Environ Fluid Mech DOI 10.

1007/s10652-006-9001-8 O R I G I NA L A RT I C L E

Multiscale plume transport from the collapse of the World Trade Center on september 11, 2001
Georgiy Stenchikov Nilesh Lahoti David J. Diner Ralph Kahn Paul J. Lioy Panos G. Georgopoulos

Received: 23 November 2005 / Accepted: 16 May 2006 Springer Science+Business Media B.V. 2006

Abstract The collapse of the world trade center (WTC) produced enhanced levels of airborne contaminants in New York City and nearby areas on September 11, 2001 through December, 2001. This catastrophic event revealed the vulnerability of the urban environment, and the inability of many existing air monitoring systems to operate efciently in a crisis. The contaminants released circulated within the street canyons, but were also lifted above the urban canopy and transported over large distances, reecting the fact that pollutant transport affects multiple scales, from single buildings through city blocks to mesoscales. In this study, ground-and space-based observations were combined with numerical weather forecast elds to initialize nescale numerical simulations. The effort is aimed at reconstructing pollutant dispersion from the WTC in New York City to surrounding areas, to provide means for eventually evaluating its effect on population and environment. Atmospheric dynamics were calculated with the multi-grid Regional Atmospheric Modeling System (RAMS), covering scales from 250 m to 300 km and contaminant transport was studied using the Hybrid Particle and Concentration Transport (HYPACT) model that accepts RAMS meteorological output. The RAMS/HYPACT results were tested against PM2.5 observations from the roofs of public schools in New York City (NYC), Landsat images, and Multi-angle Imaging SpectroRadiometer (MISR) retrievals. Calculations accu-

G. Stenchikov (B ) Department of Environmental Sciences, Rutgers University, New Brunswick, NJ 08901, USA e-mail: gera@envsci.rutgers.edu N. Lahoti P. J. Lioy P. G. Georgopoulos Department of Environmental and Occupational Medicine, UMDNJR.W. Johnson Medical School, Piscataway, NJ 08854, USA N. Lahoti P. J. Lioy P. G. Georgopoulos Environmental & Occupational Health Sciences Institute, UMDNJR.W. Johnson Medical School & Rutgers University, Piscataway, NJ 08854, USA D. J. Diner R. Kahn Jet Propulsion Laboratory, California Institute of Technology, Pasadena, CA 91109, USA

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rately reproduced locations and timing of PM2.5 peak aerosol concentrations, as well as plume directionality. By comparing calculated and observed concentrations, the effective magnitude of the aerosol source was estimated. The simulated pollutant distributions are being used to characterize levels of human exposure and associated environmental health impacts. Keywords Aerosol plume Particulate matter Transport Urban pollution Regional Atmospheric Modeling System Hybrid Particle and Concentration Transport Model Multi-angle Imaging SpectroRadiometer World Trade Center 9/11 Terrorist attack 1 Introduction This study considers the transport of airborne contaminants (mostly particulate matter [PM] or aerosols) produced by the collapse of the world trade center (WTC) in New York City (NYC) on September 11, 2001, and by the subsequent burning of the remaining materials. The massive release of aerosols and gases on September 11 affected numerous residents and commuters in the surrounding New York/New Jersey (NY/NJ) area. The continued threat of terrorist attacks on major cities raises a new issue: developing a better understanding of the ambient exposures and associated health effects caused by a massive pollutant release in highly populated areas [13]. The overall objective of this study is to reconstruct the WTC plume dispersion in NYC and surrounding areas using available ground- and space-based observations and numerical modeling to better characterize its environmental and health effects. The north and south WTC buildings were set on re by terrorist attacks at 0846 EDT and 0903 EDT, respectively, on September 11, 2001. The collapse of the WTC South Tower at 0959 EDT followed by the crash of the North Tower at 1029 EDT instantaneously produced vast amounts of coarse and ne airborne particles that spread upward and into the streets of southern Manhattan. This initially produced an intensive but relatively short-term particulate mass and gaseous release into the urban atmosphere. Materials were deposited on roofs, streets and other at surfaces and were re-suspended later by the wind, contributing to the overall airborne contamination levels from September 11 through September 13. The remains of the WTC complex, covering a 16-acre area known as ground zero, burned with varying degrees of intensity until September 14, occasionally reaching temperatures exceeding 1, 000 C. After September 14 the re began to diminish due to rain. The re at ground zero produced a continuous source of hazardous gases and aerosols for an extended period of time, which were dispersed in NYC and the surrounding areas. A detailed spatial and temporal evaluation of the airborne contaminant distribution is needed to fully understand the environmental and health impacts of the WTCs collapse. However, the existing ground-based observation networks (both for meteorological characteristics and particulate matter) are fairly sparse for this purpose, even in the NY/NJ metropolitan area. Many monitoring stations in the vicinity of the WTC did not operate properly, as they were completely plugged by large amounts of dust immediately after the collapse, or they were unavailable because of the short-term nature of the initial releases combined with the loss of electricity. Quantitative, satellite-based measurements were limited in temporal coverage. As a result, many important characteristics of the dispersed pollution eld could not be easily determined to help understand the details of associated human exposures. In

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the current study, numerical modeling of micrometeorological elds and PM transport was combined with available observations to reconstruct plume behavior as realistically as possible, and to quantitatively estimate the rate of pollutant release. In NYC and the nearby areas, air pollution is a long-standing and well-recognized health issue [4]. This region is one of the most densely populated in the US. Among the sources regularly contributing to atmospheric aerosol loading are local industries and utility generation, motor vehicle emissions, residential cooking and heating, dust raised from disturbed soils, and marine aerosol production over the coastal waters. In addition, long-range transport of emissions from the industrialized Midwest and BaltimoreWashington areas contribute to the overall pollution level [512]. However, the unexpected nature of the catastrophic event on September 11, 2001 prevented the collection of adequate amounts of quantitative information necessary to establish risk. Transport and deposition of atmospheric tracers is highly dependent on local circulation, turbulent mixing in the boundary layer, terrain, and precipitation. Using meteorological elds with a coarse spatial resolution often causes uncertainties in calculations of contaminant distribution. Unfortunately, ne-scale meteorological elds are not available from observations, and operational forecast models provide meteorological elds with spatial sampling that is not sufcient for high-resolution transport calculations. In this study, the Regional Atmospheric Modeling System (RAMS) (http://www.atmet.com/html/docs/documentation.shtml) was employed to downscale the analysis elds from the Eta Weather Prediction Model [13] conducted with spatial resolution of approximately 32 km. The RAMS databases of land elevation, vegetation cover, and sea surface temperature were improved to account for ne-scale effects of the land-surface boundary conditions and sea surface temperature. The downscaled meteorological elds were used in the Hybrid Particle and Concentration Transport model (HYPACT) (http://www.atmet.com/html/docs/documentation.shtml) for the ne grid transport and deposition calculations. The HYPACT uses RAMS meteorological output for calculating aerosol transport from localized sources combining Lagrangian and Eulerian approaches. RAMS is a comprehensive mesoscale meteorological model, which is not fully capable of simulating the ow within the citys street canyons. However, it can accurately calculate the ow above the buildings, linking it to larger-scale meteorological structures. To account for the effects of buildings on the ow in the boundary layer, the surface roughness over Manhattan was increased up to 1 m, which is a typical magnitude for metropolitan urban areas [6]. To account for the multi-scale structure of the transport, calculations were conducted in three nested domains (Fig. 1). The largest domain has a regional scale of 300 km, covering NYC and nearby areas of NY/NJ with the grid spacing of 4,000 m. The internal domains allowed calculation of the ow at 1,000 and 250 m2 spatial resolutions. The collapse of the WTC towers and the re at ground zero were not explicitly described to dene emissions of aerosols and gases. More detailed computational uid dynamics (CFD) simulations need to be conducted to calculate those processes and to obtain characteristics of air ow in the street canyons [3, 14]. However, CFD simulations require realistic lateral and upper boundary conditions that can be obtained only from ne-scale meteorological calculations like those conducted using RAMS. This study relied on available observational data to evaluate the time-dependent height of the convective cell generated by the re at ground zero, and quantied the magnitude of the aerosol emissions source from the comparison of the simulated and available observed concentrations at a number of distant locations (>3 km). The calculated

