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Chapter I
(b)
Xmsg-sm-Sp-n-cn-p-p. Cu hnh-c- GXp cmk kwtbm-P\ \nb-as-bmWv km[q-Icn-p-Xv ? hni-Z-am-p-I. (2) Xn-cn-p hnh-c{]-Imcw cq]o-Icn sSp HmIvssk-Up-IfpsS cmk-kq{Xw Fgp-Xp-I. (1)
Scoring key and Indicators (a) Law of Multiple proportions (1), Justification (1) (b) NO2, N2O, N2O3 (1) CO : 3 To understand mole concept through discussion, problem solving and assignments. Q.2. Complete the following table
{Kman-ep `mcw
_____________ _____________ 20g. CH4 Time : 5 minutes Score : 3
Indicators and Scoring Key 100 L CO2 4.46 mole 11.2 LN2 0.5 mole N2 28 L CH4 1.25 mole
196 g 14 g 20 g CH4
CO : 3 To understand mole concept through discussion, problem solving and assignment. Q.3 Arrange the following in the increasing order of their mass. (a) 1 g of Ca (b) 12 amu of carbon 23 (c) 6.02 x 10 molecules of CO2 (d) 11.2 L of N2 at STP (e) 1 mole of H2O
Xmsg-sm-Sp-n-cn-p-hsb `mcns Btcm-lW {Ia-n {Iao-Icn-p-I. (a) 1 g Imkyw (b) 12 amu Im_ 23 (c) 6.02 x 10 CO2 Xm-{X-I (d) 11.2 L of N2 at STP
(e) 1 mole of H2O Indicators and Scoring Key 12 (a) 1 g (b) 6.023 x1023 (b) < (a) < (d) < (e) < (c)
(c) 44 g (1)
(d) 14g
(e) 18g
(1) Total 2
C.O : 4 To elicit the idea of stoichiometry of chemical reaction through problem solving and assignments. Q.4. Nitrogen and hydrogen react to form ammonia according to the reaction. N2 + 3H2
(g) (g)
2NH3
(g)
If 750 L of H2 react with 500 L of N2 under similar conditions of temperature and pressure. (a) Calculate the volume of ammonia that will be formed in the reaction. (b) If any of the reactant is found in excess in the reaction, calculate its volume.
2NH3
(g)
UNIT - 2
STRUCTURE OF ATOM
CO: To familiarise the discovery of fundamental particles through discussion, diagrams and multimedia. Qn. Text The figure showing discharge tube experiment with perforated cathode is shown below :
Fluorescent coating B To vacuum Pump
(6)
+ + + + + + + -----
VVVVVVV
A + anode
-- Cathode
High Voltage
a. b. c.
Identify the rays marked as A and B How the above rays are formed ? Mention any two properties of each rays.
+ + + + + + + -----
VVVVVVV
A + anode
-- Cathode
High Voltage
a. b. c.
Scoring Key (a) A - Cathode ray B anode ray (b) Anode ray formation - 1 Cathode ray formation - 1 (c) Properties of Anode rays - 1 Properties of cathode rays - 1 1 Score CO : To understand the concept of quantum numbers through discussion, reference and assignment. (7) Qn. Text Quantam Numbers provide complete information about electron in an atom. a. Four sets of quantum numbers are given below. Select the possible set of quantum numbers and explain why others are not possible (i) n = 3, 1 = 1, m = 1, S = + (ii) n = 4, 1 = 1, m = 1, S = + (iii) n = 1, 1 = 0, m = 0, S = + (iv) n = 2, 1 = 2, m = 1, S = + b. Give the quantum numbers of the valence electron of an atom with atomic number 19.
Izmw kwJy-I Hcp B-nse Ce-Ivt{Sm-Wp-Isf-p-dn-p Fm hnh-cfpw \Ip-p. a. \mev skv Izmw kwJy-I Xmsg sImSp-n-cn-pp. CXn icn-bmb Izmw kwJy-I sXc-s-Sp-p-I. ap-h Fp-sImv km[y-am-Ip-n Fv hy-am-p-I.
