A GUIDE TO FREELY AVAILABLE AND SEARCHABLE INTERNET DATABASES FOR FREELANCE, START-UPS AND SMALL BUSINESS SAFETY DATA

SHEETS WRITERS

Theodore M. Amet Global HazCom Documents Writer

Racine, Wisconsin

June, 2012

Preface The Aha! moment for writing this guide came when I started writing Safety Data Sheets (SDSs) at Easterday Fluid Technologies, LLC, a manufacturer of industrial ink and ink related products. Since chemicals/raw substances are used in product manufacturing, the law requires manufacturers to provide customers Material Safety Data Sheets. Although I was trained to draft and write Material Safety Data Sheets with MSDS authoring software (e.g. EnviroMSDS, SAP, The WERCS), those platforms were not available to me at Easterday. We used Microsoft Office Suite to prepare GHS compliant Safety Data Sheets (according to EU Directives and Guidance Documents) to accompany ink and ink related products for clients in Europe and elsewhere. Our efforts in researching guidance documents, physical, chemical and toxicological properties of substances, and country specific regulatory information on the Internet (in addition to product literature from chemical manufacturers) yielded adequate information for creating Safety Data Sheets according to European Union regulations and standards using only Microsoft Word, rather than a specialized, and expensive, authoring program. We believe this guide will be invaluable to writers of Safety Data Sheets everywhere, especially those in small companies, and those wanting to use it as a reference document when their Safety Data Sheets/Material Safety Data Sheets authoring system is down. With your help, we will be able to keep abreast with European Chemical Regulations and update this guide as new regulations become available. If you know of additional links to free chemical, environmental, health, and toxicological databases on the Internet, please e-mail the link(s) to us at safety.writer@gmail.com . We will promptly add it in this guide. Please acknowledge this guide in Section 15 of your Safety Data Sheet whenever you use it as one of your sources for information. Thank you for your participation.

Authors Biography Dr. Theodore M. Amet is Manager, Global GHS Compliant SDSs, Labels, and MSDSs Projects at Easterday Fluid Technologies, LLC, in Saint Francis, Wisconsin. He holds a Bachelors degree in Agriculture Science from the University of Liberia, and worked as a Seed Technologist Assistant at WARDA (West Africa Rice Development Association) before joining the faculty in the College of Agriculture and Forestry, University of Liberia. Subsequently, he earned a Masters degree in Genetics (major) and Development Studies (minor) from the University College of Wales-Swansea (Swansea University) and a Ph.D. in Animal Science and Biotechnology from North Carolina State University, Raleigh, North Carolina. That was followed by a postdoctoral appointment in Molecular Reproductive Biology in the Department of Biochemistry, Molecular Biology and Cell Biology at Northwestern University, Evanston, Illinois. He also trained in clinical experimental embryology at the Reproductive Genetics Institute in Chicago, Illinois. He earned an MBA in General Management from Loyola University Chicagos School of Business Administration, Chicago, Illinois. His exposure to chemical regulations came when he worked in the Department of Global Safety Assessment and Regulatory Affairs (GSARA) at S.C. Johnson & Son, Inc. of Racine, Wisconsin. He served as Raw Substance Steward (RSS), MSDS drafter, and Regulatory Research Analyst while at S.C. Johnson. Dr. Amet is a member of the American Chemical Society (ACS) and the Society for Chemical Hazard Communication (SCHC).

ii

DISCLAIMER This guide was compiled as a service to Safety Data Sheet writers everywhere. It neither reflects the views of others, nor does it endorse one link over the other. Internet links cited in this guide and views expressed in the various sections are mine alone. Information in this document is based on data gathered from many sites. No warranty is expressed regarding the accuracy of data obtained from various chemical, health, toxicological, and environmental databases. Responsibility for the accuracy and completeness of information contained herein rests with the users who must satisfy themselves that the data is appropriate for their needs. It is always a good practice to consult a sectional expert when writing sections of the Safety Data Sheet to clarify and simplify technical matters.

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SAMPLE SAFETY DATA SHEET

according to Regulation (EC) No 1907/2006 (REACH), Annex II Product Name: Fendell Cleaning Solvent Blend No. 3 Page 1 of 25 Prepared Date: 06/27/2011 Product Code: FCSB No.3 Version: 1.00 Printing Date: 08/10/2011 1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING Information about the company and product (s) (substance/mixture) shall be provided to the Safety Data Sheet (hereinafter SDS) writer by a senior authority/manager (e.g. regulatory, product safety, EHS, etc.) in the company. The writer shall be provided with a numbering system (for generating version(s) of the SDS) as specified in ECHAs Guidance document (Guidance on the compilation of safety data sheets: http://guidance.echa.europa.eu/docs/draft_documents/fourth_draft_sds_Guidance_july_2011.pdf). Information on REACH SDS compilation can be found on ECHA Website (http://echa.europa.eu/home_en.asp). Each title page of the hazard communication document (SDS) shall have unique identifiers (product name, date(s), page number, version number, etc). Use wording that is concise and understandable to end users. Avoid technical and trade jargons whenever possible. Blank subsections are not allowed. Preferred SDS language shall be the language of the country where the product is being placed. 2. HAZARDS IDENTIFICATION The following databases which are currently available on the Internet will be used to assess/classify hazardous substances in an experimental dangerous preparation/ mixture, Fendell Cleaning Solvent Blend (FCSB) No. 3. ChemSub Online http://chemsub.online.fr/ ESIS: European chemical Substances Information System http://ecb.jrc.ec.europa.eu/esis/ Hazardous Substances Information System (HSIS) Online Database http://hsis.ascc.gov.au/ ChemBlink (Chinese Online Database of Chemicals from around the world) http://www.chemblink.com/ The Good Scents Company http://www.thegoodscentscompany.com/

Product Name: Fendell Cleaning Solvent Blend No. 3 Product Code: FCSB No. 3 Version: 1.00 The Chemical Library http://chemlib.cefic.org/index.asp

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Lets evaluate the components in our experimental mixture, Fendell Cleaning Solvent Blend (FCSB) No. 3. The product contains six substances with their weight/volume as indicated below: 1. 2. 3. 4. 5. 6.
Substance Name 3- Butanone n-Butanol Ethanol Isopropanol Toluene Xylene

3-Butanone n-Butanol Ethanol Isopropanol Toluene Xylene

CAS # 78-93-3 71-36-3 64-17-5 67-63-0 108-88-3 1330-20-7

40 60% 30 60% 10 40% 10 20 % 1 5% 1 5%

EC No. 201-159-0 200-751-6 200-578-6 200-661-7 203-625-9 215-535-7 Index No. 606-002-00-3 603-004-00-6 603-002-00-5 603-117-00-0 601-021-00-3 601-022-00-9 Weight (%) 40 60 % 30 60 % 10 40 % 10 20 % 15% 15%