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Fig. 1 The model domains used in the simulations, referenced as grids 1, 2, and 3. Symbols show the location of the ASOS and buoy stations. Land elevation is shown with black contours. Land cover classes from the USGS National Land Cover Dataset are distinguished by color over the land. Three-day average sea surface temperature (K) for September 1315, 2001, retrieved from AVHRR multi-channel observations, is shown by red contours

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PM distribution patterns over NYC, NJ, and NY were tested against available observations that included satellite retrievals, surface meteorological observations, and available PM2.5 measurements. It was found that the simulations compare favorably with observations and allow effective reconstruction of the plume evolution. This article is organized as follows: Sect. 2, describes the modeling approach and the simulation setup; Sect. 3 briey describes meteorological conditions, discusses results, and provides evaluation of the sensitivity of the results to the parameters and initialization. Results are summarized in Sect. 4.

2 Methodology To conduct multiscale atmospheric transport calculations, micrometeorological elds need to be calculated with sufcient accuracy and spatial resolution. To estimate time-varying human exposures it is also necessary to simulate the distribution of airborne contaminants with a spatial resolution of, at minimum, a city block. The routine Eta model forecast, that provides the best available meteorological elds, resides at the National Centers for Environmental Prediction (NCEP) and has a spatial resolution of about 32 km. Therefore, dynamically downscaling the Eta elds using RAMS and additional available observations was required. The micrometeorological elds obtained this way were then input to HYPACT for off-line transport calculations. 2.1 Calculation of meteorological elds RAMS Version 4.3 was employed in the analyses to calculate meteorological elds. RAMS is a compressible, non-hydrostatic, regional model with well-developed bulk cloud microphysics, and surface interaction parameterizations [15, 16]. The governing equations are approximated using the hybrid implicit-in-the-vertical time-split difference scheme of Tripoli and Cotton [17]. RAMS predicts the 3-D elds of three velocity components, temperature, water vapor mixing ratio, pressure, sub-grid-scale turbulent kinetic energy, and several types of cloud hydrometeors including cloud water, ice, graupel, and snow. The horizontal grid uses a rotated polar-stereographic projection. In the vertical direction, RAMS employs a sigma-Z terrain-following coordinate system [18]. Grid nesting is used in RAMS to provide high-spatial resolution in selected areas, while covering a large domain at lower resolution. Therefore, effects of large-scale circulation patterns can be transferred to an internal ne resolution region. A nested grid occupies a region within the computational domain of its coarser parent grid. For the external domain, lateral boundary conditions are applied by exponential relaxing (nudging) the calculated elds toward the ow obtained from the forecast model in the grid-belt along the lateral boundaries [19]. The relaxation coefcient follows a parabolic function of the distance from the boundary and is constant in height. For the internal domains the two-way interactions between nested grids are calculated following Clark and Farley [20]. Various parameterization modules were available for most physical processes, including radiation, turbulence, and land/atmosphere interaction. As vertical and horizontal resolutions are relatively different in this study, vertical turbulent eddy mixing was parameterized using the 2.5 level scheme of Mellor and Yamada [21, 22] based on a prognostic equation for turbulent kinetic energy. Horizontal turbulent mixing was

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calculated using turbulent diffusion coefcients calculated from the tensor of deformation [23]. The Two-Stream Delta-Eddington radiative schemes of Harrington [24] was used for radiative transport. Modied versions of Kuo [25] and Fritsch and Chappell [26] convective parameterizations are standard features of RAMS [27]. A modied version of the Kain and Fritsch convective scheme [28, 29] was recently implemented in RAMS [30]. However, for cloud-resolving calculations, as in this study, RAMS does not require any convective parameterization. The cloud microphysics scheme is based on Tripoli and Cotton [17, 31] and Cotton et al. [32]. This scheme consists of a set of conservation equations for water vapor and six hydrometeor types: cloud droplets, raindrops, pristine ice, snow, graupel, and aggregates. Their tendencies are affected by advection, turbulence, and microphysical transformations in size distribution and from one class to another. Calculation of land-atmosphere interaction is based on the Land EcosystemAtmosphere Feedback (LEAF-2) model [33], with 12 soil textural classes and 18 vegetation types. LEAF-2 predicts soil temperature and water content, snow cover, vegetation, and canopy air as well as turbulent and radiative exchanges between these components. LEAF-2 uses a mosaic approach where the grid cells are subdivided into smaller portions or patches corresponding to different surface characteristics occurring in the area covered by the grid cell. RAMS has been tested in numerous applications for atmospheric chemistry and air pollution, including recent studies of the sulfur cycle and acid deposition in East Asia [34], calculations of the chemical production of tropospheric ozone over Greece [35] and in the area of Phoenix, Arizona [36]. RAMS has also been recently used for climate downscaling over the US [30, 37]. The triple-nested domain used in the present simulations, centered at the coordinates of the WTC (74.03 W, 40712 N), is shown in Fig. 1. The largest (or parent) domain covers a 300 300 km area in a polar stereographic projection with projection axes at 40.783 N and 73.967 W. The parent domain is necessary to accommodate mesoscale structures to be downscaled to two smaller nested domains centered at the same central point, covering areas of 54 54 and 10.5 10.5 km, respectively. Going forward, the three domains will be referred to as grids 1, 2, and 3. The spatial resolutions of the three grids arre 4 4, 1 1, and 0.25 0.25 km and the number of grid points is 75 75, 54 54, and 42 42, respectively. The vertical grid is non-uniform, containing 39 levels starting from a 20 m-thick surface layer, and reaching 1700 m at the top of the domain, at an altitude of 16 km. The original RAMS land elevation and vegetation cover data sets are of 1 km resolution, which is sufcient to calculate mesoscale circulation but is not adequate for the needs of the present study. To conduct very ne-resolution simulations in the metropolitan area it was necessary to improve the model databases. First the high-resolution National Land Cover Dataset (NLCD) and National Elevation Data (NED) from the United States Geological Survey (USGS) were adopted. NED, a raster product, is available on the Internet at http://edcwww.cr.usgs.gov/doc/edchome/ndcdb/ndcdb.html. NED has a resolution of 1 arc-second or about 30 m for the US. A visual basic software application was developed to read pixel values and convert them to a digital data le. Land elevation is shown as black contours in Fig. 1. NLCD is a multi-layer and multi-source database that contains a 30 m resolution, 21-class land classication for the territory of the US, in the form of visual

