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Format For Instruction Plan [for Courses with Lectures,Tutorials and Labs
Course No CHE158
Text Book:
Suba Ramesh S.Varian,Pradya Tej Godbole , Engineering Chemistry , John Wiley , 1st edition. 2011
2 J.Mendham, R.C.Denney, J.D.Barnes Vogel's Text book of Inorganic and organic quantitative chemical analysis 6th Edition 2009. 3 J.D.Lee,Concise Inorganic Chemistry,Fifth Edition , Oxford University Press. 4 B.R.Puri,L.R.Sharma and K.C.Kalia,Priciples of inorganic chemistry,Vishal Publishising Co;2007-08 5 K.L.Kapoor,A text book of Physical Chemistry, Vol.3,Applications of thermodynamics,Mcmillian India Ltd,2nd Edition. 6 J.B.Yadav,Advance Practical chemistry,Krishna Publications, Merrut 12th ,Revised Edition
Other Reading Sr No Jouranls atricles as compulsary readings (specific articles, Complete reference)
Relevant Websites Sr. No. (Web adress) (only if relevant to the courses) Salient Features
7 http://www.tulane.edu/~sanelson/geol212/2compphasdiag.htm Phase, component , degree of freedom l 8 http://www.chem.arizona.edu/~salzmanr/480a/480ants/gibbsp Derivation of Gibb's phase rule, r/gibbspr.html 9 http://intro.chem.okstate.edu/PLE582901/PhaseDiagram.html Phase diagram of one component animation 10 http://serc.carleton.edu/research_education/equilibria/binary_d Phase diagram of two component animation iagrams.html 1 Approved for Autumn Session 2011-12
11 http://demonstrations.wolfram.com/GibbsPhaseRuleForOneA Phase diagram of one and two component animation ndTwoComponentSystems/ 12 http://www.doitpoms.ac.uk/tlplib/phase-diagrams/cooling.php 13 http://www.chemguide.co.uk/physical/phaseeqia/snpb.html Cooling Curves For two component lead silver system
14 http://www.tutorvista.com/content/physics/physics-iii/heat-and- Thermodynamic Processes thermodynamics/thermodynamic-processes-animation.php 15 http://www.tutorvista.com/content/chemistry/generalchemistry/thermodynamics/first-law-of-thermodynamics.php 16 http://www.tutorvista.com/content/chemistry/generalchemistry/thermodynamics/the-second-law-ofthermodynamics.php Ist Law of themodynamics 2nd Law of themodynamics
17 http://www.mhhe.com/physsci/chemistry/essentialchemistry/fla Galvanic cell sh/galvan5.swf 18 http://www.chem.iastate.edu/group/Greenbowe/sections/proje Ph Meter ctfolder/flashfiles/acidbasepH/ph_meter.html 19 http://www.chem1.com/acad/webtext/chembond/cb09.html#S coordination chemistry introduction EC1 20 http://www.materialsworldmodules.org/resources/polimarizatio Mechanism of condensation polymerisation n/4-condensation.html 21 http://www.materialsworldmodules.org/resources/polimarizatio Mechanism of addition polymerisation n/3-addition.html 22 http://www.yteach.co.uk/page.php/resources/view_all? Polymers,thermosetting,elastomer,themoplatics id=polymer_addition_polymerisation_polyethene_hydrocarbon _poly%28propene%29_poly%28phenylethene%29_poly %28chloroethene%29_poly%28tetrafluoroethene%2
Part 1
Week 1 Lecture 1 Phase rule: Statement and meaning of the termsphase, component and degrees of freedom Derivation , advantages and limitations of Gibbs phase rule ->Reference :1,->Animation: Reference 8 >Reference 1Page 235 -238Chapter 6 ->Reference :1,Page 238-238 Chapter 6 Animation:Reference 9
Lecture 2
Week 1 Week 2
Phase equilibra of one component system-water Phase equilibrium of two component system for eutectic mixtures,cooling curves classius clapeyron equation
->Reference :1,Page 239-242 Chapter 6 ->Reference :1,Page 239-242 Chapter 6 ->Reference :6,->>Reference 6Page 525 -530 ->Reference :1,Page 125-128 Chapter 4 ->Reference :1,Page 134-136 Chapter 4 ->Reference :1,Page 136-138 Chapter 4 ->Reference :1,Page 143-147 Chapter 4 ->Reference :1,Page 150-152 Chapter 4
Thermodynamic system, process , properties, energy of the thermodynamic system first law of thermodynamics and its interpretation and its applications :molar heat capacity Reversible isothermal expansion / compression of an ideal gas , adiabatic expansion of the ideal Thermo chemistry laws, bond energy Entropy, entropy change for isolated system, for ideal gas system only
Part 2
Week 4 Lecture 11 Lecture 12 Week 5 Lecture 13 Lecture 14 Lecture 15 Entropy change for mixing of ideal gases , entropy of physical and chemical changes Gibbs free energy and its physical significance Gibbs Helmholtz equation ,application of free energy ,concept of spontaneity ->Reference :1,Page 153-154 Chapter 4 ->Reference :1,Page 159-163 Chapter 4 ->Reference :1,Page 159-163 Chapter 4 Animation:Reference 18 Animation:Reference 18
