and (B) are more
of equilateral triangle.
extreme choices.
∴ Relative velocity of approach =
Kt − kt cos 60º 49d. The quantization condition means that the energies
of the system take the form: E = nhf
T So the energy difference between consecutive
∫ ( Kt − kt cos 60º )dt = a ; Kt
60º
energy states is just hf. (For example, the energy
0 60º difference between consecutive energy states n =
Kt 60º
Kt 2 and n = 3 is 3hf-2hf = hf)
For a mass oscillating on the end of a spring, the
2a
T= = 4a
K. 1 k
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K − k cos 60º
frequency of oscillation f is : f =
46.c. Space is homogeneous enough to be considered a 2π m
blackbody. This is a straightforward calculation
Consequently, we can write the energy gap between
question - given the temperature, can you determine
the wavelength of maximum intensity emitted by h k
the cosmic background radiation? consecutive states as : ∆E =
2π m
2.9 ×10 −3
λ max =
3
= 1× 10 -3 m www.aieeepage.com
50.b. The specific heat of a substance is the energy
needed to raise the temperature of 1 kg of that
substance by 1 degree K. In this case, we use 3840
47.c. The real question here is, do you know what J to heat a 3-kg block of lead up by 10 K. Apply the
wavelengths correspond to visible light? definition to calculate the specific heat:
Visible light ranges from about 400 to 700 nm in
wavelength. If the light is emitted at the low end, ∆Q = mc ∆T
400 nm, the object’s temperature is:
∆Q 3840 J J
c= = = 128
m∆T (3 kg) (10 k) kg.K
Paper - I I : Mathematics - 51 to 100
Solutions
51.d. The eqn. of chord OA is or p = aq ...(4)

x
 b Tanθ1  2b
y= 
 a  from (2) & (3), q = − and = −2b
a
x Substituting the values of p and q in (3), we get
 b Tanθ2 
The eqn. of chord OC is y =   , where 4b 2
 a  − 2a + = 6c ⇒ -a 2 + b 2 = 3ac
a
O is centre (0,0)
⇒ 2b 2 = a 2 + 3ac
A = (a cos θ1 , b sin θ1 ),
55.d. Suppose, iof possible,
C = (a cos θ2 , b sin θ2 ) . Equation of line through (4, -5) with slope m is
y + 5 = m (x - 4)
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As these are conjugate diameters,
⇒ mx - y - 4m - 5 = 0
 b Tanθ1  b Tanθ2  −b
2
   = m (−2) − 3 − 4m − 5
 a  a  −a
2
Then = 12
m2 + 1
π 
⇒ Tanθ1 = − cot θ2 = Tan  + θ2  ⇒ − 6m − 8) = 12 (m 2 + 1)
2 
π www.aieeepage.com
On squaring
⇒ θ1 ∼ θ2 = . (6 m + 8) 2 = 144 ( m 2 + 1)
2
⇒ 4 (3m + 4) 2 = 144 ( m 2 + 1)
52.a. AO 2 = a 2 cos 2 θ + b 2 sin 2 θ, CO 2 =
⇒ (3m + 4) 2 = 36 (m 2 + 1)
 π 
a 2 sin 2 θ + b 2 cos 2 θ ∵θ 2 = 2 + θ1  ⇒ 27m 2 + 24m + 20 = 0 ...(1)
 