(i) (ii) (iii) (iv) b. n = 3, n = 4, n = 1, n = 2, l = 1, l = 1, l = 0, l = 2, m = 1, m = 1, m = 0, m = 1, S = + S = + S = + S = +
Atm-anI kwJy 19 Bbp Hcp B-ns _mly-Xa sjnse Ce-Ivt{Sm-Wns Izmw kwJy-I Fgp-Xp-I. Time : 5 mts
Score : 2 + 1 = 3
Scoring Indicators : a) (ii) and (iii) correct, (i) and (iv) wrong, Explanation b) n = 4, l = 0, m = 0, S = + or -
(1 + 1)
CO To familiarise rules for filling electrons in orbitals of an atom through, discussion, reference and assignment.
(8)
a. b.
Hcp aqe-Ins Ce-Ivt{Sm hn\ymkw Hcp Ipn Fgp-Xn-bXv Xmsg ]dbpw {]Im-cam-Wv. -
1s a. b. 2s
2p
1s C.O : 2s
2p
To understand various atom models such as Thomsons atom model, Ruther Fords atom model and Bohrs atom model, through discussion, multimedia and model making. To undetrstand the nature of electro magnetic radiations and emission spectrum of Hydrogen atom through discussion, reference and problem solving. (9) Qn. Text The Hydrogen Spectrum is well explained by Bohr Model of Atom. The following diagram represents a transition of electron in hydrogen atom.
tron elec
n= n= 4 n= 3 n= 2 1
a. b. c.
Name the spectral series in which the line corresponding to the transition belongs. Calculate the wavelength of the radiation emitted during this transition. Even through there is only one electron in the hydrogen atom, its spectrum contains large number of lines. Explain.
B-ns t_m amXr-I, ssl{U-P kvs]Iv{Ss \mbn hni-Zo-Icn-p-p. Xmsg ImWn-cn-p Nn{Xw ssl{U-P B-nse Hcp Ce-It{Sm {Smknjs\ v {]Xn-\n-[o-Icn-p-p. tron elec
n= n= 4 n= 3 n= 2 1
a.
apI-fn ImWn-n-cn-p Ce-Ivt{Sm {Smkn-js ^e-am-bp-m-Ip tcJ GXv kvs]Iv{S koco-kn Ds-Sp-p. ? {]kvXpX {Smkn-js ^e-am-bp-m-Ip tdUn-tb-js Xcw-K-ssZLyw Ip-]n-Sn-p-I. ssl{U-P B-n Hcp Ce-Ivt{Sm am{X-ta-bp-p-sh-nepw AXns kvs]Iv{Sn [mcmfw tcJ-I Dv. hni-Zam-p-I. Time : 10 minutes Score : 1 + 2 + 2 = 5
b.
c.
b)
1 1 = R 2 2 n2 n1 1
Correct Substitutions. Answer with unit ( = 486.3 nm). A sample of hydrogen gas contain many hydrogen atoms. Explanation....
c)
(2) (2)
UNIT - 2
( + =1) ( + =1)
a. b. c.
Why Ionisation energy increas with atomic number in a period ? How does Ionisation very in a group ? Explain. Ionisation Energy of oxygen is less than that of Nitrogen. Why ?
a. b. c.
Hcp ]ocn-tb-Un Atm-anI kwJy IqSp-Xn-\\p-kcnv Atbm-tW-tk-j F\Pn -IqSm Imc-Wsav ? Hcp {Kqn Atbm-ssW-tk-j F\Pn amdp-Xv F-s\sbv hni-Zam-p-I. HmIvkn-Ps Asbm-ssW-tk-j F\Pn ss\{S-P-s-Xn-t\-m Ipd-hm-Wv. Fp-sImv ?
Time : 7 minutes Score : 1 + 1 + 1 = 4
Scoring Indicators : a. b. Atomic size decreases, effective nuclear charge increases, hence removal of electrons is difficult. (1) Decreases down the group Atomic size increases Effective nuclear charge decreases Extra stability of half - filled configuration of nitrogen () () ()
c.
