Safety and Health Topics | Coal Tar Pitch Volatiles

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Coal Tar Pitch Volatiles

Coal tar pitch volatiles (CTPVs) are composed of various chemical vapors that become airborne during the heating of coal tar pitch. Coal tar pitch is a black or dark-brown amorphous residue produced by the distillation or heat treatment of coal tar. It is a solid at room temperature and exhibits a broad softening range instead of a defined melting temperature. Synonyms for CTPVs vary depending upon the specific compound (e.g., pyrene, phenanthrene, acridine, chrysene, anthracene and benzo(a)pyrene). [Note: National Institute for Occupational Safety and Health (NIOSH) considers coal tar, coal tar pitch, and creosote to be coal tar products.]

Contents Home OSHA Standards Hazards and Solutions Exposure Evaluation Additional Information
Page last reviewed: 03/19/2007

OSHA has not established a substance-specific standard for occupational exposure to coal tar pitch volatiles (CTPVs). Exposures are regulated under OSHA's Air Contaminants Standard. Employees exposed to CTPVs in the coke oven industry are covered by the coke oven emissions standard.

OSHA Standards
This section highlights OSHA standards and standard interpretations (official letters of interpretation of the standards) related to CTPVs. Note: Twenty-five states, Puerto Rico and the Virgin Islands have OSHA-approved State Plans and have adopted their own standards and enforcement policies. For the most part, these States adopt standards that are identical to Federal OSHA. However, some States have adopted different standards applicable to this topic or may have different enforcement policies. General Industry (29 CFR 1910) 1910.1000, Air contaminants Table Z-1, Limits for air contaminants. (See the entry for coal tar pitch volatiles.) 1910.1002, Coal tar pitch volatiles; interpretation of term 1910.1029, Coke oven emissions Appendix A, Coke oven emissions substance information sheet Appendix B, Industrial hygiene and medical surveillance guidelines Shipyard Employment (29 CFR 1915) 1915.1000, Air contaminants. (See the coal tar pitch volatiles entry in Table Z-Shipyards.) 1915.1002, Coal tar pitch volatiles; interpretation of term. Requirements are identical to 29 CFR 1910.1002. Construction Industry (29 CFR 1926) 1926.55, Gases, vapors, fumes, dusts, and mists Appendix A, Gases, vapors, fumes, dusts, and mists. (See entry for coal tar pitch volatiles.) 1926.1102, Coal tar pitch volatiles; interpretation of term. Requirements are identical to 29 CFR 1910.1002. Standard Interpretations OSHA's coke oven emissions standard is not applicable to the construction industry. (1999, June 22). Review of Variance Request Number 2276. (1995, May 30). Discusses the adjustment of benzene soluble fractions for interferences. Natural or mined asphalts do not fall within the scope of the Coal Tar Pitch Volatiles Standard. (1983, May 26). Petroleum asphalt removed from coverage under the Coal Tar Pitch Volatiles Standard. (1983, April 8). Applicability of the Coal Tar Pitch Volatiles Standard to dust of coal tar pitch. (1982, May 17). Search all available standard interpretations.

Hazard and Solutions

Coal tar pitch volatiles (CTPVs) are found in the industry when heating of coal tar or coal tar pitch takes place. Once the pitch is heated, chemicals vaporize and may be inhaled by workers. Industries where workers are potentially exposed to CTPVs include coking, roofing, road paving, aluminum smelting, wood preserving and any others where coal tar is used. The following references aid in recognizing coal tar pitch volatiles hazards in the workplace. Hazard Recognition Evaluation of Employee Health Risk from Open Tire Burning. California Integrated Waste Management Board (CIWMB), Local Enforcement Agency (LEA) Advisory #46, (1997, November 6). Provides a compilation of available information through literature review, known tire fire data, and other available information.

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Safety and Health Topics | Coal Tar Pitch Volatiles

Coke Oven Emissions. Environmental Protection Agency (EPA). Contains information on health hazard estimates from exposure to coke oven emissions which involve coal tar pitch volatiles. ToxFAQs for Creosote. Agency for Toxic Substances and Disease Registry (ATSDR), (2002, September). Summarizes the properties and health effects for creosote, including CTPVs. Possible Solutions Engineering controls are the best methods for controlling exposure to CTPVs. Engineering controls include local and dilution ventilation, isolating and/or containing processes that emit CTPVs, and where possible, automated handling of coal tar products that generate CTPVs in open systems. Respirators may also be worn by individuals exposed to CTPVs to keep their exposures below the OSHA permissible exposure limit (PEL), and protective clothing may be used to prevent skin contact with coal tars and coal-tar products, including CTPVs. However, personal protective equipment (PPE) should be the last line of defense. The following table presents exposure limits established for CTPVs and related substances. PEL = Permissible Exposure Limit REL = Recommended Exposure Limit TLV = Threshold Limit Value PAHS = Polycyclic Aromatic Hydrocarbons Substance CTPVs OSHA PEL 0.2 mg/m3 NIOSH REL ACGIH TLV