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images. A visual basic script was used to read pixel values and to produce a digital data le. The NLCD classes were then converted to Olson type classes (http:// edcdaac.usgs.gov/glcc/globdoc1_2.html) and a LEAF2 database for RAMS was produced. In Fig. 1 vegetation classes are distinguished by color. The original RAMS Sea Surface Temperature (SST) is based on the climatologically averaged monthly mean 1 1 resolution data set [38]. However, ne-scale pollutant transport can be affected by sea breezes initiated by the actual land/sea temperature contrast; therefore, the simulations in this study used real-time SST, providing better spatial and temporal resolution for the NY metropolitan area. For this purpose 1 km resolution, multi-channel, Advanced Very High Resolution Radiometer (AVHRR) satellite retrievals [39] were acquired from the Marine Remote Sensing Laboratory of the Rutgers University Institute for Marine and Coastal Sciences. This data set had to be processed to remove the effect of clouds seen in the instantaneous retrievals, in order to produce 3-day SST composites. In Fig. 1 the composite SST eld for September 1114, 2001 is shown as red contours over a blue background corresponding to the oceanlakeriverstream surface classication group. The terrain in Fig. 1 is fairly at, not exceeding 400 m in elevation. The ne-scale features were degraded on the parent grid in Fig. 1; nevertheless the 200 m highnarrow Palisades Cliff on the west side of the Hudson River, northwest of NYC, is well captured and the coastline is well approximated. The dominant land cover type is urban, with small intrusions of grassland, marsh, and trees. The AVHRR SST for September 1114, 2001 shows warm areas of 297298 K related to the Gulf stream path. The colder waters of 296 K and below are transported southward from the Labrador Sea, along Long Island and the NJ coast. The ocean temperature in the Gulf Stream region is fairly patchy, but becomes smoother near the coast. The AVHRR SSTs were tested with buoy observations available from the National Data Buoy Center (http://www.ndbc.noaa.gov/to_station.shtml). The two stations closest to NY/NJ coast were chosen for comparison: ambrose light (station ID ALSN6, located at 40.46 N, 73.83 W); and Long Island (station ID 44025, located at 40.25 N, 73.17 W). These are also marked in Fig. 1. Figure 2 compares AVHRR composited SST, sampled at 40.46 N, 73.5 W along the NY coast and shown as a solid curve without marks, with the Ambrose Light (closed circles) and Long Island (open circles) buoy stations. The AVHRR SST, sampled between the stations, compares favorably with the station observations, catching all SST changes during this period. The buoy hourly output shows more high-frequency variations, but the three-day average AVHRR composites show fairly accurately that SST decreases from September 11 to September 17, and then stabilizes at about 294.5 K, and at the end of September drops again to 291 K. The SST change during the rst week following the WTC collapse is most important, as it drove breeze circulation during the period when the emissions were most intensive and the plume was especially dense. The meteorology calculations depended on the initial and boundary conditions that were developed using the objective analysis package within RAMS. These objectively analyzed elds are calculated from the three-hourly Eta model operational analysis [40, 41]. The Eta Model data were provided by the National Center for Atmospheric Research (NCAR) in gridded binary (GRIB) format, on a horizontal grid with a spatial resolution of 32 km. They included surface pressure, surface elevation, and 3-D elds of pressure, temperature, water vapor mixing ratio, and horizontal wind components at 26 pressure levels, for the entire US. RAMS is able to combine and blend several input data sets in the data analysis. For example, the Eta

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Fig. 2 Three-day composited sea surface temperature (K) at the NJ coast from the AVHRR retrieval at 40.46 N, 73.5 W (solid line) and hourly observations from the long island (40.25 N, 73.17 W) and Ambrose Light (40.46 N, 73.83 W) buoy stations near the NJ coast (open and lled circles, respectively)

elds could be enhanced by surface station data from NCEP and Automated Surface Observation Stations (ASOS) available from the National Climate Data Center (NCDC) (http://www4.ncdc.noaa.gov/cgi-win/wwcgi.dll?wwdiASOSPhotos). The ve ASOS stations located closest to the WTC were used in the present study, and are shown in Fig. 1. Unfortunately, upper air observations in the NY area are sparse; for example, the closest rawinsonde soundings are taken at Brookhaven national laboratory on Long Island. Therefore, upper air observations could not be used in the analysis. The objectively analyzed 3-hourly elds helped constrain the ow near the boundaries of the grid 1 domain using relaxation type boundary conditions [19] with an efolding relaxation time of 30 min. at the 5-grid-cell boundary belt. In addition, to keep the ow close to the observations during the entire simulation period, horizontal velocity, potential temperature, and Exner function = (p/p0 )R/Cp [42] were nudged in the interior of the domain, with a much greater relaxation time time of 12 h to allow small-scale high-frequency disturbances to develop. (In this formula, p and p0 are air pressure at given locations and base state pressure at the ground, respectively, R is the gas constant for dry air, and Cp is specic thermal capacity of air at constant pressure.) The majority of RAMS simulations in this study were conducted using the radiative scheme of Harrington [24], the turbulent closure of Mellor and Yamada [22],