Galvanic cells, salt bridge, EMF of the cell and free ->Reference :1,Page energy change 264-266 Chapter 7 Types of electrodes, metal metal ion electrodes, gas ->Reference :1,Page electrodes, metal insoluble metal salt electrodes, 284-286 Chapter 7 oxidation reduction electrodes Single electrode potential, Thermodynamics of reversible cell and reversible electrodes Nernst,s equation and applications Electrochemical series and applications Glass electrode, glass electrode potential ->Reference :1,Page 279-281 Chapter 7 ->Reference :1,Page 267-274 Chapter 7 ->Reference :1,Page 281-284 Chapter 7 ->Reference :1,Page 287-289 Chapter 7
Week 6
Animation:Reference 18 Test 2
Week 7
Lecture 19
Week 7
Lecture 20
Determination of pH using glass electrode, Electrode concentration cells and electrolyte concentration cells liquid junction potential, applications of concentration cells
Animation: Reference 19
Lecture 21
MID-TERM Part 3
Week 8 Lecture 22 Lecture 23 Lecture 24 Week 9 Lecture 25 Lecture 26 Lecture 27 Week 10 Lecture 28 Coordination compound terminology, Werners theory Sidwick and valence bond theory, crystal field theory Crystal field splitting in octahedral complexes, Tetrahedral complexes ->Reference :1,Page 86-90 Chapter 3 ->Reference :1,Page 91-94 Chapter 3 ->Reference :1,Page 94-96 Chapter 3 Animation:Reference 20
Crystal field splitting in square planar complexes ->Reference :1,Page magnetic properties and color in the transition metal 96101-102 Chapter 3 Factors influencing formation and stability of coordination complexes Types of ligands, Isomerism in coordination compounds( structural isomerism) ->Reference :1,Page 97-101 Chapter 3 ->Reference :1,Page 105-110 Chapter 85
Geometrical isomerism, optical isomerism, ->Reference :1,Page stereoisomerism isomerism, ionization isomerism, 110-115 Chapter 3 hydrate isomerism, linkage isomerism, coordination isomerism
Part 4
Week 10 Lecture 29 Lecture 30 Week 11 Lecture 31 Lecture 32 Lecture 33 Week 12 Lecture 34 Lecture 35 Cleavage of covalent bond , electrophile and nuclephile , inductive effect Electromeric effect, resonance effect Hyper conjugation, reaction intermediates( free radicals) Reaction intermediate( carbocations, carbanions carbenes) Introduction, Types of polymerization Mechanism of addition polymerization Thermo set polymer, elastomer, Conducting polymers, and its applications ->Reference :1,Page 341-344357 Chapter 9 ->Reference :1,Page 345-348 Chapter 9 ->Reference :1,Page 348-351 Chapter 9 ->Reference :1,Page 352-356 Chapter 9 ->Reference :1,Page 524-530 Chapter 13 ->Reference :1,Page 530-533 Chapter 13 ->Reference :1,Page 583-587 Chapter 13 Animation:Reference 21 Animation:Reference 22 Animation:Reference 23 Test3
Week 12
Lecture 36
spill over
Revision
Spill Over
Week 13 Lecture 37 Lecture 38
Phase rule: Statement and meaning of the terms- phase, component and degrees of freedom Derivation , advantages and limitations of Gibbs phase rule Phase equilibra of one component system-water Phase equilibrium of two component system for eutectic mixtures,cooling curves classius clapeyron equation Thermodynamic system, process , properties, energy of the thermodynamic system first law of thermodynamics and its interpretation and its applications :molar heat capacity
Class test based to evaluate on homework 2 students on the basis of there class teaching performance
Reversible isothermal expansion / compression of an ideal gas , Individual adiabatic expansion of the ideal gases Thermo chemistry laws, bond energy Entropy, entropy change for isolated system, for ideal gas system only ,Entropy change for mixing of ideal gases , entropy of physical and chemical changes Gibbs free energy and its physical significance,Gibbs Helmholtz equation ,application of free energy ,concept of spontaneity Galvanic cells, salt bridge, EMF of the cell and free energy change Types of electrodes, metal metal ion electrodes, gas electrodes, metal insoluble metal salt electrodes, oxidation reduction electrodes Single electrode potential Nernst,s equation and applications,
6/6
Nernst,s equation and applications, Individual Electrochemical series and applications Glass electrode, glass electrode potential, Determination of pH using glass electrode, Electrode concentration cells and electrolyte concentration cells liquid junction potential, applications of concentration cells,Coordination compound terminology, Werners theory Sidwick and valence bond theory, crystal field theory Crystal field splitting in octahedral complexes, Tetrahedral complexes Crystal field splitting in square planar complexes magnetic properties and color in the transition metal complexes Factors influencing formation and stability of coordination complexes Types of ligands, Isomerism in coordination compounds( structural isomerism) Geometrical isomerism, optical isomerism Cleavage of covalent bond , electrophile and nuclephile , inductive effect Electromeric effect, resonance effect
