Chem 124 Name Computer # 21

Winter 2011

Types of Reactions
Perform all the reactions listed in the procedure and write your observations for each: write either the evidence for a reaction (such as bubbles, heat, precipitate, changed from blue to yellow etc.) or NR for No Reaction. For each reaction that was observed, write out the formulas for reactants and resulting products, and balance each chemical equation. Use appropriate state labels (s for solid, aq for aqueous solution, etc). For reactants that you observe to NOT REACT, write out just the reactant formulas and then write NR after the arrow to signify no reaction. For each reaction that occurred, classify the reaction type using the following initials: C for Composition, D for Decomposition, M for Metathesis, and SD for Single Displacement.

Reactants
Nickel(II) nitrate + sodium phosphate Magnesium + water Hydrochloric acid + sodium hydroxide Copper + silver nitrate Nickel(II) nitrate + sodium chloride Nitric acid + potassium hydroxide

Evidence for a Reaction

Write your observations

Complete Balanced Chemical Equation

INCLUDE PHASE LABELS

Classify Reaction

Clouded and became a milky white color Magnecium floats and bubbles Solution was clear, then turned pink briefly, ended in a cloudy white color

Ni(NO3)2 (aq) + 2 Na3(PO4) (aq) Ni3(PO4)2 (aq) + 6(NO3)Na(aq) Mg (s) + H2O (l) Mg(OH)2 (aq) + H2 (g) HCl (aq) + Na(OH) (aq) H2O (l) + NaCl (aq)

M SD

M SD NR

Formed hairlike crystals of Cu (s) + 2AgNO3 (aq) Cu(NO3)2 (aq) + 2Ag (s) silver metal on the copper Stays light blue, no reaction Stayed clear, No reaction Ni(NO3)2 (aq) + NaCl (aq) NR

HNO3 (aq) + K(OH) (aq) NR 1

NR

Chem 124

Winter 2011

Reactants
Magnesium + oxygen gas Copper(II) sulfate + copper Hydrochloric acid + aluminum Calcium + water Zinc + copper(II) sulfate Copper(II) nitrate + sodium carbonate Iron(III) nitrate + sodium hydroxide

Evidence for a Reaction

Write your observations

Complete Balanced Chemical Equation

INCLUDE PHASE LABELS

Classify Reaction

A white powder of magnesium oxide formed with a bright light Stayed light blue NR

2Mg (s) + O2 (g) 2MgO (s) CuSO4 (aq) + Cu (s) NR

C NR SD SD SD M M

Gas emerged and heated 6HCl (aq) + 2Al (s) 2AlCl3 (s) + 3H2 (g) while a white solid formed Condensation in tube, heat exchange, and hydrogen gas, bubbled over Zinc turned black Turned a milky shade of light blue, formed precipitate Turned a cloudy gold color Ca (s) + 2H2O Ca(OH)2 + H2 (g) Zn (s) + CuSO4 (aq) Zn(SO4) (aq) + Cu (s) Cu(NO3) (aq) + NaCO3 (s) Cu(CO3) (aq) + NaNO3 (aq) Fe(NO3)3 (aq) + 3NaOH (aq) Fe(OH)3 (aq) + Na(NO3) (aq)

Chem 124

Winter 2011

Chem 124 Experiment 1 Post-Lab Exercise:

1. Using the results of your completed experiment, solubility rules and the reactivity series found in your text, predict the products of the following reactions if there would be visible evidence of a reaction. If no reaction occurs, write NR after the arrow. 1.

Na3PO4 (aq) + KNO3 (aq) Fe(NO3)3 (aq) + CrCl3 (aq) + Al (s) + Cu (s) + Ag (s) + K3PO4 (aq)

3Na(No)3 (aq) + K3PO4 (aq) Fe(PO4) (aq) + 3K(NO3) (aq) Cr2(CO3)3 (aq) + 6LiCl (aq) AlO + 3H2 (g) Cu(NO3)2 (aq) + H2 (g)
.

2. 3.
4.

Li2CO3 (aq)

H2O (l) HNO3 (aq) CuSO4 (aq) KOH (aq)

5.
6. 7.

NR K2(SO4) (aq) + 2H2O (l)

H2SO4 (aq) +

Chem 124 Winter 2011 2. Complete the following stoichiometry calculations. Note that the second one involves the Ideal Gas Law. See your textbook for review on both stoichiometry and gas laws. a. Hydrogen gas can be produced by reaction of many metals, like magnesium, with acids, like hydrochloric acid. How many grams of hydrogen gas could be produced from the complete reaction of 3.35 g magnesium with excess hydrochloric acid, according to the reaction below? Show all your work!

Mg (s) +
3.35 g Mg * 1 mol Mg 24.31 g Mg *

2 HCl (aq)
*

MgCl2 (aq) + H2 (g)

= 0.27 g H2

NOT BALANCED

1 mol H2 1 mol Mg

2 g H2 1 mol H2

b. (Oxygen can be generated by the thermal decomposition of potassium perchlorate, as described by the following equation: heat KClO4 (s) KCl (s) + 2 O2 (g) NOT BALANCED Calculate the volume of oxygen gas (in L), measured at 24.8C and 772 torr, produced by the decomposition of 3.75 g of potassium perchlorate. Show all your work!

PV = NRT NRT V= P 1 atm 722 torr = 1.01578947 atm 760 torr 24.8 C + 273 = 297.7 K

1 mol 3.75g KClO4 =138.55 mol KClO4 138.55g KClO4

V=

138.55(0.08206)297.7 = 3332.36 L O2 1.0157