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Def - is defined differently for different types of substances - is defined in a way dependent upon the rxn it is undergoing 2. For Acids a.
EW ' number of H FW
%s
b.
EWCa(OH) '
2
EWCa(OH) '
2
FWCa(OH) 1
b. Ag + e Ag
+
EW '
c. Ca + 2 e Ca
+2 -
EW '
d. Al + 3e Al
+3 -
EW '
EW '
FW 4
5. Precipitate Formation & Complex Formation a. Salt (ionic) cationr anions b. EWcation ' c.
FWcation r charges on cation
FWanion number of e quiv of Metal cation that will react with it
EWanion '
d.
EWsalt '
FW Ba % ' ' %2
g/equivalent
Ba (NO3)2
EWBa (NO ) '
3 2
FWBa(NO ) %2
3 2
+6 -6 +3 -2
FWFe O
2 3
number % charges
'
FWFe O 6
2 3
C. Normality Def
N ' number e quiv of Solute number me quiv Solute ' number l of Solution number ml Solution
1 equiv of solute in 1.0 liter of Solution 1 equiv/l = 1 Normal = 1 N # equiv solute = N x #l of Solution (NCV(l)) # mequiv solute = N x #ml of Solution (NCV(ml))
2. 2 NaOH +
2 moles 1 equiv
FW- 40 amu
98 amu
98/2 = 49
Nb x Vb (l) = Na x Va (l)
E. Conversion Between Molarity & Normality 1. N = Mx # H+ that react /formula of acid # OH- that react/formula of base # e- transferred/formula of redox # + charges/formula if cation 2. H3PO4 ?N 3M
d) Hence: If not told the rxn, assume that all H+ react 1. H3PO4 ?N 3M
N=3Mx3=9N
V Other Expressions of Concentration A. Molality Number of moles of Solute m ' Number of Kg of Solvent B. Mole Fraction
Number of moles of Solute Number of moles Solute % Number of moles Solvent
'
C. Wt % w/w
Vol % v/v
w/v
2. Note: 2 NaOH + H3PO4 > Na2HPO4 + 2H2O 5ppm 10ppm ppm does not work in stoichiometry
T '
2. NaOH + HCl > NaCl + H2O 8 8 8 Want to standardize Weigh out 4.00 mg NaOH
3. If 1.00 ml of HCl neutralized 4.00 mg NaOH HCl + NaOH > NaCl + H2O Calculate the NaOH Titre 4.00 mg NaOH mg NaOH ' 4.00 1.00 ml HCl ml HCl
TNaOH '
4. Suppose you have an unknown NaOH sample and it Requires 3.0 ml of the Std. HCl solution How much NaOH is present? #mg = TNaOH x #ml of Std. HCl
Number mg NaOH ' 4.00 mg NaOH 3.0 ml HCl ml HCl
= 12.0 mg NaOH
5. May relate Titre & Normality a) T = N x 8 8 Expressed in terms Normal of the substance Concentration with which the of standard solution reacts solution EW 8 of the substance with which the solution reacts
NHCl '
TCa(OH)
EWCa(OH)
EWCa(OH) '
2
FWCa(OH) 2
6. Suppose you have a 0.20 N solution of HCl. What is its a) NaOH titre? FW = 40
40 mg ' 8.0 1 ml
b) Ca(OH)2 titre?
2
74 = FW
2
74 mg ' 7.4 2 ml
c) NH4OH titre ?
4 4
FW=35
35 mg ' 7.0 1 ml
d) Al (OH)3 titre
3 3
FW= 78
78 mg ' 5.2 3 ml
7. Suppose that a solution of HCl has a NaOH titre of 0.20 mg/ml. If it takes 10.00 ml of the HCl solution to react with an unknown solution containing NaOH, how much NaOH is present? ( #mg, #g, #moles NaOH)
#
= 2.0 mg NaOH
#
Eq
For HCl Sp. Grav = Density = 1.18 36.5 - 38.0 % HCl FW of HCl = 36.5
M '
1.18 g of solution .38 g HCl 1000 ml solution x x ml of solution g of solution l of solution 36.5 g HCl mole HCl moles HCl ' 12.3 M l of solution
M ' 12.3
Eq
For H3PO4
M=
.85 g H3PO4 1.69 g solution 1000 ml solution x x g solution ml solution l of solution 98 g H3PO4 mole H3PO4
M = 14.7 M H3PO4
Acid or Base
Molarity
Normality
38 70 95 99 85 71 28