Table 1. Components of FCSB No.3; identification numbers; and corresponding weights

Source of chemical identification numbers: The European Inventory of Existing Commercial chemical Substances (EINECS) Information System (http://ecb.jrc.ec.europa.eu/esis/index.php?PGM=ein) Table 2. Hazards classification of FCSB No.3 components (according to Directive 1999/45/EC) Substance CAS # Risk Phrases (R) Safety Phrases (S) D/H Symbol(s) 3- Butanone 78-93-3 R11; R36, R66, R67 S2, S9, S16 F; Xi n-Butanol 71-36-3 R10; R22; R37/38-41, R67 S2, S7/9, S13, S26, S37/39, S46 Xn Ethanol 64-17-5 R11 S2, S7, S16 F Isopropanol 67-63-0 R11; R36, R67 S2, S7, S16, S24/25, S26 F; Xi Toluene 108-88-3 R11; R38; R48/20, R63; S2, S36/37, S46, S62 F; Xn R65, R67 Xylene 1330-20-7 R10; R20/21, R38 S2, S25 Xn An interesting work on ink is available at: http://monographs.iarc.fr/ENG/Monographs/vol65/mono65-5.pdf.

Product Name: Fendell Cleaning Solvent Blend No. 3 Product Code: FCSB No.3 Version: 1.00 Hazard Classification/Symbols Risk Phrases: (R-) 10, 11, 20/21, 22, 36, 37/38, 38, 41, 48/20, 63, 65, 66, 67 Safety Phrases: (S-) 2, 7, 7/9, 9, 13, 16, 24/25, 25, 26, 36/37, 37/39, 46, 62 2.1 Classification of the substance or mixture Product definition 2.1.1 : Mixture.

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Classification according to Regulation (EC) No 1272/2008 [CLP/GHS]

A free German database (BG RCI GisChem information system on hazardous substances: Labels and GHS classification for preparations/mixtures) will be used for classification (see link below). Input Risk and Safety Phrases, and Danger/Hazards symbols in Table 2 into the German database ( available at : http://www.gischem.de/ghs/konverter/index.htm). Include the following specifications when inputting the data: UN Number: Physical State: Packing Group: Hazard Class: 1210 Liquid II 3 (omit Do not input Hazard Class. It shall come handy in Section 14)

Please note that the above specifications will vary depending on the hazards of the preparation/mixture. Here is the classification according to Regulation (EC) No 1272/2008 (CLP/GHS) for our mixture: Flammable liquids, Category 2, Acute toxicity (dermal), Category 4, Acute toxicity (inhalation), Category 4, Acute toxicity (oral), Category 4, Aspiration hazard, Category 1, Skin corrosion/irritation, Category 2, Serious eye damage/Eye irritation, Category 1, Reproductive toxicity D, Category 2, Specific Target Organ Toxicity Single exposure: Respiratory tract irritation, Category 3, Specific Target Organ Toxicity Single exposure: Narcotic effects, Category 3, Specific Target Organ Toxicity Repeated exposure, Category 2, H225 H312 H332 H302 H304 H315 H318 H361d H335 H336 H373

Always have the Globally Harmonized Systems (GHS) within the EU poster by Sigma-Aldrich on hand. It comes in handy when the domain of a hazard code (HXXX) is to be validated. Find it at:

Product Name: Fendell Cleaning Solvent Blend No. 3 Product Code: FCSB No.3 Version: 1.00

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http://www.sigmaaldrich.com/safety-center/globally-harmonized.html [click on GHS Poster EU (PDF)] 2.1.2 Classification of the mixture according to European Directives 1999/45/EC or 67/548/EEC Highly flammable. Irritating to eyes. Harmful by inhalation, in contact with skin and if swallowed. 2.2 Label elements Labelling according to Regulation (EC) No 1272/2008 [CLP] Hazard Pictograms

Signal word

: Danger

[Find other hazard pictograms at http://www.cptec.org/symbols_referenzen.html] Hazard statement(s) EUH066 H225 H302 H304 H312 H315 H318 H332 H335 H336 H361d H373 Precautionary statement(s) P210 P233 P261 P264 P280 P310 P403 + P233 P501 : Repeated exposure may cause skin dryness or cracking. : Highly flammable liquid and vapour. : Harmful if swallowed. : May be fatal if swallowed and enters airways. : Harmful in contact with skin. : Causes skin irritation. : Cause serious eye damage. : Harmful if inhaled. : May cause respiratory irritation. : May cause drowsiness or dizziness. : Suspected of damaging the unborn child. : May cause damage to organ(s) through prolonged or repeated exposure : Keep away from heat/sparks/open flames/hot surfaces No smoking. : Keep container tightly closed. : Avoid breathing dust/fume/gas/mist/vapours/spray. : Wash hands with soap and plenty of water after handling. : Wear protective gloves/protective clothing/eye protection/face protection. : Immediately call a POISON CENTER or doctor/physician. : Store in a well-ventilated place. Keep container tightly closed. : Dispose of contents/container to be in accordance with local/regional/national regulations.

Product Name: Fendell Cleaning Solvent Blend No. 3 Product Code: FCSB No.3 Version: 1.00

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Find the CLP document at: http://eur-lex.europa.eu/LexUriServ/LexUriServ.do?uri=OJ:L:2008:353:0001:1355:EN:PDF

2.2.1

Classification according to Directive 67/548/EEC or 1999/45/EC. Hazard symbol(s) F Xi Xn Risk (R)-phrase(s) R11 R20/21 R22 R36 R37/38 R38 R41 R48/20 R63 R65 R66 R67 Safety (S)-phrase(s) S2 S7/9 S13 S16 S24/25 S26 S36/37 S37/39 S46 S62 : Flammable. : Irritant. : Harmful. : Highly flammable. : Harmful by inhalation and in contact with skin. : Harmful if swallowed. : Irritating to eyes. : Irritating to respiratory system and skin. : Irritating to skin. : Risk of serious damage to eyes. : Harmful: danger of serious damage to health by prolonged exposure through inhalation. : Possible risk of harm to the unborn child. : Harmful: may cause lung damage if swallowed. : Repeated exposure may cause skin dryness or cracking. : Vapours may cause drowsiness and dizziness. : Keep out of the reach of children. : Keep container tightly closed and in a well ventilated place. : Keep away from food, drink and animal feedingstuff. : Keep away from sources of ignition No smoking. : Avoid contact with skin and eyes. : In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. : Wear suitable protective clothing and gloves. : Wear suitable gloves and eye/face protection. : If swallowed, seek medical advice immediately and show this container or label. : If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label. : No. P: Not available. B: Not available. T: No.