Since the discriminant of (1) is (-24)2 - 4.27.20 =
∴ AO 2 + CO 2 = a 2 + b 2 1584 which is negative, there is no real value of m.
Hence no such line is possible.
53.c. AO = CO ⇒ AO 2 = CO 2 ⇒ 56.b. Given circle is the intersection of the sphere
a cos θ + b sin θ = a sin θ + b cos θ
2 2 2 2 2 2 2 2
r 2 + r .( 2iˆ − 2 ˆj − 4kˆ ) − 19 = 0
⇒ (a − b )v = (a − b ) cos θ
2 2 2 2 2
or x 2 + y 2 + z 2 + 2 x − 2 y − 4 z − 19 = 0
⇒ Tanθ = ±1 and the plane
⇒ θ = π or 3π r .(iˆ − 2 ˆj − 2kˆ ) + 8 = 0
4 4
54.a. Given equation is
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a( x4 + y 4 ) − 4bxy ( x2 − y 2 ) + 6cx2 y 2 = 0 ...(1)
Equation (1) is a homogeneous equation f fourth c(-1,1,2)
degree and since it represents two pairs at right 5
angles. i.e., sum of the coefficients of x 2 & y 2 P M Q
should be zero.
Let a ( x 4 + y 4 ) − 4bxy ( x 2 − y 2 ) + 6cx 2 y 2 = 0 We have
= ( ax 2 + pxy − ay 2 ) (x 2 + qxy − y 2 )
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CM = Length of the ⊥ from −iˆ + ˆj + 2kˆ to the plane
(ii)
where p & q are constants
On comparing similar powers, we get (−iˆ + ˆj + 2kˆ).(iˆ − 2 ˆj + 2kˆ) + 8
p + aq = - 4b .....(2) ⇒ CM =
-2a + pa = 6c ...(3) 1+ 4 + 4
p −1− 2 + 4 + 8
Again, given two pairs coincide, then =q ⇒ CM = =3
q 3
∴ PM = CP 2 − CM 2 = 25 − 9 = 4 f ' ( x) = −e − x − cos x and f ' ( x) = 0 ⇒ −(e− x + cos x) = 0
57.a. The equation of xy - plane is z = 0 i.e., 0x+0y+z=0.
⇒ 1 + e x cos x = 0 ⇒ e x cos x = −1 .
Clearly, the given plane is perpendicular to this
63.c.
plane.
64.d. Since, it is given the the reciprocal of the square of
sin x − cos x) the length of semi-conjugate axis is less than the
58.c. f ( x) = ....(1) reciprocal of the square of the length of semi-
sin x + cos x
transverse axis i.e.
sin (π + x − cos(π + x) sin x) − cos x) 1
<
1
f (π + x) = = 2
sin (π + x) + cos(π + x - sin x − cosx) b a2
Let they differ by a constant k 2
sin x − cos x
= = f ( x) 1 1 1
sin x + cos x ∴ = +
2 2
a b k2
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f (π + x) = f ( x) ⇒ f ( x) has period π Hence, the equation of the family of hyperbolas is
2
−3 x + 2
59. d. f ( x) = e x ≥ 0∀x x2 y2
− =1
Evidently f is increasing function and so f is one - a2 b2
one map.
 1 1  y2
f : (−∞, −1] → (0, e ], e 5 x3 −3 x+2
=e 4
if x = -1 ⇒ x2  2 + 2  − 2 = 1
www.aieeepage.com
b k  b
Range of f is (0, e 4 ] ⊂ (0, e 5 ] ∴ f is into map.
1 1 2
60.a. 3 x − y + 3 = 0 ⇒ y = 3 x + 3 ⇒ slope of normal ∴ 2
( x2 − y 2 ) + (x ) = 1
b k2
=3 ....(1)
Which is independent of a and has 4 points
1 (± k , ± k ) satisfying the above equation.
slope of normal of f(x) = 0 as x = 0 is −
f ' (0) ..(2)
16 − 9 9
65.c. e12 = =1−
1 16 16
By (1) and (2), f ' (0) −
3 16 + 9 9
2
2 and e2 = =1+
x 16 16
lim
x →0 f ( x ) − 5 f ( 4 x 2 ) + 4 f (7 x 2 )
2
∴ e12 + e22 ≤ 3
2x 66. b. Let the co-ordinates of A be (a, 0) and of B be (0, b),
= lim 2 2 2 then AOB being a right angled triangle, the centre
x →0 2 xf ' ( x ) − 40 xf ' (4 x ) + 56 xf ' (7 x )
of the circumscribed circle is the mid-point of AB
1
= lim a b a 2 b2
x →0 2 2
f ' ( x ) − 20 f ' (4 x ) + 28 f ' (7 x ) 2 i.e,  ,  and Radius is OC = +
 2 2 4 4
PAGE
1 1 1
= = =− Y
f ' (0) − 20 f ' (0) + 28 f ' (0) 9 f ' (0) 3
sin t (0,b)B
61.c. x = 0 is a point of (-1, 2). At x = 0, log t and  a b 
C  , 
t  2 2 
both are not defined. ∴ (a) & (b) are false. M
1- t + t 2 www.aieeepage.com
is continuous and differentiable
O A(a,0)
X
1+ t + t2 L
∀t ∈ (−1,2). ∴ c is true
Equation of the circle is
62. a. If we take f ( x ) = e − x − sin x ( x − a) ( x − 0) + ( y − 0) ( y − b) = 0
[For e x sin x = 1 ⇒ sin x = e− x ⇒ e− x − sin x = 0] ⇒ x 2 + y 2 − ax − by = 0
then
which is independent of A, B, C and D.
a b
x (0) + y (0) − ( x + 0) − ( y + 0) = 0 69. a. Roots of equation x 2 − 9 x + 8 = 0 are 1 and 8
2 2
⇒ ax + by = 0 Lety = [sin 2 α + sin 4 α + sin 6 α + ...to ∞ ] log e 2
Let AL and BM be the perpendiculars from A and B
on equation (1)  sin 2α 
⇒ y= 2 
log e 2 = tan 2 α log e 2
1 − sin α 
a2
thern, AL = =m
2
a2 + b2 ⇒ y = log e (2 tan α )
2
α
b2 ∴ e y = 2 tan
and BM = =n
2
a2 + b2 Given 2 tan α = 8 = 2 3
∴ AL + BM = m + n = a 2 + b 2 = diameter ⇒ tan 2α = 3
PAGE
of circle ⇒ tan 2α = 3
Y α
67. d . ⇒ α=
3
C’ B
−1  2π  2π π
S R
Noew, sin  sin  =π − = =α
 3  3 3
C 8 www.aieeepage.com  π 2π 3π 
∵ ≤ ≤ 
P Q
 2 3 2 
X
O 8 A 70.d. Putting x = 0 and both sides of the equation we
have
 Coordinates of   Co − ordinates of the centre 1 2 0
  =  
 point C   of the smallest circle  g = 0 1 2 =9
 Coordinate s of   Co − ordinates of the centre  2 0 1
  =  
 point C   of the smallest square  Differentiating both sides and then putting x = 0,
we get f = -5.
∴ (Coordinates of point C) = (4, 4)
PQ = 8 - 2 - 2 = 4 = QR 71. a. The system has non - zero solution if
{∴ radius of each large circle = 2 cm} sin 3θ −1 1
2
∴ PR = 4 + 4 = 4 2 2
∆ = cos 2θ 4 3 =0
4 2 2 7 7
and hence, PC = −2 2
2 Applying R 2 → R2 + 4 R1 and R3 → R3 + 7 R1
PAGE
∴ Radius of smallest circle = 2 2 − 2
sin θ −1 1
Hence, the required circle is
⇒ ∆ = cos 2θ + 4 sin 3θ 0 7 =0
( x − 4)2 + ( y − 4)2 = (2 2 − 2)2 2 + 7 sin 3θ 0 14
cos A sin A cos (A + D) ⇒ 14 cos 2θ + 56 sin 3θ - 14 - 49 sin 3θ = 0
Since, ∆ = cos B sin B cos (B + D) ⇒ 2 cos 2θ + sin 3θ - 2 = 0
68. d.
cos C sin C cos (C + D) www.aieeepage.com⇒ 2 (cos 2θ − 1) + sin 3θ = 0
Applying C 2 → C3 − (C1 cos D − C 2 sin D ) ⇒ - 4 sin 2θ + 3 sinθ − 4 sin 3 θ = 0
cos A sin A 0 ⇒ − sin θ + ( 4 sin 2 θ + 4 sin θ − 3) = 0