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and driving elds calculated using Eta elds and 3-hourly data from ASOS stations shown in Fig. 1. Comparison with observations revealed that these settings produced results superior to others tested in the course of this study. The ASOS observations accounted for observed ne structure of the ow in the vicinity of the WTC that was lost in the 32 km resolution Eta analysis. The inclusion of 6-hourly station data from NCEP did not produce an improvement because they were too sparse to affect local circulation structures. In addition, they caused inhomogeneity in the driving elds because the NCEP data are not available at each 3-h time step. Below, the results are presented along with a sensitivity analysis discussing the dependence of the results on model parameters and driving eld variations. RAMS integrations were conducted for 4 weeks, from September 11 to October 8, 2001, with a time step of 12 s. The meteorological elds were saved every 30-min. 2.2 Calculation of pollutant transport The chemical analysis of sampled aerosol particles that had settled to the ground [1] and in NY Harbor sediments [43] show that the initial WTC emissions included cement, cellulose, glass bers, asbestos, lead, and polycyclic aromatic hydrocarbons (PAHs). The WTC debris deposited in the Hudson River and then transported downstream left a distinct signature on NY Harbor sediments, affecting the sedimentary records of Ca, S, Sr, Cu, and Zn. In this study all types of aerosols and gases associated with WTC emissions were treated as tracers, and their transport calculated off-line using HYPACT model, Version 1.2. HYPACT model calculates temporal and spatial distributions of atmospheric pollutants using 3-D, time-dependent wind and turbulence elds. It can account for multiple sources and various weather regimes, including complex terrain ows, land/sea breezes, or circulation in urban areas. Species can include gases and a spectrum of aerosol sizes. Source geometry can include point, line, area, and volume sources of various orientations. HYPACT is driven by wind and potential temperature elds simulated in RAMS. The turbulence characteristics are calculated diagnostically from available meteorological information using the turbulent closure of Mellor and Yamada [21, 22]. Particle interaction with the surface is parameterized following Boughton et al. [42]. Above 100 m, the probability of particle deposition for the timescales of interest is negligible. If the particle falls below this height, the probability that the particle is deposited is computed in HYPACT from the transition probability density given by Monin [44]. HYPACT simulations were conducted for the entire period of RAMS simulations from September 11 to October 8, 2001. The HYPACT uses a 30-s. time step, interpolating RAMS 30-min. output at each time step. HYPACT output was archived every 30-min. 2.3 Primary and secondary particulate matter sources The HYPACT transport calculations were driven by the RAMS meteorological elds, and aerosol or gaseous pollutant sources. A source is characterized by the position, surface area, altitude, and rate of pollutant release. The terrorist attack caused res in both WTC towers whereby pollutants were released into the atmosphere at an altitude of about 1500 m. The collapse of the main two structures produced a very ne-scale intensive low-level jet that mixed pulverized construction materials vertically in a column at least 500 m high, and pushed pollutants into the nearby streets. However,

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the exact shape, altitude, and magnitude of the emission sources are not known. These ne-scale processes are the subject of on-going CFD studies, at a spatial resolution of a few meters [14, 45]. A signicant amount of PM from this initial release was deposited on the roofs, streets, and other man-made and natural surfaces. Later, re-suspended by wind, the particles were released and contributed as secondary sources to the overall pollution, until they were cleaned up or washed out by rain on September 14 [46, 47]. The calculations in the present study did not account for those secondary sources. This probably resulted in an underestimation of the overall airborne contaminant level in the simulations. The re on the site of the WTC that developed after the collapse of the buildings produced a continuous source of aerosols that was most intense during the rst 3 days, well exceeding the background level. As the re receded, the effective altitude of the source and the emissions release rate gradually decreased. On separate days res were present at different locations within the 16-acre ground zero area. When the heat released from the re was high, it initiated intense convection that mixed combustion products in the vertical column. The altitude of the convective mixing depends on the magnitude of thermal heat ux from the re, as well as atmospheric conditions. The situation is even more complex for the initial dust emission caused by the collapse of the WTC main structures. Therefore, for the purposes of the calculations in the present study, it was assumed that aerosols were released from the entire area of ground zero. Because of numerous uncertainties, direct simulation of the convection caused by the re was not performed; instead, an approximation of the time evolution of the altitude of the convective column was made using photographs taken from the ground and satellite observations. 2.4 Plume altitude observations The North Eastern states for Coordinated Air Use and Management (NESCAUM) organization provided a series of photographs of the plume rising from the WTC taken from Newark, NJ on September 1117, 2001. The photos show that on September 11 from 0856 to 0950 EDT, after the attack on the buildings by aircraft but before the collapse of the buildings, the plume rose above the urban canopy to the height of about 1,0001,500 m. At noon on September 11 the plume reached its highest altitude of about 1,800 m. On the next day, at 0500 EDT (and probably during the night), the altitude of the plume was below 400 m, reaching 1,500 m at 1200 EDT. However, in the late afternoon on September 12 the altitude of the plume decreased to 400 m. On September 1317 the plume was mostly conned to the 200400 m layer, sporadically rising to 800 m in the middle of the day when solar radiation heated the aerosol layer, increasing its buoyancy. After September 17 the altitude of the plume continued to decrease and stabilized above the urban canopy at about 150200 m. In addition to surface-based photographic observations, the WTC plume was observed from space. Figure 3 shows imagery and height retrievals derived from Multiangle Imaging SpectroRadiometer (MISR) observations. The MISR ies in sun-synchronous, polar orbit aboard NASAs Terra spacecraft, and measures upwelling radiance from Earth in four spectral bands centered at 446, 558, 672, and 866 nm, at each of nine xed viewing angles spread out along the ight path from 70.5 forward to 70.5 aft [48]. It is a push-broom imager, providing nearly pole-to-pole coverage of a 400 km wide swath on the day side of each orbit. MISRs highest spatial sampling

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Fig. 3 The MISR stereo height analysis of the WTC smoke plume at 1603 UTC (1203 EDT) on September 12, 2001. The upper panel depicts MISR 70 forward image of natural color reectance for Terra orbit 9,237, prominently showing the smoke plume, and indicating four patches, for which stereo-height histograms were derived. The lower panel shows histograms of height generated using the 60 and 70 forward MISR views, with 250 m vertical bin size and 1.1 km horizontal (pixel) resolution, for the four patches indicated in the upper panel. The stereo product vertical resolution is approximately the size of the histogram bins. They demonstrate that the plume height is roughly 1250 m near the WTC. Points in the histograms at 2.5 km altitude and higher are mostly cumulus clouds within the patches, whereas the points at 2 km in Patch 3 are probably part of the smoke plume.