0.1 0.2 mg/m3 (benzenemg/m3 (cyclohexane- (benzenesoluble fraction) extractable fraction) soluble fraction) 0.2 mg/m3 0.1 mg/m3 (10 hour exposure) ---

PAHs Coke Oven Emissions

0.5-0.7 mg/m3 0.150 mg/m3 (benzenesoluble fraction)

Values are for an 8 hour time-weighted-average (TWA) exposure, except for the National Institute for Occupational Safety and Health (NIOSH) REL for PAHs, which is based on a 10 hour TWA exposure. Documentation for Immediately Dangerous To Life or Health Concentrations (IDLHs). US Department of Health and Human Services (DHHS), National Institute for Occupational Safety and Health (NIOSH) Publication, (1994, May). Coal tar pitch volatiles

Exposure Evaluation
Coal tar pitch volatiles (CTPVs) are measured by passing workplace air through a sampling device and then analyzing the sample for the compounds of interest. The following references aid in evaluating levels of CTPVs. Chemical Sampling Information. OSHA. Presents, in concise form, data on a large number of chemical substances that may be encountered in industrial hygiene investigations. Intended as a basic reference for industrial hygienists engaged in OSHA field activity. Coal Tar Pitch Volatiles (benzene soluble fraction) NIOSH Manual of Analytical Methods. US Department of Health and Human Services (DHHS), National Institute for Occupational Safety and Health (NIOSH) Publication No. 2003-154, (2003). Provides chapters which contains useful information on methods, Quality Assurance, sampling, method evaluation, biological monitoring, and special measurement considerations. Benzene-Soluble Fraction and Total Particulate (Asphalt Fume) [35 KB PDF, 7 pages]. Method 5042, (1998, January 15). Polynuclear Aromatic Hydrocarbons by HPLC [65 KB PDF, 9 pages]. Method 5506, (1998, January 15). Polynuclear Aromatic Hydrocarbons by GC [37 KB PDF, 7 pages]. Method 5515, (1994, August 15). Coal Tar Pitch Volatiles (CTPV), Coke Oven Emissions (COE), and Selected Polynuclear Aromatic Hydrocarbons (PAHs). OSHA Method No. 58, (1986, July). Coal Tar Pitch Volatiles (CTPV), Coke Oven Emissions (COE), and Selected Polynuclear Aromatic Hydrocarbons (PAHs). Extracted from OSHA Method No. 58. Contains basic information needed to correctly sample and analyze coal tar pitch volatiles (CTPV), coke oven emissions (COE), and selected polynuclear aromatic hydrocarbons (PAHs). Health Effects Carcinogen Assessment of Coke Oven Emissions. Environmental Protection Agency (EPA), Office of Health and Environmental Assessment Publication No. EPA-600/6-82-003F, (1984, February). Summarizes studies of the health effects resulting from exposures to coke oven emissions. Health Effects Notebook for Hazardous Air Pollutants. Environmental Protection Agency (EPA). Lists fact sheets that describe the effects on human health of substances that are defined as hazardous by the 1990 amendments of the Clean Air Act. Polycyclic organic matter (POM). Provides a health hazard summary on polycyclic organic matter found in coal tar production plants, coking plants, coal-gasification sites, smokehouses, municipal trash incinerators, and other industries. Specific information includes environmental/occupational exposure, assessing personal exposure, health hazard information for both acute and chronic effects, physical properties, and health data from inhalation exposure. Report on Carcinogens (RoC). US Department of Health and Human Services (DHHS), National Toxicology Program (NTP). Identifies and discusses agents, substances, mixtures, or exposure circumstances that may pose a health hazard due to their carcinogenicity. Coal Tars and Coal-Tar Pitches [109 KB PDF, 3 pages]. Provides information on carcinogenicity, properties, use, production, exposure, and regulation of CTPVs. ToxFAQS for Creosote. Agency for Toxic Substances and Disease Registry (ATSDR), (2002, September). Summarizes the properties and health effects for creosote, including CTPVs. Chemical Concerns ToxFAQs for Polycyclic Aromatic Hydrocarbons (PAHs). Agency for Toxic Substances and Disease Registry (ATSDR), (1996, September). Covers what PAHs are, how a person is exposed to PAHs, the acute and chronic health effects, human and animal studies associated with high levels of exposures, medical tests to determine if a person has been exposed to PAHs, and the regulations associated with PAHs. Chemical Safety. National Institute for Occupational Safety and Health (NIOSH) Workplace Safety and Health Topic. Provides information on many hazardous chemicals and chemical concerns.