⇒ ∆ = cos B sin B 0 = 0 ⇒ sinθ ( 2 sin θ − 1) (2 sin θ + 3) = 0
cos C sin C 0 1 −3
⇒ sinθ = 0, sin θ = , sin θ =
2 2
π ⇒ (a - b) = ( d − b ) (1 + tan 2 y )
⇒ θ = nπ ,θ = nπ + (−1)n
6
b−c a−d
∴ tan 2 x = , tan 2 y =
72.a. Clearly, 7 λ + 7 µ will be divisible by 5 if c−a d −b
either : 7 λ has 3 or 7 in the unit place and 7 µ tan 2 x (b − c) (d - b)
⇒ = .....(1)
has 7 or 3 in the unit place 2
tan y (c − a ) (a - d)
or : 7 λ has 1 or 9 in the unit place and But a tan x = b tan y
7 µ has 9 or 1 in the unit place. ⇒

tan x b
= .....(2)
∴ For any chice λ , µ the digits in the unit tan y a
λ µ
place of 7 + 7 is 0, 4, 6, 8. b2 (b − c) (d − b)
= { using (1) & (2)}
It is divisible by 5 only when this digit is 0. a 2 (c − a ) ( a − d )
PAGE
1
∴ The required probability = a 2 (c − a ) ( a − d )
4 ⇒ =
73.d. Let P (E) be the probability that first 6 is tossed on b 2 (b − c ) (d − b)
the kth toss is
75.a. From the given equations we have
probabilty that   probabilty that  w 3
 6 was never    u = 1 − v, 6v = , w = (1 − u )

∴ P(E) =  tossed before 
 
 6 is
www.aieeepage.com
that
tossed

Which are satisfied by the pair

1− w 4
 k toss in  th  on the  u v w ≡ 10 0
   
 (k-1) tosses  th
 k toss
th
 76.c. Let E = (sin −1 x ) 3 + (cos −1 x ) 3
k −1 ⇒ E = (sin -1 x + cos −1 x ) 3
5 1
⇒ P(E) =    
6 6 -3sin -1 x cos −1 x (sin −1 x + cos −1 x )
The probability that Anthony will toss the first 6 is
π3 π
the sum of the probabilities that he will toss the ⇒ E= - 3 (sin -1 x cos −1 x
first 6 on his first turn (i.e., 3rd toss of game), second 8 2
turn (i.e. 6th toss of game). etc.
∴ Required Probability i.e. P(EP is given by π 3 3π π 
⇒ E= − sin -1 x  − sin −1 x 
2 5 3n −1 8 2 2 
5 1 5 1 5 1
P( E ) =     +     + .... +     + ...∞
6 6 6  6 6  6 ⇒ E=
π 3 3π 2
8
−
4
sin -1 x +
3π
2
(
sin −1 x
2
)
2
 5 1
  . π 3 3π  −1 2 π −1 
⇒ E= + (sin x) − 2 sin x 
⇒ P(E) =   3
6 6
PAGE
8 2  
 5
1-  2
 6 π 3 3π  -1 π  3π 3
⇒ E= +  sin x −  −
8 2  4 32
25
∴ Required Probability = 2
91 π 3 3π  -1 π 
⇒ E= +  sin x − 
74. b. 2
a sin x + b cos x = c 2
www.aieeepage.com 32 2  4
⇒ (b - a ) cos 2 x = c − a π3
So, the least value is
32
⇒ (b - a ) = (c - a) (1 + tan 2 x )
2 2
Now, b sin 2 y + a cos 2 y = d  π  3π 
since,  sin -1 x −  ≤  
 4  4 
⇒ (a - b ) cos 2 y = d - b
π 3 9π 2 3π 7π 3  f 2 − c 
∴ The greatest value is + × = ⇒ (y + f) 2 = −2 g  x −
32 16 2 8  2 g 

77.c. Let x = sin 2 A + sin 2 B {given} which represents a parabola with its axis
perpendicular to y-axis.
⇒ x = 1 − cos 2 A + sin 2 B 80.b. Since, P and D are the ends of semi-conjugate
⇒ x =1+ sin B − cos A 2 2 diameters of ellipse respectively, therefore, the co-
ordinates of P and D are (a cos θ be sin θ ) and
⇒ x = 1 + cos ( A + B ) cos ( A − B )
⇒ x =1− cos C cos( A − B) {∵ A + B + C = π }  π  π 
 a cos  + θ , b sin  + θ   respectively
 2  2 
1
⇒ x = 1− − cos ( A − B)
2 ∴ CP 2 + CD 2 = a 2 cos 2 θ + b 2 sin 2 θ
1 + a 2 sin 2 θ + b 2 cos 2 θ
Now, − ≤ cos ( A − B) ≤ 1
PAGE
2
∴ CP 2 + CD 2 = a 2 + b 2
1 1 1
⇒ 1− ≤1+ cos ( A − B ) ≤ 1 +
2 2 2 81. d. D
A
B
1 2 +1 E
∴ ≤x≤
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C
2 2 M
78. a. The equation of a line parallel to x + 2y = 4 is x + 2y

O
=k
The distance between these two lines is 3
By symmetry area (∆ ADE) = Area (∆ABM)
k 4
∴ − =3 So, integral is minimum when m = 0
1+4 1+4
x + x 2/3 + x1 / 6
⇒ k =4+3 5 82.a. Sinc, I = ∫ x(1 + x1 / 3 )
dx
This shifted line cuts x-axis at (k, 0).
Put x = t6
After rotation the slope of the line is tan (θ - 30 o ) ,
where ⇒ dx = 6t 5 dt , we have
1 6t 5 (t 6 + t 4 + t )
tan θ = −
2
{slope f x+2y=4} ∴ I= ∫ t 6 (1 + t 2 )
dt
Thus, the equation of the line in the new position is
6 (t 5 + t 3 + 1)
y − 0 = tan (θ − 30 ) (x - k)o
⇒ I= ∫ t2 +1
dt
where, k = 4 + 3 5 6
PAGE
79. d.
⇒ I = 6 t 3dt + ∫ ∫ 2
t +1
dt
Y
P(x,y)  t4 
⇒ I = 6   + 6 tan −1t + c
4
 
C(-g,-f)
3 2/3
O X www.aieeepage.com ∴ I=
2
x + 6 tan −1 ( x1/ 6 ) + c
Let the given line be the y-axis and the circle to 1 2e 4e 6e