is 275 m at all angles, and global data are routinely acquired at full resolution in 12 channels, 1.1 km resolution in the others (see e.g. Kahn et al. [49], Moroney et al. [50], Muller et al. [51], and Kahn et al., Aerosol Source Characterization from Spacebased Multi-angle Imaging, submitted manuscript). The WTC and other mid-latitude sites are viewed 12 times per week (see http://www-misr.jpl.nasa.gov for more details about MISR). The MISR contributes to knowledge of the global aerosol budget, providing tight constraints on aerosol optical depth from well-calibrated spectral radiances measured at precisely known air-mass factors ranging from one to three. The multi-angle observations also sample a wide range of scattering angles (about 50160 at midlatitudes), offering additional constraints on particle shape, size distribution, and single-scattering albedo, particularly over dark, uniform surfaces such as the ocean (e.g., Kahn et al. [49]). In situations where a plume has discernable contrast features in the multi-angle images, such as near re, dust, or volcanic aerosol source regions, a stereo-matching technique automatically retrieves plume-top height [50]. The height retrieval is performed both with and without MISR-derived wind correction. For the WTC case on September 12, the wind correction is very small, because the plume is oriented nearly normal to the plane of the multi-angle views. Retrieval of plume-top and cloud-top heights make use of the stereoscopic nature of MISR data, and employs rapid pattern matching algorithms [51] to determine the geometric parallax (horizontal displacement) of cloud and plume features due to

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their altitude above the surface. Photogrammetric calculations using accurate camera geometric models transform the derived parallaxes into cloud-top heights. Using the nadir and near-nadir cameras, as is done in generating MISRs operational stereo product, the quantized accuracy of the resulting height eld is 560 m. However, thin plumes do not produce sufcient image contrast at these angles for the pattern matching algorithms to work. This was addressed with special processing that used more oblique angle images, which enhance the plume appearance relative to the surface background. Using the 60 and 70 pair of angles, for example, results in a quantized height resolution of 250 m. The upper panel in Fig. 3 depicts a natural color (RGB) image from MISRs 70 forward view for Terra orbit 9,237, showing the smoke plume prominently and indicating four patches, for which stereo-height histograms were derived. The image was acquired at 1603 UTC (1203 EDT) at 275 m pixel resolution in the red band and at 1.1 km in the green and blue; the red band data were used to sharpen the image as a whole to 275 m effective resolution. The near-vertical rise of the buoyant plume directly above the WTC, viewed obliquely by the MISR 70 forward-looking camera as Terra ew southward, is revealed at high resolution, projected on the scene as an apparent south-trending column of smoke. The lower panel in Fig. 3 shows histograms of height, with 250 m bin size and 1.1 km horizontal (pixel) resolution, for the four patches indicated in the upper panel of Fig. 3. As noted above, the vertical resolution of the height retrieval is about 250 m, as these heights were generated using the 60 and 70 forward views, providing greater sensitivity to thin hazes than the standard MISR stereo height product. The results show that the height of the plume top is roughly at 1,250 m near the WTC, and it spreads upward slightly, downwind. The points in the histograms at 2.5 km and higher are mostly cumulus clouds within the patches, although the points at 2 km, especially those in Patch 3, are probably part of the smoke plume. Thus, inference of vertical mixing downwind rests on the Patch 3 data. Thinning downwind is indicated by both the small number of pixels, for which MISR stereo heights could retrieve in Patch 4, and the widening and increased transparency of the plume itself in the image. The estimates of plume altitude derived from MISR are in good agreement with the ground-based photos taken from Newark on September 12, that show the top of the plume rising vertically to an altitude about 1,0001,500 m in the middle of the day. Therefore, in the simulations aerosols were released in the atmospheric column volume with the 250 250 m base centered at the WTC, which roughly corresponds to the entire area of ground zero. The effective time-varying altitude of the volume source was chosen to be 1500 m during the rst 52 h (i.e., until 1400 EDT on September 12). After 52, 72, and 96 h the altitude of the effective source decreased to 500, 300, and 150 m respectively. The 150 m source was kept until the end of simulations on October 8. One-hundred Lagrangian particles per second were emitted randomly and statistically uniformly in the volume of the source, with a unit total mass-release rate of 1 kg/s. Below, the magnitude of the source is estimated by comparing observed and calculated concentrations. 3 Results The weather on September 1113, 2001 was clear, dry, with afternoon temperatures reaching 80 F. A cold front approached the NY metropolitan area on September 14 from the north and passed by on September 15, bringing brisk northerly winds

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and scattered showers. The temperature dropped during September 1416 by an average of 20 F to the lower 60s, 58 F below the climatological average. The most intense precipitation fell on September 14, with total amounts reaching 1.9 in. On September 17 a high-pressure system held across the region, bringing sunny skies until September 20. A weak front passed the region producing scattered showers of only 0.83 and 0.36 in/day on September 20 and 21, respectively. From September 22 to 24 the temperature rose to the low 70s, exceeding the climatology average by 37 F. On September 25 a cold front approached and stabilized in the area for 4 days. The temperature decreased to 65 F on September 29 and dropped further to 50 F on September 30 and October 1, which is 410 F below the climatological average. The accompanying scattered showers on September 24, 25, 29, 30, and October 1 were fairly weak, reaching only 0.3, 0.41, 0.04, 0.36, and 0.1 in/day, respectively. During the rst week of October, a high-pressure system brought sunny weather and a strong diurnal temperature cycle; the daily maximum exceeded 80 F. A cold front approached from the north on October 6, reducing temperatures to the lower 50s and bringing weak scattered showers of 0.12 in/day. In general, the entire period was very dry. There were no signicant precipitation events that could wash out aerosols from the atmosphere or off surfaces except for the showers that occurred on September 14. That precipitation was an important factor affecting aerosol lifetime, decreasing re intensity and reducing aerosol emissions at ground zero. Further, it would wash away most of the outdoor re-suspendable dust. Through the course of this study, the sensitivity of the results was tested with respect to several alternative model settings including coarse and ne resolution RAMS databases (Land Elevation, Land Cover, and SST), different nudging strength, and time step. The micrometeorological and tracer elds obtained with the model settings discussed in Sect. 2.1 appear to be more consistent with observations than calculations conducted with the different model congurations; it was assumed that these elds were superior and were therefore used in all simulations. Discussed in this section is the sensitivity of the simulated plume to variations in the driving meteorological elds, as a result of implementing the ASOS and NCEP data, with the model settings xed at those from Sect. 2.1. More specically, a comparison is made of results from runs when the initial and boundary conditions were constructed using only Eta data, Eta and ASOS data, and Eta, ASOS, and NCEP data, which is referred to as Eta, Eta + ASOS, and Eta + ASOS + NCEP, respectively. Also the sensitivity of the plume dispersion with respect to the release rate of Lagrangian particles was evaluated. Then a comparison of the simulated wind elds with the observations from ASOS stations was conducted, and the simulated concentrations were tested against PM2.5 observations from the roofs of three Public Schools in NYC where data are available every hour. At the end of this section the plume transport on September 12, which was characterized by a very rapid change in plume direction, is discussed and the simulated plume compared with with the satellite images. 3.1 Plume calculations using different meteorological elds Figure 4 depicts relative plume concentrations, shown as percentages, normalized to the maximum concentration at the WTC location in the lowest model layer of Grid 3 (10 m altitude), calculated using different meteorological elds. Specically, transport simulations were conducted using the RAMS elds calculated with initial and boundary conditions prepared using Eta elds (Fig. 4a), Eta and ASOS surface

