AIEEE - 2011 CHEMISTRY

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CHEMISTRY
1. The presence or absence of hydroxy group on which carbon atom of sugar differentiates RNA and DNA ? 1) 1st Sol : 2 2. Among the following the maximum covalent character is shown by the compound : 1) FeCl2 Sol : 3 3. 2) SnCl2 3)
AlCl3

2) 2nd

3)

3rd

4) 4th

Which of the following statement is wrong ?

1) The stability of hydrides increases from NH 3 to BiH 3 in group 15 of the periodic table 2) Nitrogen cannot form d p bond 4) N 2 O4 has two resonance structures Sol : 1 4. Phenol is heated with a solution of mixture of KBr and KBrO3 . The major product obtained in the above reaction is : 1) 2-Bromophenol 2) 3-Bromophenol 3) 4-Bromophenol Sol : 4 5. A 5.2 molal aqueous solution of methyl alcohol, CH 3OH , is supplied. What is the mole fraction of methyl alcohol in the solution ? 1) 0.100 2) 0.190 3) 0.086 4) 0.050 4) 2, 4, 6-Tribromophenol

3) Single N - N bond is weaker than the single P - P bond

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2) sp 2 , sp, sp 3
2 3

4) MgCl2

Sol : 3 Mole fraction = 6.

5.2 = 0.086 55.2 + 5.2

+ The hybridisation of orbitals of N atom in NO3 , NO2+ and NH 4 are respectively :

1) sp, sp 2 , sp 3 3) sp, sp , sp Sol : 2

3 2

4) sp , sp , sp www.aieeepage.com

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Ethylene glycol is used as an antifreeze in a cold climate. Mass of ethylene glycol which should be added to 4 kg of water to prevent it from freezing at -6C will be : ( K f for water = 1.86 K kg mol 1 , and molar mass of ethylene glycol = 62g mol 1 ) 1) 804.32 g 2) 204.30 g 3) 400.00 g 4) 304.60 g

Sol : 1

6 = 1.86

w 1 62 4

w=

6 62 4 = 800 g 1.86

Weight of ethylene glycol that need to be added should be more than 800 g

8.

The reduction potential of hydrogen half cell will be negative if : 1) 3)

p ( H 2 ) = 1 atm and [ H + ] = 2.0 M

p ( H 2 ) = 2 atm and [ H + ] = 1.0 M

www.aieeepage.com and [H ] = 2.0 M 4) p ( H ) = 2 atm

2

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2)

p ( H 2 ) = 1 atm and [ H + ] = 1.0 M

+

Sol : 3
2 H + + 2e H2

E = E +
E = O

0.06 [ H + ]2 log 2 PH 2

E = 0.06 log

1 2

= 0.06 ( 0.301) = 0.018V

9. Which of the following reagents may be used to distinguish between phenol and benzoic acid ? 1) Aqueous NaOH 2) Tollens reagent 3) Molisch reagent

Sol : 4 Phenols give violet colour with neutral FeCl3 10.

Trichloroacetaldehyde was subjected to Cannizzaros reaction by using NaOH. The mixture of the products contains sodium trichloroacetate and another compound. The other compound is : 1) 2, 2, 2-Trichloroethanol 2) Trichloromethanol

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4) Chloroform
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4) Neutral FeCl3

3) 2, 2, 2-Trichloropropanol Sol : 1
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NaOH 2 CCl3CHO CCl3COONa + CCl3 CH 2 OH

11.

Which one of the following orders presents the correct sequence of the increasing basic nature of the given oxides ? 1) Al2 O3 < MgO < Na2 O < K 2 O 3) Na2 O < K 2 O < MgO < Al2 O3 2) MgO < K 2 O < Al2 O3 < Na2 O 4) K 2 O < Na2 O < Al2 O3 < MgO

Sol : 1 12. A gas absorbs a photon of 355 nm and emits at two wavelengths. If one of the emissions is at 680 nm, the other is at : 1) 1035 nm 2) 325 nm 3) 743 nm 4) 518 nm
E = E1 + E2

Sol : 3

E=

hc hc + 1 2

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1 1 1 = + 355 680 x
1 1 1 = x 355 680 x = 742.7 nm 743 nm
13. Which of the following statements reagarding sulphur is incorrect ? 1) S 2 molecule is paramagnetic 2) The vapour at 200C consists mostly of S8 rings. 3) At 600C the gas mainly consists of S2 molecules. 4) The oxidation state of sulphur is never less than +4 in its compounds.

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Sol : 4 14.

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The entropy change involved in the isothermal reversible expansion of 2 moles of an ideal gas from a
3 volume of 100 dm at 27C is :

1) 38.3 J mol 1 K 1 3) 32.3 J mol 1 K 1 Sol : 1

2) 35.8 J mol 1 K 1 4) 42.3 J mol 1 K 1

S = 2.303 nR log

V2 V1

= 2.303 2 8.314 log 10

= 38.3 J mole1 K 1
15.