83. d. Since, = + + + ...∞
2 2
have the equation x + y + 2 gx + 2 fy + c = 0 , x 3! 5! 7 !
then according to given condition, we have 1 1 2 3 
2 2 2 2 2 ⇒ = 2e + + + ...∞ 
x = ( x + g ) + ( y + f ) − ( g + f − c) x 3! 5! 7 ! 
The Area bounded is shown in the figure such
1
⇒ = 2e(S )
x π 1  π 1 
that, A is  ,  and B is  , 
∞ 6 3  3 3
n
Such that S = ∑ (2n + 1) !
Hence, Required Area
n =1 π /6 π /3 π /2
1
1  ∞ 2n + 1 − 1 
A= ∫ tan xdx + ∫ 3
dx + ∫ cot x dx
Now, S =  ∑ 
2  n=1 (2n + 1) ! 
0 π /6 π /3
1 π /3
⇒ A = (log sec x)π0 /6 + (x)π /6 + (log sin x)ππ /3/2
1 ∞
 1 1  3
⇒ S=  ∑  − 
2  n =1  (2n) ! 2n + 1 π/6
 π  1 π π 
⇒ A =  logsec - logsec0 +  − 
⇒ S=
1 −1
e ( )  6 0 3 3 6
PAGE
2 π π

Substituting respective value of S in (1), we have +  log sin - log sin 
 2 3
1  1 
= 2e  = 1  1  1 π 
x  2e  ⇒ A =  log 2 - log 3  +  
 2  36
1
∴ I= ∫ f ( y ) log y 1 dy
www.aieeepage.com+  log 1 - 12 log 3 + log 2 
{where, y > 1}
0
⇒ I =0 π 4
∴A = + log
84.c. Here, y = f [ g ( x )] = f (cos x ) = cos 2 x 6 3 3
Again, 86. c. Equation of the tangent at (x, y)
dy
18x 2 = 9 πx + π 2 = (3x − π)(3x − π)(6x − π) = 0 Y−y= (X − x)
dx
π π
⇒ x= ,  dx   dy 
3 6 P1 =  x − y ,0  and P2 =  0, y − x 
Hence, the required area is  dy   dx 
π π dx
3 3 ⇒ 3x = x - y
1 dy
A= ∫
π
cos 2 xdx =
2π ∫
(1 + cos 2 x) dx
 dy 
6 6
and 3y = 2  y - x 
 dx 
π Both give the differential equation
1 sin 2 x  3 π
PAGE
⇒ A= x+  = 2xdy + ydx = 0
2 2  π 12 whose solution is xy2 = c
6
1 1 1
 1   π 87.a. Since, i- j + k = (a × b) × (c × d)
85. a. Since, f ( x ) = MIN tan x, cot x, 6 3 3
∀x ∈ 0, 
 3  2
1 ˆ 1ˆ 1 ˆ
⇒ i- j + k = [a b d ] c -[a b c] d
Y
y = cot x y = tan x www.aieeepage.com
1 1 1
6 3 3
⇒ î - ĵ + k̂ = [a b d] c ....(1)
C 6 3 3
1
y=
3 A B {∵ a, b, c are coplanar}
π π Now., [a b d] = a × b . d
O π X
6 3 2
⇒ [a b d] = a × b d cos θ
{∵ d ⊥ a, d ⊥ b ∴ d || a × b} ⇒ E = 2 {log100 a + log g 100}
⇒ [a b d] = ab sin 30 o.1.) ± 1) Since A.M. ≥ G.M.
1 1 log100 a + loga +100

⇒ [a b d] = 1.1. .1.(±1) = ± ⇒ ≥ log100a × loga 100 =1
2 2 2
Substituting respective value in (1), we have
⇒ log100 a + log a 100 ≥ 2
1 2 2  i - 2 j + 2k
c = ± i - j + k  = ± ∴ min (log100 a + log a 100) = 2
3 3 3  3
88. c. 91.a. We have
i 2π r
A( a ) where r = 0, 1, 2, 3, 4
α =e 5 ,
Clearly, α 5 = 1 and 1 + α + α 2 + α 3 + α 4 = 0
PAGE
O Now,
(b)B C( c ) 1
α 5 =1 ⇒α 4 =
α
1 1
V1 = (a × b) , V2 = (b × c),
2 2
1
1 1 ∴ 1+α +α 2 +α 3 − = 1+ α + α 2 + α 3 −α 4
V3 = (c × a) and V4 = {( c − a) × (b − a)}
3 2 www.aieeepage.com α
4
Now, V1 + V2 + V3 + V4 = 0 = - α 4 − α 4 = 2 α 4 = 2 α = 2 [∵ α = 1]
∴ V1 + V2 + V3 + V4 = 0 1
∴ log 2 1 + α + α 2 + α 3 − = log 2 = 1.
α
89. a. Let OA = 2 unit then OB = 4 unit and OC = 6 unit.
92.d.
Now,
93.c. The given expansion can be written as
1 1 {(1 + x)(1 + x)(1 + x)...(1+ x)}{1 + y )(1 + y )(1 + y )...(1 + y )
OD = OA + AC' + AB' = 2î + 2ĵ + 3k̂
2 2 n − factors n − factors
A’ O’ {(1 + z )(1 + z )(1 + z )....(1 + z )}

D’ n − factors
B’
C’ There are 3n factors in this product.
D To get a term of degreer, we choose r factors out of
B C these 3n factors and then multiply second terms in
each factor. There are 3n
O A C r such terms each having
coefficient 1.
Also,
3n
PAGE
Hence, the sum of the coefficients = Cr .
1 1
OD' = OC + CB' + B' O' = î + 2ĵ + 6k̂
2 2 94.a. First equation is log10 x 2
OD . OD' ∴ S∞ = 2 for G.P.