2.3

Other hazards Substance meets the criteria for PBT according to Regulation (EC) No 1207/2006, Annex XIII

Product Name: Fendell Cleaning Solvent Blend No. 3 Product Code: FCSB No. 3 Version: 1.00 Substance meets the criteria for vPvB according to Regulation (EC) No 1207/2006, Annex XIII Other hazards which do not result in classification : Not available.

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: Not available.

This product is classified as dangerous according to Directive 1999/45/EC and its amendments. 3. COMPOSITION/INFORMATION ON INGREDIENTS We shall use CLP/GHS Database: Annex VI to Regulation (EC) No 1272/2008 on Classification, Labelling and Packaging of Dangerous Substances. Here is the link: http://esis.jrc.ec.europa.eu/index.php?PGM=cla Enter either index number, EC number, CAS number, or substance name in the appropriate field. See Table 1. 3.1 Description of the substance/mixture : Mixture
Classification

Table 3. Hazard ingredients

Chemical/ Substance Name 3Butanone CAS No.
78-93-3

EC No.

Index No.

RRN* Weight (%)

40 60 %

67/548/EEC

Regulation (EC) No. 1272/2008[ CLP]

Type

201-1590

606-002-003

F; R11 Xi; R36-66-67

Flam. Liq. 2, H225 Eye irrit. 2, H319 STOT SE 3, H336 EUH066

[1] [2]

n-Butanol

71-36-3

200-751-6

603-004-00-6

30 60 %

R10 Xn; R22 Xi; R37/38, R41, R67

Ethanol

64-17-5

200-578-6

603-002-00-5

10 40 %

F; R11

Flam. Liq. 3, H226 Acute Tox. 4* H302 STOT SE 3 H335 Skin Irrit. 2 H315 Eye Dam. 1 H318 STOT SE 3 H336 Flam. Liq. 2 H225

[1] [2]

[2]

RRN: REACH Registration Number (readily available on the Internet for these chemicals).

Product Name: Fendell Cleaning Solvent Blend No. 3 Product Code: FFSB No.3 Version: 1.00

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Classification

Chemical/ CAS No. Substance Name

Isopropanol 67-63-0

EC No.

Index No.

RRN* Weight (%)

10 20 %

67/548/EEC

Regulation (EC) No. 1272/2008[ CLP]

Type

200-6617

603-117-000

F, R11 Xi; R36, R67

Toluene

108-88-3

203-6259

601-021-003

1 5%

F; R11 Repr. Cat. 3 R63 Xn; R48/20, R65 Xi; R38, R67

Xylene

1330-207

215-535-7

601-022-00-9

15%

R10 Xi; R38 [concentration limit]

Flam. Liq. 2 H225 Eye Irrit. 2 H319 STOT SE 3 H336 Flam. Liq. 2 H225 Repr. 2 H361d*** Asp. Tox. 1 H304 STOT RE 2 H373** Skin Irrit. 2 H315 STOT SE 3 H336 Flam. Liq. 3 H226 Acute Tox. 4* H332 Acute Tox. 4* H312 Skin Irrit. 2 315 See Section 2 for the full text of the Hstatements declared above.

[1] [2]

[1] [2]

[1] [2]

See Section 2 for the full text of the Rphrases declared above.

3.2

Additional information [1] Substance classified with a health or environmental hazard [2] Substance with a workplace exposure limit [3] Substance meets the criteria for PBT according to Regulation (EC) No 1207/2006, Annex XIII [4] Substance meets the criteria for vPvB according to Regulation (EC) No 1207/2006, Annex XIII

Occupational exposure limits, if available, are listed in Section 8. Product Name: Fendell Cleaning Solvent Blend No. 3 Product No: FCSB No.3 Version: 1.00 4. FIRST AID MEASURES

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Research occupational hazards of the substance/mixture and appropriate first aid measures before hand. There are various sources to turn to for information (e.g., product (M) SDS, Haz-Map site, EHS sites, The Emergency Response Guidebook [ERG 2008], etc. Consult an expert/authority on Occupational Health and Safety for assistance when writing this section. Useful links: Haz-Map

http://hazmap.nlm.nih.gov Database of hazardous chemicals and occupational diseases International Programme on Chemical Safety (IPCS INCHEM) http://www.inchem.org Database of chemical safety information CDC NIOSH Pocket Guide to Chemical Hazards (NPG) http://www.cdc.gov/niosh/npg A source of information on general industrial hygiene for hundreds of chemical used in the work environment International Chemical Safety Cards http://www.cdc.gov/niosh/ipcs/nicstart.html Provides safety and health information on chemical Environment, Health and Safety Online (EHSO) http://www.ehso.com/hmerg.php The Emergency Response Guide (ERG 2008) and other hazards information The Merck Manuals http://www.merckmanuals.com A trusted source for medical information CAMEO Chemicals http://www.cameochemicals.noaa.gov U.S. DHHS Chemical Information Services http://sis.nlm.nih.gov/chemical.html The Ships Captains Medical Guide http://www.dft.gov.uk/mca/mcga-seafarer_information/mcga-dqs_st_shs_seafarer_informationmedical/mcga-dqs_st_shs_ships_capt_medical_guide.htm

First-Aid Information http://www.osha.gov/dsg/hazcom/firstaid.html Product Name: Fendell Cleaning Solvent Blend No. 3 Product No: FCSB No.3 Version: 1.00 4.1 4.1.1 Description of first aid measures General information

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: General first aid measures should be followed. In case of persistent adverse effects, seek immediate medical attention. Remove contaminated clothing and shoes promptly, and wash thoroughly before re-use. : NOTE: Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervous system damage. Intentional misuse by deliberately concentrating and inhaling the contents may be harmful or fatal.

4.1.2

Following inhalation

: Emergency responders should use positive air supplied respiratory protection when removing the victim from area. Remove person to fresh air. If not breathing, administer CPR until help arrives, or the victim starts to breathe on their own. Give artificial respiration if breathing has stopped. Seek medical attention immediately. 4.1.3 Following skin contact : If exposure occurs, immediately flush the affected area thoroughly with water for at least 15 minutes. Use soap if available. Remove contaminated clothing, including shoes, after flushing has begun. Wash clothing before re-use. If irritation persists, seek medical attention. : Immediately flush affected eye with water for at least 20 minutes. ilt the head to prevent chemical from transferring to the unaffected eye. Seek medical attention without delay after flushing. : DO NOT INDUCE VOMITING if swallowed. Rinse mouth out with water. Dilute with milk or water. Never give anything to drink if the victim is unconscious or having convulsions. Seek medical attention immediately. Contact Poison Control Center at once. : Appropriate personal protective attire should be worn. : Suitable medical intervention should be provided based on symptoms. : Irritating to eyes, skin, and respiratory tract upon exposure. High vapour concentrations are irritating to eyes, nose, throat, and lungs; may cause unconsciousness or other signs of central nervous system depression. Frequent or prolonged skin contact may irritate the skin and cause skin rash (dermatitis). May cause skin sensitization, an allergic reaction which becomes evident on Page 10 of 25 Prepared Date: 06/27/2011 Printing Date: 08/10/2011

4.1.4

Following eye contact

4.1.5 Following ingestion

4.1.6 4.1.7

Self protection of the first aider Note to the doctor

4.2

Most important symptoms and effects, both acute and delayed

Product Name: Fendell Cleaning Solvent Blend No. 3 Product No: FCSB No. 3 Version: 1.00

re-exposure to this material. Small amounts of this liquid may be drawn into the lungs by either swallowing or vomiting. This may cause severe and delayed health effects such as inflammation of the lungs (pulmonary edema) and infection of the bronchi (bronchopneumonia). Ingestion may cause irritation of digestive track and diarrhea. 4.3 Indication of any immediate medical attention and special treatment needed : Always get immediate medical attention/advice when symptoms persist.

