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MATERIAL SAFETY DATA SHEET (MSDS)

1. CHEMICAL IDENTITY Chemical Name Synonyms Formula UN number Hazchem code ( EAC) Liquefied Petroleum Gas LPG, Propane, Butane, Propylene, Purofax, Bottled gas C3H6-C3H6-C4H10 (Mixture) 1075 2WE Petroleum gases, liquified Flammable , class2 5 Hazardous ingredients Propane Butane 10 Propylene CAS No. 106-97-8 115-07-1 Trade name Chemical classification CAS Number UN Hazard class LPG Aromatic mixture 68476-85-7 2

REGULATED IDENTIFICATION Shipping Name Shipping code/ Label Hazardous waste Id No.

2. PHYSICAL AND CHEMICAL DATA Boiling point/ Range Melting/ Freezing Point C Vapour Density ( Air =1) Specific gravity ( at 50 C ) (water =1) >-40 NP 1.5 0.51-0.58 Physical state Vapour Pressure ( at 20 C ) mm Hg Solubility in water ( at 30 C) pH Gas at 15 c and 1 atm DNA Floats Not pertinent Appearance Odour Other Informations Soluble in Organic solvents, Alcohol Colourless Mercaptane added for Odour

3. FIRE AND EXPLOSION DATA Flash point C (CC) NA (OC) Explosion sensitivity to May impact explode Combustible Material Flammable Material Pyrophoric Material NO YES NO

Flammability LFL % v UFL % v Explosion sensitivity to static electricity Explosive Material Oxidizer Organic Peroxide Emits CO, CO2

1.9 9.5 May explode NO NO NO

TDG Flammability Auto ignition Temperature C Hazardous Polymerization Corrosive Material Other information

2 466.1 will not occur NO

Hazardous Combustion Products 4. REACTIVITY DATA Chemical stability Incompatibility with other Materials Reactivity Hazardous Reaction Products

Stable Strong oxidiser No reaction with common materials but may react with oxidising materials. Not available.

5. HEALTH HAZARD DATA Route of entry Inhalation, Skin Effect of exposure/ Concentration in air greater than 10 % causes dizziness in few minutes. 1 % conc. gives the same Symptoms symptoms in 10 mts. High concentration causes asphyxiation. Liquid on skin causes frostbite. Emergency treatment Permissible Exposure Limit LD 50 orl-rat: Not listed LCLo ihl-hmn: NFPA Hazard signals If inhaled remove the victim to fresh air area. Provide artificial respiration. Skin: Remove the wetted cloths and wash the affected area with plenty of water. Eyes: Flush with plenty of water for 15 min. seeks medical aid. TLV-TWA ( ACGIH) 1000 ppm STEL(ACGIH) Not listed Odour IDLH 5000 to 20000 ppm threshold Health Flammability Reactivity Special 1 4 0 -

MATERIAL SAFETY DATA SHEET (MSDS)


6. PREVENTIVE MEASURES PERSONAL PROTECTIVE MATERIAL HANDLING AND STORAGE PRECAUTIONS Avoid contact with liquid or gas. Provide hand gloves, safety goggles, gas mask, protective clothing and shoes. Keep in tightly closed cylinders in a cool, well ventilated area, away from heat, flame, sparks.

7. EMERGENCY AND FIRST AID MEASURES FIRE ( Class of fire : C ) Fire extinguish media Special Procedures Unusual Hazards EXPOSURE First Aid Measures___

Water spray, DCP, CO2 Keep the containers cool by spraying water if exposed to fire. Otherwise containers will explode in fire. Eyes : Flush with plenty of water for at least 10 minutes Skin: Remove contaminated clothing and wash affected skin with water. Inhalation: Remove victims to fresh air. If not breathing, give artificial respiration. Ingestion: if conscious, have victim drink water or milk. Do not induced vomiting. Obtain medical attention immediately. No specific antidote. Treat symptomatically. Shut off leaks if without risk. Warn everybody that air mixture is explosive. Allow gas to burn under control.

Antidotes/ Dosages SPILLS Steps to be taken Waste Disposal Method

8. ADDITIONAL INFORMATION/ REFERENCES ECOLOGICAL INFORMATION Ecotoxicity Persistence

DNA DNA A common air contaminant. Flammable when exposed to heat or flame. Keep OTHER INFORMATION containers tightly closed. Slightly explosion hazard. No food chain concentration potential REFERENCES ( FOR OBTAINING MORE INFORMATION) 1. Hazardous chemicals Data Book: G 1. Hand book of environmental data: Karen Verschueren: van Weiss: Noyes Data corp USA Nostrand Reinhold Co., USA 9. MANUFACTURER/SUPPLIER'S DATA SHV Energy Private Limited IVth Floor, SDE Serene Chambers, 8.2.334, Road No.7, Banjara Hills, Hyderabad-34 PH : +191-4023540079 Fax: +91-40-23540083 Contact person in Emergency Emergency leader

Local Bodies Involved Standard Packing Term card details/ Ref Others

The District Magistrate By Tank trucks Not pertinent -

10. DISCLAIMER

Information contained in this material safety data sheet is believed to be reliable but no representation; guarantee or warranties of any kind are made as to its accuracy, suitability for a particular application or results to be obtained from them. It is up to the user/distributor to ensure that the information contained in the material safety data sheet is relevant to the product manufactured/ handled or sold by him as the case may be. SHV makes no warranties, expressed or implied, in respect of the adequacy of this document for any particular purpose.

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