Now, cos DOD' =
OD OD' or 2 log10 x = y ...(1)
n
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(2) (1) + (2) (2) + (3) (6) From second equation S n = (a + l )
⇒ cos DOD ' = 2
4 + 4 + 9 1 + 4 + 36
2 y2 20 40
∴
 24 
∠DOD ' = cos −1  ∴ We have y (3 y + 5) = 7 log 10 x = 7 y

 697 
[By (1)]
 1 
2
⇒ 7 y 2 − 60 y − 100 = 0
90. a. Let E = 2log100a − log a  
 100 
⇒ ( y − 10) (7 y + 10) = 0
3 2
⇒ cos θ + sin θ = .
10 r
⇒ y = 10, y ≠ −
7 100.d. Convert the eqn. in normal form. Then
⇒ 2 log10 x = 10 ⇒ log10 x = 5 ⇒ x = 105 l b
= r cos(θ − α), α = Tan −1 &
95.a. The given inequality
a +b
2 2
a
| x| 1 1 1
1− ≥ ⇒ ≥ l
1+ | x | 2 1+ | x | 2 P=
a 2 + b2
⇒ 1+ | x |≤ 2 ⇒ | x | ≤ 1
⇒ − 1 ≤ x ≤ 1 ⇒ x ∈ [−1,1] ∴ foot of ⊥ r is (ρ, α ) i.e.,
96.c. Put x = r cos θ, y = r sin θ ,  l b
 2 , Tan −1 
then 3 x + 4 y = 5  a +b
2 a
PAGE
⇒ 3r cos θ + 4r sin θ = 5
5
⇒ 3cos θ + 4sin θ =
r
2
97.a. The eqn. 11+0 cos θ + sin θ = is
r
www.aieeepage.com
K
cos θ + sin θ = & passing thro`
r
(1, π 2 ) ⇒ 0 + 1 = K1 ⇒ K = 1
1
∴ cos θ + sin θ = is required eqn.
r
l
98.b. The ⊥ + 0 a cos θ + b sin θ = is
r
π  π  K
a cos θ  + θ  + b sin θ  + θ  =
2  2  r
passing thro` pole ⇒ (0, 0) ⇒
K
O+b = ⇒ O (O + b) = K
O
PAGE
⇒K =O
∴ required eqn. is −a sin θ + b cos θ = 0
b b
⇒ Tanθ = ⇒ θ = Tan -1  
a a
99.d.
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P = r cos(θ − α) is eqn. of line in normal form.
Here P = 3, α = π .
4
(
∴ r cos θ − π
4 )=3
 1 1 
⇒ r  cos θ⋅ _ sin θ ⋅ =3
 2 2
Paper - I I I : Chemistry - 101 to 150
Solutions
101.b. The bismuth endpoint is the point at which all the choice D or, better still, 2 x 3 with a decimal
bismuth in the solution has reacted with EDTA, somewhere is 6 with a power of ten after it, also
and the additional EDTA that is added then begins choice D only.
to react with the coper ions. While the EDTA reacts 104.b. This is a typical “qhat if” question if you understood
with bismuth, no increase in absorbance takes place. what was happening in figure 1 you should’ve been
This produces the straight line betwen x=0 and x= 3 able to apply your understanding to this question.
on the graph. When the EDTA reacts with copper, a Q: What will happen at the begining of this new
complex is formed that absorbs light. As this reaction reaction?
progresses, absorpotion increases; this is indicated A: At the beginning of the reaction, only the
by the linear portion of the graph with positive slope. reactnat, which absorbs light, is present/ The graph
The bismuth endpoint is the point at which should thus begin with a high positive value
PAGE
absorption just begins; this is clearly at the point Q: Now, s the titrant is added one drop at a time, it
where 3 mL of EDTA has been added, so choice B is reacts with the reactant to form the product. What
correct. Chice A is wrong because when 2.5 mL happens to the curve at this time?
EDTA has been added there is no absorption A: The conentration of the reactant decreases. As
occurring. This means that there is still some the reaction proceeeds, the amount of light
bismuth in the solution that is reacting with the absorbed by the reactant therefore also decrease,
EDTA. Choice C, 4.0 mL, is wrong because at this and the vurve should slope wownward.
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point the copper complex is forming, meaning that Q: When the endpoint is reached, what happens?
all of the bismuth has alreadyreacted. The other A: A minimum is reached. When the endpoint is
horizontal line, on the upper right side of the graph, reached, only the product will be present. At that
indicates that, once all the copper has reacted, no point the basorbance will be zeor since the product
further complex is formed and the basorption doesn’t absorb light?
remains constnats as more EDTa is added 5 mL is Q. Then what?
therefore the copper endpoint, but we are looking A: As additional titrant is added, the titrant, which
for the bismuth endpoint, so choice D is wrong. no longer has anything to react with, will accumulate
102.a. Choice B is contradicted in the passage. We looked in the solution. The titrant does absorb light, so
at the K’s and determined that the copper complex the absorbance will increase after the end point.
is less stable. Choice C is half right and half wrong, Therefore choice B is the correct answer. (this
the copper complex absorbs, but the bismuth question illustrates again, the importance of
complex does not, and thus has a zero slope. The understanding versus memory.
statement in choice D is true, but not an answer to 105.b. This question can be answered via Beer’s law. The
this question. For one thing, it is not necessary stem says that the container is twice as long, and
that the absorbance occur in the visible region. It is the answer choices al have something to do with
true that the copper EDTA complex absorbs light, absorbance; absorbance and pathlenght through
and so produces color, but there is nothing in the the container are compared in Equation 1.
passage to indicate that an especially intense color Absorbance is directly proportional to the
would be needed, so choice D is wrong. pathlength. So if we double b, we double the
103.d. This question is a good candidate for last to be absorbance at every point in the titration. The
PAGE