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Fig. 4 (a) Simulated with Eta initialization, low-level tracer concentrations averaged for the 8-h period from 0800 to 1600 EDT on September 11, 2001, (b) Same as (a) but simulated with Eta + ASOS initialization, (c) Same as (a) but simulated with Eta + ASOS + NCEP run initialization, (d) Same as (a) but simulated with Eta run initialization and 1,000 particle per second release rate

measurements (Fig. 4b), and Eta, ASOS, and NCEP surface station data (Fig. 4c). Simulations were also conducted releasing 1,000 Lagrangian particles per second using Eta initialization. This particle release rate was 10 times higher in magnitude than that in the employed routine simulations and it effectively improved the plume discrete spatial approximation during the entire run, compared to the run with a release rate of 100 particles per second (Fig. 4d). Concentrations were averaged for the initial 8 h post collapse. During this period, aerosol from the WTC was transported

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to the south-southeast. All simulations produced similar results. In simulations with Eta+ASOS and Eta+ASOS+NCEP elds, the direction of highest concentration rotated a little bit more to the east than in simulations with Eta elds only (Fig. 4a). The plume calculated with the 1,000-particle-per-second release rate shows more spatial dispersion, but in general the results are close to the simulations with the 100-particleper-second release rate. From this analysis, which shows weak dependence on driving meteorological elds and spatial approximation of plume, it can be concluded that the RAMS initialization using Eta and ASOS data and the 100-particle-per-second release rate allow sufciently accurate calculation of the concentration eld for the initial post event period. The root mean square error between the concentration eld obtained in calculations with different initial conditions and particle release rate shown in Fig. 4 did not exceed 10%. It is also shown that for the rst 8 h following the attack the plume affected mostly lower Manhattan and northwest Brooklyn. In Brooklyn the concentrations were less than 10% of the peak value seen over Manhattan. 3.2 Winds ASOS provided the best wind observations available to test the accuracy of the simulations. Therefore, in order to test the RAMS simulations, calculations initialized with the Eta elds only were compared with (in this case, independent) ASOS wind observations (see Fig. 5). The comparisons were conducted at ve locations: Teterboro Airport (TEB), Newark Airport (EWR), NY Central Park, LaGuardia Airport (LGA), and JFK Airport (JFK). The stations are shown in Fig. 1 and their exact geographic coordinates are reported in Fig. 5. The comparison was conducted for about 4 days and data are presented in universal time (UTC = EDT + 5 = EST + 4). The simulated winds generally compare well with observations, both in magnitude and direction for all the locations. The wind pattern at Central Park is most complex because it is affected by local circulation in central Manhattan. The surface wind speed did not exceed approximately 5 m/s at all station locations (Fig. 5). There were several distinct wind regimes. The wind was predominantly northwesterly from September 11 to midday on September 12. Then the wind blew predominantly from the south on September 13. On September 14 the wind was fairly variable both in space and time, blowing predominantly southwest in the morning. The fast-moving cold front on September 14 brought north and then northeast winds almost simultaneously at all stations. A vertical solid line is drawn at 1600 UTC (1200 EDT) on September 12, when the wind direction changed dramatically and it was especially difcult to compare the plume position with observations. This issue is discussed further in Sect. 3.4. Winds calculated using Eta + ASOS data and Eta + ASOS + NCEP data (not shown) are not substantially different from those using only Eta driving elds. This might be expected from the analysis presented in Sect. 3.1. This conrms that Eta 3-D input is mostly important for the meteorology simulations. It also shows that RAMS with the selected setting conguration is capable of downscaling the wind eld to the very ne resolution needed for transport calculations. 3.3 Concentrations Plume evolution was calculated using HYPACT, driven by meteorological elds from RAMS simulations, and initialized with Eta and ASOS data, as discussed in Sect. 2.2.

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Fig. 5 Simulated (with Eta initialization) and observed surface wind vectors for ASOS station locations in the vicinity of the WTC shown in Fig. 1. Vertical solid line shows 1200 EDT, when the plume was observed by Landsat and MISR blowing in the southwest direction. The horizontal axis shows universal time (UTC)

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To evaluate the transport simulations, PM2.5 concentration data that were routinely collected on the roofs of public school buildings in NYC were used. These instruments were not compromised by the initial dust and smoke release caused by the collapse and continued to collect reliable data during the entire period of interest, beginning on September 11, 2001. For comparison three school locations were selected where observations were reported every hour: Public School (PS)-64 at 600 E 6th Street in Lower Manhattan.; PS-199 at 3920 48th Avenue in Queens; and PS-274 at 800 Bushwick Avenue in Brooklyn. These schools (except PS-274) were at a sufcient distance from the southeast sector of the major impact immediately after the collapse of the WTC buildings so their sensors were not damaged by the initially intense PM release. PS-64, located about 3 km northeast of the WTC, was the observation site closest to the WTC, and received the (relatively) highest level of PM. PS-199 is located in the same northeast sector from the WTC at a distance of about 78 km. Therefore it is possible that the plume reached these two locations at about the same time. PS-274 is south of PS 199, in the east-southeast sector from the WTC where plume characteristics and timing might be different from the above two school locations. However, PS-274 is separated from the WTC by about the same distance as PS-199. At these distances the plume was well organized and did not experience uctuations related to near-source processes. Figure 6 depicts observed and simulated concentrations for the three school locations between 1200 UTC (0800 EDT) on September 11 and 2400 UTC (2000 EDT) September 14. In the simulations, concentrations were sampled from the fourth model layer at an altitude of 89 m. The exact geographic coordinates of the schools are given in Fig. 6. Using the simulation and observation data, the concentrations were normalized to the maximum value of the peaks found at each location. Two key questions were considered in analyzing the data: (a) Do the model outputs reproduce the observed timing of the concentration spikes? and (b) How large should the aerosol release rate be in simulations in order to reproduce the observed aerosol concentrations in the plume? The second question is of great scientic and practical interest because the actual aerosol release rate was never measured. The WTC aerosol emission source varied in magnitude and spatial distribution and released aerosols and gases at varying altitudes. Moreover, there were multiple additional sources, such as transportation, industrial activities, long-distance transport from remote sources, and local re-suspension of deposited aerosol particles, not accounted for in the simulations that produced background concentrations. Therefore an attempt was made to estimate the aerosol source intensity using concentrations in the peaks that were signicantly above background PM levels. The effect of aerosols on the ow was not considered, therefore transport is linear and concentrations are linearly proportional to the magnitude of the source. This assumption could fail if aerosol optical depth was high and its radiative heating/cooling effect on the hydrodynamic ow was signicant. However, this was not the case for the WTC plume. It must be mentioned that for all three locations major plume impact was well estimated, showing almost perfect timing for the observed concentration peaks. For September 11, the simulations do not show any signal at the three locations. The increase of observed concentrations seen at PS-274, which is closest to the main direction of the plume transport on this day, was not that high. The series of peaks on September 1214 is fairly similar at PS-64 and PS-199, and has a shape different from that at PS-274. For PS-64 and PS-199 a comparison was made of simulated and observed peak concentrations to avoid differences in the timing of the corresponding