5. FIRE FIGHTING MEASURES

Useful resources: Carriage of Dangerous Goods [International Maritime Dangerous Goods (IMDG) Code]. It has information on fire fighting procedures. Find it here: http://www.krs.co.kr/kor/dn/Rul/1025.pdf. You may want to check CAMEO Chemicals for additional guide to fire fighting. Here is the link to CAMEO Chemicals: http://www.cameochemicals.noaa.gov . The fire chief in your city/town may be able to provide information on hazardous chemicals fire fighting procedures, and personal protective equipment for fire fighters. Fire Fighting Measures : The following applies to 3-Butanone (from CAMEO Chemicals) FLASHPOINT: 26oF SPECIFC GRAVITY: 0.806 @ 68o F EXPLOSIVE LIMITS: LEL: 1.8%, UEL: 11.0%. AUTOIGNITION TEMPERATURE: 961.0oF.

5.1

Extinguishing media Suitable extinguishing media : Either allow fire to burn out under controlled conditions, or extinguish with alcohol type or all purpose type foam, or dry chemical powder. Try to cover liquid spills with appropriate foam. Use water spray to cool fire exposed surfaces. Avoid spraying water directly into storage containers due to danger of boilover. Shut off fuel to fire if possible to do so without hazard. If a spill has not ignited, use water spray to disperse the vapours. : Do not use high volume water jet. : Flammable liquid; may release vapours that form flammable mixtures when temperatures are at or above the flash point. There is a danger of explosion when container is heated or in fire. Toxic gases will form upon combustion. Vapour may may accumulate in low or confined areas or travel to a considerable distance to a source of ignition and flash back. Avoid runoff into storm sewers and ditches. : Smoke, fumes, oxides of carbon, irritating or toxic vapours or gases. Page 11 of 25 Prepared Date: 06/27/2011 Printing Date: 08/10/2011

Unsuitable extinguishing media 5.2 Special hazards arising from the mixture

Hazardous combustion products

Product Name: Fendell Cleaning Solvent Blend No. 3 Product No: FCSB No.3 Version: 1.00 5.3 Advice for fire-fighters Protective equipment for fire fighters

: Respiratory and eye protection gear is required for fire fighting personnel. Full protective equipment (Bunker Gear) and a self-contained breathing apparatus (SCBA) should be used for all indoor fires and any significant outdoor fires. Use portable fire extinguisher for small outdoor fires. Use of SCBA may not be required. : Exposure to decomposition products may cause health hazards. Cool containers exposed to fire with water spray.

5.4

Additional information

Move unexposed containers from fire area if this can be done without risk. 6. ACCIDENTAL RELEASE MEASURES 6.1 Personal precautions, protective equipment and emergency procedures : : Wear suitable personal protective equipment (e.g. clothing, gloves, safety goggles, and mask/respirator). Ensure adequate ventilation; remove all sources of ignition. Notify the appropriate authorities immediately. : Eliminate ignition source. Shut off leak if safe to do so. Take all additional action necessary to prevent and remedy the adverse effects of the spill. Isolate hazard area and deny entry to unauthorized or unprotected personnel. Contain spilled liquid with sand or earth. DO NOT use combustible materials such as saw dust. Absorb spill with an inert material (e.g., sand or earth). Then place in a chemical waste container. : Respiratory and eye protection gear is required for emergency responders. Full protective equipment (Bunker Gear) and a self-contained breathing apparatus (SCBA) should be used for all indoor fires and any significant outdoor fires. Use portable fire extinguisher for small outdoor fires. Use of SCBA may not be required. : Avoid dispersal of spilt material and runoff into soil, storm sewers and ditches which lead to natural waterways, or the immediate environment. Inform the relevant authorities if the product has entered into the environment.

6.1.1 For non-emergency personnel Protective equipment

Emergency procedures

6.1.2

For emergency responders personal protective equipment

6.2

Environmental precautions

6.2

Methods of containment and cleaning up

6.3.1 On water : If spill in water, remove from water surface by skimming Product Name: Fendell Cleaning Solvent Blend No. 3 Page 12 of 25 Product No: FCSB No. 3 Prepared Date: 06/27/2011 Version: 1.00 Printing Date: 08/10/2011 or with suitable absorbent material and place in appropriate disposal container. If allowed by local environmental regulatory agencies, you may use a suitable dispersant. : Contain spill and absorb with an inert material (e.g., dry sand or earth). Then place in an appropriate waste container for disposal according to local regulations. Large spills should be disposed of via a licensed waste disposal establishment/contractor. : Contaminated absorbent material may pose similar hazard as the spill product.

6.3.2 On ground/floor

6.3.3 6.4

Other information Reference to other sections

See Section 1 for emergency contact information (should be available in an actual document (M)SDS). See Section 8 for information on appropriate personnel protective equipment. See Section 13 for additional disposal information. 7. HANDLING AND STORAGE

7.1 7.1.1

Precautions for safe handling Protective measures : Wear appropriate personal protective equipment. Do not get in eyes, on skin, or on clothing. Do not breathe vapour or mist. Do not eat, drink, or smoke when using this product. Use only with adequate ventilation. Keep away from sources of ignition. Keep only in original container. Keep tightly closed when not in use. Do not reuse container. Avoid release to the environment. : Avoid eating, drinking and smoking in areas where this product is handled, used and stored. Wash hands before eating, drinking and smoking, and at the end of the working period. Contaminated work clothing and protective equipment should not be brought into eating, smoking and drinking areas. Wash soiled clothing before re-using.