done. Whenever we do answer it howerver, it should absorbance would therefore increase twice as fast,
be done with a minimum of actual calculation. i.e. the slope is doubled.
The width of the container is the variable b; the
L mol EDTA mol Bi g path length that the beam must travel through . ε
mL × × × × =g
mL L mol EDTA mol is a constant and doesn’t change, c is the molar
concentration,and b is the path length. You an see
For question 1, we found that the volume of EDTA
that b and c are directly related to the absorbance,
(Y) needed was 3 mL, the question gives us the
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concentration of EDTA as 0.1 M, the passage, or its
equations, tell us that the reaction is one to one,
so any change in b or c will result in a similar change
in A. If, for example, the solution contains the
copper(II)- EDTA complex, this solution would have
and the periodic table says that bismuth weights
a certain constant absorptivity, ε . However, the
209 g/mol. We can thus plug in and calculate:
amount of light actually absorbed by a particular
1 0.1 1 209 sample will depend on the concentration of the
3× × × × = 0.0627 solution and the length of the path through which
1000 1 1 1 light travels. If the concentration is increasede,
This could have been simplified to (0.3) (0.2)=0.06, which means that the value of cc increases, then
the absorbance will also increase. Likewise, if the
distance traveled by the
light moving through the solution increases, this will also making your selection!
increase the absorbance. So, if the diameter of the 112.a. The change in Gibbs´ free energy is related to ∆ H
flask containing the solution is increased from 10
centimeters to 20 centimeters, twice as mich ight and ∆ S by the equation ∆ G = ∆ H –T ∆ S , at
will be absorbed. Therefore the value of A, for any
given concentration, will be twice as great, even equilibrium, however ∆ G =0, and T= Tequib hence
though the absorptivity per centimeter will, of
course, remain the same. The absorbance is a ∆H
measure of the actual amount of light absorbed, ∆ H = Teq ∆ S , Tequib = ∆ S .
not of the solution’s characteristic capacity to
113.c. The longest chain is seven carbons, a heptene.
absorb light. Now, if the absorbance during a
Answer C gives the lowest numbered carbon
titration had originally increased form zero to x,
attached to the double bond.
and the length of the light path were doubled, the
absorbance would then increase from zero to 2x 114.a. −21.76 × 10−19
when the same amount of titrant is added. This En of H = J
would double the slope of the graph, so the correct n2
PAGE
answer is choice B.
−21.76 × 10−19
106.d. Since Z is the number of protons and A is the ∴ En of He+ = × Z2 J
number of protons plus neutrons, Z cannot be larger n2
than A.
107.c. The atomic number defines the element. −21.76 × 10−19 × 4
∴ E3 of He+ = J
108.b. The functional groups are indicated below. 9
Hence energy equivalent to E3 must be supplied to
ester O
O
www.aieeepage.com remove the electron from 3rd orbit of He + .
Wavelength corresponding to this energy can be
O determined by applying the relation.
phenyl ring carboxylic acid
OH hc
E=
λ
109.c. N 2 H 4 
→ N2 or
2 0
Equivalent weight of hc 6.625 ×10 −34 × 3 × 108 × 9
λ= =
130 E 21.76 × 10−19 × 4
N 2 H 6 SO4 = = 32.5
4 = 0.255 × 10 −10 m=2055Å
Number of equivalents of 115.d. β in this equation represents the compressibility
5 1 factor of the system.
KMnO4 = 20 × = 116.c. Along with a collision, the molecules must have
50 × 1000 500
enough energy and must strike each other with the
and if weight of hydraize sulphate be x gm then
proper spatial orientation in order for a collision to
x occur.
equivalents of hydrazine sulphate = 117.d. Note that only I and II are correct statements.
32.5
At T1 ∆Gº is on the positive side of the ordinate.
PAGE
1 x 32.5
∴ = or x = = 0.065g
500 32.5 500  ∂ ∆ Gº 
Note also that the slope  ∆ T  , at the minima
 P
Hence wt. of N 2 H 6 SO4 in 10 ml solution = 0.065g
(T3), is zero.
∴ Wt. of N 2 H 6 SO4 in 1000ml solution = 6.5g. 118.c. The carbon atom of a carboxylic acid is at a higher
oxidation state than the carbon atom in either an
110.c. Note that when the concentration of Y is held
alcohol or an aldehyde. Potassium chromate is a
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constant at 2.0M the concentration of X is tripled,
the rate of tripled. Also, note that when [X] is held
strong oxidant. Although ozone produces an
oxidized product, it only works on alkenes.
constant at 2.0M and [Y] is tripled, the rate of
119.a. Volume of balloon =
unchanged. Hence the rate is directly related to
the concentration of [X] but independent on the 4 3 4 22 21 21 21
concentration of [Y]. πr = × × × × = 4851ml
3 3 7 2 2 2
111.b. A sneaky loophole, and probably not one you
Calculation of total volume of hydrogen in the
would have though of before seeing the answer
cylinder at N.T.P.
choices. Always read all answer choices before
change in energy (a state function) should be zero.
P1V1 P2V2
= But, from the first law of thermodynamics,
T1 T2
∆ Esystem = Qin − Wout , or, in this case,
P1 =1 atm P2 =20 atm Qin = Wout = 60, 000kJ . Some of you who have
V1 =? V2 =2.82l studied thermodynamics may be bothered by this
answer, because you think the second law of
T1 =273K T2 =273+27=300K