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Fig. 6 Simulated with the Eta+ASOS initialization, normalized tracer concentrations at 89 m altitude (solid line) and normalized observed PM2.5 concentrations (open circles) at, (a) Public School (PS)-64 in lower Manhattan, sampled at grid 3 resolution, (b) PS-199 in Queens, sampled at grid 2 resolution, (c) PS-274 in Brooklyn, sampled at grid 2 resolution. The horizontal axis shows universal time (UTC)

plume passings. The effective PM release rates on September 13 and 14 need to be about 0.2 and 0.01 kg/s, respectively, to reproduce the observed concentrations. All locations gave similar estimates within a factor of 2. These effective emission rates are representative of smoke produced by the re at ground zero. It must be emphasized that, using the above approach, only the peak aerosol production is estimated; the source could have yielded different emission rates at other times. Recycled aerosol deposits could be another complication. For example, at the PS-274 site, higher concentrations observed on September 13 and 14, but not reproduced by the simulations, might be caused by resuspension of WTC dust because more material was deposited in this sector on September 11. In addition, the effective plume altitude, as well as the aerosol release rate, are fairly variable and are only roughly approximated in the simulations. The aerosol surface concentrations are also sensitive to the turbulent structure of the boundary layer, since, they develop as a result of horizontal transport and vertical mixing from the core of the plume that could be (e.g., in case of high-elevated aerosol source for a re) as high as 8001,000 m.

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3.4 Transport directionality In Sect. 3.3 it was shown that the model accurately calculates the timing of concentration spikes at different locations, providing condence in the simulated plume directionality. Here, analyses were conducted for what is probably the most complex period of plume evolution in the afternoon of September 12. The simulations were tested against visual Landsat imagery (Fig. 7), which provides a higher-resolution view than the MISR imagery in Fig. 3. Figure 7d shows the observed plume blowing toward the southwest at 1530 UTC (1130 EDT) half an hour before the image in Fig. 3 was taken. The plume is viewed in the nadir only by Landsat, so all layers containing aerosols are superposed. The plume spreads from the WTC along the Hudson River toward the Bayonne Peninsula and Newark Bay. It turns out that it is very difcult to reproduce this plume position in simulations because of rapid wind direction changes at this time. The Landsat and MISR images catch the extreme southwest position of the plume, just after it rotated clockwise and was about to rotate back. Figure 7a presents the position of the simulated plume at 1530 UTC (1130 EDT), when it almost reaches its extreme southwest position. (In these gures, concentrations are vertically averaged from 750 to 1,050 m, to mimic nadir satellite imagery, and are then normalized to the maximum value.) The range of altitudes was chosen in accordance with MISR estimates of the plume altitude (see histograms in Fig. 3). Figures 7b and 7c show the subsequent plume positions with a 30-min. time step. The simulated plume compares favorably with the Landsat image (Fig. 7d) and MISR image (Fig. 3), and it reproduces almost perfectly the directionality of plume transport, (Fig. 7a, b and c). As mentioned above, the wind on September 12 was variable, especially near the surface (see Fig. 5), with a signicant vertical sheer. Therefore, the position of the plume observed from space is very sensitive to the altitude of the upper part of the plume seen in nadir view from space. Because of the strong dependence of wind on time and altitude, this case provides an ideal consistency test between simulations and satellite observations. The MISR estimates the altitude of the top of the plume during this period to be about 1,250 m with an uncertainty of about 250 m. The simulations show that the portions of the plume below 750 m and above 1,050 m do not rotate as far clockwise as in Fig. 7d, and move counterclockwise rapidly soon after 1600 UTC (1200 EDT). This suggests that the core of the smoke layer was between 750 and 1,050 m, which is within the error bars of the MISR estimates. The ASOS wind observations in Fig. 5 conrm the rapid, near-surface wind changes. All stations show northeast wind before 15301600 UTC (11301200 EDT). Only at the Central Park and the LaGuardia Airport stations are there short, sporadic periods of easterly wind. At LaGuardia Airport, the model captures those easterly winds very well. All stations then show a sudden change in wind direction, at about 1600 UTC (1200 EDT). The simulations produce an accurate approximation of plume directionality and evolution. Consistent with the MISR plume-top altitude retrievals, the simulations show that most of the aerosol mass was likely transported within the 7501,050 m layer. This demonstrates important internal consistency between ne-scale atmospheric dynamics, transport calculations, and satellite observations. Nevertheless, this analysis also indicates that comparisons between simulations and observations should be conducted with reasonable caution, especially for periods of strong changes in wind magnitude and direction.

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Fig. 7 Simulated with the Eta+ASOS initialization, vertically averaged from 600 to 1,000 m, and normalized tracer concentrations on September 12, 2001 at (a) 1600 UTC (1200 EDT), (b) 1630 UTC (1230 EDT), (c) 1700 UTC (1300 EDT), and (d) Landsat image at 1600 UTC (1200 EDT) on September 12 showing the plume blowing southwest

3.5 Spatial-temporal distribution of aerosol concentration near the surface Figure 8 shows evolution of the 8-h average plume concentration for the 96 h period, beginning at 0800 EDT on September 11, normalized as in Figs. 4 and 7 and using the same contour intervals and color scheme. In Fig. 8 local EDT times are used.