C.O : (Same as above) (12) Qn. Text A group of ions are given below. Na+, Al3+, O2--, Ca2+, Mg2+, F--, N3-, Br-8
a. b.
Two of the above ions are not iso electronic. Identify them. Arrange them in the order of increasing ionic radii ?
Ch-bn cv Atbm-Wp-I sFtkm Ce-Ivt{Sm-WnIv B. Ch Is-pI ? Chsb Atbm-WnI tdUn-bkns Btcm-lW {Ia-n Fgp-Xp-I. Time : 4 minutes Score : 1 + 1 = 2
UNIT - 4
ip{Is A-co-n Im_ k_v HmIvssk-Uns C3O2 kmnyw ASp Imev Is-n-bp-p-v. Cu C3O2 \v eqbnkw kv{SIvN \nt-in-p-I. (kq-N\ : HmIvkn-P B- tamfn-Iyq-fns A-m-Wv.)
Time : 3 minutes Score : 1 + 1 = 2
Mental Process : 7, 9
Scoring Indicators Key points and Distribution of scores. a) b) [Ca]2+ [:.F.:]2 or [:.F.:] [Ca]2+ [:.F.:] 1
:O::C: :C: :C: :O:
..
..
..
1 score
C.O: 18, 54 Qn. 14 The steps involved in the formation of KCL are given below in a random order. Cl (g) + e Cl--(g) H1 = - 355 KJ / mol = +89 KJ/mol
K ( g ) , H 2 K (s)
Cl2 Cl , H ( g ) 3
K (+g ) + e K(g)
H4
KCl(s) , Hf
a) b) c) Q.
Construct the Born Haber Cycle using the above steps. Calculate the value of Hf Name the law on which the above calculation is based on.
cq]-s-Sp-Xns hnhn[ L-, {Ia-cln-Xambn Xmsg-sm-Sp-n-cn-p-p. Cl (g) + e Cl--(g) H1 = - 355 KJ / mol = +89 KJ/mol
K ( g ) , H 2 K (s)
Cl2 Cl , H ( g ) 3
K (+g ) + e K(g)
H4
KCl(s) , Hf
a. b. c.
apI-fn sImSp sp-I D]-tbm-Knv t_m-tl-_ sskn cq]-sSpp-I. {]kvXpX cmk-{]-h-\ns Hf aqeyw Ip-]n-Sn-p-I. GXp \nb-as ASn-m-\am-n-bm-Wv, Hf Ip-]n-Sn-p-Xv. Time : 3 minutes Score : 1 + 2 + = 4 10
Hesss Law
C.O : 21 Qn. 15 Complete the following table Molecule CH4 NH3 PCl5 XeF4 Q. No. of bond pair on Central atom ......... 3 ........... ........... No. of lone pair on central atom 0 ........... ........... ........... Shapes ........... .......... Triagonal bipyramidel Square planar
t_mv s]b-dp-IfpsS Fw
......... 3 ........... ...........
BIrXn
........... .......... Triagonal bipyramidel Square planar Time : 7 minutes Score : 4
11
C.O. 22, 23, 24 Qn. 16 Account for the following. a) b) c) Q H2O is a liquid while H2S is a gas at room temperature. Even though N-F bond is more polar than N-H bond, NH3 has greater dipole moment than NF3. H2 molecule is formed while He2 does not.
Mental Process : 6, 7 Scoring Indicators, Key, distribution of success. a) b) c) Hydrogen bonding in H2O Diagrams of NH3 and NF3 showing dipoles - lone pair and N-F moments in opposite direction - cancels. Filled orbitals - Against Paulis Principle.
UNIT - 5
STATES OF MATTER
CO : 5 To understand gas laws and ideal gas equation through discussion and problem solving. Qn. 17 The effect of pressure on the volume of 0.09 mole of CO2, at 300 K is given below. a) b) c) Plot a graph of PV against P Give the nature of the graph. Which grap law is verified here ? A balloon occupies a volume of 700 ml at 250C and 760 mm of pressure. What will be its volume at a higher attitude where temperature is 150C and pressure is 600 mm of Hg. 12 (1) (1) Pressure / 104 Pa 2 3.5 6.0 8.0 10.0 Volume / 10-3 m3 112 64.2 37.4 28.1 22.4
PV
b)
( + = 1)
c)
(2)
C.O : 6 To familiarise Kinetic Theory of gases and to understand the deviation of real gases from ideal behaviour through discussion, problem solving and charting. Qn. 18 The following graphs are obtained for He at different conditions.