thermodynamics demands Wout < Qin . The
20 × 2.82 × 273 problem here is that confusion can sometimes arise
∴ V1 = = 51.324l = 51324ml
300 × 1 between two definition of Qin . In this problem, we
Actual volume to be transferred into balloons =
51324–2820ml=48504ml. are using it as the net flow of heat into the system.
No.of balloons that can be filled up = In some situations, this is broken down into a
48504 Qin and a Qout , and in that sense, it is true that
PAGE
= 9.999 = 10
4851 Wout < Qin . But that’s not the way this problem is
120.a. If matter can leave our universe, it must be open. set up.
Incidentally, Stephen Hawking has theorized that 125.b. When two ions come together to form an ionic bond,
black holes also radiate mass into our universe. energy is released. The more energy released, the
121.b. The only correct choice here is II, although the two stronger the ionic bond. The amount of energy
halves of the cell are connected by the salt bridge released is determined by the equation :
www.aieeepage.com E = 1.44 q q
which permits a current to flow, the salt bridge does
not allow mixing of the two solutions. Note also 1 2
that only the oxidation of zinc, to zinc ions (Zn2+) r2
occurs at the zinc electrode. where E=energy in eV, q1 and q2 are the charges on
122.c. Tautomers are formed when a hydrogen is moved each ion, and r is the distance between the two
within a structure. The shifted hydrogen is circled nuclei. While changes in ionic charge and ionic
below. radius will effect the energy of the bond, changes
O in temperature will not.
OH 126.c. Fatty acids are stored as triglycerides.
127.a. Standard enthalpy of hydrogenation of cyclohexene
H H (–199kJ mol–1) means the enthalpy of hydrogenation
of one double bond. Now benzene has three double
Structure A Structure B bonds, the enthalpy of the reaction would be
123.b. Initial concentration of each gas = 1 mole
Let the No. of moles of NO2 reacted at equilibrium = = 3 × −119 = −357 kJ mol –1
x
Then, + 3 H2
SO2 ( g ) + NO2 ( g ) SO3 ( g ) + NO3 ( g )
(1− x ) (1− x ) (1+ x ) (1+ x )
Actual enthalpy of the reaction can be evaluated
[SO3 ][ NO ] = K as below.
PAGE
Now we know that,
[SO2 ][ NO2 ] c or ∆ H (Reaction) =∆ H fº (Product) –∆ H fº (Reactants)
(1 + x) (1 + x) = −156 − (49 + 0)
= 16 (1 + x)2
(1 − x) (1 − x) ; (1 − x ) 2 = 16 or = −205 kJ mol –1
(1 + x) ∴ Resonance energy = ∆ H Exp − ∆ cal
=4
(1 − x )
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3
= −357 − ( −205)
= −152 kJ mol –1
1 + x = 4 − 4 x or 5 x = 3 ; x = 5 = 0.6
128.c. Vapor pressure always increases with increasing
Thus the concentration of NO at equilibrium temperature.
= 1 + x = 1 + 0.6 = 1.6 moles 129.d. In vapour phase 1 mole (or 78g) benzene has volume
Concentration of NO2 at equilibrium 78 × 1
at 20ºC = × 2750 ml
=1 − x = 1 − 0.6 = 0.4 moles 0.877
124.b. If each cycle returns to the same state, then the 1 mole (or 92g) toluene has volume at
92 × 1 a
20ºC = × 7720 ml = 0.31
0.867 a−x
PBº 78 × 2750 a − 23814 × 10 −19
∴ × = 1× 0.0821× 293 or = 0.31
760 0.877 × 1000 a
PBº = 74.74mm On usual calculations, a = 3.451× 10
−18
mol
Similarly, 131.b. Cyclopropane suffers from a great deal of ring strain,
making it far less stable than propene, Cyclohex-
Prº 92 × 7720 anone is far more stable than the ring structure of
∴ × = 1× 0.0821× 293
760 0.867 × 1000 the oxirane. The meta – and para–xylenes are
approximately equal in stability. Benzene is far more
or Pr = 22.37mm ;
º
stable than a multiply unsaturated compound and
cyclopentane is significantly more stable than
Pmixture = 46.0 mm (Given) 1-ethyle-cyclobutene due to the ring strain in the
PAGE
latter.
∴ PM = PBº ⋅ X B + Prº ⋅ X r ; 132.c. A high heat capacity means that water gain or lose
∴ 46 = 74.74 ⋅ X B + 22.37(1 − X B ) energy with smaller changes in temperature. This
corresponds to I and III only.
(∴ X B + X r = 1) 133.c. The chemical reactions taking place at the two
electrodes are
∴ on calculation X B (liquid phase) = 0.45; At cathode : Cu 2 + + 2e − → Cu
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X r (liquid phase) = 0.55 H 2O H + + OH −
Also, PB = PBº ⋅ X B (1) However, note that only Cu 2 + ions will be
discharged so as these are present in solution and
or 74.74 × 0.45 = 46.0
H − ions will be discharged only when all the
⇒ X B ( g ) = 0.73
Cu 2 + ions have been deposited.
130.c. Minimum number of β -particles required
At anode : 2OH − → H 2O + O + 2e −
=346 min–1
No. of β -particles required for carrying out the O + O → O2
6.909 × 60 minutes
experiment for Thus in first case, Cu 2 + ion will be discharged at
= 346 × 6.909 × 60 = 143431 the cathode and O2 gas at the anode. Let us cal-
∴ Amount of β -particles required culate the volume of gas ( O2 ) discharged during
143431 electrolysis.
= = 2.3814 × 10−19 mol According to Faraday’s second law
6.023 × 10 23
Now we know that, 31.75 g Cu = 8g of oxygen
PAGE
0.693 0.693 = 5.6 litres of O 2 at NTP
λ= = = 0.0104 hr −1
T1 66.6 5.6
2 0.4 g Cu = × 0.4 litres of O2 at NTP
31.75
Further we know that,
=0.07055 litres=70.55 ml
2.303 a
λ= log As mentioned earlier, when all the Cu 2 + ion will be
t a−x
where www.aieeepage.com
deposited at cathode, H ions will start going to
+
a=Initial concentration of β -particles cathode liberating hydrogen ( H 2 ) gas, i.e.

