CHAPTER ONE.

Environmental Management System An environmental management system is the process used by an organization to manage, review, correct, and improve the organizations approach to business. Employees are asked to consider how they affect the environment every day. An EMS offers a structured way to incorporate environmental considerations into day-to-day operations; it promotes continual improvement of the environment and human health.

---------------------------------------------------------------------------------------------------------------Photosynthesis -[photo-], "light," and s???es?? [synthesis], "putting together", "composition") is a chemical process that converts carbon dioxide into organic compounds, especially sugars, using the energy from sunlight. [1] Photosynthesis occurs in plants, algae, and many species of bacteria, but not in archaea. Photosynthetic organisms are called photoautotrophs, since they can create their own food. In plants, algae, and cyanobacteria, photosynthesis uses carbon dioxide and water, releasing oxygen as a waste product. Photosynthesis is vital for all aerobic life on Earth. In addition to maintaining normal levels of oxygen in the atmosphere, photosynthesis is the source of energy for nearly all life on earth, either directly, through primary production, or indirectly, as the ultimate source of the energy in their food,[2] the exceptions being chemoautotrophs that live in rocks or around deep sea hydrothermal vents. The rate of energy capture by photosynthesis is immense, approximately 100 terawatts,[3] which is about six times larger than the power consumption of human civilization.[4] As well as energy, photosynthesis is also the source of the carbon in all the organic compounds within organisms' bodies. In all, photosynthetic organisms convert around 100115 petagrams of carbon into biomass per year.[5][6] Factors The leaf is the primary site of photosynthesis in plants. There are three main factors affecting photosynthesis and several corollary factors. The three main are: Light irradiance and wavelength Carbon dioxide concentration Temperature. Light intensity (irradiance), wavelength and temperature At constant temperature, the rate of carbon assimilation varies with irradiance, initially increasing as the irradiance increases. However, at higher irradiance, this relationship no longer holds and the rate of carbon assimilation reaches a plateau. (Irradiance is the power of electromagnetic radiation per unit area (radiative flux) incident on a surface. Radiant emittance or radiant exitance is the power per unit area radiated by a surface. The SI units for all of these quantities are watts per square meter (W/m2), while the cgs units are ergs per square centimeter per second (ergcm-2s-1, often used in astronomy). These quantities

are sometimes called intensity, but this usage leads to confusion with radiant intensity, which has different units. All of these quantities characterize the total amount of radiation present, at all frequencies. It is also common to consider each frequency in the spectrum separately. When this is done for radiation incident on a surface, it is called spectral irradiance, and has SI units W/m3, or commonly Wm-2nm-1. If a point source radiates light uniformly in all directions through a non-absorptive medium, then the irradiance decreases in proportion to the square of the distance from the object.) At constant irradiance, the rate of carbon assimilation increases as the temperature is increased over a limited range. This effect is seen only at high irradiance levels. At low irradiance, increasing the temperature has little influence on the rate of carbon assimilation. These two experiments illustrate vital points: First, from research it is known that, in general, photochemical reactions are not affected by temperature. However, these experiments clearly show that temperature affects the rate of carbon assimilation, so there must be two sets of reactions in the full process of carbon assimilation. These are, of course, the light-dependent 'photochemical' stage and the light-independent, temperature-dependent stage. Second, Blackman's experiments illustrate the concept of limiting factors. Another limiting factor is the wavelength of light. Cyanobacteria, which reside several meters underwater, cannot receive the correct wavelengths required to cause photoinduced charge separation in conventional photosynthetic pigments. To combat this problem, a series of proteins with different pigments surround the reaction center. This unit is called a phycobilisome. Carbon dioxide levels and photorespiration As carbon dioxide concentrations rise, the rate at which sugars are made by the light-independent reactions increases until limited by other factors. ---------------------------------------------------------------------------------------------------------------Hypoxia (environmental)

Hypoxia, or oxygen depletion, is a phenomenon that occurs in aquatic environments as dissolved oxygen (DO; molecular oxygen dissolved in the water) becomes reduced in concentration to a point where it becomes detrimental to aquatic organisms living in the system. Dissolved oxygen is typically expressed as a percentage of the oxygen that would dissolve in the water at the prevailing temperature and salinity (both of which affect the solubility of oxygen in water; see oxygen saturation and underwater). An aquatic system lacking dissolved oxygen (0% saturation) is termed anaerobic, reducing, or anoxic; a system with low concentrationin the range between 1 and 30% saturationis called hypoxic or dysoxic. Most fish cannot live below 30% saturation. A "healthy" aquatic environment should seldom experience less than 80%. The exaerobic zone is found at the boundary of anoxic and hypoxic zones.