7.1.2 Advice on general occupational hygiene

7.2

Conditions for safe storage, including any incompatibilities Technical measures and storage conditions

: Store at ambient/room temperature. Protect from extreme cold and heat. Store in a segregated and approved area. Store away from strong oxidizing agents. Loosen closure cautiously with non-sparking tools before opening. Keep only in original container. Store and use away from sparks, heat, open flames and other ignition sources. Ground and bond containers and receiving equipment. Store locked up. Store away from direct sun -light in a dry, cool and well-ventilated area. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Ground and bond containers when transferring material. Ventilation required along storage floor. Product Name: Fendell Cleaning Solvent Blend No. 3 Page 13 of 25 Product No: FCSB No. 3 Prepared Date: 06/27/2011 Version: 1.00 Printing Date: 08/10/2011 Packaging materials 7.3 Specific end use(s) Recommendations Industrial sector specific solutions : Steel drum, HDPE (High Density Poly Ethylene) -2 plastic bottles and containers. : For industrial use only. : Unavailable

8. EXPOSURE CONTROL/PERSONAL PROTECTION There is no workplace exposure data available on the product itself. Data for a solvent in the mixture is

provided for EU member countries where available. 8.1 8.1.1 Control parameters Occupational Exposure Limits (OELs) :

International Exposure Limits can be found at this site: http://www.dguv.de/ifa/en/gestis/limit_values/index.jsp Table 4. Occupational Exposure Limit(s) -OELs EC No.: 201-159-0 Occupational Exposure Limit Values CAS No.: 78-93-3 (3-Butanone) Chemical Name: Long term limit Short term limit Limit value type 3-Butanone (8-hour TWA) (15-minutes period) Country ppm mg/m3 ppm mg/m3 Austria 100 295 200 590 MAK Belgium 200 600 300 900 VLEP Bulgaria 590 1000 OEL (MH Decree No 13/2003) Croatia 200 600 300 900 EU OEL (TWA/STEL) Czech Republic 203.4 600 305.1 900 PEL, NPK-P Denmark 50 145 100 290 OEL Estonia 200 600 300 900 EU OEL (TWA/STEL) Finland 100 300 OEL (HTP-arvot) France 200 600 300 900 VLEs Germany 200 600 200 600 MAK Greece 200 600 300 900 EU OEL Hungary 600 900 K, CK Ireland 200 600 300 900 OELV (NAOSH, 8/2007) Italy 200 600 300 900 ACGIH Latvia 67 200 300 900 AER Lithuania 200 600 300 900 IPRV, TPRV Netherlands 590 900 MAC-TGG Norway 75 220 Gjennomsnittsverdier (average values) Poland 450 900 NDS, NDSCh Portugal 200 300 VLE-MP, VLE-CD Romania 63 200 101 300 VLA (TWA, STEL) Slovakia 200 600 900 NPEL Note: Highlighted numbers/values were obtained from various Internet sources. Product Name: Fendell Cleaning Solvent Blend No. 3 Page 14 of 25 Product No: FCSB HA-1 Prepared Date: 06/27/2011 Version: 1.00 Printing Date: 08/10/2011 EC No.: 201159-0 CAS No.: 7893-3 Chemical Name: 3-Butanone Country Spain Sweden Switzerland Occupational Exposure Limit Values (3-Butanone) Long term Short term limit Limit value type limit (15-minutes (8-hour TWA) period) ppm 200 50 200 mg/m3 600 150 590 ppm 300 100 200 mg/m3 900 300 590

VLA-ED, VLA-EC NGV, KTV VME, VLE

Turkey United Kingdom

200 200

600 600

300 300

900 899

TWA, STEL WEL (EH40/2005)

Note: Highlighted numbers/values were obtained from various Internet sources. Recommended monitoring procedures : If this product contains ingredients with exposure limits, personal, workplace atmosphere or biological monitoring may be required to determine the effectiveness of the ventilation or other control measures and/or the necessity to use respiratory protective equipment. Reference should be made to European Standard EN 689 for methods for the assessment of exposure by inhalation of chemical agents and national guidance documents for methods for the determination of hazardous substances. : See occupational exposure limit value table for guidance. : Not available.

Derived effect levels [DNEL] Predicted effect concentrations (PNEC Summary) 8.1 8.1.1 Exposure controls Appropriate engineering controls

: Provide adequate local exhaust ventilation to maintain worker below exposure limits. The use of mechanical ventilation controls is recommended whenever this product is used in a confined space, is heated above ambient temperatures, or is agitated. Use explosion-proof ventilation equipment. (http://www.chemie.de/tools/gebotszeichen/) (93/68/EEC, 93/95/EEC, and 96/58/EC) : Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mist, or dust. Page 15 of 25 Prepared Date: 06/27/2011 Printing Date: 08/10/2011

8.2 8.2.1

Personal protective equipment (Directives and Amendments) Eye and face protection

Product Name: Fendell Cleaning Solvent Blend No. 3 Product No: FCSB No. 3 Version: 1.00 8.2.2 Skin protection Hand protection

: Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this in necessary. : Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. : Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and

Body protection

Other skin protection

the risks involved and should be approved by a specialist before handling this product. 8.3 Respiratory protection : Use approved respiratory protection equipment. Respirator selection should be based on the form and concentration of contaminants in the air and in accordance with local regulations. : Emission from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. Ensure that emission is at the acceptable level.

8.4

Environmental exposure controls

9. PHYSICAL AND CHEMICAL PROPERTIES 9.1 Information on basic physical and chemical properties [Note: Physicochemical analysis was not done on the mixture.]

Physical state : Liquid. Colour : Characteristic. Odour : Solvent odour. Odour threshold : Not determined. pH : Not available . Melting/freezing point [o F] : Not available. Initial boiling point/range [o F] : Not available. Flash point [o F] : Not available. Evaporation rate (n-Butyl Acetate : Not available. = 1) Flammability (solid, gas) : Not available. Upper flammability : Not available. Lower flammability : Not available. o Vapour pressure, mm Hg @ 75 F : Not available. Vapour density (Air = 1) : Not available . Relative density : Not available. Solubility in water, Wt % @ 68 o F : Not available. Partition coefficient: n: Not available. octanol/water Product Name: Fendell Cleaning Solvent Blend No. 3 Product No: FCSB No. 3 Version: 1.00 Auto-ignition temperature Decomposition temperature Viscosity of Liquid, CST @ 25o C Explosive properties Oxidizing properties 9.2 Other information : Not available. : Not applicable. : Not available. : Not available. : Not available.

Page 16 of 25 Prepared Date: 06/27/2011 Printing Date: 08/10/2011

: Provide other relevant physicochemical properties here.

10. STABILITY AND REACTIVITY 10.1 Reactivity : Highly flammable. Avoid ignition sources. Strong oxidizing

agents. 10.2 10.3 10.4 10.5 10.6 Chemical stability Possibility of hazardous reactions Conditions to avoid Incompatible materials : Stable under normal conditions. : Hazardous polymerization will not occur. : Open flames and sources of ignition. : Strong oxidizing agents.

Hazardous decomposition products : Burning can produce oxides of carbon.