13
PV nRT
PV nRT
The graph A is drawn at high Temperature and low pressure and graph B is drawn at low Temperature and high pressure. a) Which graph represents ideal behaviour ? b) Compare the two graphs and justify your observation highlighting the faulty assumptions of Kinetic Theory of gases.
PV nRT
PV nRT
{Km^v F hc-n-cn-p-Xv Db Dujvam-hnepw Xmgv a-n-ep-am-Wv. {Km^v _n hc-n-cn-p-Xv Xmgv Dujvam-hnepw Db a-n-ep-am-Wv. a. GXp {Km^mWv "sFUn-b' kz`m-hs kqNn-n-p-Xv. b. Cu {Km^p-I hni-Ie\w sNbvXv Kinetic Theory of gasse sXmb \nK-a\ - hni-Zam-p-I. Time : 5 minutes Score : 3 Scoring Indicators with Key a) b) C.O : 8 To understand the concept of liquefaction of gases through discussion and reference. 14 Graph A Two faulty assumption and Explanation 1 Score 1 + 1 = 2 score
Qn. 19 Critical temperature of some substances are given below. Substance H2 N2 CO 2 NH3 Tc /K 33.2 126 304.1 405.5
a) b)
Which of the above gas can be easily liquefied. Is it possible to liquify CO2 gas above 31.10C by applying pressure ? Comment.
GXm\pw Kymkp-IfpsS {Inn- sSw]-td- Xmsg-n-cn-p-p. Substance H2 N2 CO 2 NH3 Tc /K 33.2 126 304.1 405.5
a) b)
15
Qn. 20 a) Certain properties of liquids are given below. Classify them on the basis of effect of temperature on them. Evaporation, Vapor pressure, surface Tension, Viscocity Boiling does not occur when a liquid is heated in a closed vessel. Comment on the statement.
b) a)
{Zmh-IfpsS GXm\pw khn-tij KpW- Xmsg-sm-Sp-n-cn-p-p. Dujvam- hns kzm[o-\n-\\p-kcnv Ahsb Xcw-Xn-cn-p-I. _mjv]o-IcWw, hmX-Iaw, - {]X-e_ew, hnkvtIm-kn-n. - AS ]m{X-n Hcp {ZmhIw Nq-Sm-n-bmepw Xnf-bvp-n-.
Time : 7 minutes Score : 4
b)
Scoring Key with Indicators a) Those which increase with increase in Temp Evaporation, V.P - 1 Those which decrease with increase in Temp. S.T, Viscosity - 1 b) Density of the liquid phase and vapour phase becames same. The clear boundary between liquid and vapour disappears Explanations - 2 score
C.O : 5 To understand gas laws and ideal gas equation, through discussion and problem solving. Qn. 21 A graph representing variation of pressure with 1/v at a particular temperature T, is given below.
