Institute of commerce education

Department Of science
Class: XI Science ICE/14022012

(c)

N/m3

(d)

none of them

Chemistry Paper I

Max. Marks:60 Duration: 2 hours

Section B (Short answers/questions) any 8 (32)

Q:1. Define following: i. Polymorphism ii. Latent heat of fusion iii. Stoichometry iv. Heisenbergs principle Q:2. Calculate the mass of ZnSO4 and the volume of H2 produced by reacting 327gm of Zn at S.T.P. (Zn=65.4, S=32, O=16, H=1) Zn+H2SO4 ZnSO4+H2 Q:3. Define heat of formation and calculate the heat of formation of the following: 3C+4H2 C3H8 (Hf=??) C+O2 CO2 (Hf=-394 kj/mol) H2+12O2 H2O (Hf=-286kj/mol) C3H8+5O2 3CO2+4H2O (Hf=-2200kj/mol) Q:4. Differentiate: i. Endothermic and exothermic reaction ii. Ideal and real gas Q:5. Derive q=E+PV and state the law related to this equation. Q:6. Q:7. Q:8. Q:9. Explain the formation of ionic bond with the energy changes. Explain that paullis principle is correct for the atom of carbon. (At.no=6) Derive the gas equation with the value of gas constant in any one unit system. What is the density of CH4 at 127oC and 3.5atm?

Section A MCQs (Compulsory

i. Which of the following has no charge? (a) (c) ii. (a) (c) iii. (a) (c) iv. (a) (c) v. (a) (c) vi. (a) (c) (a) (c) (a) (c) ix. (a) (c) x. (a) particle particles Density Volume 0 2 02 32 22 88 Pressure Heat O-2 ClIonic Co ordinate Normal temperature Low pressure Nm-2 (b) (d) (b) (d) (b) (b) (d) (b) (d) (b) (d) (b) (d) (b) (d) (b) (d) particles none of them melting point none of them 1 3 18 64 44 none of them volume None of them (b) (d) Na+ Na

(10)

Which of the following is an extensive property?

The value of azimuthal quantum number for 4p orbital is?

Third energy level can contain _______ maximum electrons.

the formula mass of CO2 is 44, for one mole how many grams of CO2 needed?

Q:10. Explain: i. How nature of chemical bond can be find out by electro negativity. ii. how evaporation differ from vaporization iii. chemical bonding in NH4+ iv. the electronic configuration of Mg+2 ion (Mg=12) Q:11. Write a short note on hydrogen bonding and dipole moment. Q:12. How covalent bond gets ionic behavior? Give example to support your answer

In isochoric process ____ remain unchanged.

Section C (Detailed answers/questions) any 2 (18)

Q: 13. (a) An organic compound having C, H and O. by the combustion of 23.46gm sample, 20.42gm H2O and 33.27gm of CO2 is produced. What will be the molecular formula If the molecular mass of this compound is 62 amu. (b) Q:14. (a) What is hybridization? Explain the structure of SP2 hybridized molecule. Starting from K.E=Ze22r and P.E=-Ze2r calculate the frequency of the light emitted during electron transition.

vii. Which of the following is smaller in all?

viii. The bond between NaCl is ________. covalent hydrogen high Pressure none of them Nm2

(b)

Explain sigma and pi bond along with a suitable example of each

Boyles law fails at _____

Q:15. (a) 700J heat is absorbed by the system and 300J work is done on the system calculate the internal energy. Also define system and its types (b) Give the evidence of nucleus?

The unit of pressure is?