11. TOXICOLOGICAL INFORMATION Useful links: IUCLID DB (http://ecb.jrc.ec.europa.eu/esis/index.php?PGM=dat); IARC (http://www.iarc.fr/); and HSDB (http://toxnet.nlm.nih.gov/cgi-bin/sis/htmlgen?HSDB) 11.1 Information on toxicological effects 11.1.2 Mixture 11.1.2.1 (a) Acute toxicity Substance name: : There are no data available on the product itself. Data on a substance in the mixture is provided. : Relevant effects:

: Test Species Route of Administration Dose/Result Exposure Remark LD50 Rat Oral > 636 mg/kg Toluene LDLO Human Oral 50 mg/kg LC50 Mouse Inhalation vapour 6405 -7436 ppm 6 hour (s) Identifiers: TCLO Human Inhalation vapour 200 ppm EC No.: 203-625-9 LD50 Rabbit Dermal 12124 mg/kg CAS No.: 108-88-3 LD50 Mouse Intra-peritoneum (i.p.) 66 mg/kg Index No.: 601-021-00-3 LD50 Rat Intra venous (i.v.) 1960 mg/kg Inhalation vapour 28.1 mg/l 4 hour (s) LC50 Rat Conclusion/Summary : Vapours may cause drowsiness and dizziness. Product Name: Fendell Cleaning Solvent Blend No. 3 Page 17 of 25 Product No: FCSB No. 3 Prepared Date: 06/27/2011 Version: 1.00 Printing Date: 08/10/2011 (b) Irritation Inhalation : : May cause irritation to the nose, throat, and lungs. High vapor concentrations may cause unconsciousness or other signs of central nervous system depression. : Frequent or prolonged contact may irritate the skin and cause skin rash (dermatitis). May cause skin sensitization, an allergic reaction which becomes evident on re-exposure to this material. : Severely irritating. If not removed promptly will injure eye

Skin contact

Eye contact

tissue, which may result in permanent damage. Ingestion (c) (d) Corrosivity Sensitization : May cause irritation of the digestive tract and diarrhea. : Severely irritating to eyes. Repeated exposure may cause skin dryness or cracking. : May cause skin sensitization and or respiratory system irritation due to extended exposure of the preparation above stated occupational exposure limits. : No data available. : No data available. : No known significant effects or critical hazards. : No information but adverse effects unlikely. : No known significant effects or critical hazards. : No known significant effects or critical hazards.

(e) (f) (g) (h) (i)

Single dose toxicity Repeated dose toxicity Carcinogenicity Mutagenicity Toxicity for reproduction

11.1.2.2 CMR effects (carcinogenic, mutagenic or toxic for reproduction) 11.2 Potential adverse health effects

: Small amounts of this liquid may be drawn into the lungs by either swallowing or vomiting. This may cause severe and delayed health effects such as inflammation of the lungs ( pulmonary edema) and infection of the bronchi(bronchopneumonia). Ingestion may cause irritation to the digestive tract or diarrhea.

: There is no evidence that exposure to 3-Butanone alone causes progressive or irreversible neurotoxic effects. However, simultaneous over-exposure to 3-Butanone and n-Hexane can potentiate the known irreversible neurotoxic Product Name: Fendell Cleaning Solvent Blend No. 3 Page 18 of 25 Product No: FCSB No. 3 Prepared Date: 06/27/2011 Printing Date: 08/10/2011 Version: 1.00 11.3 Potential chronic health effects effects of n-Hexane. There is no reported human evidence that these neurotoxic effects occur when exposure to both chemicals is maintained below established regulatory limits. 11.4 Other information : The mixture is not likely to be carcinogen in humans.

SECTION12. ECOLOGICAL INFORMATION Useful links: IUCLID DB (http://ecb.jrc.ec.europa.eu/esis/index.php?PGM=dat) and HSDB (http://toxnet.nlm.nih.gov/cgi-bin/sis/htmlgen?HSDB) Note: Ecological testing has not been conducted on this mixture. Ecotoxicological information on components

in the mixture is presented below. 12.1 Toxicity : Species Pimephales promelas Daphnia magna Scenedesmus quadricauda Species Pimephales promelas Daphnia magna Scenedesmus subspicatus Species Alburnus alburnus Daphnia magna Chlorella pyrenoidosa Value (mg/l) 3220 > 520 4300 Value (mg/l) < 1630 1983 > 500

3-Butanone [CAS#: 78-93-3] ecotoxicological data Aquatic toxicity Effect dose Exposure time (h) Acute fish toxicity LC50 96 hour (s) Acute Daphnia toxicity EC50 48 hour (s) Acute algae toxicity EC3 7 days n-Butanol [CAS#: 71-36-3] ecotoxicological data Aquatic toxicity Effect dose Exposure time (h) Acute fish toxicity LC50 96 hour (s) Acute Daphnia toxicity EC50 48 hour (s) Acute algae toxicity EC50 96 hour (s) Ethanol [CAS#: 64-17-5] ecotoxicological data Aquatic toxicity Effect dose Exposure time (h) Acute fish toxicity LC50 96 hour (s) Acute Daphnia toxicity LC50 48 hour (s) Acute algae toxicity EC50 Not specified Isopropanol [CAS#: 67-63-0] ecotoxicological data Aquatic toxicity Effect dose Exposure time (h) Acute fish toxicity LC50 96 hour (s) Acute Daphnia toxicity EC50 48 hour (s) Acute algae toxicity EC50 96 hour (s) Toluene [CAS#: 108-88-3] ecotoxicological data Aquatic toxicity Effect dose Exposure time (h) Acute fish toxicity LC50 96 hour (s) Acute Daphnia toxicity EC50 48 hour (s) Acute algae toxicity EC50 48 hour (s) Product Name: Fendell Cleaning Solvent Blend No. 3 Product No: FCSB No. 3 Version: 1.00

Value (mg/l) 10000 - 11500 9268 - 14221 9310 Value (mg/l) 9640 13299 > 1000 Value (mg/l) 28 11.5 125 - 160

Species Pimephales promelas Daphnia magna Scenedesmus subspicatus Species Pimephales promelas Daphnia magna Scenedesmus subspicatus

Page 19 of 25 Prepared Date: 06/27/2011 Printing Date: 08/10/2011 Species Cyprinus carpio Palaemonetes pugio Scenedesmus quadricauda Value (mg/l) > 780 0.85 > 200

Xylene [CAS #: 1330-20-7] ecotoxicological data Aquatic toxicity Effect dose Exposure time (h) Acute fish toxicity LC50 96 hour (s) Acute invertebrate toxicity LC50 48 hour (s) Acute algae toxicity Mortality Unknown 12.2 Persistence and degradability

: No data available for the product. Incubation time 5 days Evaluation (inoculum) Sewage

