SOLUTIONS

Q.1 When mercuric iodide is added to the aqueous solution of potassium iodide, the (A) freezing point is raised (C) freezing point is lowered (B) freezing point does not change (D) boiling point does not change.

Q.2 The freezing point of equimolal aqueous solution will be highest for (A) (B) (C) (D) C6H5NH3Cl (aniline hydrochloride) Ca(NO3)2 La(NO3)2 C6H12O6 (glucose).

Q.3 Osmotic pressure of a solution is 0.0821 atm at temperature of 300 K. The concentration in mole/litre will be (A) 0.33 (B) 0.066 (C) 0.3 102 (D) 3

Q.4 Increasing the temperature of an aqueous solution will cause (A) decrease in molality (C) decrease in mole fraction (B) decrease in molarity (D) decrease in % (w/w)

Q.5 The vapour pressure of a solution of 5 g of non electrolyte in 100 g of water at a particular temperature is 2985 Nm2. The vapour pressure of pure water at that temperature is 3000 Nm 2. The molecular weight of the solute is (A) 180 (B) 90 (C) 270 (D) 200

Q.6 How many moles of Fe2+ ions are formed when excess iron is treated with 500 mL of 0.4N HCl under inert atmosphere ? Assume no change in volume. (A) 0.4 (B) 0.1 (C) 0.2 (D) 0.8

Q.7 The van't Hoff factor for 0.1 M Ba(NO3) 2 solution is 2.74. The degree of dissociation is (A) 91.3% (B) 87% (C) 100% (D) 74%

Q.8 For a sparingly soluble salt ApBq, the relationship of its solubility product (LS) with its solubility (S) is : (A) LS = Sp + q pp qq (C) LS = Spq pp qq (B) LS = Sp + q pq qp (D) LS = Spq (p q)p + q

Q.9 A molal solution is one that contains one mole of a solute in (A) 1000 g of the solvent (C) one litre of solution (B) one litre of solvent (D) 22.4 litre of the solution.

Q.10 A 0.004 M solution of K2SO4 is isotonic with a 0.010 M solution of glucos at the same temperature. The apparent per cent degree of dissociation of K2SO4 is (A) 25% (B) 50% (C) 75% (D) 100%

ANSWER KEY
Q.No. Ans. 1 A 2 D 3 C 4 B 5 A 6 B 7 B 8 A 9 A 10 C

SOLUTIONS (SOLUTIONS)
Ans.1 When HgI2 K2 [HgI4] l 2K+ + [HgI4]2 Thus there is a net decrease in number of ions present in solution. Two formula units of KI i.e., four ions decrease to three ions in K2[HgI4]. As number of ions decrease T decreases or f.p., is raised.

Ans.2 Highest freezing point (i.e., least depression in freezing point) is when i is least. The van't Hoff factor, i is minimum in case of glucose (i = 1). Ans.3 = CRT or C = /RT C=
0.821 atm (0.0821 L atm K 1 mol1) 300 K

= 0.3 x 10-2 mol L-1 Ans.4 An increase in temperature increases the volume of the solution and thus decreases its molarity.
(3000 2985) 3000 Nm
2

Ans.5

5 / MB 100 / 18

(For a dilute solution)

5 15 100 = MB 18 3000

or

MB = 180

Ans.6 Fe + 2HCl FeCl2 + H2

Moles of Fe2+ formed = = Ans.7 Initial At.equilibrium

1 Moles of HCl used 2

1 0.4 500 = 0.1 2 1000

Ba(NO3)2 l Ba2+ + 2NO3 0.1 M

(01 x) + + 2x . 01 + 2x . = = 2.74 01 . 01 . 0.1 + 2x = 0.274

or

x=

0174 . = 0.087 2 x 0.087 x 100 = x 100 = 87% 01 . 01 .

% =

Ans.8 ApBq l pA+ qB Solubility S pS qS (on 100% ionisation) KsP of ApBq = (A+)p (B)q = (pS)p (qS)q = (Sp + q) (pp qq) Ans.9 One molal solution contains one mole solute in 1000 g of solvent. Ans.10 The dissociation of K2SO4 may be written as K2SO4 2K+ + SO42 c(2) c c(1 ) The concentration of species in the solution is c(1 ) + (2) + c = c(1 + 2) (where c = 0.004 M) Hence, c (1 + 2) = 0.01 M. or
= 2 0.04 1 = 0.75
1 0.01

FG H

IJ K

The percent of dissociation is 0.75 100, i.e. 75%.