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Internal assessment resource number Chem/2/_G2 PAGE FOR TEACHER USE

2008 Internal Assessment Resource


Subject Reference: Chemistry 2.3 Internal assessment resource reference number: Chem/2/3_G2

Chemistry Calculations 2

Supports internal assessment for: Achievement Standard 90763 v2 Solve simple quantitative chemical problems Credits: 2

Date version published: Ministry of Education quality assurance status

April 2008 For use in internal assessment from 2008

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Internal assessment resource number Chem/2.3_G2 PAGE FOR STUDENT USE

2008 Internal Assessment Resource Subject Reference: Chemistry 2.3 Internal assessment resource reference number: Chem/2/3_G2 Chemistry Calculations 2 Achievement Standard 90763 v2 Solve simple quantitative chemical problems Credits: 2 Time allowed: 1 hour This is a closed book activity.

Student Instructions Sheet


For some of the following calculations you will need to refer to the Periodic Table on page 6 to find the required molar masses of elements. Give answers to 3 significant figures where appropriate. 1 Calculate the amount (in moles) of carbon dioxide, CO2, in 23.0 g of the gas? M(CO2) = 44.0 g mol1

Calculate the mass of 2.65 mol of sodium hydroxide, NaOH. M(NaOH) = 40.0 g mol1

24.5 mL of a solution contains 0.00257 mol of HCl. Calculate the concentration, in mol L1, of the HCl solution.

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Internal assessment resource number Chem/2.3_G2 PAGE FOR STUDENT USE

Calculate the amount (in mole) of NaOH present in 15.6 mL of 0.152 mol L1 solution.

5(a) Caffeine is a stimulant which has a mass composition of 49.5% carbon, 5.20% hydrogen, 28.9% nitrogen and 16.5% oxygen. Calculate the empirical formula of caffeine.

(b)

If the molar mass of caffeine is 194 g mol1, use your answer to part (a) above to determine the molecular formula of caffeine.

6.

Calculate the percentage of carbon and oxygen in sucrose, C12H22O11.

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Internal assessment resource number Chem/2.3_G2 PAGE FOR STUDENT USE

500 mL of 0.253 mol L1 NaHCO3 solution is mixed with 800 mL of 0.824 mol L1 NaHCO3 solution. What is the concentration of the final solution?

A chemist found that 4.69 g of sulfur combined with fluorine to produce 15.81 g of gas. Determine the empirical formula of the compound.

What mass of CO2 is produced in the complete combustion of 36.5 g of ethanol according to the following equation? C2H5OH + 3 O2 2 CO2 + 3 H2O

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Internal assessment resource number Chem/2.3_G2 PAGE FOR STUDENT USE

10

What mass of iron can be produced if 50.0 g of carbon monoxide react with iron(III) oxide according to the following equation? Fe2O3 + 3 CO 2 Fe + 3 CO2

11

Hydrated magnesium sulfate is heated in a crucible. The following data is collected: mass of crucible and lid = 26.49 g mass of hydrated magnesium sulfate = 2.13 g mass crucible, lid and magnesium sulfate after first heating = 27.55 g mass of crucible, lid and magnesium sulfate after second heating = 27.53 g Use these results to determine the formula of hydrated magnesium sulfate. M(MgSO4) = 120.3 g mol1 M(H2O) = 18.0 g mol1

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Internal assessment resource number Chem/2.3_G2 PAGE FOR STUDENT USE

PERIODIC TABLE OF THE ELEMENTS 18 Atomic Number 1 3 Li 6.9 11 Na 23.0 19 K 39.1 4 Be 9.0 12 Mg 24.3 20 Ca 40.1 21 Sc 45.0 2 1 H 1.0 Molar Mass / g mol
1

2 13 5 B 10.8 13 Al 27.0 6 C 12.0 14 Si 28.1 14 7 N 14.0 15 P 31.0 15 8 O 16.0 16 S 32.1 16 9 F 19.0 17 Cl 35.5 17 He 4.0 10 Ne 20.2 18 Ar 40.0

3 22

4 23 Ti 47.9

5 24 V 50.9

10

11

12

25 26 27 28 29 30 31 32 33 34 35 36 Cr Mn Fe Co Ni Cu Zn Ga Ge As Se Br Kr 52.0 54.9 55.9 58.9 58.7 63.5 65.4 69.7 72.6 74.9 79.0 79.9 83.8 46 Pd 106 78 Pt 195 47 48 49 Ag Cd In 108 112 115 79 80 81 Au Hg Tl 197 201 204 50 Sn 119 82 Pb 207 51 Sb 122 83 Bi 209 52 Te 128 84 Po 210 53 I 127 85 At 210 54 Xe 131 86 Rn 222

37 38 39 40 41 42 43 44 45 Rb Sr Y Zr Nb Mo Tc Ru Rh 85.5 87.6 88.9 91.2 92.9 95.9 98.9 101 103 55 Cs 133 87 Fr 223 56 Ba 137 88 Ra 226 71 Lu 175 103 Lr 262 72 Hf 179 104 Rf 73 Ta 181 105 Db 74 W 184 106 Sg 75 Re 186 107 Bh 76 77 Os Ir 190 192 108 Hs 109 Mt