(Biochemical Oxygen Demand BOD values) Substance name Quantity Degradation rate (%) 3-Butanone Unknown 83

n-Butanol Ethanol Isopropanol Toluene Xylene

Unknown 10 mg/l 10 mg/l Unknown Isomers

66 74 78* Completely 72

5 days 5 days 20 days Short duration 20 days

Sewage sludge Filtered sewage seed Filtered sewage seed Sewage seed Activated sewage

* Theoretical Oxygen Demand (ThOD) value. 12.3 Bioaccumulative potential : No data available. (BCF Bio Concentration Factor). log n-octanol/water partition coefficient (log Kow) estimate log Kow Remarks Substance name Estimated BCF 3-Butanone 3 0.29 Low bioaccumulation n-Butanol 3 0.88 Low bioaccumulation Ethanol 3 -0.31 Low bioaccumulation Isopropanol 3 0.05 Low bioaccumulation Toluene 13 (eel) , 90 (Golden ide) 2.73 Low to moderate bioaccumulation Xylene 6 23.4 3.2 Low bioaccumulation Mobility in soil : No data available. Koc The soil absorption coefficient Substance name Koc value 3-Butanone 29 n-Butanol 72 Ethanol 1 Isopropanol 25 Toluene variable Xylene 39 365 for individual isomers Results of PBT and vPvB assessment PBT : No data available. vPvB : No data available. Other adverse effects : No known significant effects or critical hazards. Page 20 of 25 Prepared Date: 06/27/2011 Printing Date: 08/10/2011

12.4

Remarks (soil mobility) Very high mobility High mobility Very high mobility Very high mobility High to moderate mobility Very high to moderate mobility

12.5

12.6

Product Name: Fendell Cleaning Solvent Blend No. 3 Product No: FCSB No. 3 Version: 1.00 13. DISPOSAL CONSIDERATIONS

The information in this section contains generic advice and guidance. Waste Codes/Waste Designations according to EWC/AVV can be found at Waste Support Company ( http://www.wastesupport.co.uk/ewccodes), GPT Waste Management (http://www.gptwaste.com/european-waste-catalogue-codes.asp), 360 Environment (http://www.360environmental.co.uk/legislation/waste_legislation/european_waste_catalogue_codes/) and in the European Waste Catalogue and Hazardous Waste List. Find the latter information at http://www.environ.ie/en/Publications/Environment/Waste/WEEE/FileDownLoad,1343,en.pdf Packaging and packaging waste :

Directives and Amendments 13.1 Waste treatment methods Product Methods of disposal

: 94/63/EC and 2005/20/EC

: The generation of waste should be avoided or minimized whenever possible. Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe way. Waste product residue should not be disposed of via the foul sewer. Consult an expert on the disposal of recovered and surplus material. Incinerate, or recover by distillation. Ensure disposal is in compliance with current government requirements and ensure conformity with local authority regulations. : The generation of waste should be avoided or minimized whenever possible. Waste packaging should be recycled, or dispose of according to state and local authority regulations. Consult your State/Local Land Waste Management Authority. : 08 03 99* 15 01 01 15 01 02 : waste not otherwise specified. : paper and cardboard packaging. : plastic packaging.

Packaging waste Methods of disposal

Waste codes/ waste designation according to EWC/AVV

: The listed waste numbers according to the European Waste Code (EWC) are intended as recommendation for users. The final classification has to be worked out together with the local waste disposal company/authority. Note: An asterisk [*] next to the a code (08 03 99*) indicates it is a hazardous waste. : This material and its container must be disposed of according to local authority regulations. Empty containers or packaging may contain some product residue. Avoid dispersal of spilt material and runoff to come in contact with soil, waterways, drains and sewers. Product Name: Fendell Cleaning Solvent Blend No. 3 Page 21 of 25 Product No: FCSB No. 3 Prepared Date: 06/27/2011 Version: 1.00 Printing Date: 08/10/2011 Special precautions 14. TRANSPORTATION INFORMATION Useful links: UK Department of Transportation Dangerous Goods Database http://www.dft.gov.uk/dangerous-goodsdatabase/?xgovk3w=bl1000&xgovf0p=|xgovs9k=dft|xgovr3h=dangerousgoods|xgovc8h=1000|xgovk3 w=bl1000|&xgovd2v=en&xgovj6d=138566a41b22fdc972c0f470249d4e76a2b97234 UK Department of Transportation [find The Ship Captains Medical Guide] http://www.dft.gov.uk

UK Department of Transportation (Carriage of dangerous goods) http://www2.dft.gov.uk/pgr/freight/dgt1 [Access the Dangerous Goods Database] Carriage of Dangerous Goods International Maritime Dangerous Goods Code http://www.mardep.gov.hk/en/msnote/pdf/msin0664anx.pdf http://www.generalcargoship.com/IMDG-code.html

The Swedish Transport Agency http://www.transportstyrelsen.se/en/Shipping/Freight--Cargo/Bulk-Cargoes/Emergency-Procedures/ IATA Dangerous Goods Regulations

http://www.iata.org/whatwedo/cargo/dangerous_goods/Documents/DGR52TrainingRequirements15.pdf

RoadSafe Europe http://www.roadsafeeurope.com/ Civil Aviation Authority: Requirements and Guidance Material for Operators http://www.caa.co.uk/docs/33/CAP%20789.pdf European Aviation Safety Agency
http://www.easa.europa.eu/approvals-and-standardisation/safety-assessment-of-foreign-aircraft-SAFA.php

International Civil Aviation Organization (ICAO) Dangerous Goods http://www.icao.int/anb/FLS/DangerousGoods/ ICAO Technical Instructions for the Safe Transport of Dangerous Goods by Air http://www.icao.int/anb/FLS/DangerousGoods/TechnicalInstructions/ Technical Instructions for the Safe Transport of Dangerous Goods http://www.icao.int/icaonet/dcs/9284/9284_2007_2008_addcorr_en.pdf

Product Name: Fendell Cleaning Solvent Blend No. 3 Product No: FCSB No. 3 Version: 1.00

Page 22 of 25 Prepared Date: 06/27/2011 Printing Date: 08/10/2011

IATA Dangerous Goods Regulation Manual 2010 http://www.pdfqueen.com/iata-dangerous-goods-regulations-manual-2010-(dgr)

ADR/RID 1210 Printing Ink Related Material 3 ADN/ADNR 1210 Printing Ink Related Material 3 F1 II IMDG 1210 Printing Ink Related Material 3 F1 II ICAO-TI/IATA-DGR 1210 Printing Ink Related Material 3 F1 II

14.1 UN No 14.2 Proper Shipping Name 14.3 Transport hazard class 14.4 Classification code 14.5 Packing group 14.6 Hazard label