Oxygen depletion can result from a number of natural factors, but is most often a concern as a consequence of pollution and eutrophication in which plant nutrients enter a river, lake, or ocean, and phytoplankton blooms are encouraged. While phytoplankton, through photosynthesis, will raise DO saturation during daylight hours, the dense population of a bloom reduces DO saturation during the night by respiration. When phytoplankton cells die, they sink towards the bottom and are decomposed by bacteria, a process that further reduces DO in the water column. If oxygen depletion progresses to hypoxia, fish kills can occur and invertebrates like worms and clams on The floor is covered with crabs, fish, and clams apparently dead or dying from oxygen depletion. the bottom may be killed as well.

Solutions To combat hypoxia, it is essential to reduce the amount of land-derived nutrients reaching rivers in runoff. Defensively this can be done by improving sewage treatment and by reducing the amount of fertilizers leaching into the rivers. Offensively this can be done by restoring natural environments along a river; marshes are particularly effective in reducing the amount of phosphorus and nitrogen (nutrients) in water. Technological solutions are also possible, such as that used in the redeveloped Salford Docks area of the Manchester Ship Canal in England, where years of runoff from sewers and roads had accumulated in the slow running waters. In 2001 a compressed air injection system was introduced, which raised the oxygen levels in the water by up to 300%. The resulting improvement in water quality led to an increase in the number of invertebrate species, such as freshwater shrimp, to more than 30. Spawning and growth rates of fish species such as roach and perch also increased to such an extent that they are now amongst the highest in England.[6] In a very short time the oxygen saturation can drop to zero when offshore blowing winds drive surface water out and anoxic depthwater rises up. At the same time a decline in temperature and a rise in salinity is observed (from the longterm ecological observatory in the seas at Kiel Fjord, Germany). New approaches of long-term monitoring of oxygen regime in the ocean observe online the behavior of fish and zooplankton, which changes drastically under reduced oxygen saturations (ecoSCOPE) and already at very low levels of water pollution.

---------------------------------------------------------------------------------------------------------------Phytoplankton (English pronunciation: /?fa?to?'pl?kt?n/) are the autotrophic component of the plankton community. The name comes from the Greek words f?t?? (phyton), meaning "plant", and p?a??t?? (planktos), meaning "wanderer" or "drifter".[1] Most phytoplankton are too small to be individually seen with the unaided eye. However, when present in high enough numbers, they may appear as a green discoloration of the water due to the presence of chlorophyll within their cells (although the actual color may vary with the species of phytoplankton present due to varying levels of chlorophyll or the presence of accessory pigments such

as phycobiliproteins, xanthophylls, etc.). Ecology

Phytoplankton are photosynthesizing microscopic organisms that inhabit the upper sunlit layer of almost all oceans and bodies of fresh water. They are agents for "primary production," the creation of organic compounds from carbon dioxide dissolved in the water, a process that sustains the aquatic food web.[2] Phytoplankton obtain energy through the process of photosynthesis and must therefore live in the well-lit surface layer (termed the euphotic zone) of an ocean, sea, lake, or other body of water. Phytoplankton account for half of all photosynthetic activity on Earth.[3] Thus phytoplankton are responsible for much of the oxygen present in the Earth's atmosphere half of the total amount produced by all plant life.[4] Their cumulative energy fixation in carbon compounds (primary Phytoplankton are the foundation of the oceanic food chain production) is the basis for the vast majority of oceanic and also many freshwater food webs (chemosynthesis is a notable exception). The effects of anthropogenic warming on the global population of phytoplankton is an area of active research. Changes in the vertical stratification of the water column, the rate of temperature-dependent biological reactions, and the atmospheric supply of nutrients are not expected to have important effects on future phytoplankton productivity. [5][6] Additionally, changes in the mortality of phytoplankton due to rates of zooplankton grazing may be significant. As a side note, one of the more remarkable food chains in the ocean remarkable because of the small number of links is that of phytoplankton -feeding krill (a crustacean similar to a tiny shrimp) feeding baleen whales.