11 / 11
* In ENG courses wherever the total exceeds 100, consider x best out of y components of CA, as explained in teacher's guide available on the UMS
Plan for Tutorial: (Please do not use these time slots for syllabus coverage)
Tutorial No. Lecture Topic Type of pedagogical tool(s) planned (case analysis,problem solving test,role play,business game etc)
Tutorial 1
Phase rule: Statement and meaning of the termsphase, component and degrees of freedom, Derivation of Gibbs phase rule
Problem solving
Tutorial 2
phase equilibria of one component system-water. Phase equilibria of two component system, classius clapeyron equation
Problem solving
Tutorial 3
Thermodynamic system, process , properties, energy of Problem solving,Test the thermodynamic system, first law of thermodynamics and its interpretation and its applications :molar heat capacity, Reversible isothermal expansion / compression of an ideal gas , adiabatic expansion of the ideal gases, Thermo chemistry laws, bond energy Entropy, entropy change for isolated system, for ideal gas system only, Entropy change for mixing of ideal gases , entropy of physical and chemical changes, Gibbs free energy and its physical significance Gibbs Helmholtz equation ,application of free energy ,concept of spontaneity, Galvanic cells, salt bridge, EMF of the cell and free energy change, Types of electrodes, metal metal ion electrodes, gas electrodes, metal insoluble metal salt electrodes, oxidation reduction electrodes Nernst,s equation ,electrochemical series and applications Glass electrode, glass electrode potential, Determination of pH using glass electrode Problem solving
Tutorial 4
Tutorial 5
Problem solving
Tutorial 6 Tutorial 7
After Mid-Term
Tutorial 8 Electrode concentration cells and electrolyte Problem solving concentration cells,liquid junction potential, applications of concentration cells, Coordination compound terminology, Werners theory, Sidwick and valence bond theory, crystal field theory Crystal field splitting in octahedral complexes, Tetrahedral complexes, Crystal field splitting in square planar complexes magnetic properties and color in the transition metal complexes, Factors influencing formation and stability of coordination complexes Problem solving
Tutorial 9
Types of ligands, Isomerism in coordination compounds Problem solving Electromeric effect, resonance effect, Hyper conjugation, reaction intermediates Introduction, Types of polymerization, Mechanism of addition polymerization, Conducting polymers, and its applications Problem solving,Test Problem solving
*Each experiment of the lab will be evaluated using following relative scheme:
Component J/E WR VIVA % of Marks 20 50 30
List of experiments :Lecture Number Lecture Topic Pedagogical Tools Or Equipment Planned Glass Apparatus lab Manual Not Applicable
Expremental Determine the strength of given solution of ferrous and D\Group w ammonium sulphate(Mohrs salt) by titrating against 1 potassium dichromate solution Expremental To find the order of the reaction using Iodine Clock and D\Group w method. 2 Expremental To estimate the amount of copper and zinc in a given and D\Group w sample of Brass. 3
Glass Apparatus
Not Applicable
Glass Apparatus
Not Applicable
Expremental To study the hydrolysis of methyl acetate catalyzed by Thermostat water bath and D\Group w HCl at room temperature kinetically. 4 Expremental To determine the equivalence conductance of a weak and D\Group w electrolyte at infinite dilution using kohlraush law 5 Conductivity meter
Not Applicable
Not Applicable
Expremental To calibrate pH meter. To prepare buffer solution and pH meter and D\Group w to determine the pH of buffer solutions. To prepare and 6 describe titration curve for hydrochloric acid- sodium hydroxide titration using pH meter.
Not Applicable
Mid Term
Expremental To verify the Beers-Lambert law for solution of and D\Group w CoCl2.6H2O (in water) and K2Cr2O7 (in water). 7 Expremental To draw a cooling curve of a pure compound and and D\Group w mixture. 8 Colorimeter Not Applicable
Glass Apparatus
Not Applicable
Expremental Separation of given organic compound using thin layer Glass Apparatus and D\Group w chromatography, and calculate it retention factor. 9 Expremental To detect the functional group of the given compound and D\Group w and prepare it derivative. 10 Glass Apparatus
Not Applicable
Not Applicable
Spill Over
Expremental and D\Group w 11 Not Applicable