F1 II

14.7 Environmental hazard 14.8 Special provision(s) Additional Information

Marine pollutant: No No 163 640C Hazard identification number 33 EAC 3Y Ltd Qty LQ6 Transport Category/ Unit 2 240L Excepted Quantities E2 Packaging P001, PP1, MP19 Portable Tanks and Bulk Cont. T4; TP1, TP8 Tunnel code D/E Excpt. Qty. E2 Packaging instruction: 364 Ltd.and Excpt Qty LQ6 E2 No 163 640C 163 Emergency schedules (EmS) Fire F-E Spillage S-D Ltd. Qty. 5l Cargo Aircraft only Quantity limitation: 60.0 L No Not available Passenger and Cargo Aircraft Quantity limitation: 1.0 L Packing instructions: Y341 5.0 L 353

14.9 Transport in bulk according to Annex II of MARPOL 73/78 and IBC Code: Not applicable. Product Name: Fendell Cleaning Solvent Blend No. 3 Product No: FCSB No. 3 Version: 1.00 15. REGULATORY INFORMATION 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture EU Regulation (EC) No. 1907/2006 (REACH) REACH Status : In compliance. Page 23 of 25 Prepared Date: 06/27/2011 Printing Date: 08/10/2011

Annex XIV List of substances subject to authorization Substances of Very High Concern Candidate List : None of the components in the mixture are listed. Annex XVII Restriction on the manufacture, placing on the market and use of certain dangerous substances, mixtures and articles [http://ec.europa.eu/enterprise/sectors/chemicals/files/markrestr/annex_xvii_301206_en.pdf] : Contains Toluene (Note: product is not for sale to the general public and is not intended for use in adhesives and spray paints.) Other EU regulations European inventory : All components are listed or exempt.

Endocrine Disrupters

: Components not listed (http://www.chemsec.org/list/sin-list-20) [EU Directive 2000/60/EC, Annex X and Regulation (EEC) No. 793/93] : Components not listed. : Components not listed.

Integrated Pollution Prevention and Control List (IPPC) Air Integrated Pollution Prevention and Control List (IPPC) Water International regulations

Chemical Weapons Convention List Chemical Weapons Convention List Chemical Weapons Convention List Schedule I Chemicals Schedule II Chemicals Schedule III Chemicals Not listed Not listed Not listed

15.2

Chemical Safety Assessment : No Chemical Safety Assessment has been carried out for this mixture.

Product Name: Fendell Cleaning Solvent Blend No. 3 Product No: FCSB No. 3 Version: 1.00 16. OTHER INFORMATION NOTE

Page 24 of 25 Prepared Date: 06/27/2011 Printing Date: 08/10/2011

: This Safety Data Sheet was created as a guide, teaching aid and training tool for freelance safety data sheet writers. The mixture is fictitious and information in the document is based on suggestions in the Guidance on the Compilation of Safety Data Sheets (draft October 2010). Please be reminded that the document does not purport to be a legal advice on compiling Safety Data Sheets. Guidance on the Compilation of Safety Data Sheets (draft October 2010) for the European Union is normative. : The product has been classified and marked in accordance with EU Directives/Ordinance on Hazardous Materials. : : : : : : None. To comply with Regulation (EC) No 1272/2008 [CLP/GHS] Conforms to Regulation (EC) 1907/2006 (REACH), Annex II 1.00 August 10, 2011 Theodore M. Amet, Manager Global GHS Compliant SDSs Labels, and MSDSs Projects

Product

16.1

Indication of changes Date of previous issue Revisions Nature of version Version Date of issue Prepared by

16.2

Abbreviations and acronyms ADN: Accord europen relative au transport international des marchandises dangereuses par voie de navigation intrieure. ADNR: Accord europen relative au transport international des marchandises dangereuses par marine sur le Rhin ADR: Accord europen sur le transport des merchandises dangereuses par route (European Agreement concerning the International Carriage of Dangerous Goods by Road) AVV (Austria): Abfallverzeichnis-Verordnung BG RCI (Germany): Berufsgenossenschaft Rohstoffe und chemische Industrie CAS: Chemical Abstracts Service CDC: Centers for Disease Control and Prevention CLP: Regulation on the Classification, Labelling, and Packaging of substances and mixtures1 D/H: Danger/Hazard DGR: Dangerous Goods Regulation DPD: Dangerous Preparations Directive (Directive 1999/45/EC). DSD: Dangerous Substances Directive (Directive 67/548/EEC). EC: European Commission EHS: Environment, Health, and Safety
1

CLP Document - REGULATION (EC) No 1272/2008 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL of 16 December, 2008 on classification, labeling, and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC and amending Regulation (EC) No 1907/2006. Product Name: Fendell Cleaning Solvent Blend No. 3 Page 25 of 25 Product No: FCSB No. 3 Prepared Date: 06/27/2011 Version: 1.00 Printing Date: 08/10/2011 EINECS: European Inventory of Existing Commercial chemicals Substances EmS: Emergency Schedule ESIS: Existing chemical Substances Information System EU: European Union GHS: Globally Harmonized System of Classification and Labelling of Chemicals HSDB: Hazardous Substances Data Bank IARC: International Agency for Research on Cancer IATA: International Air Transport Association ICAO: International Civil Aviation Organization IBC Code: International Code for the Construction and equipment of Ships Carrying Dangerous Chemicals in Bulk IUCLID DB: International Uniform Chemical Information Database TI: Technical Instructions for the Safe Transport of Dangerous Goods by Air :

16.3

Key literature references and sources of data

ECHA (European Chemicals Agency) http://echa.europa.eu/ ESIS (Existing chemical Substances Information System) http://ecb.jrc.ec.europa.eu/esis/. GESTIS International Limit values Database http://www.dguv.de/ifa/en/gestis/limit_values/index.jsp Guidance for downstream users

http://guidance.echa.europa.eu/docs/guidance_document/du_en.pdf Guidance on information requirements and chemical safety assessment, Chapter R.12: Use descriptor system http://guidance.echa.europa.eu/docs/guidance_document/information_requirements_r12_en.pdf Guidance on the compilation of safe data sheets http://guidance.echa.europa.eu/docs/draft_documents/draft_guidance_on_safety_data_sheets_20100324.pdf TOXNET: Toxicology Data Network. http://toxnet.nlm.nih.gov Information from technical literature Internet research Suppliers (Material) Safety Data Sheets. DISCLAIMER This guide was compiled as a service to Safety Data Sheet writers everywhere. It neither reflects the views of others, nor does it endorse one link over the other. Internet links cited in this guide and views expressed in the various sections are mine alone. Information in this document is based on data gathered from many sites. No warranty is expressed regarding the accuracy of data obtained from various chemical, health, toxicological, and environmental databases. Responsibility for the accuracy and completeness of information contained herein rests with the users who must satisfy themselves that the data is appropriate for their needs. It is always a good practice to consult a sectional expert when writing sections of the Safety Data Sheet to clarify and simplify technical matters. END OF SAMPLE SAFETY DATA SHEET