Which of the following facts about the complex Cr ( NH 3 )6 Cl3 is wrong ? 1) The complex involves d 2 sp3 hybridisation and is octahedral in shape. 2) The complex is paramagnetic 3) The complex is an outer orbital complex 4) The complex gives white precipitate with silver nitrate solution.

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Sol : 3 16. The structure of IF7 is : 1) square pyramid 3) octahedral Sol : 4 17. The rate of a chemical reaction doubles for every 100C rise of temperature. If the temperature is raised by 500C, the rate of the reaction increases by about : 1) 10 times 2) 24 times 3) 32 times 4) 64 times 2) trigonal bipyramid 4) pentagonal bipyramid

Sol : 3

25 times = 32
18.

The strongest acid amongst the following compounds is : 1) CH 3COOH 2) HCOOH 3) CH3CH2CH(Cl)CO2H

Sol : 3 - I effect of chlorine on carbon 19.

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4) ClCH2CH2CH2COOH

Identify the compound that exhibits tautomerism. 1) 2-Butene 2) Lactic acid 3) 2-Pentanone

4) Phenol
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Sol : 3 20.

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A vessel at 1000 K contains CO2 with a pressure of 0.5 atm. Some of the CO2 is converted into CO on the addition of graphite. If the total pressure at equilibrium is 0.8 atm, the value of K is : 1) 1.8 atm 2) 3 atm 3) 0.3 atm 4) 0.18 atm

Sol : 1
CO 2 + C
(g)

(s)

2 CO ( g )
2x

0.5 x

0.5 x + 2 x = 0.8

x = 0.3

K
21.

( 2 0.3) =
0.2

= 1.8 atm

In context of the lanthanoids, which of the following statements is not correct? 1) There is a gradual decrease in the radii of the members with increasing atomic number in the series

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3) 2.82 BM
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2) All the members exhibit +3 oxidation state. 3) Because of similar properties the separation of lanthanoids is not easy. 4) Availability of 4f electrons results in the formation of compounds in +4 state for all the members of the series. Sol : 4 22. a and b are van der Waals constants for gases. Chlorine is more easily liquefied than ethane because 1) a and b for Cl2 > a and b for C2H6 2) a and b for Cl2 < a and b for C2H6 3) a for Cl2 < a for C2H6 but b for Cl2 > b for C2H6 4) a for Cl2 > a for C2H6 but b for Cl2 < b for C2H6 Sol : 4 23. The magnetic moment (spin only) of [NiCl4]2 is : 1) 1.82 BM 2) 5.46 BM

4) 1.41 BM

Sol : 3

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= n (n + 2) = 2 (2 + 2)
24. In a face centred cubic lattice, atom A occupies the corner positions and atom B occupies the face centre positions. If one atom of B is missing from one of the face centred points, the formula of the compound is : 2) AB2 3) A2B3 4) A2B5 1) A2B B

Sol : 4 A

1 1 8 : 5 8 2
2
A2 B5

25.

The outer electron configuration of Gd (Atomic No : 64) is : 1) 4f 3 5d 5 6s 2 2) 4f 8 5d 0 6s 2

Sol : 4 26. 1) BF63

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2) BH 4 3) B(OH) 4

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3) 4f 4 5d 4 6s 2

4) 4f 7 5d1 6s 2

Boron cannot form which one of the following anions? 4) BO 2

Sol : 1 Boron doesnt have a vacant d orbital 27. Ozonolysis of an organic compound gives formldehyde as one of the products. This confirms the presence of : 1) two ethylenic double bonds 2) a vinyl group 3) an isopropyl group Sol : 2 28. Sodium ethoxide has reacted with ethanoyl chloride. The compound that is produced in the above reaction is : 1) Diethyl ether 2) 2-Butanone 3) Ethyl chloride Sol : 4 4) Ethyl ethanoate 4) an acetylenic triple bond

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NaCl C2 H 5ONa + CH 3COCl CH 3 COOC2 H 5

The degree of dissociation ( ) of a weak electrolyte, A x By is related to vant Hoff factor (i) by the expression :

i 1 1) = (x + y 1)
Sol : 1

i 1 2) = x + y + 1

3) =

x + y 1 i 1

4) =

x + y +1 i 1

Ax B y

xA + yB
x y

total moles : 1 + ( x + y )

i = 1 + ( x + y ) i 1 = ( x + y 1)
30.

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4) Benzophenone

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Silver Mirror test is given by which one of the following compounds? 1) Acetaldehyde 2) Acetone 3) Formaldehyde

Sol : 1, 3

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