Documente Academic
Documente Profesional
Documente Cultură
Class
Register
Number
CHEMISTRY
5070/04
Paper 4
September 2011
1 hour
INSTRUCTIONS TO CANDIDATES
Write your name, class, index number and register number in the spaces at the top
of this page and on any separate answer paper used.
2
DSE 2011
DHARUMAVANTHA
SCHOOL
[Turn
over]
This question paper consists of 12 printed pages.
E xam i n ati o n s
DSE 2011
STT 11 / Chem 4
For Examiners
use only
.......................................
moles [1]
(b) (i) The sulfuric acid was poured into a beaker and 0.12 g of magnesium was
added.
The magnesium reacted with the sulfuric acid and hydrogen was produced.
How many moles of magnesium were added?
[Ar: Mg, 24]
.......................................
moles [1]
(ii) Write the equation for the reaction between magnesium and sulfuric
acid.
...........................................................................................................
.......... [1]
(iii) Using your answers to (a)(iii), (b)(i) and (b)(ii), suggest which reagent
was in excess, magnesium or sulfuric acid?
DSE 2011
STT 11 / Chem 4
For Examiners
use only
For Examiners
use only
4
...........................................................................................................
.......... [1]
(c) Give a positive test for hydrogen gas.
test ...................................................................................................................
..................
observation .......................................................................................................
............ [1]
[Total: 7]
2. The apparatus below is used to compare the results of passing a current
through aqueous copper(II) sulfate using different electrodes.
[2]
(iii) Explain why a colour change is not seen in the solution in this cell.
..........................................................................................................................
........... [1]
DSE 2011
STT 11 / Chem 4
For Examiners
use only
5
(c) (i) What colour change is seen in the solution in the other cell?
..........................................................................................................................
.........
(ii)
[1]
At which electrode H, I, J or K is a gas
produced......................................... [1]
(iii) Name this
gas.....................................................................................................
[1]
[1]
[Total: 10]
For questions 3 to 5 inclusive, place a tick in the box against the best
answer.
3. Which of the following is a property of
(a) It turns litmus paper blue.
(b) It reacts with any metal to give hydrogen.
(c) It liberates ammonia from ammonium salts.
(d) It reacts with any base to give a salt.
[Total: 1]
4. Water containing a little dilute sulfuric acid was electrolysed, using carbon
electrodes.
If 20 cm3 of hydrogen was given off at the cathode, what volume of oxygen
would be given off at the anode?
(a) 10 cm3
(b) 20 cm3
DSE 2011
STT 11 / Chem 4
For Examiners
use only
6
(c) 30 cm3
(d) 40 cm3
[Total: 1]
(a) A
(b) B
(c) C
(d) D
[Total: 1]
6..A student was given a sample of marble, which is impure calcium carbonate.
The student was asked to determine the percentage of calcium carbonate in the
sample.
The sample of marble was added to a previously weighed container, which was
then reweighed.
Mass of container + marble = 9.40 g
Mass of container = 7.85 g
(a) Calculate the mass of marble used in the experiment.
..................................... g [1]
The sample was placed in a volumetric flask and 50.0 cm3 of 1.00 mol/dm3
hydrochloric acid (an excess) was added.
When the reaction had finished the solution was made up to 250 cm3 with
distilled water.
This was solution G.
DSE 2011
STT 11 / Chem 4
7
25.0 cm3 of solution G was transferred to a titration flask and a few drops of
methyl orange indicator was added.
0.100 mol/dm3 sodium hydroxide was added to the solution from a burette until
an endpoint was reached.
(c) What was the colour change of the methyl orange?
The colour changed from............................................
to............................................
[1]
Three titrations were done. Parts of the burette with liquid levels before and after
each titration are shown below.
Summary
DSE 2011
STT 11 / Chem 4
For Examiners
use only
For Examiners
use only
8
Tick the best titration results.
Using these results, the average volume of 0.100 mol/dm3 sodium hydroxide
was.......................... cm3.
[4]
(e) Calculate how many moles of sodium hydroxide are in the average volume of
0.100 mol/dm3 sodium hydroxide in (d).
DSE 2011
STT 11 / Chem 4
For Examiners
use only
......................................... g
(ii) Using your answers to parts (j) and (k)(i) calculate the mass of calcium
carbonate in the sample of marble.
......................................... g
(iii) Using your answers to parts (a) and (k)(ii) calculate the percentage of
calcium carbonate in the sample of marble.
......................................... % [3]
[Total: 15]
7. (a) The reaction between aqueous barium chloride and dilute sulfuric acid
produces a precipitate of barium sulfate.
State the colour of this precipitate.
..
.................................................................................................................
.... [1]
DSE 2011
STT 11 / Chem 4
10
A series of experiments are done to find the mass of precipitate when different
volumes of dilute sulfuric acid are added to a fixed volume of aqueous barium
chloride.
Solution J is 1.00 mol/dm3 barium chlorides.
Solution K is sulfuric acid of unknown concentration.
10 cm3 of J is put into each of six test-tubes. Increasing volumes of K are added
to each test-tube. The mixtures are filtered and the precipitates washed with
water, dried and placed in a previously weighed container which is reweighed.
(b) The table below shows the results of these experiments.
Complete the final column.
(c) Plot the mass of precipitate against the volume of K on the grid. Join the
points with two best fit straight lines.
DSE 2011
STT 11 / Chem 4
For Examiners
use only
For Examiners
use only
11
[3]
(a) One of the results is incorrect. Circle this result on your grid and suggest
what the correct result should be.
............................................... g [1]
(b) Use the data on your grid to deduce
DSE 2011
STT 11 / Chem 4
For Examiners
use only
12
(a) Write the equation for the reaction between barium chloride and sulfuric
acid.
...........................................................................................................
.......... [1]
(b) Using your answers to (e)(iii) and (f), calculate the concentration of the
sulfuric acid, K,used in the experiment.
DSE 2011
STT 11 / Chem 4
13
Suggest the formula of two compounds which could have been used to make up V.
.......................................................................................................................................
[Total: 13]
Go back and check your answers
DSE 2011
STT 11 / Chem 4
For Examiners
use only
14
GOOD LUCK
DSE 2011
STT 11 / Chem 4
For Examiners
use only