x=Consumed concentration of β -particles
H + + e− H H + H → H2
a λT 0.0104 × 6.909 However, the anode reaction remains same as
log = =− = −0.0312
a − x 2.303 2.303 previous. Thus in the second (latter) case, amount
of H 2 collected at cathode should be calculated.
8 g of O 2 = 1 g of H 2 remaining liquid becomes richer in toluene.
According to the graph, a liquid mixture 25 mole%
5.6 litres of O2 at NTP = 11.2 litres of hydrogen in benzene will boil at –100ºC. As we boil the liquid
Quantity of electricity passed after 1st electrolysis, its composition and boiling point move to the left
i.e. Q=Ct and up on the “boiling point line” until we reach
the desired point.
1.2 × 7 × 60 = 504 couloumbs 140.d. Geletinous precipitate e.g. Al(OH)3 are among the
504 coulombs will liberate most difficult to filter.
5.6 × 504 141.d. A spontaneous reaction is one in which the Gibbs
= = 29.24 ml
96500 free energy is negative. A negative ∆ G can only
Similarly, H 2 liberated by 504 coulombs be possible if ∆ H is negative and ∆ S is positive.

142.c. The Arhenius Law states that
504 K=A exp (–Ea/RT)
=11.2 × = 58.48 ml This can be rearranged to :
96500
In K= In A –Ea/RT
PAGE
Total volume of O2 liberated = If we plot in K vs 1/T, the slope of the graph is –Ea/
70.55+29.24 = 99.79 ml. R.
Vol. of H 2 liberated = 58.48 ml c 3 × 1010 cm. sec −1

143.a. v= = −3
= 1× 1013 sec −1
134.d. We can rearrange ∆ G = ∆ H − T∆ S to: λ 3 × 10 cm
144.b. CH3 CH3
∆H−∆G |
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|
T= HC ≡ CH
NaNH2 CH3CHCH2CH2Br
CH3CHCH2CH2C ≡ H
∆S NH3
has no protection group.

substituting given values :
In (1) the protected form of the reactant is
6028 − 22
T= = 273º K O O
22 Br
In (2) it is
135.d. The first step is the formation of a Grignard reagent O
(cyclohexylmagnesium bromide). This reacts with Si(CH3)3
O
ketone as shown below:
Cl MgCl 145.b. Crystal field spiltting energy for tetrahedral
+ Mg
complexes ∆t ( where only four ligands approach
MgCl
O MgCl
+
H , H2O
OH the central metal ion producing weak field around
O
+ HOMgCl
it ) is lesser ( about half ) than the crystal field
splitting energy of octahedral complexes ∆0 (
136.a. On an oxyacid, when the central atom is different
and each central atom has the same number of where six ligands approach the central metal ion
oxygens, the central atom with the greatest producing strong field around it ) ∆t and ∆ 0 are
Electronegativity produces the strongest oxyacid.
137.d. The Nearnst equation is really about non-standard 4
PAGE
conditions, so A seems doubtful. Standard potential related to each other as ∆t = ∆0
is just the potential at standard conditons. This
9
definition does not directly involve equilibrium, so 146.d ‘1000 tunch’ silver is 100% pure silver.
B seems doubtful as well. C is kind of silly if you 147.d. The ideal gas law is PV = nRT.
think about it: standard potentials are measured 148.d. As described in the question stem, a semilog plot is
under standard conditions. But D is a true statemnt: generated when one of the coordinates (usually
you need two half-reactions to make an actual the y-coordinate) is plotted as the logarithm.
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reaction. Equation 5 is an exponential equation. You may
138.c. The rate d[XY2] / dt is unaffected by changes in know that the semilog plot of such a function would
[X], therefore it is zero order in X. Tripling [Y] causes result in a straight line. This can also be seen
the rate to increase nine times, that is, by a factor of directly by actually taking the logarithm of both
32. Since the rate increases with the square of the sides.
increase in [Y], the rate is second order in Y, the rate The equation of a generic straight line has the form
law is: y = mx+b, where m is the slope and b the y-intercept.
d [XY2] / dt = k[Y]2 In this case, if we take y=In k, and x as (1/T), then
139.d. As we boil the mixture the escaping vapor contains the equation above conforms to that for a straight
more of the more volatile component, benzene. The line,
with m=-Ea/R and b = In A.
The y-intercept is b, which in this case is In A.
In k In A
1/T
Note that the y-intercept corresponds to a point

where T is infinity, and so obviously it is not an
actual data point we can measure. This is obtained
by extrapolating a straight line that can be
constructed with values from physically resonable
PAGE
temperatures.
149.a. As the pressure increases, we can see from equation
2 that the numerator and denominator wuld become
very close in value, i.e., the fraction would
approach 1.
Choice B is incorrect because it depicts the initial
region as linear, but the form of the equation is not
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that of a straight line. Also, it has the y-value become
one abruptly, rather than approaching it
asymptotically.
Choices C and D are incrrect because they show
the value of θ increasing without bound.
150.b. You probably know already that increasing the
temperature would increase the rate of a eaction.
Specifically, a general rule of thumb is that for every
100C or 10 K increase, the rate doubles. So we know
that statement II is correct.
In order to determine if statements I and III are
correct, we need to know more about HOW a
temperature increase leads to a higher reaction rate.
The temperature is an indication of the energy of
the molecules. The higher the temperature, the more
energetic these molecules are, and thus the more
likely it is that they have enough energy to overcome
the activation barrier for a reaction
Note that a high temperature does not actually lower
the activation barrier, it just makes it easier for the
molecules to overcome it. So statement III is
PAGE
incorrect.
An increase in temperature does lead to a higher
rate constant. This can be seen from equation 5. As
T increases, -Ea/RT becomes less negative: it thus
increases in value, and so does exp (-Ea/RT). k.
therefore also increases. Statement I is correct and
so B is the correct choice.
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as light were shone. 1

∆ QA→ B = ∆ U A→ B + 2 R | n 2 ⋅ (500 − 0) = 1000 R ln 2

1 ( − q ) ( dQ) q ρ Intensity at this centre = 4 I (= I C )

1 40.c. When free end which is at distance l moves with

51.d. The eqn. of chord OA is or p = aq ...(4)

both are not defined. ∴ (a) & (b) are false. M

Applying C 2 → C3 − (C1 cos D − C 2 sin D ) ⇒ - 4 sin 2θ + 3 sinθ − 4 sin 3 θ = 0

cos A sin A 0 ⇒ − sin θ + ( 4 sin 2 θ + 4 sin θ − 3) = 0

7 µ has 9 or 1 in the unit place. ⇒

78. a. The equation of a line parallel to x + 2y = 4 is x + 2y

Let the given line be the y-axis and the circle to 1 2e 4e 6e

⇒ [a b d] = ab sin 30 o.1.) ± 1) Since A.M. ≥ G.M.

1 1 log100 a + loga +100

A’ O’ {(1 + z )(1 + z )(1 + z )....(1 + z )}

OD . OD' ∴ S∞ = 2 for G.P.

48504 Qin and a Qout , and in that sense, it is true that

Now we know that, 31.75 g Cu = 8g of oxygen

a=Initial concentration of β -particles cathode liberating hydrogen ( H 2 ) gas, i.e.

Similarly, H 2 liberated by 504 coulombs be possible if ∆ H is negative and ∆ S is positive.

Vol. of H 2 liberated = 58.48 ml c 3 × 1010 cm. sec −1

has no protection group.

Note that the y-intercept corresponds to a point

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