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rates n sw ers A
= 3.7 104s1 7 Rate = k[ester][OH] rate k= [ester][OH ] 0.00069 dm 3 s1 mol 0.05 dm 3 0.10 dm 3 mol mol = 0.138dm3mol1s1 8 a) The graph is a straight line so the reaction is first order with respect to bromine. b) i) Half-lives are all close to 200s wherever they are read from the graph. ii) This is consistent with the answer to a). The half-life for a first-order process is independent of the starting concentration. 9 For a first-order reaction the gradient of the rateconcentration graph gives the rate constant. 10 a) Rate = k[RBr][OH] b) Second order =
1 of 4
= 3400dm3mol1s1 13 a) Rate = k[RBr] rate 40.40 dm 3 s1 mol b) k = = [RBr] 0.02 dm 3 mol = 2020s1 14 a) 2H2(g) + 2NO(g) N2(g) + 2H2O(g) b) Rate = k[H2(g)][NO(g)]2