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Safety and Health Topics | Coal Tar Pitch Volatiles

Report on Carcinogens (RoC). US Department of Health and Human Services (DHHS), National Toxicology Program (NTP), (latest version). Identifies and discusses agents, substances, mixtures, or exposure circumstances that may pose a health hazard due to their carcinogenicity. Polycyclic Aromatic Hydrocarbons: 15 Listings [217 KB PDF, 8 pages]. Provides results of animal (mouse) experiments which demonstrate carcinogenicity of 15 polycyclic aromatic hydrocarbons (PAHs). Also discusses the properties, use, exposure, production, and regulation of PAHs. Right to Know Hazardous Substance Fact Sheets. New Jersey Department of Health and Senior Services, Division of Epidemiology, Environmental and Occupational Health. Includes detailed reports on specific chemicals, covering hazard summaries, identification, exposure routes, health hazards, and ways of reducing exposure. The following polycyclic aromatic hydrocarbons (PAHs) are included. Acenaphthene [38 KB PDF, 6 pages]. (1998, November). Anthracene [35 KB PDF, 6 pages]. (2002, June). Benz(a)anthracene [35 KB PDF, 6 pages]. (2008, August). Benzo(b)fluoranthene [35 KB PDF, 6 pages]. (2001, July). Benzo(a)pyrene [35 KB PDF, 6 pages]. (2007, October). Creosote [35 KB PDF, 6 pages]. (2007, February). Coal Tar Pitch [35 KB PDF, 6 pages]. (2009, August). Fluorene [35 KB PDF, 6 pages]. (1999, May). Naphthalene [35 KB PDF, 6 pages]. (2004, October).

Additional Information
Related Safety and Health Topics Pages Asphalt Fumes Benzene Other Resources NIOSH Pocket Guide to Chemical Hazards. National Institute for Occupational Safety and Health (NIOSH) Publication No. 2005-149, (2007, September). Presents key information and data in abbreviated or tabular form for chemicals or substance groupings (e.g. cyanides, fluorides, manganese compounds) that are found in the work environment. Coal tar pitch volatiles Coke oven emissions Agency for Toxic Substances and Disease Registry (ATSDR). Provides a database of health information to prevent harmful exposures and disease. The following publications give information about polycyclic aromatic hydrocarbons (PAHs) and emphasize the human health effects that may result from exposure to them. Public Health Statement for Polycyclic Aromatic Hydrocarbons (PAHs). (1995, August). ToxFAQs for Polycyclic Aromatic Hydrocarbons (PAHs). (1996, September). The following is a list of literature references pertaining to coal tar pitch volatiles (CTPVs). Jongenteelen, F.J. "Biological exposure limit for occupational exposure to coal tar pitch volatiles at cokeovens." Int-arch-Occupational and Environmental Health 63.8(1992): 511-516. Armstrong, B. and G. Theriault. "Compensating lung cancer patients occupationally exposed to coal tar pitch volatiles." Occupational and Environmental Medicine 53.3(1996, March): 160-167. Baranski, B., et al. "Correlation between polycyclic aromatic hydrocarbons concentration and airborne particle mutagenicity in rubber factory." Pol Journal of Medicine and Environmental Health 5.4(1992): 357-362. Rogaczewska, T., D. Ligocka, and K. Nowicka. "Hygienic characteristics of carbon black used in tyre production." Pol Journal of Occupational Medicine 2.4(1989): 367-375. Tremblay, C., et al. "Estimation of risk of developing bladder cancer among workers exposed to coal tar pitch volatiles in the primary aluminum industry." American Journal of Industrial Medicine 27.3(1995, March): 335-348. Armstrong, B., et al. "Lung cancer mortality and polynuclear aromatic hydrocarbons: a case-cohort study of aluminum production workers in Arvida, Quebec, Canada." American Journal of Epidemiology 139.3(1994, February 1): 250-262. Spinelli, J.J., et al. "Mortality and cancer incidence in aluminum reduction plant workers." Journal of Occupational Medicine 52.4(1995, April): 255-261. Ronneberg, A. "Mortality and cancer morbidity in workers from an aluminum with prebaked carbon anodes-part I: Exposure assessment." Occupational and Environmental Medicine 52.4(1995, April): 242-249. Ronneberg, A. "Mortality and cancer morbidity in workers from an aluminum with prebaked carbon anodes-part II: Cancer morbidity." Occupational and Environmental Medicine 52.4(1995, April): 250-254. Ronneberg, A. "Mortality and cancer morbidity in workers from an aluminum with prebaked carbon anodes-part III: Mortality from circulatory and respiratory diseases." Occupational and Environmental Medicine 52.4(1995, April): 255-261. Rogaczewska, T. and D. Ligocka. "Occupational exposure to coal tar pitch volatiles, benzo/a/purene and dust in tyre production." International Journal of Occupational Medicine and Environmental Health 7.4(1994): 379-386.
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