T1
1 v
T3
a) b)
Resketch the graph and include graphs for two temperatures T2 and T3. Where T2>T1>T3. Name the graph 16
{Km^mWv XmsgmWn-n-cn-p-Xv. -
T1
1 v
T3
a)
Cu T, Dujvam-hn-t\-m Db Dujvam-hmb T2, Xmgv Dujvam-hmb T3 Fnhbn Dm-Ip Pressure, 1/volume hyXn-bm\w Ds-Spn {Km^ns\ ]p\h-cbvp-I. (T2>T1>T3] Cu {Km^p-Iv Fp t]cmWv ]d-bp-Xv. Time : 6 minutes Score : 3
b)
P T3
1 V
T3
b)
Isotherm - Score 1
17
UNIT - VI
THERMODYNAMICS - 1
C.O : 51 Q. Text : Select the odde one out from the following sets. i) ii) iii) Temperature, pressure, mass, density (Insensitive property) Human body, Earth, water in a closer vessel (Types of system) Internal energy, work, enthalpy, entropy (State Function)
Dujvam-hv, aw, amv, k{X, amv (Ckohv t{]mn) a-\pjy ico-cw, `qan ASv sh ]m{X-nse shw (-\y-XykvX hyql-) CtW F\Pn, {]hr-n, FYm]n, Ft{Smn (tv ^Mvj)
Time : 5 minutes Score : 3
Mental Process : 3, 7 Scoring Indicator with key points i) ii) iii) mass - extensive property Water in a closer vessel - closed vessel Work path formation -1 -1 -1
C.O : 52 Q. Text : Calculate the internal energy change in each of the following systems. System - I System II System III 10 KJ heat energy is released by the system to the surrounding but no work in done No heat change with surrounding but 25 KJ of work is done on the system 25 KJ of heat energy is absorbed by the system and 10 KJ of work is done by the system.
hyqlw 3
Mental Process : 5, 7 Scoring Indicator with key : System I II III C.O: 53 Q. Text : An experimental data is given U = -10KJ U = +25 KJ U = 25 -- 10--15KJ U = q+w
N 2 + 3H 2 2NH 3
(g) (g)
(g)
H = -91.8 KJ/mol
a) b) i) ii)
Give the significance of -ve sign of H From the above data calculate H values for the following reactions.
2NH3 N 2 + 3H 2
(g) (g)
(g) (g)
(s)
H = ?
(g)
2NH 2 + 6H 2 4 NH 3
H = ?
H = -91.8 KJ/mol
a) b)
i) ii)
H = ?
(g)
H = ?
Time : 5 minutes Score : 3
-1 -1 -1
19
C.O: 54 Q. Text CO2 can be prepared from C and O2 by different methods. Method 1 Method 2 C(graphite) +O2(g) CO2 (g) C(graphite) +O2 (g) CO (g) CO (g) + O2 (g) CO2 (g) It is found that total enthalpy change in two methods are same. a) b) State the law behind this observation. Calculate the standard enthalpy of formation of CH3-OH(l) from the following data. CH3-OH(l) +3/2O2 (g) CO2 (g) +2H2O(l) C(s) +O2(g) CO2 (g) H2(g) + O2 (g) -- H2O(l) H0 = -726KJ/mol H0 = -393KJ/mol H0 = -286KJ/mol 2 1
Xmsg Xncnp hkvXpXIfn \npw CH3-OH(l) s mtUUv FYm]n Hm^v t^mtaj Ip]nSnpI.
CH3-OH(l) +3/2O2 (g) CO2 (g) +2H2O(l) C(s) +O2(g) CO2 (g) H2(g) + O2 (g) -- H2O(l) H0 = H0 = H0 = -726KJ/mol -393KJ/mol -286KJ/mol 2
Time : 5 minutes Score : 3 Scoring Indicator with Key a) b) Hesss Law of Constant heat summation
0 C(s) + 2H2(g) + O2(g) CH3-OH(l) H = -239KJ/mol
1 2
20
UNIT 7
CHEMICAL EQUILIBRIUM
C.O 57 Consider a general gaseous reaction aA + bB i) ii) iii) cC + dD 1 2
Give the expression for Kp and Kc for the above reaction Suggest two equilibria for which Kp and Kc are equal. Give justification
For the equilibrium 2SO3 (g) 2SO2(g) + O2(g) Kc at 4700C is 3.25x10-9mol /lit. What will be the value of Kp at this temperature ? 2
\ntinpI.
2SO3 (g) 2SO2(g) + O2(g) F kpe\mhbn 4700C KC bpsS aqeyw -9 3.25x10 mol /lit BsWn CtX Dujvamhn KpbpsS aqeysambncnpw. 2 Time : 8 min Score : 5 Mental Process 5,6,7 Scoring Indicators i) ii) iii) Expressions for Kp & Kc Two suitable equilibria Equation Answer with unit 1x2=2 1x2=2 1 1
21