57 Lanthanide Series La 139 89 Actinide Series Ac 227

58 Ce 140 90 Th 232

59 Pr 141 91 Pa 231

60 61 62 63 64 65 66 67 68 69 70 Nd Pm Sm Eu Gd Tb Dy Ho Er Tm Yb 144 147 150 152 157 159 163 165 167 169 173 92 93 94 95 96 97 98 99 100 101 102 U Np Pu Am Cm Bk Cf Es Fm Md No 238 237 239 241 247 249 251 254 257 258 255

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Internal assessment resource number Chem/2/3_G2 PAGE FOR TEACHER USE

AS90763 v2 Assessment Schedule: Chemistry Calculations 2 - Chem/2/3_G2 Q 1 2 3 4 5 n(CO2) =


23.0 g 44.0 g mol
1

Evidence = 0.523 mol


1

Judgement for Achievement Correct Correct Correct


3

Judgement for Merit

Judgement for Excellence

m = 2.65 mol x 40.0 g mol = 106 g c=


0.00257 mol 24.5 x 10
3

= 0.105 mol L x 15.6 x 10


1
3

L
1

n = 0.152 mol L

L = 2.37 x 10

mol

Correct
1

(a) n(C) = n(N) =

49.5 g 12.0 g mol

= 4.13 mol n(H) = n(O) =

5.20 g 1.0 g mol 16.5 g

= 5.20 mol = 1.03 mol

28.9 g 14.0 g mol


1

= 2.06 mol

16.0 g mol 1

Amount in moles of each element correct. Correct process, but incorrect empirical formula used.

Empirical and molecular formulae correct.

empirical formula C4H5N2O (b) molecular formula C8H10N4O2 6 M(C12H22O11) = 342 g mol1 % C= %O= 7
144 g 342 g mol 1 176 g 342 g mol 1

x 100 = 42.1 % x 100 = 51.5 %

Process correct but incorrect molar mass of sucrose used.

% of C and O correct

n(NaHCO3) = (0.253 mol L1 x 0.500 L) + (0.824 mol L1 x 0.800 L) = 0.786 mol Total volume = 1.30 L concentration of final solution =
0.786 mol 1.3 L

= 0.604 mol L1

Correct total amount of NaHCO3 OR correct process for calculating concentration using a volume of 1.3 L.

Correct determination of concentration of final solution.

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Internal assessment resource number Chem/2/3_G2 PAGE FOR TEACHER USE

n(S) =

4.69 g 32.1g mol


1

= 0.146 mol

Correct amount of S OR F.

m(F) = 15.81 4.69 = 11.1 g n(F) =


11.1g 19.0 g mol 1

Correct process with one minor error. eg Incorrect mass of F.

Correct determination empirical formula.

= 0.584 mol

Hence S : F = 1 : 4 and empirical formula is SF4. 9 M(C2H5OH) = 46.0 g mol1 (i) n(C2H5OH) =
36 .5 g 46 .0 g mol 1

36.5 g / 46.0 g mol1 = 0.793 mol

Correct process used in either step (i) or (iii).

(ii) n(CO2) = 2 x n(C2H5OH) = 1.59 mol (iii) m(CO2) = 1.59 mol x 44.0 g mol1 = 69.8 g 10 (i) n(CO) =
2 3

Correct process with one minor error. eg An incorrect molar mass.

Correct answer for mass of CO2 produced.

50 .0 g 28 .0 g mol
1

= 1.79 mol

Correct process used in either step (i) or (iii).

(ii) n(Fe) = x n(CO) = 1.19 mol (iii) m(Fe) = 1.19 mol x 55.9 g mol1 = 66.5 g 11 mass of anhydrous MgSO4 = 1.04 g mass of H2O = 1.09 g amount of MgSO4 = amount H2O =
1.04 g 120 .3 g mol
1

Correct process with one minor error. eg An incorrect molar mass. Correct determination of either amount of MgSO4 or H2O.

Correct answer for mass of Fe produced.

= 8.65 x 103 mol

Correct determination of masses of MgSO4 and H2O.

Correct formula for hydrated salt.

1.09 g 18.0 g mol 1

= 6.06 x 102 mol

ratio n(H2O) / n(MgSO4) = 7 formula is MgSO4.7H2O

Sufficiency Statement In the application of the assessment schedule, the learner's response to each question is only awarded one level of A, M or E. The requirements for sufficiency are as follows:
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Internal assessment resource number Chem/2/3_G2 PAGE FOR TEACHER USE

Achievement Merit Excellence

SIX questions answered correctly at achievement or higher. 6xA SEVEN questions answered correctly with FOUR answers at merit level or higher PLUS THREE answers at achievement level or higher. 4xM + 3xA EIGHT questions answered correctly with THREE answers at excellence level PLUS TWO answers at merit level or higher PLUS THREE other answers at achievement level or higher AND answers to all questions except 5, 8 and 11 require 3 significant figures and units. 3xE + 2xM + 3xA

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