Phytoplankton are also crucially dependent on minerals. These are primarily macronutrients such as nitrate, phosphate or silicic acid, whose availability is governed by the balance between the so-called biological pump and upwelling of deep, nutrient-rich waters. However, across large regions of the World Ocean such as the Southern Ocean, phytoplankton are also limited by the lack of the micronutrient iron. This has led to some scientists advocating iron fertilization as a means to counteract the accumulation of human- produced carbon dioxide (CO2) in the atmosphere.[7] Large-scale experiments have added iron (usually as salts such as iron sulphate) to the oceans to promote phytoplankton growth and draw atmospheric CO2 into the ocean. However, controversy about manipulating the ecosystem and the efficiency of iron fertilization has slowed such experiments.[8] While almost all phytoplankton species are obligate photoautotrophs, there are some that are mixotrophic and other, non-pigmented species that are actually heterotrophic (the latter are often viewed as zooplankton). Of these, the best known are dinoflagellate genera such as Noctiluca and Dinophysis, that obtain organic carbon by ingesting other organisms or detrital material. The term phytoplankton encompasses all photoautotrophic microorganisms in aquatic food webs. Phytoplankton serve as the base of the aquatic food web, providing an essential ecological

function for all aquatic life. However, unlike terrestrial communities, where most autotrophs are plants, phytoplankton are a diverse group, incorporating protistan eukaryotes and both eubacterial and archaebacterial prokaryotes. There are about 5,000 known species of marine phytoplankton.[9] There is uncertainty in how such diversity has evolved in an environment where competition for only a few resources would suggest limited potential for niche differentiation.[10] When two currents (in this case the Oyashio and Kuroshio currents) collide, they create eddies. Phytoplankton become concentrated along the boundaries of these eddies, tracing out the motions of the water. Algal bloom off south England In terms of numbers, the most important groups of phytoplankton include the diatoms, cyanobacteria and dinoflagellates, although many other groups of algae are represented. One group, the coccolithophorids, is responsible (in part) for the release of significant amounts of dimethyl sulfide (DMS) into the atmosphere. DMS is converted to sulfate and these sulfate molecules act as cloud condensation nuclei, increasing general cloud cover. In oligotrophic oceanic regions such as the Sargasso Sea or the South Pacific Gyre, phytoplankton is dominated by the small sized cells, called picoplankton, mostly composed of cyanobacteria (Prochlorococcus, Synechococcus) and picoeucaryotes such as Micromonas.

Environmental threats A 2010 study published in Nature found that marine phytoplankton have declined substantially in the world's oceans over the past century. Since 1950 alone, phytoplankton concentrations in surface waters were reported to have decreased by about 40%, possibly in response to ocean warming.[11][12] The study generated debate among scientists and led to several communications, also published in Nature.[13][14] [15][16] This study has not yet been substantiated. Aquaculture Phytoplankton are a key food item in both aquaculture and mariculture. Both utilize phytoplankton as food for the animals being farmed. In mariculture, the phytoplankton is naturally occurring and is introduced into enclosures with the normal circulation of seawater. In aquaculture, phytoplankton must be obtained and introduced directly. The plankton can either be collected from a body of water or cultured, though the former method is seldom used. Phytoplankton is used as a foodstock for the production of rotifers,[17] which are in turn used to feed other organisms. Phytoplankton is also used to feed many varieties of aquacultured molluscs, including pearl oysters and giant clams. --------------------------------------------------------------------------------------------------------------Global warming

Global warming refers to the current rise in the average temperature of Earth's atmosphere and oceans and its projected continuation. In the last 100 years, Earth's average surface temperature increased by about 0.8 C (1.4 F) with about two thirds of the increase occurring over just the last three decades.[2] Warming of the climate system is unequivocal, and scientists are more than 90% certain most of it is caused by increasing concentrations of greenhouse gases produced by human activities such as deforestation and burning fossil fuels.[3][4][5][6] These findings are recognized by the national science academies of all the major industrialized countries.[7][A] An increase in global temperature will cause sea levels to rise and will change the amount and pattern of precipitation, and a probable expansion of subtropical deserts.[11] Warming is expected to be strongest in the Arctic and would be associated with continuing retreat of glaciers, permafrost and sea ice. Other likely effects of the warming include more frequent occurrence of extreme weather events including heat waves, droughts and heavy rainfall events, species extinctions due to shifting temperature regimes, and changes in crop yields. Warming and related changes will vary from region to region around the globe, with projections being more robust in some areas than others.[12] In a 4 C world[clarification needed], the limits for human adaptation are likely to be exceeded in many parts of the world, while the limits for adaptation for natural systems would largely be exceeded throughout the world. Hence, the ecosystem services upon which human livelihoods depend would not be preserved.[13]

