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| | c
= +
|
+ c
\ .
Classic
cont ribut ion
( SRK)
Cont ribut ion from
hydrogen bonding
( associat ion and
solvat ion)
CPA-EoS is developed by CERE / DTU
7
Experimental set-up
A
B
Gas
supply
D
Water bath I Water bath II
F
C M C M C C
G
I
I
H
I
Dewpoint analyser
Karl
Fischer
Gas
clock
J
I
A: Gas regulator E: Coil I: Metering valve
B: Shutdown valve F: Thermo element J: Flow meter
C: Valve G: El. heated pressure regulator --- Heat tracing
D: Pressure transmitter H: Safety valve M: Moisturizer
C: Condenser
C
E
A
B
Gas
supply
D
Water bath I Water bath II
F
C M C M C C
GG
I
I
H
I
Dewpoint analyser
Karl
Fischer
Karl
Fischer
Gas
clock
Gas
clock
J
II
A: Gas regulator E: Coil I: Metering valve
B: Shutdown valve F: Thermo element J: Flow meter
C: Valve G: El. heated pressure regulator --- Heat tracing
D: Pressure transmitter H: Safety valve M: Moisturizer
C: Condenser
C
E
0
50
100
150
200
250
300
350
-20 -15 -10 -5 0 5 10 15 20
Temperature [C]
W
a
t
e
r
c
o
n
t
e
n
t
[
p
p
m
(
m
o
l
)
]
Measurement (Karl Fischer)
CPA-EoS hydrate
CPA-EoS water
CPA-EoS ice
8
Results
Comparison of experimental data for natural gas - water at 150 bar to stable and meta-
stable phases predicted with the CPA-EoS
T. Lkken et al, Conference paper IGRC Paris (2008)
Data for the equilibrium
water content in methane
and a natural is available in
the temperature range -20
to 20C and pressures up
to 150 bar
9 - Classification: Open
Knowledge of phase behaviour of natural gas an its
trace components is crucial for a safe and efficient
production.
CPA-EoS combined with thermodynamic models for
the ice and gas hydrate phases gives excellent results
for calculation of:
Equilibrium water content of natural gas
Water dew point temperature
Natural gas hydrate temperature
Ice precipitation temperature
Aqueous dew points
Summary
Classification: Internal 2011-08-04
Water content of high pressure natural gas
Kjersti O. Christensen
Researcher
kchr@statoil.com, +47 99 48 76 84
www.statoil.com
Thank you