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Fig. 8 Simulated with the Eta + ASOS initialization, 8-h average normalized low-level tracer concentrations for September 1115 in the lower layer of the model at the altitude of 10 m. The contour intervals and the color scheme are the same as in Fig. 7

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During the rst 24 h, the plume moved south-southeast, and was nearly conned to this sector. It is not surprising that a weak PM2.5 concentration spike was detected only at PS-274, located in Brooklyn. The area of high-relative concentrations > 50% of the maximum value during this period spreads only about 35 km from the WTC, barely reaching the Brooklyn coast at Buttermilk Channel. More aerosol dispersion was observed on September 12 between 08001600 EDT, corresponding to the rapid wind direction variations shown in Fig. 5. The plume rotated fairly rapidly, producing small PM2.5 spikes at all three school locations. At 16002400 EDT on September 12, the plume rst affected the north-to-northeast sector producing high concentrations at distances of 11.5 km from the WTC. It is interesting that one PM2.5 sample was taken by NY University (NYU) at 25th Street and 1st Avenue approximately 1.0 km northeast of the WTC. Although, it was collected from a long term sampler, the only time it was affected by the WTC plume was 16002400 EDT on September 12 as is seen in Fig. 8. It was assumed that the instrument was affected by the plume for 1/2 h and then clogged and stopped sampling. Based upon the lack of prior contact with the plume, it was estimated that the ambient concentration of ne particles detected during that half-hour period was 500 to 600 g/m3 (L.C. Chen, personal communication). However, the modeling results in Fig. 8 suggest that the plume was over the area for a few hours. Thus, the estimate by Chen could be accurate, if the sampler clogged in the rst 1/2 hour; the values could be lower depending upon how long the sampler remained operational over the 3-hour period. On the morning of September 13, the wind moved the plume to the east, dispersing PM in a wide southeastnortheast sector. This transport produces signicant PM2.5 spikes at PS-64, PS-199 and PS-274; the signal arrived a couple of hours earlier at PS-274 than at the other two locations. Later on September 13, and on the morning of September 14, the plume blew in the east, north and south directions, producing concentration peaks at all three schools between about 06001000 UTC (02000600 EDT). At the end of the day on September 14, the wind again blew to the east and southeast, producing detectable signals at PS-199 and PS-274. On the morning of September 15, as shown in Fig. 8, the plume blew to the south. Figures for the rest of this period are not shown because the magnitude of the source decreased signicantly after the September 14 rain. The period documented shows that the simulated plume was distributed fairly consistently with the ground-based PM2.5 observations that were made a few kilometers from the WTC site. The predominant transport during this entire period was to the south-southeast (about 75% probability). There were two episodes of northward aerosol transport, affecting upper Manhattan on September 12 and 13, three periods when the plume blew to the east and northeast, affecting Queens and the Bronx, and one period on September 12 when the plume blew to NJ (see Fig. 8). The results discussed in this section are consistent with the plume dispersion analysis conducted using the CALMET-CALPUFF modeling system in Gilliam et al. [3]. Both CALMETCALPUFF and RAMS/HYPACT employed a constant altitude aerosol source of 50 m for the entire simulation period. However Gilliam et al. presented calculations performed with coarser horizontal resolution (500500 m) and employed a different turbulent closure which caused effectively more rapid dispersion of the plume. For example relative concentrations over Brooklyn obtained in Gilliam et al.

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were about one order of magnitude lower than the RAMS/HYPACT simulations of the present study.

4 Summary and Conclusions This study demonstrates that the combination of numerical modeling and groundand space-based observations allow reconstruction of the aerosol plume from the WTC site for the entire period of interest. Micrometeorological and tracer transport modeling provides a framework for utilizing available observations. This increases the credibility of the simulations, and allows rough estimation of the effective emission rates of PM observed in the urban atmosphere during this event. The results of this work can be summarized as follows:

(1)

(2)

(3)

(4)

(5)

High-quality, ne-scale micrometeorological elds produced as part of this study were consistent with the observations for the entire period of interest following the September 11, 2001 event. The PM transport compares favorably with ground-based observations and satellite images. Simulations give reliable information about the spatial distribution of pollutants and the timing of the maximum near-surface concentrations at different locations. On September 12, the southeast transport was very episodic, making comparisons with observations difcult. However, the model accurately reproduces the plume directionality on this day. Simulated PM concentrations at the surface, and plume directionality, are sensitive to the altitude of the convective column developed by the re at ground zero. MISR estimated the altitude of the plume on September 12 to be about 1,0001,250 m at 1600 UTC (1200 EDT). The MISR retrievals allow better calibration of the surface estimates of plume altitude. The vertical structure of the ne-scale wind eld also appears to be consistent with the MISR altitude estimates. This example shows an important role that quantitative satellite retrievals can play in monitoring ne-scale processes during disasters, when ground-based observation networks are suppressed or destroyed by catastrophic conditions. The simulated ne-scale meteorological elds from mesoscale model simulations account for the larger-scale meteorological structures and could be used as boundary conditions for CFD calculations. During the rst 3 days, when the magnitude of aerosol source was largest, aerosols were transported predominantly to the south-southeast, affecting lower Manhattan and Brooklyn. However, over Brooklyn the aerosol concentrations were at least an order of magnitude lower than would be expected in the vicinity of the WTC. It was found that the effective peak ne PM release rates from the re at ground zero have to be in the range of 10200 g/s to be consistent with PM2.5 concentrations observed in Manhattan, Brooklyn, and Queens during the 3 days following the collapse of the WTC. However, this estimate implicitly included contributions from secondary sources (such as re-suspension of particles) that were not accounted for in the simulations. Presumably, their contribution was relatively small in the 5 km vicinity of the source during the considered period when the primary aerosol source from the re at ground zero was relatively strong. The

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September 14 rain reduced the re, and removed aerosols deposited after the collapse of the WTC. The present study estimated from observations rather than simulating directly the aerosol emission processes that resulted from the collapse of the main WTC structures and the re at ground zero. These processes dene the amount of material released and the way in which it was initially distributed vertically. At ne spatial scales these processes are controlled by meteorological conditions, such as the vertical temperature gradient, wind shear, and boundary layer turbulence; also they are dependant on the detailed hydrodynamic ow within street canyons surrounding ground zero. To reduce uncertainties in future studies, it would be interesting to simulate emissions and transport interactively, and to account realistically for aerosol source variability as a function of the micrometeorological environment. Having interactive aerosol release modeling capability would also allow one to calculate aerosol microphysics explicitly and estimate its effect on aerosol transport and deposition patterns.
Acknowledgements This work was sponsored by USEPA grant CR827033. Additional support was provided by a supplement to the NIEHS EOHSI center grant P30 ES05022. We thank Praveen Amar of NESCAUM for providing plume photographs; Jennifer Bosch of the Rutgers University Institute of Marine and Coastal Sciences for providing AVHRR SST retrievals; the developers of RAMS and HYPACT, Bob Walko and Craig Tremback, for consulting on RAMS/HYPACT modications; and Linda Everett of EOHSI for help with editing and manuscript preparation. Georgiy Stenchikov was partially supported by NJDEP grant SR04-048. The research of David Diner and Ralph Kahn is supported, in part, by the MISR project at JPL, under contract with NASA. Ralph Kahn is also supported by the NASA Climate and Radiation Research & Analysis program, under H. Maring. We thank Catherine Moroney of JPL for the special stereo processing of the MISR WTC data.

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