--------------------------------------------------------------------------------------------------------------A carbon sink is a natural or artificial reservoir that accumulates and stores some carboncontaining chemical compound for an indefinite period. The process by which carbon sinks remove carbon dioxide (CO2) from the atmosphere is known as carbon sequestration. The main natural sinks are: Absorption of carbon dioxide by the oceans via physicochemical and biological processes Photosynthesis by terrestrial plants Oceans are at present CO2 sinks, and represent the largest active carbon sink on Earth, absorbing more than a quarter of the carbon dioxide that humans put into the air. At the present time, approximately one third[14] of human generated emissions are estimated to be entering the ocean. The solubility pump is the primary mechanism driving this, with the biological pump playing a negligible role. This stems from the limitation of the biological pump by ambient light and nutrients required by the phytoplankton that ultimately drive it. Climate change may also affect the biological pump in the future by warming and stratifying the surface ocean, thus reducing the supply of limiting nutrients to surface waters. ---------------------------------------------------------------------------------------------------------------Eutrophication (Greek: eutrophiahealthy, adequate nutrition, development; German: Eutrophie) or more precisely hypertrophication, is the movement of a body of water's trophic status in the direction of increasing biomass, by the addition of artificial or natural substances, such as nitrates and phosphates, through fertilizers or sewage, to an aquatic system. In other

terms, it is the "bloom" or great increase of phytoplankton in a water body. Negative environmental effects include hypoxia, the depletion of oxygen in the water, which induces reductions in specific fish and other animal populations. Other species (such as Nomura's jellyfish in Japanese waters) may experience an increase in population that negatively affects other species. Eutrophication can be human-caused or natural. Untreated sewage effluent and agricultural runoff carrying fertilizers are examples of human-caused eutrophication. However, it also occurs naturally in situations where nutrients accumulate (e.g. depositional environments), or where they flow into systems on an ephemeral basis. Eutrophication generally promotes excessive plant growth and decay, favouring simple algae and plankton over other more complicated plants, and causes a severe reduction in water quality. Phosphorus is a necessary nutrient for plants to live, and is the limiting factor for plant growth in many freshwater ecosystems. The addition of phosphorous increases algal growth. These algae assimilate the other necessary nutrients needed for plants and animals. When algae die they sink to the bottom where they are decomposed and the nutrients contained in organic matter are converted into inorganic form by bacteria. The decomposition process uses oxygen and deprives the deeper waters of oxygen which can kill fish and other organisms. Also the necessary nutrients are all at the bottom of the aquatic ecosystem and if they are not brought up closer to the surface, where there is more available light allowing for photosynthesis for aquatic plants, a serious strain is placed on algae populations. Enhanced growth of aquatic vegetation or phytoplankton and algal blooms disrupts normal functioning of the ecosystem, causing a variety of problems such as a lack of oxygen needed for fish and shellfish to survive. The water becomes cloudy, typically coloured a shade of green, yellow, brown, or red. Eutrophication also decreases the value of rivers, lakes, and estuaries for recreation, fishing, hunting, and aesthetic enjoyment. Health problems can occur where eutrophic conditions interfere with drinking water treatment.[2] Ocean waters Eutrophication is a common phenomenon in coastal waters. In contrast to freshwater systems, nitrogen is more commonly the key limiting nutrient of marine waters; thus, nitrogen levels have greater importance to understanding eutrophication problems in salt water. Estuaries tend to be naturally eutrophic because land- derived nutrients are concentrated where run-off enters a confined channel. Upwelling in coastal systems also promotes increased productivity by conveying deep, nutrient-rich waters to the surface, where the nutrients can be assimilated by algae. T In addition to runoff from land, atmospheric fixed nitrogen can enter the open ocean. A study in 2008 found that this could account for around one third of the oceans external (non-recycled) nitrogen supply, and up to 3% of the annual new marine biological production.[10] It has been suggested that accumulating reactive nitrogen in the environment may prove as serious as putting carbon dioxide in the atmosphere.[11]