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Given:
y y y y y
EDTA soln prepared by 4.0 gram disodium salt dissolved in 1 liter water Average of 42.35 mL req to titrate 50.0 mL aliq of 0.7682 g MgCO3/L std. Titration of 25 mL mineral water at pH 10 req 18.81 mL of EDTA. A 50 mL aliq of mineral water (made alkaline to ppt Mg as Mg(OH)2 and w/ Ca-spec indicat) req 31.54 mL EDTA soln. Calc a) Molarity of EDTA soln. (b) conc(ppm) of CaCO3 in water (c) conc (ppm) of MgCO3
0.04235 L x M = = M=
= 0.010757 M
ppm CaCO3 =
c) mmole CaCO3 = mmole EDTA (w/o Mg) wt CaCO3 (mg) = 31.54 mL x 0.010757 mmol/mL x 100.087 mg/mmol = 33.9571 mg (in 50 mL water sample) ppm CaCO3 = = = 679.14 mg/L (ppm) as CaCO3
y y y
(CaCO3 + MgCO3) - CaCO3 810 mg/L 679.14 mg/L = 130.96 mg/L CaCO3 130.96 mg/L CaCO3 x
17.25. Given:
y y y y y y
Calamine = mixture of Zn and Fe oxides 1.022 g calamine dissolved in acid and diluted to 250 mL KF was added to 10 mL aliq to mask the Fe After adjustment of pH, titration of Zn 2+ consumed 38.71 mL (0.01294 M) EDTA A 2nd aliq 50 mL, added w/ buffer and titrated, consumed 2.4 mL (0.002727 M ) ZnY 2- solution Calculate % ZnO and % Fe2O3 in the sample Fe3+ + ZnY2FeY- + Zn 2+
Solution: mmole Zn = mmole EDTA mg Zn = 38.71 mL x 0.01294 mmol/mL x 65.409 mg Zn/mmol = 32.7639 mg Zn in 10 mL aliquot mg Zn = 32.7639 mg x
= 819.096 mg Zn
mg ZnO = 819.096 mg Zn x
= 1019.4464 mg ZnO
% ZnO =
x 100 = 99.75%
mmole Fe = mmole EDTA mg Fe = 2.4 mL x 0.002727 mmol/mL x 55.845 mg Fe/mmol = 0.3655 mg Fe in 50 mL aliquot mg Fe= 0.3655 mg Fe x
= 1.8275 mg Fe
= 2.6128 mg
% Fe2O3 =
x 100 = 0.25%
17-29. Given:
y y y y y y
0.3284 gram Brass sample (containing Pb, Zn, Cu, Sn) dissolved in HNO3 SnO2.4H2O was removed by filtration, filtrate was diluted to 500 mL 10 mL aliq + buffer, for titration of (Pb, Zn, Cu) required 37.56 mL (0.0025 M) EDTA In a 25 mL aliquot, Cu was masked w/ thiosulfate, then Pb and Zn were titrated with 27.67 mL EDTA. In another 100 mL aliquot, CN- ion was used to mask the Cu +Zn; and titration of Pb required 10.80 mL EDTA Determine composition of the brass sample; evaluate % Sn by difference.
Solution: Conc of Pb, Zn, Cu in 10 mL aliquot = 37.56 mL x 0.0025 mmol/mL x Conc of Pb, Zn in 25 mL aliquot = 27.67mL x 0.0025 mmol/mL x
= 4.695 mmol
= 1.39 mmol
= 0.135 mmol Conc of Pb in 100 mL aliquot = 10.8 mL x 0.0025 mmol/mL x --------------mg Cu = [4.695 mmol 1.39 mmol] x 63.546 mg Cu/mmol = 210.02 mg Cu
% Cu = ----------------
x 100 = 63.95%
% Zn =
x 100 = 24.996%
x 100 = 8.50%
17.32 Titration Curve Derive a titration curve for 50 mL (0.01M) Sr2+ w/ 0.02M EDTA in a solution buffered to pH 11.0 Calculate p Sr values after addition of 0.0 mL, 10.0 mL, 24.0 mL, 24.9 mL, 25.0 mL, 25.1 mL, 26.0 mL, and 30.0 mL EDTA
Solution: K SrY = 4.3 x 108 KSrY = 4 K SrY ; [ 4 EDTA at pH 11 = 0.85] KSrY = 0.85 (4.3 x 108) = 3.655 x 108 *At Initial pt and pre-equiv pt, pSr are computed from equil conc. At 0.0 mL EDTA added, [Sr2+] = At 10.0 mL EDTA added, [Sr2+] = At 24.0 mL EDTA added, [Sr2+] = At 24.9 mL EDTA added, [Sr2+] =
1 x 10-2 M
pSr = 2.0 5 x 10-3 M 2.7 x 10-4 M 2.67 x 10-5 M pSr = 2.3 pSr = 3.6 pSr = 4.6
[Sr2+ ]2 =
= 4.27 x 10 -6
pSr = 5.37
; KSrY =
KSrY; [Y4-] =
4 CT
8.00 7.16
7.86
7.00
6.00
6.15 5.37
5.00
pSr
4.00
4.60
1.00